Abstract

The bandgap of iron-doped ZnS has been reported by others to change significantly under the addition of a few atomic percent of iron, which would have significant implications for solar energy. Here, thin films of FexZn1-xS with x = 0 to 0.24 were made by co-deposition of Fe and ZnS using thermal evaporation. In contrast to results on nanoparticles and electrodeposited materials, all co-deposited films had optical properties consistent with a direct bandgap of ~3-3.5 eV. The absorption peak at 2.7 µm from substitutional Fe2+ in the ZnS films was well isolated up to concentrations of over 2% (~1021cm−3), despite the small crystallite size, suggesting the films may have applications as mid-infrared saturable absorbers. Increasing dopant concentration resulted in band edge softening. Density functional calculations are presented and are consistent with our observations of the Fe:ZnS films, demonstrating spin-polarized midgap states and additional states at the band edge.

© 2015 Optical Society of America

1. Introduction

Transition-metal doped zinc chalcogenides have been studied extensively for their luminescence properties [1]. Recently, they have been the subject of renewed interest, for production of low-cost, nontoxic solar cells [2], as possible dilute magnetic semiconductors [3,4], and as materials for mid-infrared laser sources [5,6] and saturable absorbers. FexZn1-xS thin films have also been suggested for use in photoconversion as absorbers, due to reported tunability of the band gap and favorable large absorption coefficients [7,8]. Several stable crystal forms exist in the FexZn1-xS system, with widely varying properties. Pyrite (FeS2) is a semiconductor with a bandgap of 0.95 eV while the bandgap of pure ZnS is 3.5-3.8eV depending on the crystal form and preparation method [9]. FeS is reported to be an antiferromagnetic semiconductor at room temperature [10], but samples may be iron deficient, leading to metallic conductivity [11]. Comparison of different synthesis routes for production of thin films for optical applications is thus important.

Various fabrication techniques, including electrochemical deposition [8], spin-coating of nanoparticles [12], pyrolytic spray deposition [13] metal organic chemical vapor deposition (MOCVD) [14,15], and physical vapor deposition methods such as MBE [16] have been used to make such films. Widely varying properties have been reported, possibly because of the challenges of maintaining phase and chemical purity. In particular, for FexZn1-xS thin films made by electrochemical deposition, reduction of the (assumed indirect) band gap from 3.1 eV to 0.6 eV was reported [8] when increasing x from 0.0 to 0.2. Other reports [7,13,14] also indicated a reduction of bandgap, for both indirect and direct gap models fitted to absorption data. However, Schottky diodes grown by MBE between Fe0.04Zn0.96S and Fe indicated that the doped material was an n-type semiconductor with an estimated direct bandgap of ~3.6eV [16], almost the same as the pure material. Our results support the observation of a nearly constant direct bandgap in the ZnS host under the addition of elemental Fe up to x = 0.16 for vacuum-deposited material. Density functional theory calculations are in good agreement with the observed properties of the films.

In addition to changes in the bandgap, isolated transition metal impurities typically introduce d-electron related absorption. For Fe in crystalline ZnS, there is a strong absorption band at 2.7µm [17,18], of interest for the development of mid-infrared lasers; thin films may allow the development of compact waveguide sources. The presence of a well-defined absorption peak in the infrared is clear evidence of substitutional placement of Fe in the ZnS lattice. The mid-gap states have also been proposed for demonstration of the principle of an intermediate band solar cell [19].

In this paper, we used physical vapor deposition (PVD) for the production of Fe-doped ZnS; both co-deposition from Fe and ZnS sources and co-deposition of FeS and ZnS were performed. The iron sulfide source was used to explore whether formation of FeS during synthesis might explain the inconsistency of previous results. Due to reports of an indirect band gap in Fe:ZnS, which would be associated with crystallographic changes, the structural as well as optical properties were investigated. We found that atomic Fe doping resulted in only a small reduction in a direct bandgap. Films made with the FeS source were absorptive and largely disordered, which supports the conjecture that earlier reports of a reduced bandgap may have been due to the formation of this and other compounds during synthesis. The Fe2+ absorption peak in our films at 2.7 µm is well-isolated, with a width and position similar to that of single crystal Fe:ZnS recently used to demonstrate a broadly tuneable mid-IR laser [20].

2. Experimental

Two deposition systems were used in the work described here, one ultrahigh vacuum (UHV) chamber with a base pressure of 4 x 10−9 Torr with turbomolecular and Ti sublimation pumps and a diffusion- pumped (DP), liquid nitrogen trapped system with a base pressure of 2x 10−6 Torr. Source materials used were Fe (99.98%) and FeS (99.9%) obtained from Sigma Aldrich, and ZnS (99.99%) obtained from Alfa Aesar. In the UHV system, Fe was e-beam evaporated and ZnS was evaporated from a Knudsen cell, whereas in the diffusion-pumped system, ZnS was evaporated from a Mo boat and the Fe and FeS were vaporized using an alumina-coated basket (R.D. Mathis). Substrates were single crystal (100) silicon, UV grade fused silica, IR quartz, CaF2 and c-plane sapphire. Substrates were sonicated in acetone and isopropanol, and blown dry with nitrogen before loading. Deposition rates for the Fe and FeS sources varied between 0.2 and 1 Å/sec, while ZnS was deposited between 4 and 12 Å/sec. All films were deposited onto room temperature substrates.

Films were characterized by X-ray diffraction (D8 Advance DaVinci from Bruker), and optical spectroscopy over the range 300nm - 4µm (OLIS 14, Bruker Tensor 27). Energy dispersive X-ray spectroscopy (EDS) in a Hitachi TM3000 was used to determine the atomic percentage of Fe in the films and Rutherford Backscattering Spectrometry (1.7 MeV tandem accelerator at Arizona State Univ.) was used to confirm these values. Concentration values given in the paper and shown in the figures are the atomic percentage of Fe in the films (i.e. 10% Fe corresponds to Fe0.2Zn0.8S), as all films were found to have a metal:sulfur ratio close to 1. Transmission electron micrographs and diffraction patterns were obtained using a JEOL JEM-ARM200F. Thicknesses were measured with a Tencor alphastep. Films deposited in the DP system were 160-250 nm thick, while those deposited in the UHV system were up to 3.5µm thick.

3. Results and discussion

Several reports on the formation of Fe-doped ZnS have used Tauc plot fits to an indirect gap model to determine the change in the bandgap upon the addition of iron. Because a crystal structure change would necessarily accompany the transformation from the direct bandgap of pure ZnS, detailed structural studies were undertaken using X-ray diffraction (Fig. 1) and transmission electron microscopy. The results indicate that only the explicit use of FeS starting material during growth of the films results in any significant alteration in the structure.

 figure: Fig. 1

Fig. 1 X-ray diffraction of sample films. From top –films from the diffusion pumped system with iron content 12% (from Fe), 0%(red) and 7.4% (FeS source), a pure FeS film and a 3.5µm thick film with 1.9% Fe deposited in UHV. The amorphous quartz substrate reflection appears at ~22°.

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3.1 Structure

X-ray diffraction and transmission electron microscopy were used to assess phase purity and determine grain size, for comparison with earlier nanoparticle-derived material properties. The full-width half maximum was 0.5-1° for the ZnS and Fe:ZnS film peaks independent of the film thickness or deposition system, implying grain sizes of 10-20 nm (determined using the Debye-Scherrer formula). The broad peak at low angles is from the substrate. The predominant film-related peak was at 28.7°, coincident with both the ZnS (111) cubic (sphaelerite) and (0002) hexagonal (wurtzite) reflections, with additional peaks evident around 47° and 56° that also index to both the hexagonal and cubic forms of ZnS. The small peak at approximately 25.8° in the 3.5 µm thick Fe:ZnS (UHV 1.9%) film is due to CuKβ radiation from the non-monochromatic X-ray source. For the films doped with high concentrations of Fe, there was a slight reduction in the lattice constant, consistent with the smaller ionic radius of Fe; e.g. for 12% Fe, the main peak shifted to 29° (~2% reduction). The mixed film made from pre-reacted FeS showed a double peak near 28.7°, suggesting phase separation, while the pure FeS film, which was 38nm thick (to permit optical studies), displayed weak peaks from the (0002) and (200) reflections that match those seen in MOCVD growth [14]. It is clear from the X-ray data that the origin of iron in a doped ZnS film is responsible for significant structural differences. Fe from an atomic source appears to incorporate substitutionally, while FeS as the source leads to a composite, rather than an iron-doped ZnS film.

TEM studies were performed on a 73 nm thick film with 6.5% Fe, co-deposited in the DP chamber from elemental Fe and ZnS directly onto a carbon coated TEM grid, with results shown in Fig. 2(a). The film was composed of ~10-20 nm crystalline grains, a value similar to that indicated by XRD results. Electron diffraction patterns from all areas of the film studied showed hexagonal symmetry associated with either the (111) sphaelerite or (002) wurtzite structure. While for pure ZnS films the lateral grain size typically increases to ~500 nm in a micron-thick film [21], SEM (not shown), XRD and TEM studies on our films indicate that the inclusion of even 0.2% transition metal ions in ZnS suppresses grain growth.

 figure: Fig. 2

Fig. 2 TEM bright-field micrographs and diffraction images for the a) Fe:ZnS and b) FeS:ZnS films deposited onto carbon grids. Insets are Fourier transforms of the selected regions of the images.

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TEM studies on a 20 nm thick DP film (3% Fe) deposited from FeS and ZnS showed evidence of crystallinity in only a few small regions (Fig. 2(b)), and the electron diffraction patterns had poorly resolved rings with only slight modulation in the intensity as a function of azimuth. Bright field images suggested possible phase separation in agreement with the X-ray diffraction results. Grain sizes in the film were on the order of 4-5 nm.

3.2 Optical properties

The optical response of the films made in the two vacuum systems was very similar, suggesting that contamination from background gases was not a significant problem in theDP chamber. Figure 3 shows the transmission of three films with a low concentration of Fe, made by different methods, measured relative to bare substrates of the type used for each film. The interference fringes are of different amplitudes because the two DP films were deposited on fused silica, while the UHV film was deposited on sapphire, and the higher substrate index reduces the contrast with the film. The closer spacing of the UHV interference fringes is due to the larger thickness of the film. The measured film thicknesses were 337 nm for the DP Fe + ZnS film, 230nm for the DP FeS + ZnS film and 2225 nm for the UHV Fe + ZnS film. The low concentration (2.1% Fe) UHV Fe + ZnS film has the sharpest cutoff and the (thinner) DP Fe + ZnS film shows similar transparency, with a cutoff at 335nm indicating a bandgap of approximately 3.7eV. The film deposited using FeS as a source has increased absorption through the entire visible range, but slightly increased short wavelength transmission, which is attributed to the non-uniform inclusion of iron into the structure and the presence of FeS. The inset shows the transmission for pure ZnS and pure FeS films for comparison. The higher transparency at short wavelengths for the DP deposited ZnS films is partly due to the smaller thickness, but in addition, the grain size in the UHV films increases with large thicknesses and may cause increased scatter.

 figure: Fig. 3

Fig. 3 Optical transmission of selected Fe-doped ZnS films. Inset shows pure ZnS and FeS films.

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Samples were analyzed using the Swanepoel [22,23] method to obtain n, k and α values for the materials as a function of energy, and selected films were also analyzed by ellipsometry. Figure 4(a) shows that there was good agreement between the methods and Fig. 4(b) shows a sample Tauc plot using the direct gap model. While the index of refraction remained close to that of pure ZnS, the imaginary part of the refractive index increased upon the addition ofiron, and band edge softening was observed. The most common treatment of such states is to fit the excess absorption to an Urbach model [24], with a dependence given by

 figure: Fig. 4

Fig. 4 a)Absorption coefficient for pure ZnS, 6.8% and 12% Fe films, analyzed by ellipsometry (dashed lines-E) and the Swanepoel method (solid lines-S) and b) Tauc plot for these samples, showing increased absorption and softening of the band edge with the addition of iron.

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α(E)=α0e(E/EU)

Where α0 and EU (the Urbach Energy) are fitting parameters and E is the photon energy. The Urbach energy characterizes the width of the exponential absorption edge. The derived EU values (Fig. 5(a)) increased upon the addition of iron to the films.

 figure: Fig. 5

Fig. 5 a) derived Urbach energy and b) band gap, Eg as a function of Fe concentration, as determined from (S) Swanepoel and (E) ellipsometry analysis.

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Tauc plots were made to determine the value of the direct bandgap as a function of Fe content and the results are shown in Fig. 5(b). The uncertainties shown in the values of the bangap, Eg, are due to residual curvature in the plots. Other groups [7,8,14] have presented results on similar materials using an indirect gap model, but experimental crystallographic observations and band structure calculations [25] support the existence of a direct bandgap atthe doping levels used in this study.

Low levels of transition metal doping in ZnS films results in only small changes in the visible optical properties, and in a fine-grained microstructure with reduced short-wavelength scatter. Up to 4% Fe, little change was seen in the values of k in the visible region. However, pronounced absorption was observed in the near infrared, where there is an absorption band at 0.46 eV (3700 cm−1,2.7 µm) attributed to Fe2+ [5]. Figure 6(a) shows the near infrared absorption coefficient due to the 5E to 5T2 transition, for a film with 2.1% Fe and a thickness of 3.5 µm. The strong, well-isolated peak suggests that similar films with lower doping levels may be useful as thin film saturable absorbers or possibly as laser gain media for the mid-infrared [6], depending on scattering and lifetime characteristics.

 figure: Fig. 6

Fig. 6 a) measured absorption in the mid-IR for a film with 2.1% Fe and b) density of states calculated for pure ZnS (dashed lines) and FeZn23S24 (solid lines), with green and blue for the two spin states. The energies in the pure ZnS plot are shifted by −1.8eV to allow comparison of the curve shapes. Ev and Ec indicate the valence and conduction band edges and EF denotes the position of the Fermi level for each material.

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4. Modeling

Density functional theory (DFT) calculations were undertaken to determine the density of states (DOS) for iron substituted for zinc in a crystalline ZnS lattice. While numerical values of the band gap obtained in such a calculation are often underestimates, valuable comparisons can be made between similar structures.

Spin unrestricted DFT calculations were performed using the Amsterdam Density Functional BAND-structure program (BAND 2013 [26]) on a 3x2x2 repetition of the primitive cubic structure (Zn24S24). A Zn atom was subsequently substituted with a Fe atomgiving a structure with the chemical composition FeZn23S24, corresponding to ~2% Fe. The structures were initially optimized using the Local Density Approximation (LDA) [27]. A second geometry optimization was then performed using the more accurate Perdew-Burke-Ernzerhof (PBE) [28] functional. A double-ζ basis set was used for all atoms. The 3d, 4s and 4p electrons of Zn and Fe were treated as valence electrons in the calculation as were the 3s and 3p electrons of S. The convergence criteria on all simulations were 1.36 x 10−2 eV for the energy and 2.7 x 10−2 eV/Å for the gradient.

Figure 6(b) shows the band structure calculated for pure ZnS and FeZn23S24. To make comparison of the curve shapes easier, the plot for the pure ZnS is shifted by 1.8eV. The positions of the valence band (Ev) and conduction band (Ec) edges are indicated for each of the materials, and the two spin states (denoted alpha and beta) are displayed by multiplying the beta density of states by −1.

The pure ZnS film has a calculated bandgap of 3eV, and the Fermi energy (EF) lies very close to the valence band edge. When iron is introduced, narrow d-orbital levels due to the Fe ions appear mid-gap, the Fermi energy shifts, and additional, spin polarized states appear near the valence band edge. We identify the valence band edge in Fe:ZnS as shown because the mid-gap states are localized and sparse. With EF near the lower level associated with the impurity, there is sufficient occupation so that transitions between different energy levels on a single ion can give rise to infrared absorption.

The additional (alpha) states at the valence band edge result in softening of the band edge, in agreement with experimental results, although both the density of states (based on the absorption changes), and the energy range (compared to the observed Urbach energy) are overestimated compared to experiment. The bandgap for the beta states is essentially unchanged from the undoped case.

The modeling is in agreement with the experimental observation of a slightly narrowed gap and ionic mid-gap levels, and supports the observation that the films retain approximately the same bandgap energy as crystalline ZnS. The location of the Fermi level, within the Fe intragap states for the doped material, suggests this as a candidate for demonstration of the intermediate band solar cell concept [29].

5. Conclusion

We find that for elemental Fe added to ZnS, the iron enters the lattice as Fe2+, and introduces additional states at the band edge. It does not change the structure or direct gap of the ZnS at concentrations below 8-10%. Films deposited from a mixture of FeS and ZnS showed very little crystallinity, and had an increased level of absorption, suggesting that the FeS and ZnS formed a near-amorphous composite material with absorption from a variety of Fe binding positions. Prior reports of a widely tunable indirect bandgap are likely due to phase impurity rather the inclusion of iron.

Fe2+ absorption with a FWHM of 0.2eV, comparable to that reported in single crystals by Mirov, et al. [5], was observed in the near infrared. This suggests that these films may find use as saturable absorbers or possibly as waveguide laser materials and that they warrant further study.

Acknowledgments

This work was supported by a NorTEM seed grant, NoTUR grant NN9291K and NFR contract 219686/O70

References and links

1. H. Hu and W. Zhang, “Synthesis and properties of transition metals and rare-earth metals doped ZnS nanoparticles,” Opt. Mater. 28(5), 536–550 (2006). [CrossRef]  

2. C. Tablero, “Correlation effects and electronic properties of Cr-substituted SZn with an intermediate band,” J. Chem. Phys. 123(11), 114709 (2005). [CrossRef]   [PubMed]  

3. P. C. Patel and P. C. Srivastava, “Fe doping in ZnS for realizing nanocrystalline-diluted magnetic semiconductor phase,” J. Mater. Sci. 49(17), 6012–6019 (2014). [CrossRef]  

4. J. Xie, “First-principles study on the magnetism in ZnS-based diluted magnetic semiconductors,” J. Magn. Magn. Mater. 322(19), L37–L41 (2010). [CrossRef]  

5. S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013). [CrossRef]  

6. V. Fedorov, D. Martyshkin, M. Mirov, I. S. Moskalev, S. Vasilyev, J. Peppers, S. B. Mirov, and V. P. Gapontsev, “Fe-doped II-VI Mid-Infrared Laser Materials for the 3 to 8 μm Region,” in CLEO:2013, OSA Technical Digest (online) (Optical Society of America, 2013), p. JM4K.2.

7. A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995). [CrossRef]  

8. A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995). [CrossRef]  

9. H. C. Ong and R. P. H. Chang, “Optical constants of wurtzite ZnS thin films determined by spectroscopic ellipsometry,” Appl. Phys. Lett. 79(22), 3612–3614 (2001). [CrossRef]  

10. J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976). [CrossRef]  

11. C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006). [CrossRef]  

12. S. S. H. Abdullah, “Optical effect of Fe doped wurtzite ZnS nanoparticles,” Proceedings of the 2nd WSEAS International Conference on Nanotechnology191–194 (2010).

13. S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008). [CrossRef]  

14. Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006). [CrossRef]  

15. F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).

16. B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007). [CrossRef]  

17. Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

18. K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982). [CrossRef]  

19. J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011). [CrossRef]  

20. M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015). [CrossRef]  

21. M. Nematollahi, X. Yang, L. M. Aas, Z. Ghadyani, M. Kildemo, U. J. Gibson, and T. W. Reenaas, “Molecular beam and pulsed laser deposition of ZnS:Cr for intermediate band solar cells,” Sol. Energ. Mat. Sol. Cells (to be published) (2015).

22. R. Swanepoel, “Determination of the thickness and optical-constants of amorphous-silicon,” J. Phys. E Sci. Instrum. 16(12), 1214–1222 (1983). [CrossRef]  

23. D. Minkov and R. Swanepoel, “Computerization of the optical characterization of a thin dielectric film,” Opt. Eng. 32(12), 3333–3337 (1993). [CrossRef]  

24. J. D. Dow and D. Redfield, “Toward a unified theory of Urbach’s rule and exponential absorption edges,” Phys. Rev. B 5(2), 594–610 (1972). [CrossRef]  

25. A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013). [CrossRef]  

26. E. J. Baerends and E. J. Baerends, “Precise density-functional method for periodic structures,” Phys. Rev. B Condens. Matter 44(15), 7888–7903 (1991). [CrossRef]   [PubMed]  

27. S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980). [CrossRef]  

28. J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996). [CrossRef]   [PubMed]  

29. Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015). [CrossRef]  

References

  • View by:

  1. H. Hu and W. Zhang, “Synthesis and properties of transition metals and rare-earth metals doped ZnS nanoparticles,” Opt. Mater. 28(5), 536–550 (2006).
    [Crossref]
  2. C. Tablero, “Correlation effects and electronic properties of Cr-substituted SZn with an intermediate band,” J. Chem. Phys. 123(11), 114709 (2005).
    [Crossref] [PubMed]
  3. P. C. Patel and P. C. Srivastava, “Fe doping in ZnS for realizing nanocrystalline-diluted magnetic semiconductor phase,” J. Mater. Sci. 49(17), 6012–6019 (2014).
    [Crossref]
  4. J. Xie, “First-principles study on the magnetism in ZnS-based diluted magnetic semiconductors,” J. Magn. Magn. Mater. 322(19), L37–L41 (2010).
    [Crossref]
  5. S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
    [Crossref]
  6. V. Fedorov, D. Martyshkin, M. Mirov, I. S. Moskalev, S. Vasilyev, J. Peppers, S. B. Mirov, and V. P. Gapontsev, “Fe-doped II-VI Mid-Infrared Laser Materials for the 3 to 8 μm Region,” in CLEO:2013, OSA Technical Digest (online) (Optical Society of America, 2013), p. JM4K.2.
  7. A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
    [Crossref]
  8. A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
    [Crossref]
  9. H. C. Ong and R. P. H. Chang, “Optical constants of wurtzite ZnS thin films determined by spectroscopic ellipsometry,” Appl. Phys. Lett. 79(22), 3612–3614 (2001).
    [Crossref]
  10. J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976).
    [Crossref]
  11. C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006).
    [Crossref]
  12. S. S. H. Abdullah, “Optical effect of Fe doped wurtzite ZnS nanoparticles,” Proceedings of the 2nd WSEAS International Conference on Nanotechnology191–194 (2010).
  13. S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008).
    [Crossref]
  14. Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
    [Crossref]
  15. F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).
  16. B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
    [Crossref]
  17. Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).
  18. K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982).
    [Crossref]
  19. J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
    [Crossref]
  20. M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
    [Crossref]
  21. M. Nematollahi, X. Yang, L. M. Aas, Z. Ghadyani, M. Kildemo, U. J. Gibson, and T. W. Reenaas, “Molecular beam and pulsed laser deposition of ZnS:Cr for intermediate band solar cells,” Sol. Energ. Mat. Sol. Cells (to be published) (2015).
  22. R. Swanepoel, “Determination of the thickness and optical-constants of amorphous-silicon,” J. Phys. E Sci. Instrum. 16(12), 1214–1222 (1983).
    [Crossref]
  23. D. Minkov and R. Swanepoel, “Computerization of the optical characterization of a thin dielectric film,” Opt. Eng. 32(12), 3333–3337 (1993).
    [Crossref]
  24. J. D. Dow and D. Redfield, “Toward a unified theory of Urbach’s rule and exponential absorption edges,” Phys. Rev. B 5(2), 594–610 (1972).
    [Crossref]
  25. A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
    [Crossref]
  26. E. J. Baerends and E. J. Baerends, “Precise density-functional method for periodic structures,” Phys. Rev. B Condens. Matter 44(15), 7888–7903 (1991).
    [Crossref] [PubMed]
  27. S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980).
    [Crossref]
  28. J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996).
    [Crossref] [PubMed]
  29. Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
    [Crossref]

2015 (2)

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

2014 (1)

P. C. Patel and P. C. Srivastava, “Fe doping in ZnS for realizing nanocrystalline-diluted magnetic semiconductor phase,” J. Mater. Sci. 49(17), 6012–6019 (2014).
[Crossref]

2013 (2)

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

2012 (1)

Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

2011 (1)

J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
[Crossref]

2010 (2)

F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).

J. Xie, “First-principles study on the magnetism in ZnS-based diluted magnetic semiconductors,” J. Magn. Magn. Mater. 322(19), L37–L41 (2010).
[Crossref]

2008 (1)

S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008).
[Crossref]

2007 (1)

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

2006 (3)

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006).
[Crossref]

H. Hu and W. Zhang, “Synthesis and properties of transition metals and rare-earth metals doped ZnS nanoparticles,” Opt. Mater. 28(5), 536–550 (2006).
[Crossref]

2005 (1)

C. Tablero, “Correlation effects and electronic properties of Cr-substituted SZn with an intermediate band,” J. Chem. Phys. 123(11), 114709 (2005).
[Crossref] [PubMed]

2001 (1)

H. C. Ong and R. P. H. Chang, “Optical constants of wurtzite ZnS thin films determined by spectroscopic ellipsometry,” Appl. Phys. Lett. 79(22), 3612–3614 (2001).
[Crossref]

1996 (1)

J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996).
[Crossref] [PubMed]

1995 (2)

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
[Crossref]

1993 (1)

D. Minkov and R. Swanepoel, “Computerization of the optical characterization of a thin dielectric film,” Opt. Eng. 32(12), 3333–3337 (1993).
[Crossref]

1991 (1)

E. J. Baerends and E. J. Baerends, “Precise density-functional method for periodic structures,” Phys. Rev. B Condens. Matter 44(15), 7888–7903 (1991).
[Crossref] [PubMed]

1983 (1)

R. Swanepoel, “Determination of the thickness and optical-constants of amorphous-silicon,” J. Phys. E Sci. Instrum. 16(12), 1214–1222 (1983).
[Crossref]

1982 (1)

K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982).
[Crossref]

1980 (1)

S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980).
[Crossref]

1976 (1)

J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976).
[Crossref]

1972 (1)

J. D. Dow and D. Redfield, “Toward a unified theory of Urbach’s rule and exponential absorption edges,” Phys. Rev. B 5(2), 594–610 (1972).
[Crossref]

Abbad, A.

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

Ahsan, N.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Antonucci, V.

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
[Crossref]

Arico, A.

A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
[Crossref]

Aricò, A. S.

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

Arthur, G. S.

K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982).
[Crossref]

Baerends, E. J.

E. J. Baerends and E. J. Baerends, “Precise density-functional method for periodic structures,” Phys. Rev. B Condens. Matter 44(15), 7888–7903 (1991).
[Crossref] [PubMed]

E. J. Baerends and E. J. Baerends, “Precise density-functional method for periodic structures,” Phys. Rev. B Condens. Matter 44(15), 7888–7903 (1991).
[Crossref] [PubMed]

Benstaali, W.

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

Bentata, S.

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

Bentounes, H. A.

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

Bhosale, C. H.

S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008).
[Crossref]

Bouadjemi, B.

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

Burke, K.

J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996).
[Crossref] [PubMed]

Cao, J. X.

J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
[Crossref]

Chang, R. P. H.

H. C. Ong and R. P. H. Chang, “Optical constants of wurtzite ZnS thin films determined by spectroscopic ellipsometry,” Appl. Phys. Lett. 79(22), 3612–3614 (2001).
[Crossref]

Crea, F.

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

Deulkar, S. H.

S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008).
[Crossref]

Ding, J. W.

J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
[Crossref]

Dong, S.

F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).

Dow, J. D.

J. D. Dow and D. Redfield, “Toward a unified theory of Urbach’s rule and exponential absorption edges,” Phys. Rev. B 5(2), 594–610 (1972).
[Crossref]

Edwards, D. A.

K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982).
[Crossref]

Ekins-Daukes, N. J.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Ernzerhof, M.

J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996).
[Crossref] [PubMed]

Fan, X. W.

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Farrell, D. J.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Fedorov, V.

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

Feng, Q. J.

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Frolov, M. P.

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Ge, W. K.

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

Giordano, N.

A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
[Crossref]

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

Guillemoles, J.-F.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Hess, O.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Horwood, J. L.

J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976).
[Crossref]

Hu, H.

H. Hu and W. Zhang, “Synthesis and properties of transition metals and rare-earth metals doped ZnS nanoparticles,” Opt. Mater. 28(5), 536–550 (2006).
[Crossref]

Kashyout, A.

A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
[Crossref]

Kashyout, A. B.

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

Kita, T.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Korostelin, Y. V.

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Kozlovsky, V. I.

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Lewis, K. L.

K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982).
[Crossref]

Li, B. K.

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

Liu, Y. C.

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Lu, Y. M.

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Martyshkin, D.

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

Minkov, D.

D. Minkov and R. Swanepoel, “Computerization of the optical characterization of a thin dielectric film,” Opt. Eng. 32(12), 3333–3337 (1993).
[Crossref]

Mirov, M.

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

Mirov, S.

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

Monforte, G.

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

Moskalev, I.

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

Nitsuk, Y. A.

Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

Nusair, M.

S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980).
[Crossref]

Okada, Y.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Ong, H. C.

H. C. Ong and R. P. H. Chang, “Optical constants of wurtzite ZnS thin films determined by spectroscopic ellipsometry,” Appl. Phys. Lett. 79(22), 3612–3614 (2001).
[Crossref]

Patel, P. C.

P. C. Patel and P. C. Srivastava, “Fe doping in ZnS for realizing nanocrystalline-diluted magnetic semiconductor phase,” J. Mater. Sci. 49(17), 6012–6019 (2014).
[Crossref]

Pattrick, R. A. D.

C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006).
[Crossref]

Pearce, C. I.

C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006).
[Crossref]

Perdew, J. P.

J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996).
[Crossref] [PubMed]

Phillips, C. C.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Podmar’kov, Y. P.

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Purtov, Y. N.

Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

Pusch, A.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Redfield, D.

J. D. Dow and D. Redfield, “Toward a unified theory of Urbach’s rule and exponential absorption edges,” Phys. Rev. B 5(2), 594–610 (1972).
[Crossref]

Savinova, S. A.

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Sharon, M.

S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008).
[Crossref]

Shen, D. Z.

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Shoji, Y.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Skasyrsky, Y. K.

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Sogabe, T.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Sou, I. K.

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

Srivastava, P. C.

P. C. Patel and P. C. Srivastava, “Fe doping in ZnS for realizing nanocrystalline-diluted magnetic semiconductor phase,” J. Mater. Sci. 49(17), 6012–6019 (2014).
[Crossref]

Swanepoel, R.

D. Minkov and R. Swanepoel, “Computerization of the optical characterization of a thin dielectric film,” Opt. Eng. 32(12), 3333–3337 (1993).
[Crossref]

R. Swanepoel, “Determination of the thickness and optical-constants of amorphous-silicon,” J. Phys. E Sci. Instrum. 16(12), 1214–1222 (1983).
[Crossref]

Tablero, C.

C. Tablero, “Correlation effects and electronic properties of Cr-substituted SZn with an intermediate band,” J. Chem. Phys. 123(11), 114709 (2005).
[Crossref] [PubMed]

Tamaki, R.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Townsend, M. G.

J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976).
[Crossref]

Vaksman, Y. A.

Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

Vaughan, D. J.

C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006).
[Crossref]

Vosko, S.

S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980).
[Crossref]

Wang, C.

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

Wang, J. N.

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

Webster, A. H.

J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976).
[Crossref]

Wilk, L.

S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980).
[Crossref]

Xie, J.

J. Xie, “First-principles study on the magnetism in ZnS-based diluted magnetic semiconductors,” J. Magn. Magn. Mater. 322(19), L37–L41 (2010).
[Crossref]

Yang, G.

F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).

Yatsun, V. V.

Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

Yoshida, K.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Yoshida, M.

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Zhang, J. H.

J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
[Crossref]

Zhang, J. Y.

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Zhang, W.

H. Hu and W. Zhang, “Synthesis and properties of transition metals and rare-earth metals doped ZnS nanoparticles,” Opt. Mater. 28(5), 536–550 (2006).
[Crossref]

Zhang, Y. L.

J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
[Crossref]

Zhu, F.

F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).

Appl. Phys. Lett. (2)

H. C. Ong and R. P. H. Chang, “Optical constants of wurtzite ZnS thin films determined by spectroscopic ellipsometry,” Appl. Phys. Lett. 79(22), 3612–3614 (2001).
[Crossref]

B. K. Li, C. Wang, I. K. Sou, W. K. Ge, and J. N. Wang, “Anomalous photocurrent observed in an Fe–ZnS:Fe Schottky diode,” Appl. Phys. Lett. 91(17), 172104 (2007).
[Crossref]

Appl. Phys. Rev. (1)

Y. Okada, N. J. Ekins-Daukes, T. Kita, R. Tamaki, M. Yoshida, A. Pusch, O. Hess, C. C. Phillips, D. J. Farrell, K. Yoshida, N. Ahsan, Y. Shoji, T. Sogabe, and J.-F. Guillemoles, “Intermediate band solar cells: Recent progress and future directions,” Appl. Phys. Rev. 2(2), 021302 (2015).
[Crossref]

Can. J. Phys. (1)

S. Vosko, L. Wilk, and M. Nusair, “Accurate spin-dependent electron liquid correlation energies for local spin-density calculations - a critical analysis,” Can. J. Phys. 58(8), 1200–1211 (1980).
[Crossref]

Funct. Mater. (1)

Y. A. Nitsuk, Y. A. Vaksman, V. V. Yatsun, and Y. N. Purtov, “Optical absorption and diffusion of iron in ZnS single crystals,” Funct. Mater. 19, 182–186 (2012).

J. Chem. Phys. (1)

C. Tablero, “Correlation effects and electronic properties of Cr-substituted SZn with an intermediate band,” J. Chem. Phys. 123(11), 114709 (2005).
[Crossref] [PubMed]

J. Cryst. Growth (1)

K. L. Lewis, G. S. Arthur, and D. A. Edwards, “The incorporation of iron impurities in cubic ZnS,” J. Cryst. Growth 59(1-2), 201–209 (1982).
[Crossref]

J. Lumin. (1)

S. Mirov, V. Fedorov, I. Moskalev, M. Mirov, and D. Martyshkin, “Frontiers of mid-infrared lasers based on transition metal doped II–VI semiconductors,” J. Lumin. 133, 268–275 (2013).
[Crossref]

J. Magn. Magn. Mater. (1)

J. Xie, “First-principles study on the magnetism in ZnS-based diluted magnetic semiconductors,” J. Magn. Magn. Mater. 322(19), L37–L41 (2010).
[Crossref]

J. Mater. Sci. (1)

P. C. Patel and P. C. Srivastava, “Fe doping in ZnS for realizing nanocrystalline-diluted magnetic semiconductor phase,” J. Mater. Sci. 49(17), 6012–6019 (2014).
[Crossref]

J. Phys. E Sci. Instrum. (1)

R. Swanepoel, “Determination of the thickness and optical-constants of amorphous-silicon,” J. Phys. E Sci. Instrum. 16(12), 1214–1222 (1983).
[Crossref]

J. Solid State Chem. (2)

J. H. Zhang, J. W. Ding, J. X. Cao, and Y. L. Zhang, “Infrared, visible and ultraviolet absorptions of transition metal doped ZnS crystals with spin-polarized bands,” J. Solid State Chem. 184(3), 477–480 (2011).
[Crossref]

J. L. Horwood, M. G. Townsend, and A. H. Webster, “Magnetic susceptibility of single-crystal Fe1−xS,” J. Solid State Chem. 17(1-2), 35–42 (1976).
[Crossref]

Laser Phys. Lett. (1)

M. P. Frolov, Y. V. Korostelin, V. I. Kozlovsky, Y. P. Podmar’kov, S. A. Savinova, and Y. K. Skasyrsky, “3 J pulsed Fe:ZnS laser tunable from 3.44 to 4.19 μm,” Laser Phys. Lett. 12(5), 055001 (2015).
[Crossref]

Mater. Chem. Phys. (3)

A. Kashyout, A. Arico, N. Giordano, and V. Antonucci, “Influence of Annealing Temperature on the Crystallographic and Optical-Properties of Electrodeposited Znfes Thin-Film Semiconductors,” Mater. Chem. Phys. 41(1), 55–60 (1995).
[Crossref]

S. H. Deulkar, C. H. Bhosale, and M. Sharon, “Optical studies on non-stiochiometric (Zn, Fe)S chalcogenide bulk pellets prepared by coprecipitation,” Mater. Chem. Phys. 111(2-3), 260–264 (2008).
[Crossref]

Q. J. Feng, D. Z. Shen, J. Y. Zhang, Y. M. Lu, Y. C. Liu, and X. W. Fan, “Influence of Fe content on the structural and optical properties of ZnFeS thin films,” Mater. Chem. Phys. 96(1), 158–162 (2006).
[Crossref]

Mater. Sci. Semicond. Process. (1)

A. Abbad, S. Bentata, H. A. Bentounes, W. Benstaali, and B. Bouadjemi, “Study of electronic and magnetic properties of binary zinc sulfide and ternary manganese- and iron-substituted alloys,” Mater. Sci. Semicond. Process. 16(3), 576–581 (2013).
[Crossref]

Opt. Eng. (1)

D. Minkov and R. Swanepoel, “Computerization of the optical characterization of a thin dielectric film,” Opt. Eng. 32(12), 3333–3337 (1993).
[Crossref]

Opt. Mater. (1)

H. Hu and W. Zhang, “Synthesis and properties of transition metals and rare-earth metals doped ZnS nanoparticles,” Opt. Mater. 28(5), 536–550 (2006).
[Crossref]

Optoelectron. Adv. Mater.-, Rapid Commun. (1)

F. Zhu, S. Dong, and G. Yang, “Ferromagnetic properties in Fe-doped ZnS thin films,” Optoelectron. Adv. Mater.-, Rapid Commun. 4, 2072–2075 (2010).

Phys. Rev. B (1)

J. D. Dow and D. Redfield, “Toward a unified theory of Urbach’s rule and exponential absorption edges,” Phys. Rev. B 5(2), 594–610 (1972).
[Crossref]

Phys. Rev. B Condens. Matter (1)

E. J. Baerends and E. J. Baerends, “Precise density-functional method for periodic structures,” Phys. Rev. B Condens. Matter 44(15), 7888–7903 (1991).
[Crossref] [PubMed]

Phys. Rev. Lett. (1)

J. P. Perdew, K. Burke, and M. Ernzerhof, “Generalized gradient approximation made simple,” Phys. Rev. Lett. 77(18), 3865–3868 (1996).
[Crossref] [PubMed]

Rev. Mineral. Geochem. (1)

C. I. Pearce, R. A. D. Pattrick, and D. J. Vaughan, “Electrical and magnetic properties of sulfides,” Rev. Mineral. Geochem. 61(1), 127–180 (2006).
[Crossref]

Sol. Energy Mater. Sol. Cells (1)

A. B. Kashyout, A. S. Aricò, G. Monforte, F. Crea, V. Antonucci, and N. Giordano, “Electrochemical deposition of ZnFeS thin film semiconductors on tin oxide substrates,” Sol. Energy Mater. Sol. Cells 37(1), 43–53 (1995).
[Crossref]

Other (3)

V. Fedorov, D. Martyshkin, M. Mirov, I. S. Moskalev, S. Vasilyev, J. Peppers, S. B. Mirov, and V. P. Gapontsev, “Fe-doped II-VI Mid-Infrared Laser Materials for the 3 to 8 μm Region,” in CLEO:2013, OSA Technical Digest (online) (Optical Society of America, 2013), p. JM4K.2.

S. S. H. Abdullah, “Optical effect of Fe doped wurtzite ZnS nanoparticles,” Proceedings of the 2nd WSEAS International Conference on Nanotechnology191–194 (2010).

M. Nematollahi, X. Yang, L. M. Aas, Z. Ghadyani, M. Kildemo, U. J. Gibson, and T. W. Reenaas, “Molecular beam and pulsed laser deposition of ZnS:Cr for intermediate band solar cells,” Sol. Energ. Mat. Sol. Cells (to be published) (2015).

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Figures (6)

Fig. 1
Fig. 1 X-ray diffraction of sample films. From top –films from the diffusion pumped system with iron content 12% (from Fe), 0%(red) and 7.4% (FeS source), a pure FeS film and a 3.5µm thick film with 1.9% Fe deposited in UHV. The amorphous quartz substrate reflection appears at ~22°.
Fig. 2
Fig. 2 TEM bright-field micrographs and diffraction images for the a) Fe:ZnS and b) FeS:ZnS films deposited onto carbon grids. Insets are Fourier transforms of the selected regions of the images.
Fig. 3
Fig. 3 Optical transmission of selected Fe-doped ZnS films. Inset shows pure ZnS and FeS films.
Fig. 4
Fig. 4 a)Absorption coefficient for pure ZnS, 6.8% and 12% Fe films, analyzed by ellipsometry (dashed lines-E) and the Swanepoel method (solid lines-S) and b) Tauc plot for these samples, showing increased absorption and softening of the band edge with the addition of iron.
Fig. 5
Fig. 5 a) derived Urbach energy and b) band gap, Eg as a function of Fe concentration, as determined from (S) Swanepoel and (E) ellipsometry analysis.
Fig. 6
Fig. 6 a) measured absorption in the mid-IR for a film with 2.1% Fe and b) density of states calculated for pure ZnS (dashed lines) and FeZn23S24 (solid lines), with green and blue for the two spin states. The energies in the pure ZnS plot are shifted by −1.8eV to allow comparison of the curve shapes. Ev and Ec indicate the valence and conduction band edges and EF denotes the position of the Fermi level for each material.

Equations (1)

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α ( E ) = α 0 e ( E / E U )

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