Abstract

Single crystalline titanium dioxide thin film in the rutile phase (r-TiO2) is exfoliated from bulk material using a He+-implantation method, and is bonded onto SiO2 substrate to form a heterostructure using Cu-Sn bonding technology. The exfoliated r-TiO2 thin film was examined to be in good quality, and the exfoliation mechanism of ion-implanted r-TiO2 was analyzed. The obtained r-TiO2 thin film heterostructure with high refractive index contrast has a potential application in the fabrication of high-Q optical microcavities in visible wavelengths, which is useful in integrated photonic devices.

© 2021 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

1. Introduction

Titanium dioxide (TiO2) is of much interest to many fields due to its unique properties, especially its degradation of H2O to H2 and O2, as well as its UV-absorption ability, that are widely used in photocatalysis and cosmetics [1,2]. As a wide bandgap semiconductor, TiO2 is also useful to transparent optoelectronic devices owing to its excellent optical properties [35], including moderately high refractive index, large bandgap of 3.1∼3.2 eV, low thermal expansion coefficient, negative thermo-optic coefficient [6,7], large Kerr nonlinearity [8,9], etc. In particular, because of its moderately high refractive index and light absorption below 390 nm wavelength, TiO2 has been added to the family of materials suitable for optical microcavities, such as whispering-gallery-mode resonators (WGMRs) and photonic crystals for control and manipulation of visible light [10]. Therefore, TiO2 thin films can be applied in visible photonics, optical sensing, photovoltaics, etc. Among its three (anatase, rutile and brookite) phases, TiO2 in rutile phase has the largest refractive index, (>2 for the amorphous phase, >2.5 for the anatase phase, and >2.7 for the rutile phase), as well as greater thermal stability, so that optical microcavities based on rutile TiO2 (r-TiO2) thin film can achieve higher-Q value in visible wavelengths.

Most TiO2 thin films are fabricated using epitaxial growth methods, such as sputtering, electron beam evaporation, sol-gel, etc, but the resulting TiO2 thin films are mostly polycrystalline or nanoparticle composites, rather than single-crystalline [1113]. Although r-TiO2 thin films homostructure can be formed by metal-organic chemical vapor deposition (MOCVD) [14,15], r-TiO2 thin film heterostructure still has not been realized. Considering the importance of r-TiO2 thin film heterostructure with high refractive index contrast in making high-performance photonic devices that depend on optical microcavities with high-Q, fabrication of single-crystalline r-TiO2 thin film heterostructure is of urgent interest.

Ion implantation as a promising technology has many useful applications [1621]. In particular, thin film fabrication using ion-implantation assisted with wafer bonding, well-known as “smart-cut” [22,23], should be valuable for integrated optoelectronics. The principle of this method is: light ions such as H+ and He+ with fluences of 1016-1017 ions/cm2 implanted into a crystal generate a large concentration of dislocations and defects at the end of ion range, which trap H+/He+ into the bubbles/cracks [2426]. Subsequent wafer bonding and annealing treatments can promote the He bubbles to aggregate into large cavities. As a result, the implantation area above the damage layer can be exfoliated from the bulk as a thin film [2730]. This layer splitting method can be used to fabricate single-crystalline r-TiO2 thin films. Ion-implantation characteristized by controllability and reproducibility has unique advantage in controlling the thickness of the exfoliated r-TiO2 films.

Wafer bonding is the key step in the fabrication of uniform sub-micrometer r-TiO2 thin film. A controlled split-off or exfoliation is possible only after proper bonding of the implanted sample onto a supporting substrate. Traditional direct bonding method that has been successfully applied to fabrication of LiNbO3 on insulator (LNOI) structure, has rigid requirements on the flatness and smoothness of both the donor and substrate wafer surfaces [31,32]. However, the surface roughness of ion-implanted r-TiO2 sample cannot satisfy these requirements. Since the thermal treatment at elevated temperature (>400°C) is required for the exfoliation of the implanted r-TiO2 samples, the glass transition temperature (about 350°C) of the BCB resin as well as the difference in the thermal expansion coefficient between the bonded materials prohibits the indirect bonding method using BCB resin. Thus, both direct bonding and BCB bonding cannot be used for fabricating r-TiO2 thin film heterostructure. Cu/Sn solid-liquid interdiffusion (SLID) wafer-level bonding is an attractive technique for encapsulation and interconnection of micro-electro-mechanical systems (MEMS) due to its low cost, high temperature stability, high bond strength, and hermeticity [33,34]. The Sn layer melts and the intermetallic compounds (IMCs) solidify isothermally at bonding temperatures ranging from 250 to 300°C. The overall goal of the Cu-Sn bonding process is to achieve a Cu-Cu3Sn-Cu final bonding layer that is thermodynamically stable (melting temperature higher than 676°C) [35]. Therefore, Cu-Sn bonding technology is suitable for r-TiO2 thin film exfoliation.

In this paper, low energy He+ ions with high ion fluence were implanted into rutile TiO2 single crystal and aggregated at the end of the ion range (approximate 680 nm), in combination with Cu-Sn bonding and annealing, a heterostructure of single-crystalline r-TiO2 thin film onto SiO2 substrate can be formed. Scanning electron microscopy (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD) and atomic force microscopy (AFM) were used to examine the properties of exfoliated r-TiO2 thin film. Rutherford backscattering spectroscopy/channeling (RBS/channeling) and transmission electron microscopy (TEM) were applied to analyze the exfoliation mechanism of the ion-implanted r-TiO2.

2. Materials and methods

2.1 Fabrication of the r-TiO2 thin film heterostructure

200 keV He+ ions with ion fluence of 8×1016 ions/cm2 were implanted into rutile TiO2 single crystals along the [001] axis at liquid nitrogen conditions to inhibit dynamic thermal effect during ion-implantation process. Before the implantation, the sample with size of 5mm×5mm×0.5 mm was optically polished and cleaned. During the implantation, the ion beams were electrically scanned to ensure a uniform implantation over the sample, and the sample was tilted by 7o off the beam direction in order to minimize the channeling effect. The implantation process was performed at an LC-4 Ion Implanter at the Institute of Semiconductors of the Chinese Academy of Sciences.

After the implantation, the implanted sample was cleaned using the standard RCA recipe. Atomic force microscopy (AFM) and optical microscope were used to check the intactness of the sample surface, showing that the surface roughness before and after implantation is almost the same, lower than 0.5 nm. After the cleaning process film coating was implemented. A 2μm SiO2 thin film was deposited on the implanted sample surface using plasma-enhanced chemical vapor deposition (PECVD) to form a heterostructure with high refractive index contrast. Then the surfaces of both the deposited SiO2 and a 10mm×10mm×0.5 mm virgin r-TiO2 single crystal acting as a receptor were successively covered by 100 nm chromium (Cr) and 5μm Cu with magnetron sputtering, and 1.5μm Sn layers with thermal evaporation. Considering the thermal expansion coefficients matching, it is better to use the same donor and receptor sample for Cu-Sn bonding. The thickness of Cr, Cu and Sn were chosen according to the simulation model established in Ref. [35] that predict the intermetallic compounds development during the bonding process, and Cr layer was used as an adhesive to attach the r-TiO2-SiO2 heterostructure with Cu-Sn bonding layer strongly [33]. The coating processes were conducted at low temperature without imposing influence on the damage region in the He+-implanted r-TiO2 samples. After the coatings, the coated surface of both the donor and receptor r-TiO2 samples were brought into contact and pressed together at 150°C, and Cu-Sn bonding strongly was completed after annealing at an elevated temperature of 270°C for 20 minutes. R-TiO2 thin film was exfoliated from the bulk material after annealing at 400°C for 10 hours. The receptor r-TiO2 bulk can act as a substrate to facilitate the r-TiO2 thin film exfoliation as well as preserve the intactness of the TiO2 thin film. This thin film fabrication process is illustrated in Fig. 1.

 figure: Fig. 1.

Fig. 1. Schematic presentation of r-TiO2 thin film heterostructure fabrication using ion-implantation together with Cu-Sn bonding: (a) 200 keV He+-implantation into r-TiO2 donor wafer at ion fluence of 8×1016 ions/cm2. (b) Film coating on both the r-TiO2 donor and receptor wafer. (c) Cu-Sn bonding of the coated donor and receptor wafers together. (d) r-TiO2 thin film exfoliation from bulk after annealing.

Download Full Size | PPT Slide | PDF

2.2 Characterization of the r-TiO2 thin film

The lattice damage induced by the ion-implantation was analyzed using Rutherford backscattering spectroscopy/channeling (RBS/channeling) measurement, which was performed by 2 MeV He2+ ions at a scattering angle of 165o in the 1.7 MV tandem accelerator at Peking University. The sample was mounted on a three-axis high precision goniometer in a vacuum chamber, which can be carefully angle oriented to minimize backscatter for the channeling measurements. The backscattering counts (yield) were recorded as a function of the channel (energy) of the different target atoms. Stopping and Range of Ion Matter (SRIM 2008) was used to simulate the distribution of implanted He+-ions in r-TiO2. The inner lattice structural properties in cross-section, especially in the damage layer, were observed with transmission electron microscopy (TEM) using the Tecnai G2 F20 S-Twin at 200 kV with a field emission gun. The TEM samples were prepared using Focused Ion Beam (FIB) technique. The surface morphology of the exfoliated TiO2 thin film was investigated using optical microscopy (OM) and atomic force microscopy (AFM) methods. AFM was performed under ambient conditions on a Bruker Multi-mode VIII microscope, operating in tapping mode at a cantilever frequency of 250 ± 10 kHz. Scanning electron microscopy (SEM) and Energy Dispersive X-ray Spectroscopy (EDS) were used to examine the properties of the fabricated r-TiO2 thin film heterostructure. The crystal structure of the r-TiO2 thin film was investigated by XRD (Empyrean) using CuK-α radiation working in the θ-2θ mode.

3. Results and discussion

Different implantation parameters, including ion fluences, energy, temperature, flux, can induce different lattice damages, and for good layer splitting there exist critical values of the ion fluence and annealing temperature. A wide range of implantation parameters were applied to the r-TiO2 samples. Bubbles and craters were found on the surface of the samples implanted with 200 keV He+ ions at fluences larger than 7×1016 ions/cm2 after annealing at temperature of 550°C for 1 hour [21]. With increase of the annealing temperature and time, the number of bubbles and craters increases. High annealing temperature can also cause breakage of the Cu-Sn bonding. We found that the critical annealing temperature for layer splitting decreases with increasing ion fluence, and to realize wafer exfoliation, 200 keV He+ ions with 8×1016 ions/cm2 fluence at liquid nitrogen temperature should be used for the implant. This phenomenon can be attributed to the high concentration of defects created by He+-implantation. It is well known that implanted ions lose their energy through nuclear interactions with the lattice atoms at the end of the ion range, which can generate vacancy-interstitial pairs. Ions with higher fluences can generate more vacancies, and the liquid nitrogen environment can inhibit the dynamic thermal effects during the implantation that can promote the out-diffusion of implanted ions. Therefore, with low-temperature thermal treatment, high density of vacancies is more likely to trap the implanted He+-ions into bubbles. However, He+-ions with higher ion fluences may also induce damage in the exfoliated r-TiO2 thin film, which would weaken its single-crystalline properties. Thus, 8×1016 ions/cm2 fluence at liquid nitrogen temperature is appropriate implantation parameters to fabricate r-TiO2 thin film in good quality. The implantation parameters mentioned in this paper are examined to be suitable for r-TiO2 thin film exfoliation. Figure 2 shows nothing happened on the ion-implanted r-TiO2 sample surface before thermal treatments, but the bubbles and craters appearing on the implanted-sample surface after annealing at only 400°C for 1 hour, and the number of craters increases with increase of the annealing time.

 figure: Fig. 2.

Fig. 2. Surface morphology of ion-implanted r-TiO2 sample before (a) and after annealing at 400°C for 1 hour (b) and 5 hours (c).

Download Full Size | PPT Slide | PDF

Following the fabrication process shown in Fig. 1, the implanted sample was attached to the substrate to form the heterostructure through Cu-Sn bonding, and r-TiO2 thin film with thickness of 680 nm was exfoliated from bulk after annealing at 400°C for 10 hours. The cross-section of the fabricated r-TiO2 thin film heterostructure detected by SEM is shown in Fig. 3. We see that it is composed of the exfoliated r-TiO2 thin film, the deposited SiO2 layer, the Cr layer, and the Cu-Sn compound. The thickness of the exfoliated r-TiO2 thin film shown in Fig. 3 is in consistent with the ion range simulated with SRIM2008, which confirms that the aggregation of implanted He+-ions contributes to thin film exfoliation. EDS was used to identify the compositions of the heterostructure, as shown in Fig. 4, which clearly shows the staggered layers in the r-TiO2 thin film heterostructure. The surface roughness inherently induced by the straggling of the implanted ions was smoothed using Ar+-ion etching. Finally, high quality single-crystalline r-TiO2 thin film heterostructure was fabricated. Rocking curve, θ-2θ measurements with Cu Kα x rays were used to analyze the lattice properties of the exfoliated thin film, as shown in Fig. 5. As the x rays probe depth is limited, excluding the r-TiO2 substrate, the detected diffraction peak at 2θ=62.75o corresponding to (002) crystal plane, demonstrates the good crystalline property of our exfoliated r-TiO2 thin film. The other two small peaks are attributed to SiO2 and Cu-Sn compound. As the x-rays probe range exclude the r-TiO2 substrate, so this (002) diffraction peak comes from r-TiO2 thin film.

 figure: Fig. 3.

Fig. 3. Cross-section images of the fabricated r-TiO2 thin film heterostructure detected by SEM.

Download Full Size | PPT Slide | PDF

 figure: Fig. 4.

Fig. 4. The component elements in each layer of r-TiO2 thin film heterostructure detected by EDS.

Download Full Size | PPT Slide | PDF

 figure: Fig. 5.

Fig. 5. XRD results of the exfoliated r-TiO2 thin film.

Download Full Size | PPT Slide | PDF

Since the ion range of the implanted He+-ions is within 1μm, RBS/Channeling technique can be used to investigate the lattice damage in the ion-implanted r-TiO2 sample. For demonstrating the lattice damage, the He+-ions backscattered from the target Ti and O atoms were collected. The backscattering yield of the ion-implanted r-TiO2 sample with ion fluence of 8×1016 ions/cm2, as well as the aligned and random spectra from a virgin r-TiO2 sample detected by RBS/Channeling are shown in Fig. 6(a). The same minimum yields of around 2% at the surface region of both virgin and as-implanted r-TiO2 samples indicate the good quality of our exfoliated r-TiO2 thin film. In contrast with the aligned spectra, there is a clear bulge in the backscattering spectra of the as-implanted r-TiO2 sample. It can be attributed to the disordered lattice induced by nuclear energy deposition during the ion-implantation. The damage profile, i.e., the relative number of displaced lattice atoms, was extracted from the RBS spectra by using a multiple-scattering dechanneling model based on Feldman’s procedure and applied for all target elements in the crystal [36,37]. The peak damage ratio of nearly 50% was detected at the depth of around 680 nm below the sample surface, which is consistent with the SRIM result shown in Fig. 6(b). This indicates that the density of defects (in the damage layer at the damage ratio of 50%) is high enough to trap the implanted He+-ions into bubbles or cracks, which facilitates layer splitting.

 figure: Fig. 6.

Fig. 6. RBS/Channeling spectra (a) and damage profile (b) of 200 keV He+-implanted r-TiO2 at ion fluence of 8×1016 ions/cm2. In (a), the aligned and random spectra from the virgin r-TiO2 are shown for comparison. The distribution of the implanted He+-ions as simulated by SRIM is shown in (b) by the solid red curve.

Download Full Size | PPT Slide | PDF

The number of displacements per atom (dpa) vs. the depth (z) can be calculated using the expression of dpa(z)=Ndispl(z)×N1/N0, where N1 is the ion fluence, Ndispl is the number of displacements per incident ion and unit length (taken from SRIM 2008), and N0 is the atomic density of r-TiO2. The calculated dpa peak is 1.65 for the ion-implanted r-TiO2 sample with ion fluence of 8×1016. This dpa number is for layer splitting in ion-implanted r-TiO2.

To better understand the nature of the inner-structure, TEM measurements were done for the He+-implanted r-TiO2 sample, and the results are presented in Fig. 7. All these TEM images are in cross-section geometry, and the sample surface is marked in the figure. The damage layer at depth of 680 nm below sample surface can be clearly seen in Fig. 7(a). We see that it is consistent with the thickness of exfoliated r-TiO2 thin film, as well as the RBS result. Figures 7(b) - (e) show that the damage layer has a high concentration of He nanobubbles as well as dislocations induced by nuclear displacement, and the thickness of damage layer is about 80 nm, consistent with the RBS result. Figure 7(b) is a high-resolution TEM micrograph of the damage layer. The wavy-strings oriented along energetically preferred planes are resulted from the aggregation of He+-ions. The enlarged image in Fig. 7(c) show that it consists of He bubbles. One can see in Fig. 7(d) that the lattice structures on both sides of the string are dislocated and somewhat tilted, suggesting that these bubble strings lay on twin boundaries. He bubbles of around 4 nm size are also detected in the damage region, as shown in Fig. 7(e). Figure 7(e) demonstrates that, consistent with RBS results, in spite of the severely disordered lattice structure in the damage layer, it is not fully amorphous and unbroken lattice structure can still be clearly seen. Figure 7(f) shows that the lattice structure near implanted sample surface corresponding to the exfoliated thin film region is in good single-crystalline, indicating that the exfoliated r-TiO2 thin film is almost perfect and can preserve good optical and physical properties.

 figure: Fig. 7.

Fig. 7. TEM images of the internal structure of the ion-implanted r-TiO2 sample.

Download Full Size | PPT Slide | PDF

4. Conclusion

Heterostructure composed of r-TiO2 thin film on SiO2 substrate with high refractive index contrast is fabricated by means of 200 keV He+-implantation at ion fluence of 8×1016 ions/cm2 together with Cu-Sn bonding. The exfoliated r-TiO2 thin film is investigated and shown to be in good quality, and the layer-splitting process induced by ion-implantation is investigated. The fabricated r-TiO2 thin film heterostructure here should be useful in many applications, such as fabrication of optical microcavities with high Q in visible wavelengths.

Funding

National Natural Science Foundation of China (11872198, 12005147, 61575129, 61905148, 61975094, U2030110 [NSAF]); Natural Science Foundation of Guangdong Province (2018A030310560); Guangdong Province for Science and Technology Innovative Young Talents (2018KQNCX398); Science and Technology Planning Project of Shenzhen Municipality (JCYJ2018030117948918, JCYJ20190808141011530, JCYJ20190813103201662, JCYJ20190813103207106); Post-doctoral research project of SZTU (20180305); State Key Laboratory of Nuclear Physics and Technology, Peking University (NPT2020KFJ16).

Disclosures

The authors declare no conflicts of interest.

References

1. V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015). [CrossRef]  

2. N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020). [CrossRef]  

3. G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010). [CrossRef]  

4. J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014). [CrossRef]  

5. X. Wang, M. Fujimaki, and K. Awazu, “Photonic crystal structures in titanium dioxide (TiO2) and their optimal design,” Opt. Express 13(5), 1486–1497 (2005). [CrossRef]  

6. B. Guha, J. Cardenas, and M. Lipson, “Athermal silicon microring resonators with titanium oxide cladding,” Opt. Express 21(22), 26557–26563 (2013). [CrossRef]  

7. S. S. Djordjevic, K. Shang, B. Guan, S. T. S. Cheung, L. Liao, J. Basak, H.-F. Liu, and S. J. B. Yoo, “CMOS-compatible, athermal silicon ring modulators clad with titanium dioxide,” Opt. Express 21(12), 13958–13968 (2013). [CrossRef]  

8. R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989). [CrossRef]  

9. H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009). [CrossRef]  

10. J. T. Choy, J. D. B. Bradley, P. B. Deotare, I. B. Burgess, C. C. Evans, E. Mazur, and M. Lončar, “Integrated TiO2 resonators for visible photonics,” Opt. Lett. 37(4), 539–541 (2012). [CrossRef]  

11. C. C. Evans, C. Liu, and J. Suntivich, “Low-loss titanium dioxide waveguides and resonators using a dielectric lift-off fabrication process,” Opt. Express 23(9), 11160–11169 (2015). [CrossRef]  

12. Qiang Zhang and Chaoyang Li, “Pure anatase phase titanium dioxide films prepared by mist chemical vapor deposition,” Nanomaterials 8(10), 827 (2018). [CrossRef]  

13. I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018). [CrossRef]  

14. W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018). [CrossRef]  

15. W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018). [CrossRef]  

16. Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013). [CrossRef]  

17. Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016). [CrossRef]  

18. Y.-J. Ma, F. Lu, X.-B. Ming, M. Chen, X.-H. Liu, and J.-J. Yin, “Analysis of Si-implanted Nd:YVO4 crystal: the relation between lattice damage and waveguide formation,” Appl. Opt. 51(23), 5657–5663 (2012). [CrossRef]  

19. Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013). [CrossRef]  

20. Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Fabrication of TiO2 thin films with both anatase and rutile structures together using the ion-implantation method,” Opt. Mater. Express 8(3), 532–540 (2018). [CrossRef]  

21. B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015). [CrossRef]  

22. M. Bruel, “Application of hydrogen ion beams to silicon on insulator material technology,” Nucl. Instrum. Methods Phys. Res., Sect. B 108(3), 313–319 (1996). [CrossRef]  

23. P. Rabiei and W. H. Steier, “Lithium niobate ridge waveguides and modulators fabricated using smart guide,” Appl. Phys. Lett. 86(16), 161115 (2005). [CrossRef]  

24. Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016). [CrossRef]  

25. Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015). [CrossRef]  

26. Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Twinning and defect formation mechanism in He+/H+-implanted KTiOPO4,” Opt. Mater. Express 7(9), 3204–3213 (2017). [CrossRef]  

27. T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002). [CrossRef]  

28. A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999). [CrossRef]  

29. P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006). [CrossRef]  

30. T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000). [CrossRef]  

31. P. Rabiei and P. Gunter, “Optical and electro-optical properties of submicrometer lithium niobate slab waveguides prepared by crystal ion slicing and wafer bonding,” Appl. Phys. Lett. 85(20), 4603–4605 (2004). [CrossRef]  

32. H. Hu, R. Ricken, and W. Sohler, “Lithium niobate photonic wires,” Opt. Express 17(26), 24261–24268 (2009). [CrossRef]  

33. B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014). [CrossRef]  

34. B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017). [CrossRef]  

35. T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013). [CrossRef]  

36. L. C. Feldman and J. M. Rodgers, “Depth profiles of the lattice disorder resulting from ion bombardment of silicon single crystals,” J. Appl. Phys. 41(9), 3776–3782 (1970). [CrossRef]  

37. K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990). [CrossRef]  

References

  • View by:
  • |
  • |
  • |

  1. V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
    [Crossref]
  2. N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
    [Crossref]
  3. G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
    [Crossref]
  4. J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
    [Crossref]
  5. X. Wang, M. Fujimaki, and K. Awazu, “Photonic crystal structures in titanium dioxide (TiO2) and their optimal design,” Opt. Express 13(5), 1486–1497 (2005).
    [Crossref]
  6. B. Guha, J. Cardenas, and M. Lipson, “Athermal silicon microring resonators with titanium oxide cladding,” Opt. Express 21(22), 26557–26563 (2013).
    [Crossref]
  7. S. S. Djordjevic, K. Shang, B. Guan, S. T. S. Cheung, L. Liao, J. Basak, H.-F. Liu, and S. J. B. Yoo, “CMOS-compatible, athermal silicon ring modulators clad with titanium dioxide,” Opt. Express 21(12), 13958–13968 (2013).
    [Crossref]
  8. R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989).
    [Crossref]
  9. H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
    [Crossref]
  10. J. T. Choy, J. D. B. Bradley, P. B. Deotare, I. B. Burgess, C. C. Evans, E. Mazur, and M. Lončar, “Integrated TiO2 resonators for visible photonics,” Opt. Lett. 37(4), 539–541 (2012).
    [Crossref]
  11. C. C. Evans, C. Liu, and J. Suntivich, “Low-loss titanium dioxide waveguides and resonators using a dielectric lift-off fabrication process,” Opt. Express 23(9), 11160–11169 (2015).
    [Crossref]
  12. Qiang Zhang and Chaoyang Li, “Pure anatase phase titanium dioxide films prepared by mist chemical vapor deposition,” Nanomaterials 8(10), 827 (2018).
    [Crossref]
  13. I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
    [Crossref]
  14. W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
    [Crossref]
  15. W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
    [Crossref]
  16. Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
    [Crossref]
  17. Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
    [Crossref]
  18. Y.-J. Ma, F. Lu, X.-B. Ming, M. Chen, X.-H. Liu, and J.-J. Yin, “Analysis of Si-implanted Nd:YVO4 crystal: the relation between lattice damage and waveguide formation,” Appl. Opt. 51(23), 5657–5663 (2012).
    [Crossref]
  19. Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
    [Crossref]
  20. Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Fabrication of TiO2 thin films with both anatase and rutile structures together using the ion-implantation method,” Opt. Mater. Express 8(3), 532–540 (2018).
    [Crossref]
  21. B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015).
    [Crossref]
  22. M. Bruel, “Application of hydrogen ion beams to silicon on insulator material technology,” Nucl. Instrum. Methods Phys. Res., Sect. B 108(3), 313–319 (1996).
    [Crossref]
  23. P. Rabiei and W. H. Steier, “Lithium niobate ridge waveguides and modulators fabricated using smart guide,” Appl. Phys. Lett. 86(16), 161115 (2005).
    [Crossref]
  24. Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
    [Crossref]
  25. Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
    [Crossref]
  26. Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Twinning and defect formation mechanism in He+/H+-implanted KTiOPO4,” Opt. Mater. Express 7(9), 3204–3213 (2017).
    [Crossref]
  27. T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
    [Crossref]
  28. A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
    [Crossref]
  29. P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
    [Crossref]
  30. T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000).
    [Crossref]
  31. P. Rabiei and P. Gunter, “Optical and electro-optical properties of submicrometer lithium niobate slab waveguides prepared by crystal ion slicing and wafer bonding,” Appl. Phys. Lett. 85(20), 4603–4605 (2004).
    [Crossref]
  32. H. Hu, R. Ricken, and W. Sohler, “Lithium niobate photonic wires,” Opt. Express 17(26), 24261–24268 (2009).
    [Crossref]
  33. B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
    [Crossref]
  34. B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017).
    [Crossref]
  35. T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
    [Crossref]
  36. L. C. Feldman and J. M. Rodgers, “Depth profiles of the lattice disorder resulting from ion bombardment of silicon single crystals,” J. Appl. Phys. 41(9), 3776–3782 (1970).
    [Crossref]
  37. K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
    [Crossref]

2020 (1)

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

2018 (5)

Qiang Zhang and Chaoyang Li, “Pure anatase phase titanium dioxide films prepared by mist chemical vapor deposition,” Nanomaterials 8(10), 827 (2018).
[Crossref]

I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
[Crossref]

W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
[Crossref]

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Fabrication of TiO2 thin films with both anatase and rutile structures together using the ion-implantation method,” Opt. Mater. Express 8(3), 532–540 (2018).
[Crossref]

2017 (2)

Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Twinning and defect formation mechanism in He+/H+-implanted KTiOPO4,” Opt. Mater. Express 7(9), 3204–3213 (2017).
[Crossref]

B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017).
[Crossref]

2016 (2)

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

2015 (4)

C. C. Evans, C. Liu, and J. Suntivich, “Low-loss titanium dioxide waveguides and resonators using a dielectric lift-off fabrication process,” Opt. Express 23(9), 11160–11169 (2015).
[Crossref]

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
[Crossref]

B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015).
[Crossref]

2014 (2)

B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
[Crossref]

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

2013 (5)

B. Guha, J. Cardenas, and M. Lipson, “Athermal silicon microring resonators with titanium oxide cladding,” Opt. Express 21(22), 26557–26563 (2013).
[Crossref]

S. S. Djordjevic, K. Shang, B. Guan, S. T. S. Cheung, L. Liao, J. Basak, H.-F. Liu, and S. J. B. Yoo, “CMOS-compatible, athermal silicon ring modulators clad with titanium dioxide,” Opt. Express 21(12), 13958–13968 (2013).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
[Crossref]

T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
[Crossref]

2012 (2)

2010 (1)

G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
[Crossref]

2009 (2)

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

H. Hu, R. Ricken, and W. Sohler, “Lithium niobate photonic wires,” Opt. Express 17(26), 24261–24268 (2009).
[Crossref]

2006 (1)

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

2005 (2)

P. Rabiei and W. H. Steier, “Lithium niobate ridge waveguides and modulators fabricated using smart guide,” Appl. Phys. Lett. 86(16), 161115 (2005).
[Crossref]

X. Wang, M. Fujimaki, and K. Awazu, “Photonic crystal structures in titanium dioxide (TiO2) and their optimal design,” Opt. Express 13(5), 1486–1497 (2005).
[Crossref]

2004 (1)

P. Rabiei and P. Gunter, “Optical and electro-optical properties of submicrometer lithium niobate slab waveguides prepared by crystal ion slicing and wafer bonding,” Appl. Phys. Lett. 85(20), 4603–4605 (2004).
[Crossref]

2002 (1)

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

2000 (1)

T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000).
[Crossref]

1999 (1)

A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
[Crossref]

1996 (1)

M. Bruel, “Application of hydrogen ion beams to silicon on insulator material technology,” Nucl. Instrum. Methods Phys. Res., Sect. B 108(3), 313–319 (1996).
[Crossref]

1990 (1)

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

1989 (1)

R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989).
[Crossref]

1970 (1)

L. C. Feldman and J. M. Rodgers, “Depth profiles of the lattice disorder resulting from ion bombardment of silicon single crystals,” J. Appl. Phys. 41(9), 3776–3782 (1970).
[Crossref]

Aasmundtveit, K. E.

T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
[Crossref]

Adair, R.

R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989).
[Crossref]

Afra, B.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Awazu, K.

Bahnemann, D.

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Bakhru, H.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

Basak, J.

Bierschenk, T.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Biswas, P.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Bradley, J. D. B.

Bruel, M.

M. Bruel, “Application of hydrogen ion beams to silicon on insulator material technology,” Nucl. Instrum. Methods Phys. Res., Sect. B 108(3), 313–319 (1996).
[Crossref]

Burgess, I. B.

Cardenas, J.

Chadha, T.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Chase, L. L.

R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989).
[Crossref]

Chen, A.

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

Chen, M.

Cheung, S. T. S.

Choy, J. T.

Deotare, P. B.

Di Valentin, C.

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Djordjevic, S. S.

Duan, A.

T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
[Crossref]

Etacheri, V.

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Evans, C. C.

Fan, R.

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Feldman, L. C.

L. C. Feldman and J. M. Rodgers, “Depth profiles of the lattice disorder resulting from ion bombardment of silicon single crystals,” J. Appl. Phys. 41(9), 3776–3782 (1970).
[Crossref]

Feng, X.

W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
[Crossref]

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

Fischer, A. J.

G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
[Crossref]

Fujimaki, M.

Fujino, Y.

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

Gibson, B. C.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Greentree, A. D.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Guan, B.

Guan, J.

B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015).
[Crossref]

B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
[Crossref]

Guha, B.

Gunter, P.

P. Rabiei and P. Gunter, “Optical and electro-optical properties of submicrometer lithium niobate slab waveguides prepared by crystal ion slicing and wafer bonding,” Appl. Phys. Lett. 85(20), 4603–4605 (2004).
[Crossref]

Hoivik, N.

T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
[Crossref]

Hong, I. K.

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

Hu, H.

Huang, S. H.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Huntington, S. T.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Hyun, S.

B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017).
[Crossref]

Izuhara, T.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

Jamieson, D. N.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Jiao, Y.

B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015).
[Crossref]

B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
[Crossref]

Khattak, S. A.

I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
[Crossref]

Kim, J. Y.

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

Kim, J.-M.

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

Kim, N. H.

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

Kluth, P.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Koleske, D. D.

G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
[Crossref]

Kremer, F.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Kwak, H.

A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
[Crossref]

Lee, B.

B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017).
[Crossref]

Lee, Y.-J.

G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
[Crossref]

Levy, M.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000).
[Crossref]

A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
[Crossref]

Li, Chaoyang

Qiang Zhang and Chaoyang Li, “Pure anatase phase titanium dioxide films prepared by mist chemical vapor deposition,” Nanomaterials 8(10), 827 (2018).
[Crossref]

Li, Y.

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

Liao, L.

Lipson, M.

Liu, C.

Liu, H.-F.

Liu, X.-H.

Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
[Crossref]

Y.-J. Ma, F. Lu, X.-B. Ming, M. Chen, X.-H. Liu, and J.-J. Yin, “Analysis of Si-implanted Nd:YVO4 crystal: the relation between lattice damage and waveguide formation,” Appl. Opt. 51(23), 5657–5663 (2012).
[Crossref]

Llewellyn, D. J.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Loncar, M.

Long, H.

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

Lu, F.

Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Fabrication of TiO2 thin films with both anatase and rutile structures together using the ion-implantation method,” Opt. Mater. Express 8(3), 532–540 (2018).
[Crossref]

Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Twinning and defect formation mechanism in He+/H+-implanted KTiOPO4,” Opt. Mater. Express 7(9), 3204–3213 (2017).
[Crossref]

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
[Crossref]

Y.-J. Ma, F. Lu, X.-B. Ming, M. Chen, X.-H. Liu, and J.-J. Yin, “Analysis of Si-implanted Nd:YVO4 crystal: the relation between lattice damage and waveguide formation,” Appl. Opt. 51(23), 5657–5663 (2012).
[Crossref]

Lu, P.

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

Luan, C.

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
[Crossref]

Ludhi, N. A.

I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
[Crossref]

Luu, T.-T.

T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
[Crossref]

Ma, C.-D.

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
[Crossref]

Ma, J.

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
[Crossref]

Ma, Y.-J.

Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Fabrication of TiO2 thin films with both anatase and rutile structures together using the ion-implantation method,” Opt. Mater. Express 8(3), 532–540 (2018).
[Crossref]

Y.-J. Ma, F. Lu, B.-X. Xiang, J.-L. Zhao, and S.-C. Ruan, “Twinning and defect formation mechanism in He+/H+-implanted KTiOPO4,” Opt. Mater. Express 7(9), 3204–3213 (2017).
[Crossref]

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
[Crossref]

Y.-J. Ma, F. Lu, X.-B. Ming, M. Chen, X.-H. Liu, and J.-J. Yin, “Analysis of Si-implanted Nd:YVO4 crystal: the relation between lattice damage and waveguide formation,” Appl. Opt. 51(23), 5657–5663 (2012).
[Crossref]

Mazur, E.

Ming, X.-B.

Monifi, F.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Moore, D.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Naramoto, H.

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

Oh, S.-G.

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

Olivero, P.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Osgood Jr, R. M.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000).
[Crossref]

A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
[Crossref]

Ozawa, K.

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

Ozdemir, S. K.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Park, J.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Payne, S. A.

R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989).
[Crossref]

Pillai, S. C.

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Prawer, S.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Rabeau, J. R.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Rabiei, P.

P. Rabiei and W. H. Steier, “Lithium niobate ridge waveguides and modulators fabricated using smart guide,” Appl. Phys. Lett. 86(16), 161115 (2005).
[Crossref]

P. Rabiei and P. Gunter, “Optical and electro-optical properties of submicrometer lithium niobate slab waveguides prepared by crystal ion slicing and wafer bonding,” Appl. Phys. Lett. 85(20), 4603–4605 (2004).
[Crossref]

Radojevic, A. M.

A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
[Crossref]

Ramadan, T. A.

T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000).
[Crossref]

Reeves, M. E.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

Reichart, P.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Ricken, R.

Ridgway, M. C.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
[Crossref]

Rodgers, J. M.

L. C. Feldman and J. M. Rodgers, “Depth profiles of the lattice disorder resulting from ion bombardment of silicon single crystals,” J. Appl. Phys. 41(9), 3776–3782 (1970).
[Crossref]

Rodriguez, M. D.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Roy, A. N.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

Ruan, S.-C.

Rubanov, S.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Salzman, J.

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

Santiago, P. M.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Sato, K.

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

Schauries, D.

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

Schneider, J.

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Shang, K.

Sohler, W.

Steier, W. H.

P. Rabiei and W. H. Steier, “Lithium niobate ridge waveguides and modulators fabricated using smart guide,” Appl. Phys. Lett. 86(16), 161115 (2005).
[Crossref]

Subramania, G.

G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
[Crossref]

Suntivich, J.

Tanveer Ahmad, S.

I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
[Crossref]

Ullah, I.

I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
[Crossref]

Wang, L.

B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015).
[Crossref]

B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
[Crossref]

Wang, M.

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

Wang, W.

W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
[Crossref]

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

Wang, X.

Wang, Y. G.

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

Xiang, B.

B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
[Crossref]

Xiang, B.-X.

Xu, B.

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Y.-J. Ma, F. Lu, M. C. Ridgway, C.-D. Ma, and B. Xu, “Micro-structure analysis of He+ ion implanted KTP by TEM,” Opt. Mater. Express 5(5), 986–995 (2015).
[Crossref]

Yamaguchi, S.

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

Yang, G.

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

Yang, L.

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Yin, J.-J.

Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
[Crossref]

Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
[Crossref]

Y.-J. Ma, F. Lu, X.-B. Ming, M. Chen, X.-H. Liu, and J.-J. Yin, “Analysis of Si-implanted Nd:YVO4 crystal: the relation between lattice damage and waveguide formation,” Appl. Opt. 51(23), 5657–5663 (2012).
[Crossref]

Yoo, S. J. B.

Yoon, J.

B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017).
[Crossref]

Zhang, Qiang

Qiang Zhang and Chaoyang Li, “Pure anatase phase titanium dioxide films prepared by mist chemical vapor deposition,” Nanomaterials 8(10), 827 (2018).
[Crossref]

Zhao, J.-L.

Zhao, W.

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

Adv. Mater. (1)

G. Subramania, Y.-J. Lee, A. J. Fischer, and D. D. Koleske, “Log-pile TiO2 photonic crystal for light control at near-UV and visible wavelengths,” Adv. Mater. 22(4), 487–491 (2010).
[Crossref]

Adv. Opt. Mater. (1)

J. Park, S. K. Ozdemir, F. Monifi, T. Chadha, S. H. Huang, P. Biswas, and L. Yang, “Titanium dioxide whispering gallery microcavities,” Adv. Opt. Mater. 2(8), 711–717 (2014).
[Crossref]

Appl. Opt. (1)

Appl. Phys. Lett. (5)

P. Rabiei and W. H. Steier, “Lithium niobate ridge waveguides and modulators fabricated using smart guide,” Appl. Phys. Lett. 86(16), 161115 (2005).
[Crossref]

T. A. Ramadan, M. Levy, and R. M. Osgood Jr, “Electro-optic modulation in crystal-ion-sliced z-cut LiNbO3 thin films,” Appl. Phys. Lett. 76(11), 1407–1409 (2000).
[Crossref]

P. Rabiei and P. Gunter, “Optical and electro-optical properties of submicrometer lithium niobate slab waveguides prepared by crystal ion slicing and wafer bonding,” Appl. Phys. Lett. 85(20), 4603–4605 (2004).
[Crossref]

T. Izuhara, R. M. Osgood Jr, M. Levy, M. E. Reeves, Y. G. Wang, A. N. Roy, and H. Bakhru, “Low-loss crystal-ion-sliced single-crystal potassium tantalate films,” Appl. Phys. Lett. 80(6), 1046–1048 (2002).
[Crossref]

A. M. Radojevic, M. Levy, H. Kwak, and R. M. Osgood Jr, “Strong nonlinear optical response in epitaxial liftoff single-crystal LiNbO3 films,” Appl. Phys. Lett. 75(19), 2888–2890 (1999).
[Crossref]

Ceram. Int. (1)

W. Wang, X. Feng, C. Luan, and J. Ma, “Effect of Nb doping on structural and electrical properties of homoepitaxial rutile TiO2:Nb films,” Ceram. Int. 44(2), 2432–2435 (2018).
[Crossref]

Diamond Relat. Mater. (1)

P. Olivero, S. Rubanov, P. Reichart, B. C. Gibson, S. T. Huntington, J. R. Rabeau, A. D. Greentree, J. Salzman, D. Moore, D. N. Jamieson, and S. Prawer, “Characterization of three-dimensional microstructures in single-crystal diamond,” Diamond Relat. Mater. 15(10), 1614–1621 (2006).
[Crossref]

J. Appl. Phys. (1)

L. C. Feldman and J. M. Rodgers, “Depth profiles of the lattice disorder resulting from ion bombardment of silicon single crystals,” J. Appl. Phys. 41(9), 3776–3782 (1970).
[Crossref]

J. Electron. Mater. (1)

T.-T. Luu, A. Duan, K. E. Aasmundtveit, and N. Hoivik, “Optimized Cu-Sn wafer-level bonding using intermetallic phase characterization,” J. Electron. Mater. 42(12), 3582–3592 (2013).
[Crossref]

J. Ind. Eng. Chem. (1)

N. H. Kim, J. Y. Kim, J.-M. Kim, I. K. Hong, and S.-G. Oh, “Preparation of melanoidin/TiO2 composites with improved UV screening ability and suppressed photocatalytic activity for cosmetic application,” J. Ind. Eng. Chem. 86, 186–193 (2020).
[Crossref]

J. Mater. Res. (1)

Y.-J. Ma, P. M. Santiago, M. D. Rodriguez, F. Kremer, D. Schauries, B. Afra, T. Bierschenk, D. J. Llewellyn, F. Lu, M. C. Ridgway, and P. Kluth, “Orientation dependence of swift heavy ion track formation in potassium titanyl phosphate,” J. Mater. Res. 31(15), 2329–2336 (2016).
[Crossref]

J. Mater. Sci.: Mater. Electron. (1)

B. Lee, S. Hyun, and J. Yoon, “Cu–Sn and Ni–Sn transient liquid phase bonding for die-attach technology applications in high-temperature power electronics packaging,” J. Mater. Sci.: Mater. Electron. 28(11), 7827–7833 (2017).
[Crossref]

J. Photochem. Photobiol., C (1)

V. Etacheri, C. Di Valentin, J. Schneider, D. Bahnemann, and S. C. Pillai, “Visible-light activation of TiO2 photocatalysts: advances in theory and experiments,” J. Photochem. Photobiol., C 25, 1–29 (2015).
[Crossref]

Mater. Chem. Phys. (1)

W. Wang, M. Wang, X. Feng, W. Zhao, C. Luan, and J. Ma, “Effects of deposition temperature on the structural and optical properties of single crystalline rutile TiO2 films,” Mater. Chem. Phys. 211, 172–176 (2018).
[Crossref]

Mater. Sci. Eng., B (1)

Y.-J. Ma, F. Lu, J.-J. Yin, and C.-D. Ma, “Radiation damage study of MeV ions-implanted Nd:YVO4 crystal,” Mater. Sci. Eng., B 178(20), 1464–1468 (2013).
[Crossref]

Mod. Phys. Lett. B (1)

I. Ullah, S. A. Khattak, S. Tanveer Ahmad, and N. A. Ludhi, “Sol-gel synthesis and optical properties of titanium dioxide thin film,” Mod. Phys. Lett. B 32(09), 1850076–1850086 (2018).
[Crossref]

Nanomaterials (1)

Qiang Zhang and Chaoyang Li, “Pure anatase phase titanium dioxide films prepared by mist chemical vapor deposition,” Nanomaterials 8(10), 827 (2018).
[Crossref]

Nucl. Instrum. Methods Phys. Res., Sect. B (3)

B.-X. Xiang, Y. Jiao, J. Guan, and L. Wang, “Ion implantation induced blistering of rutile single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 354, 255–258 (2015).
[Crossref]

M. Bruel, “Application of hydrogen ion beams to silicon on insulator material technology,” Nucl. Instrum. Methods Phys. Res., Sect. B 108(3), 313–319 (1996).
[Crossref]

K. Sato, Y. Fujino, S. Yamaguchi, H. Naramoto, and K. Ozawa, “Ion channeling studies of C+ irradiated TiC single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. B 47(4), 421–426 (1990).
[Crossref]

Opt. Eng. (1)

Y.-J. Ma, F. Lu, J.-J. Yin, and X.-H. Liu, “Refractive index profile in ion-implanted neodymium-doped yttrium vanadate waveguide: the relation between index change and lattice damage,” Opt. Eng. 52(9), 097101 (2013).
[Crossref]

Opt. Express (5)

Opt. Lett. (1)

Opt. Mater. (1)

Y.-J. Ma, F. Lu, C.-D. Ma, B. Xu, and R. Fan, “Analysis of layer splitting in x and z-cut KTiOPO4 implanted by H+ ions,” Opt. Mater. 54, 1–5 (2016).
[Crossref]

Opt. Mater. Express (3)

Phys. Rev. B (1)

R. Adair, L. L. Chase, and S. A. Payne, “Nonlinear refractive index of optical crystals,” Phys. Rev. B 39(5), 3337–3350 (1989).
[Crossref]

Phys. Status Solidi A (1)

B. Xiang, J. Guan, Y. Jiao, and L. Wang, “Fabrication of ion-sliced lithium niobate slabs using helium ion implantation and Cu–Sn bonding,” Phys. Status Solidi A 211(10), 2416–2420 (2014).
[Crossref]

Thin Solid Films (1)

H. Long, A. Chen, G. Yang, Y. Li, and P. Lu, “Third-order optical nonlinearities in anatase and rutile TiO2 thin films,” Thin Solid Films 517(19), 5601–5604 (2009).
[Crossref]

Cited By

OSA participates in Crossref's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Figures (7)

Fig. 1.
Fig. 1. Schematic presentation of r-TiO2 thin film heterostructure fabrication using ion-implantation together with Cu-Sn bonding: (a) 200 keV He+-implantation into r-TiO2 donor wafer at ion fluence of 8×1016 ions/cm2. (b) Film coating on both the r-TiO2 donor and receptor wafer. (c) Cu-Sn bonding of the coated donor and receptor wafers together. (d) r-TiO2 thin film exfoliation from bulk after annealing.
Fig. 2.
Fig. 2. Surface morphology of ion-implanted r-TiO2 sample before (a) and after annealing at 400°C for 1 hour (b) and 5 hours (c).
Fig. 3.
Fig. 3. Cross-section images of the fabricated r-TiO2 thin film heterostructure detected by SEM.
Fig. 4.
Fig. 4. The component elements in each layer of r-TiO2 thin film heterostructure detected by EDS.
Fig. 5.
Fig. 5. XRD results of the exfoliated r-TiO2 thin film.
Fig. 6.
Fig. 6. RBS/Channeling spectra (a) and damage profile (b) of 200 keV He+-implanted r-TiO2 at ion fluence of 8×1016 ions/cm2. In (a), the aligned and random spectra from the virgin r-TiO2 are shown for comparison. The distribution of the implanted He+-ions as simulated by SRIM is shown in (b) by the solid red curve.
Fig. 7.
Fig. 7. TEM images of the internal structure of the ion-implanted r-TiO2 sample.

Metrics