Abstract

The electrochromic modulation of plasmonic metasurfaces showing structural colors is a promising strategy to realize dynamic electronic reflective displays. However, hybridizing electrochromic polymers with large-area plasmonic metasurfaces remains challenging. In this study, we present a poly(3,4-ethylenedioxythiophene) (PEDOT)-coated gold nanodisk (PCGN) metasurface, which is fabricated based on techniques of large-area anodic aluminum oxide template-assisted deposition and electrochemical polymerization. Experimental and numerical results demonstrated that fast and reversible electrochromic modulation was realized within the PCGN metasurface. The wavelength control of the localized surface plasmon resonance of the PCGN metasurface originated from the electrically driven refractive index change of the PEDOT layer. The PCGN metasurface is promising for the high yield manufacturing of devices applied in dynamic reflective displays.

© 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

1. Introduction

Electronic reflective displays represent one of the most important technologies of dynamic visual displays, which are widely used in daily applications, such as mobile phones, e-readers, electronic paper and billboards. Compared with other emissive techniques based on light-emitting diodes or liquid crystals, reflective displays are of lower energy consumption and higher visibility free from the influences of the viewing angle and the ambient light intensity [1]. The reconfigurable control of the reflectively displayed patterns relies on the dynamic modulation of colored pixels by manipulating their electrochemical or electromechanical processes [24]. The pixels can be made of dye pigments, photonic crystals, plasmonic nanostructures and so on. Among them, pixels based on plasmonic structures are more preferable because their colors are immune to chemical bleaching and they can be manufactured in higher spatial resolutions [5,6].

The modulation of plasmonic colors can be realized by (i) overlaying dynamic transmission or polarization modulators made of stimuli-responsive materials to filtrate the structural colors or (ii) using stimuli-responsive materials as the composition of plasmonic nanostructured systems to directly modulate the resonances by controlling the factors, such as the morphology, arrangement, material and the environmental refractive index of the nanostructure units, for the purpose of the intrinsic variation of the structural colors. For example, liquid crystals (LCs) represent some of the most typical stimuli-responsive materials whose transmission and refractive index can be changed by external stimulations, such as acoustic waves [7], voltages [8], light fields [9,10] and so on. LCs can serve as filters, templates for ordering metal nanocrystals and dynamic media, leading to the effective modulation of plasmonic colors. However, LC-based plasmonic modulation suffers from low color brightness because LCs are polarization selective materials [1].

In addition, some metals can serve as switchable components in plasmonic structures to realize the reconfigurable morphology variation or the reversible change of the refractive index by using chemical reactions, such as the reversible electrochemical deposition approach of silver [1113]. This strategy breaks the limit of polarization dependency in the case of LC-based systems. However, both LC- and switchable-metal-based pixels cannot be realized with an ultrathin thickness or a relatively high resolution because relatively large-scale LCs and macroscale electrochemical deposition cells are needed to compose the pixels, restricting their application and integration in miniaturized optical systems.

Hybridizing electrochromic polymers with plasmonic metasurfaces is a feasible solution. Electrochromic polymers themselves, such as polypyrrole, polythiophene, polyaniline and poly(3,4-ethylenedioxythiophene) (PEDOT), are dynamic color generators, whose intrinsic color, refractive index and transparency depend on their redox states and can be tuned by driving different voltages [14,15]. However, macroscale electrochromic polymers are difficult to process into high-resolution pixels because their sufficient color saturation and contrast demand large thicknesses, which also leads to a high response time to complete the redox reaction of the entire volume of the polymers. Instead, their hybridization with plasmonic metasurfaces is more preferable, in which the electrochromic polymer serves as the dynamic medium around the plasmonic metasurface. In this case, the pixel size depends on the micro-/nanoscale metasurface, which can be lowered and precisely fabricated. The thickness of the polymer can reach down to tens of nanometers, resulting in fast modulation.

Effective color changes and high contrast modulation can still be realized by electrically tuning the plasmonic resonances. The commonly used structures of plasmonic metasurfaces are gratings [16,17], nanoholes [1822], nanomeshes [23], nanoparticles and nanocrystal assemblies [2428]. For the purpose of a high resolution and well-defined morphology, most of these structures are fabricated using high cost and time-consuming techniques, such as electron beam lithography or focused ion beam lithography, limiting their area and practical applicability. Developing a low-cost fabrication process of a large-area metasurface hybridized with electrochromic polymers to realize effective plasmonic modulation remains challenging.

In this work, we present a PEDOT-coated gold nanodisk (PCGN) metasurface, in which the ordered-arranged and well-defined gold (Au) nanodisk array is fabricated through a low-cost and large-area process based on the anodic aluminum oxide (AAO) template assisted deposition. An ultrathin layer of PEDOT is in situ synthesized on the Au nanodisk array by the electrochemical polymerization of 3,4-ethylenedioxythiophene (EDOT) monomers. The reflective intensity and the plasmonic resonant wavelength of the PCGN metasurface can be shifted by tuning the applied voltages to realize fast and reversible electrochromic modulation. Numerical simulation results demonstrated that the modulation was due to environmental refractive index changes around the plasmonic Au nanodisks caused by the ultrathin PEDOT coating in different redox states stimulated by the voltages.

2. Methods

Materials: 3,4-ethylenedioxythiophene (EDOT), acetonitrile, acetone and tetrabutylammonium hexafluorophosphate (TBAPF6) were purchased from Aladdin and used as received. 0.1 M TBAPF6-acetonitrile solution was prepared and then EDOT was dissolved in the TBAPF6-acetonitrile solution. Commercial ITO glass slide (length of 2.5 cm and width of 1 cm) was cleaned with deionized water before used. The high purity gold particles (99.999%) for the use of PVD were purchased from ZhongNuo Advanced Material (Beijing) Technology Co. Ltd., China. The AAO template was homemade.

Fabrication of AAO templates: The AAO templates were prepared in a two-step anodization process. Briefly, polished Al foils were anodized in a 0.3 M oxalic acid solution at 40 V in 2–6 °C for 4 h. Then, the anodic oxide layer was removed in a mixture of H3PO4 (6 wt.%) and H2CrO4 (1.8 wt.%) at 60 °C. It was anodized again using the same solution and voltage. The thickness of the AAO was controlled by anodizing time. Subsequently, a polymethyl methacrylate (PMMA) layer was coated on AAO from a PMMA/methylbenzene solution. The Al layer was removed in mixture of CuSO4 and HCl solutions. The removal of the thin barrier layer was carried out in H3PO4 solution (5 wt.%) at 30 °C. PMMA/AAO sheets were put in acetone so that PMMA was dissolved leaving AAO membrane suspending in acetone. The AAO was mounted on the substrates in the liquid and attached on them with the quick drying of the acetone.

Nanofabrication: Films of Au (200 nm) with Ti (5 nm) adhesion deposited on ITO glass slide substrates surface using sputtering. AAO template with nanohole periodicity of 470 nm and hole diameter of 260 nm was transferred onto surface of the gold/ITO glass substrates in acetone solution at room temperature. After that, the thickness of 40 nm Au film deposited into the nanohole of AAO template with a method of electron beam evaporation without sample stage rotation. The deposition rate for Ti and Au is RTi ≈ 0.016 nm/s and RAu≈0.05 nm/s, respectively. A gold nanodisk array was obtained after removing the AAO templates.

Spectroelectrochemistry Setup: Reflection spectra were detected by a UV-Vis-NIR fiber optic spectrometer (PG2000-Pro back-thinned spectrometer, Ideaoptics, China) with a light source (IDH2000, Ideaoptics, China). Angle-resolved spectrum system (R1, angle-resolved spectrum system, Ideaoptics, China) was used to ensure that the incident angle of light was 0°. The PEDOT/Au nanodisk array/Au/ITO glass substrate was clamped against a homemade cell with an O-ring silicone gasket preventing leakage of electrolyte solution. Then the substrate was mounted the sample stage of the spectrometer. Surface plasmons were excited at the periodic nanostructure–dielectric interface and Reflection-SPR signals were detected by fiber optic spectrometer.

Electrochemical measurements were carried out using a three-electrode system with the electrochemical workstation (CHI660E, Shanghai Chenhua, China). Au nanodisk array/ITO glass substrate served as the working electrode with an area of 2 cm2. The counter electrode was a platinum wire about 2 cm and an Ag|AgCl|KCl electrode was used as the reference electrode. PEDOT polymer films were obtained on the surface of periodic nanostructure at a constant potential about 1.22 V lasting 20 s in an acetonitrile solution with 0.1 M TBAPF6 containing 0.02 M EDOT monomer. Then, the substrates were transferred to a monomer-free acetonitrile solution with 0.1 M TBAPF6 by cyclic voltammetry to stabilize the polymer films. Combining the fiber optic spectrometer with electrochemical workstation, SPR response of Au nanodisk array was studied by applying the different potential from −1 to 1 V.

3. Results and discussion

Figure 1(a) illustrates the fabrication process of the PCGN metasurface. It is fabricated based on the template-assisted physical vapor deposition (PVD) technique. A layer of 200 nm Au was first deposited onto the indium tin oxide (ITO) glass substrate with an adhesive layer of 5 nm Ti between them. Subsequently, an AAO membrane with a thickness of 500 nm was transferred onto the Au layer in acetone. The large area AAO membrane was perforated by many ordered-arranged nanoholes, and it served as the template during the PVD process. The period and the size of the nanoholes are 470 and 260 nm, respectively. Afterwards, 40 nm thick Au was deposited into the holes of the AAO template and located on the underlying Au substrate. Because of the sufficient difference between the thicknesses of the AAO template and the Au deposited in the nanoholes, the Au nanodisk array can remain on the substrate after the mechanical peeling-off of the AAO template. Figure 1(b) shows the scanning electron microscopy (SEM) image of the ordered-arranged and well-defined Au nanodisks. The period and diameter of the gold nanodisks were the same as those of the AAO nanoholes, resulting from the conformal deposition of Au into the nanoholes during the PVD process. Finally, the synthesis of the PEDOT coating was carried out at the surface of the Au nanodisk array in situ. The electrochemical polymerization reaction happened in a conductive solution, where 0.02 M EDOT monomers and 0.1 M TBAPF6 were distributed in acetonitrile. The mixed solution was simultaneously connected with the Au nanodisk array, a Pt wire and an Ag/AgCl electrode, which served as the working, counter and reference electrodes, respectively. The three-electrode system was driven and monitored using an electrochemical workstation. In this experiment, the PEDOT coating was fabricated and driven by a constant voltage of 1.22 V (vs. the potential of the Ag/AgCl electrode) for 20 s. As shown in Fig. 1(c), after the electrochemical polymerization, the diameter of the nanodisks was slightly increased, which demonstrated the formation of the PEDOT coating. The average thickness of the PEDOT coating was 27 nm. In addition, because the AAO template was fabricated based on a bottom-up technique, both the Au nanodisk array and the PCGN metasurface could be of large areas. The photographs of the Au nanodisk array and the PCGN metasurface with a ∼1 cm2 area are shown in the insets of Figs. 1(b) and (c), respectively.

 figure: Fig. 1.

Fig. 1. (a) Schematic illustration of the fabrication process of the PCGN metasurface. (b) and (c) SEM images of the Au nanodisk array and the PCGN metasurface, respectively. The scale bars stand for 500 nm. Insets of (b) and (c) are the optical photographs of the Au nanodisk substrate and the PCGN metasurface, the scale bars stand for 2 mm.

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To demonstrate the modulation capability of the PCGN metasurface, we built a spectroelectrochemistry setup, in which the metasurface can be electrically driven and simultaneously optically characterized. The setup was the combination of a reflective spectral system and the aforementioned three-electrode electrochemistry system. Differently, the metasurface was immersed in the conductive solution without EDOT monomers. Figure 2(a) shows the reflection spectra of the Au nanodisk array in air, the PCGN metasurface in air and the PCGN metasurface in the conductive solution. For each one of the three spectra, a major reflection dip occurred at short wavelength. The dip wavelengths were 550, 615 and 678 nm, respectively. All the three reflection dips were generated from the absorption caused by the plasmonic resonance of Au nanodisks. The PEDOT coating and conductive solution increased the environmental refractive index around the Au nanodisks, resulting in the red shift of the resonant wavelength.

 figure: Fig. 2.

Fig. 2. (a) Reflection spectra of the Au nanodisk substrate in air, the PCGN metasurface in air, and the PCGN metasurface in the conductive solution. (b) Electrochromic modulation of the PCGN metasurface: Reflection spectra of the PCGN metasurface with different driven voltages. (c) Reflection spectra of PEDOT film on planar Au substrate driven by voltages ranging from −1 to 1 V. (d) Time resolved electrochromic modulation: the resonant wavelength of the PCGN metasurface with the driven varied voltages switching between 1 and −1 V.

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The analogous mechanism could be used to dynamically modulate the plasmonic resonances. In detail, both the intensity and the wavelength of the plasmonic resonance induced absorption could be controlled by adjusting the dielectric constants of the PEDOT coating, which was realized by driving different voltages on it. Figure 2(b) shows the reflection spectra of the PCGN metasurface under different driven voltages. With the voltages ranging from 1 to −1 V, the resonant wavelength shifts from 653 to 718 nm, and the lowest reflectance decreases from 53% to 48%. Varying the driven voltage can lead to the change of the chemical properties of PEDOT, such as the redox state, the molecular composition and configuration, the doping level of ions or electrons and so on [15]. Consequently, the complex refractive index of PEDOT is also changed [29]. With the voltage decreases from 1 V to −1 V, the real part of the refractive index increased, resulting in the red shift of the resonant wavelength. Furthermore, the change of the complex refractive index of PEDOT also leads to the decrement of the effective impedance of the PCGN metasurface at the corresponding resonant wavelengths, which results in a higher impedance matching between air and the PCGN metasurface and generating lower reflection. It is worth mentioning that the spectral modulation of the PCGN metasurface was based on the hybrid contribution of the plasmonic Au nanodisks and the electrochromic PEDOT rather than solely that of the PEDOT. This can be proved by the reflection spectra of a reference sample, i.e., a PEDOT coated planar Au film, as shown in Fig. 2(c). The variation of the driven voltage mainly caused the change of the reflection intensity at the wavelength near to 600 nm, but the dip wavelength shifted slightly.

We also investigated the response time of the electrochromic modulation of the PCGN metasurface. It was characterized by recording the real-time resonant wavelength under an alternating voltage that is periodically switched between 1 and −1 V, as shown in Fig. 2(d). The resonant wavelength reversibly fluctuated between 652 and 719 nm. Right after the switching of the voltage, the resonant wavelength was changed immediately and dramatically. Then, when it got close to the opposite value, the variation slowed down. This phenomenon was related to the ratio of the electrochemical redox reactions. It was dominated by the reactant concentration, which was highest right after the switch and then lowered down. Herein, we define the response time of the electrochromic modulation as the duration from the beginning of the switching to the moment when the wavelength reaches 95% of the entire shift, which is ∼10 s. This short response time could be attributed to the small thickness of the PEDOT coating, which was only 27 nm. The thin film facilitated the redox reactions due to (i) the high surface area which provided plentiful sites for the exchange of electrons or ions, and (ii) the low amount of reactants per unit area.

To interpret the mechanism of the plasmonic modulation using the PCGN metasurface, we carried out numerical simulations using the full-wave 3D finite-different time-domain method. The model was established according to the realistic microscopic morphology of the PCGN metasurface. The refractive index of the conductive solution was measured using a refractometer, which was 1.33. The refractive indices of Au and PEDOT were acquired from the reported results [30]. Accordingly, we calculated three samples, which, respectively, corresponded to the Au nanodisk array in air, the oxidation-state PCGN metasurface in the conductive solution under a 0.5 V driven voltage and the reduction-state PCGN metasurface in the conductive solution under a −1.0 V driven voltage.

Illuminated by a normal incident plane wave, the reflection spectra and the near-field distributions of the three samples were recorded. Figure 3(a) shows the three simulated reflection spectra, whose resonant wavelengths match well with the ones in the experimentally measured results, i.e., 550 nm for the Au nanodisk, 675 nm for the oxidation-state PCGN metasurface and 716 nm for the reduction-state PCGN metasurface. This demonstrated the validity of the simulations. Figure 3(b) shows the electric field (E-field) distributions of the three samples at the resonant wavelengths. No matter with or without the PEDOT coating, the highly enhanced E-fields always located at the opposite edges of the Au nanodisks, featuring the dipole mode of the localized surface plasmon resonance (LSPR) of the Au nanodisk. Namely, the electrochromic modulation was based on the same LSPR mode. The maximum E-field enhancements (E/E0, where E stands for the local E-field and E0 stands for the incident E-field) for the Au nanodisk, the oxidation-state PCGN and the reduction-state PCGN are 17, 47, and 78, respectively. It demonstrated that the PCGN metasurface was of the capability of higher near-field localization, which could be attributed to its higher absorption. The PEDOT coating served as an impedance matching layer between air and the Au nanodisk substrates, preventing a larger amount of light from being reflected [31]. The shift of the resonance wavelength was due to the change of the refractive indexes the PEDOT coating, which increased during the transition from the oxidation state to the reduction state [29]. As a result, the electrochromic modulation of both the reflection intensity and the resonant wavelength was realized.

 figure: Fig. 3.

Fig. 3. Simulated (a) reflection spectra and (b) electric field distribution plots of the Au nanodisk substrate in air, the oxidation-state PCGN metasurface in the conductive solution, and the reduction-state PCGN in the conductive solution.

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4. Conclusions

In conclusion, the PCGN metasurface was fabricated using a low cost and large area process based on the AAO template assisted PVD and electrochemical polymerization. The ultrathin PEDOT coating served as a dynamic medium surrounding the plasmonic Au nanodisks. By driving different voltages on the PCGN metasurface, the refractive index of PEDOT could be tuned resulting in the shift of the resonant wavelength and the variation of the reflective intensity of the metasurface. As a result, fast and reversible electrochromic modulation of plasmonic resonances was achieved on the large area metasurface. With further explorations, we believe this technique is promising for high-yield manufactures of devices applied in dynamic reflective displays.

Funding

National Natural Science Foundation of China (11774163).

Disclosures

The authors declare no conflict of interest.

References

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References

  • View by:

  1. L. Shao, X. Zhuo, and J. Wang, “Advanced plasmonic materials for dynamic color display,” Adv. Mater. 30(16), 1704338 (2018).
    [Crossref]
  2. R. A. Hayes and B. J. Feenstra, “Video-speed electronic paper based on electrowetting,” Nature 425(6956), 383–385 (2003).
    [Crossref]
  3. A. C. Arsenault, D. P. Puzzo, I. Manners, and G. A. Ozin, “Photonic-crystal full-colour displays,” Nat. Photonics 1(8), 468–472 (2007).
    [Crossref]
  4. J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
    [Crossref]
  5. K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
    [Crossref]
  6. T. Xu, Y. K. Wu, X. Luo, and L. J. Guo, “Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging,” Nat. Commun. 1(1), 59 (2010).
    [Crossref]
  7. Y. J. Liu, X. Ding, S.-C. S. Lin, J. Shi, I.-K. Chiang, and T. J. Huang, “Surface acoustic wave driven light shutters using polymer-dispersed liquid crystals,” Adv. Mater. 23(14), 1656–1659 (2011).
    [Crossref]
  8. J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
    [Crossref]
  9. Y. Zhang, Q. Liu, H. Mundoor, Y. Yuan, and I. I. Smalyukh, “Metal nanoparticle dispersion, alignment, and assembly in nematic liquid crystals for applications in switchable plasmonic color filters and E-polarizers,” ACS Nano 9(3), 3097–3108 (2015).
    [Crossref]
  10. Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
    [Crossref]
  11. C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
    [Crossref]
  12. A. Tsuboi, K. Nakamura, and N. Kobayashi, “A localized surface plasmon resonance-based multicolor electrochromic device with electrochemically size-controlled silver nanoparticles,” Adv. Mater. 25(23), 3197–3201 (2013).
    [Crossref]
  13. G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
    [Crossref]
  14. A. L. Dyer, A. M. Österholm, D. E. Shen, K. E. Johnson, and J. R. Reynolds, “Conjugated electrochromic polymers: Structure-driven colour and processing control,” Electrochromic Materials and Devices113–184 (2013).
  15. M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
    [Crossref]
  16. A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
    [Crossref]
  17. T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
    [Crossref]
  18. Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
    [Crossref]
  19. M. Atighilorestani, H. Jiang, and B. Kaminska, “Electrochromic-polymer-based switchable plasmonic color devices using surface-relief nanostructure pixels,” Adv. Opt. Mater. 6(23), 1801179 (2018).
    [Crossref]
  20. S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
    [Crossref]
  21. K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
    [Crossref]
  22. K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
    [Crossref]
  23. M. Shahabuddin, T. McDowell, C. E. Bonner, and N. Noginova, “Enhancement of electrochromic polymer switching in plasmonic nanostructured environment,” ACS Appl. Nano Mater. 2(3), 1713–1719 (2019).
    [Crossref]
  24. J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
    [Crossref]
  25. S. Heo, A. Agrawal, and D. J. Milliron, “Wide dynamic range in tunable electrochromic Bragg stacks from doped semiconductor nanocrystals,” Adv. Funct. Mater. 29(37), 1904555 (2019).
    [Crossref]
  26. P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
    [Crossref]
  27. J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
    [Crossref]
  28. N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
    [Crossref]
  29. A. Baba, J. Lübben, K. Tamada, and W. Knoll, “Optical properties of ultrathin poly(3,4-ethylenedioxythiophene) films at several doping levels studied by in situ electrochemical surface plasmon resonance spectroscopy,” Langmuir 19(21), 9058–9064 (2003).
    [Crossref]
  30. P. B. Johnson and R. W. Christy, “Optical constants of the Noble metals,” Phys. Rev. B 6(12), 4370–4379 (1972).
    [Crossref]
  31. L. Feng, P. Huo, Y. Liang, and T. Xu, “Photonic metamaterial absorbers: Morphology engineering and interdisciplinary applications,” Adv. Mater.1903787 (2019).

2019 (6)

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

M. Shahabuddin, T. McDowell, C. E. Bonner, and N. Noginova, “Enhancement of electrochromic polymer switching in plasmonic nanostructured environment,” ACS Appl. Nano Mater. 2(3), 1713–1719 (2019).
[Crossref]

S. Heo, A. Agrawal, and D. J. Milliron, “Wide dynamic range in tunable electrochromic Bragg stacks from doped semiconductor nanocrystals,” Adv. Funct. Mater. 29(37), 1904555 (2019).
[Crossref]

J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
[Crossref]

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

2018 (3)

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

M. Atighilorestani, H. Jiang, and B. Kaminska, “Electrochromic-polymer-based switchable plasmonic color devices using surface-relief nanostructure pixels,” Adv. Opt. Mater. 6(23), 1801179 (2018).
[Crossref]

L. Shao, X. Zhuo, and J. Wang, “Advanced plasmonic materials for dynamic color display,” Adv. Mater. 30(16), 1704338 (2018).
[Crossref]

2017 (2)

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
[Crossref]

2016 (5)

K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
[Crossref]

P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
[Crossref]

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
[Crossref]

J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
[Crossref]

2015 (2)

Y. Zhang, Q. Liu, H. Mundoor, Y. Yuan, and I. I. Smalyukh, “Metal nanoparticle dispersion, alignment, and assembly in nematic liquid crystals for applications in switchable plasmonic color filters and E-polarizers,” ACS Nano 9(3), 3097–3108 (2015).
[Crossref]

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

2013 (1)

A. Tsuboi, K. Nakamura, and N. Kobayashi, “A localized surface plasmon resonance-based multicolor electrochromic device with electrochemically size-controlled silver nanoparticles,” Adv. Mater. 25(23), 3197–3201 (2013).
[Crossref]

2012 (2)

A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
[Crossref]

K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
[Crossref]

2011 (1)

Y. J. Liu, X. Ding, S.-C. S. Lin, J. Shi, I.-K. Chiang, and T. J. Huang, “Surface acoustic wave driven light shutters using polymer-dispersed liquid crystals,” Adv. Mater. 23(14), 1656–1659 (2011).
[Crossref]

2010 (2)

T. Xu, Y. K. Wu, X. Luo, and L. J. Guo, “Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging,” Nat. Commun. 1(1), 59 (2010).
[Crossref]

Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
[Crossref]

2009 (1)

J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

2007 (1)

A. C. Arsenault, D. P. Puzzo, I. Manners, and G. A. Ozin, “Photonic-crystal full-colour displays,” Nat. Photonics 1(8), 468–472 (2007).
[Crossref]

2003 (2)

R. A. Hayes and B. J. Feenstra, “Video-speed electronic paper based on electrowetting,” Nature 425(6956), 383–385 (2003).
[Crossref]

A. Baba, J. Lübben, K. Tamada, and W. Knoll, “Optical properties of ultrathin poly(3,4-ethylenedioxythiophene) films at several doping levels studied by in situ electrochemical surface plasmon resonance spectroscopy,” Langmuir 19(21), 9058–9064 (2003).
[Crossref]

1972 (1)

P. B. Johnson and R. W. Christy, “Optical constants of the Noble metals,” Phys. Rev. B 6(12), 4370–4379 (1972).
[Crossref]

Agrawal, A.

S. Heo, A. Agrawal, and D. J. Milliron, “Wide dynamic range in tunable electrochromic Bragg stacks from doped semiconductor nanocrystals,” Adv. Funct. Mater. 29(37), 1904555 (2019).
[Crossref]

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Arsenault, A. C.

A. C. Arsenault, D. P. Puzzo, I. Manners, and G. A. Ozin, “Photonic-crystal full-colour displays,” Nat. Photonics 1(8), 468–472 (2007).
[Crossref]

Atighilorestani, M.

M. Atighilorestani, H. Jiang, and B. Kaminska, “Electrochromic-polymer-based switchable plasmonic color devices using surface-relief nanostructure pixels,” Adv. Opt. Mater. 6(23), 1801179 (2018).
[Crossref]

Baba, A.

A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
[Crossref]

A. Baba, J. Lübben, K. Tamada, and W. Knoll, “Optical properties of ultrathin poly(3,4-ethylenedioxythiophene) films at several doping levels studied by in situ electrochemical surface plasmon resonance spectroscopy,” Langmuir 19(21), 9058–9064 (2003).
[Crossref]

Basu, T.

J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
[Crossref]

Baumberg, J. J.

J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
[Crossref]

Berggren, M.

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

Bohn, C.

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Bonner, C. E.

M. Shahabuddin, T. McDowell, C. E. Bonner, and N. Noginova, “Enhancement of electrochromic polymer switching in plasmonic nanostructured environment,” ACS Appl. Nano Mater. 2(3), 1713–1719 (2019).
[Crossref]

Byers, C. P.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Chang, W.-S.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Chen, X.

G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
[Crossref]

Chiang, I.-K.

Y. J. Liu, X. Ding, S.-C. S. Lin, J. Shi, I.-K. Chiang, and T. J. Huang, “Surface acoustic wave driven light shutters using polymer-dispersed liquid crystals,” Adv. Mater. 23(14), 1656–1659 (2011).
[Crossref]

Christy, R. W.

P. B. Johnson and R. W. Christy, “Optical constants of the Noble metals,” Phys. Rev. B 6(12), 4370–4379 (1972).
[Crossref]

Chu, S.

G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
[Crossref]

Clapp, L.

J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Cormier, S.

J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
[Crossref]

Crispin, X.

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

Cui, Y.

Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
[Crossref]

Dahlin, A. B.

K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
[Crossref]

K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
[Crossref]

De Volder, M. F. L.

J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
[Crossref]

Ding, X.

Y. J. Liu, X. Ding, S.-C. S. Lin, J. Shi, I.-K. Chiang, and T. J. Huang, “Surface acoustic wave driven light shutters using polymer-dispersed liquid crystals,” Adv. Mater. 23(14), 1656–1659 (2011).
[Crossref]

Duan, H.

K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
[Crossref]

Dyer, A. L.

A. L. Dyer, A. M. Österholm, D. E. Shen, K. E. Johnson, and J. R. Reynolds, “Conjugated electrochromic polymers: Structure-driven colour and processing control,” Electrochromic Materials and Devices113–184 (2013).

El-Sayed, M.

P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
[Crossref]

Emilsson, G.

K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
[Crossref]

K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
[Crossref]

Fabiano, S.

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

Feenstra, B. J.

R. A. Hayes and B. J. Feenstra, “Video-speed electronic paper based on electrowetting,” Nature 425(6956), 383–385 (2003).
[Crossref]

Feng, L.

L. Feng, P. Huo, Y. Liang, and T. Xu, “Photonic metamaterial absorbers: Morphology engineering and interdisciplinary applications,” Adv. Mater.1903787 (2019).

Fery, A.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Gao, C.

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

Gao, Z.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

Gardner, D.

Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
[Crossref]

Geldmeier, J. A.

P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
[Crossref]

Gu, P.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Guo, L. J.

T. Xu, Y. K. Wu, X. Luo, and L. J. Guo, “Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging,” Nat. Commun. 1(1), 59 (2010).
[Crossref]

Halas, N. J.

J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
[Crossref]

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Hayes, R. A.

R. A. Hayes and B. J. Feenstra, “Video-speed electronic paper based on electrowetting,” Nature 425(6956), 383–385 (2003).
[Crossref]

He, S.

Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
[Crossref]

Hegde, R. S.

K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
[Crossref]

Heikenfeld, J.

J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Heo, S.

S. Heo, A. Agrawal, and D. J. Milliron, “Wide dynamic range in tunable electrochromic Bragg stacks from doped semiconductor nanocrystals,” Adv. Funct. Mater. 29(37), 1904555 (2019).
[Crossref]

Hoener, B. S.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
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Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
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J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
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C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
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J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
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A. L. Dyer, A. M. Österholm, D. E. Shen, K. E. Johnson, and J. R. Reynolds, “Conjugated electrochromic polymers: Structure-driven colour and processing control,” Electrochromic Materials and Devices113–184 (2013).

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A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
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S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
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A. C. Arsenault, D. P. Puzzo, I. Manners, and G. A. Ozin, “Photonic-crystal full-colour displays,” Nat. Photonics 1(8), 468–472 (2007).
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S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
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P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
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A. L. Dyer, A. M. Österholm, D. E. Shen, K. E. Johnson, and J. R. Reynolds, “Conjugated electrochromic polymers: Structure-driven colour and processing control,” Electrochromic Materials and Devices113–184 (2013).

Ringe, E.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

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J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
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J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Shahabuddin, M.

M. Shahabuddin, T. McDowell, C. E. Bonner, and N. Noginova, “Enhancement of electrochromic polymer switching in plasmonic nanostructured environment,” ACS Appl. Nano Mater. 2(3), 1713–1719 (2019).
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L. Shao, X. Zhuo, and J. Wang, “Advanced plasmonic materials for dynamic color display,” Adv. Mater. 30(16), 1704338 (2018).
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K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
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Shen, D. E.

A. L. Dyer, A. M. Österholm, D. E. Shen, K. E. Johnson, and J. R. Reynolds, “Conjugated electrochromic polymers: Structure-driven colour and processing control,” Electrochromic Materials and Devices113–184 (2013).

Shi, J.

Y. J. Liu, X. Ding, S.-C. S. Lin, J. Shi, I.-K. Chiang, and T. J. Huang, “Surface acoustic wave driven light shutters using polymer-dispersed liquid crystals,” Adv. Mater. 23(14), 1656–1659 (2011).
[Crossref]

Shinbo, K.

A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
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M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
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Smalyukh, I. I.

Y. Zhang, Q. Liu, H. Mundoor, Y. Yuan, and I. I. Smalyukh, “Metal nanoparticle dispersion, alignment, and assembly in nematic liquid crystals for applications in switchable plasmonic color filters and E-polarizers,” ACS Nano 9(3), 3097–3108 (2015).
[Crossref]

Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
[Crossref]

Smith, M. S.

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

Song, Y. Y.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

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A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
[Crossref]

Stavrinidou, E.

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

Sun, B.

J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Sun, N.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Swearer, D. F.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Tada, K.

A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
[Crossref]

Talin, A. A.

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Tamada, K.

A. Baba, J. Lübben, K. Tamada, and W. Knoll, “Optical properties of ultrathin poly(3,4-ethylenedioxythiophene) films at several doping levels studied by in situ electrochemical surface plasmon resonance spectroscopy,” Langmuir 19(21), 9058–9064 (2003).
[Crossref]

Tordera, D.

K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
[Crossref]

Tsuboi, A.

A. Tsuboi, K. Nakamura, and N. Kobayashi, “A localized surface plasmon resonance-based multicolor electrochromic device with electrochemically size-controlled silver nanoparticles,” Adv. Mater. 25(23), 3197–3201 (2013).
[Crossref]

Tsukruk, V. V.

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
[Crossref]

Tybrandt, K.

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

Velmurugan, J.

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Vignolini, S.

J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
[Crossref]

Walter, E. C.

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Wang, G.

G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
[Crossref]

Wang, J.

L. Shao, X. Zhuo, and J. Wang, “Advanced plasmonic materials for dynamic color display,” Adv. Mater. 30(16), 1704338 (2018).
[Crossref]

Wang, L.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Wang, Y.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

Wei, J. N.

K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
[Crossref]

Wei, P.

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

Wong, C.

G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
[Crossref]

Wu, Y. K.

T. Xu, Y. K. Wu, X. Luo, and L. J. Guo, “Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging,” Nat. Commun. 1(1), 59 (2010).
[Crossref]

Xia, X. H.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

Xiong, K.

K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
[Crossref]

K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
[Crossref]

Xu, J.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

Xu, T.

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

T. Xu, Y. K. Wu, X. Luo, and L. J. Guo, “Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging,” Nat. Commun. 1(1), 59 (2010).
[Crossref]

L. Feng, P. Huo, Y. Liang, and T. Xu, “Photonic metamaterial absorbers: Morphology engineering and interdisciplinary applications,” Adv. Mater.1903787 (2019).

Yang, J. K. W.

K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
[Crossref]

Yang, S.

J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Yang, X.

K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
[Crossref]

Yin, Y.

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

Yorulmaz, M.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Yu, L.

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

Yu, S.

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

Yu, Y.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Yuan, Y.

Y. Zhang, Q. Liu, H. Mundoor, Y. Yuan, and I. I. Smalyukh, “Metal nanoparticle dispersion, alignment, and assembly in nematic liquid crystals for applications in switchable plasmonic color filters and E-polarizers,” ACS Nano 9(3), 3097–3108 (2015).
[Crossref]

Zhai, T. T.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

Zhang, G.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Zhang, H.

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Zhang, S.

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

Zhang, W.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Zhang, Y.

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

Y. Zhang, Q. Liu, H. Mundoor, Y. Yuan, and I. I. Smalyukh, “Metal nanoparticle dispersion, alignment, and assembly in nematic liquid crystals for applications in switchable plasmonic color filters and E-polarizers,” ACS Nano 9(3), 3097–3108 (2015).
[Crossref]

Zhao, J.

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

Zheng, B.

J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
[Crossref]

Zhou, J.

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

Zhou, K.

J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Zhou, Z.

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

Zhu, W.

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Zhuo, X.

L. Shao, X. Zhuo, and J. Wang, “Advanced plasmonic materials for dynamic color display,” Adv. Mater. 30(16), 1704338 (2018).
[Crossref]

Zozoulenko, I.

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

ACS Appl. Mater. Interfaces (2)

Z. Zhou, Y. Yu, N. Sun, H. Mohwald, P. Gu, L. Wang, W. Zhang, T. A. F. Konig, A. Fery, and G. Zhang, “Broad-range electrically tunable plasmonic resonances of a multilayer coaxial nanohole array with an electroactive polymer wrapper,” ACS Appl. Mater. Interfaces 9(40), 35244–35252 (2017).
[Crossref]

P. A. Ledin, J. W. Jeon, J. A. Geldmeier, J. F. Ponder, M. A. Mahmoud, M. El-Sayed, J. R. Reynolds, and V. V. Tsukruk, “Design of hybrid electrochromic materials with large electrical modulation of plasmonic resonances,” ACS Appl. Mater. Interfaces 8(20), 13064–13075 (2016).
[Crossref]

ACS Appl. Nano Mater. (1)

M. Shahabuddin, T. McDowell, C. E. Bonner, and N. Noginova, “Enhancement of electrochromic polymer switching in plasmonic nanostructured environment,” ACS Appl. Nano Mater. 2(3), 1713–1719 (2019).
[Crossref]

ACS Nano (4)

J. Xu, J. Xu, Y. Zhang, T. T. Zhai, Z. Kueng, J. Li, Y. Wang, Z. Gao, Y. Y. Song, and X. H. Xia, “Electrochromic-tuned plasmonics for photothermal sterile window,” ACS Nano 12(7), 6895–6903 (2018).
[Crossref]

J. Olson, A. Manjavacas, T. Basu, D. Huang, A. E. Schlather, B. Zheng, N. J. Halas, P. Nordlander, and S. Link, “High chromaticity aluminum plasmonic pixels for active liquid crystal displays,” ACS Nano 10(1), 1108–1117 (2016).
[Crossref]

Y. Zhang, Q. Liu, H. Mundoor, Y. Yuan, and I. I. Smalyukh, “Metal nanoparticle dispersion, alignment, and assembly in nematic liquid crystals for applications in switchable plasmonic color filters and E-polarizers,” ACS Nano 9(3), 3097–3108 (2015).
[Crossref]

G. Wang, X. Chen, S. Liu, C. Wong, and S. Chu, “Mechanical chameleon through dynamic real-time plasmonic tuning,” ACS Nano 10(2), 1788–1794 (2016).
[Crossref]

Adv. Funct. Mater. (2)

A. Baba, K. Tada, R. Janmanee, S. Sriwichai, K. Shinbo, K. Kato, F. Kanoko, and S. Phanichphant,“Controlling surface plasmon optical transmission with an electrochemical switch using conducting polymer thin films,” Adv. Funct. Mater. 22(20), 4383–4388 (2012).
[Crossref]

S. Heo, A. Agrawal, and D. J. Milliron, “Wide dynamic range in tunable electrochromic Bragg stacks from doped semiconductor nanocrystals,” Adv. Funct. Mater. 29(37), 1904555 (2019).
[Crossref]

Adv. Mater. (5)

K. Xiong, G. Emilsson, A. Maziz, X. Yang, L. Shao, E. W. H. Jager, and A. B. Dahlin, “Plasmonic metasurfaces with conjugated polymers for flexible electronic paper in color,” Adv. Mater. 28(45), 9956–9960 (2016).
[Crossref]

M. Berggren, X. Crispin, S. Fabiano, M. P. Jonsson, D. T. Simon, E. Stavrinidou, K. Tybrandt, and I. Zozoulenko, “Ion electron-coupled functionality in materials and devices based on conjugated polymers,” Adv. Mater. 31(22), 1805813 (2019).
[Crossref]

Y. J. Liu, X. Ding, S.-C. S. Lin, J. Shi, I.-K. Chiang, and T. J. Huang, “Surface acoustic wave driven light shutters using polymer-dispersed liquid crystals,” Adv. Mater. 23(14), 1656–1659 (2011).
[Crossref]

A. Tsuboi, K. Nakamura, and N. Kobayashi, “A localized surface plasmon resonance-based multicolor electrochromic device with electrochemically size-controlled silver nanoparticles,” Adv. Mater. 25(23), 3197–3201 (2013).
[Crossref]

L. Shao, X. Zhuo, and J. Wang, “Advanced plasmonic materials for dynamic color display,” Adv. Mater. 30(16), 1704338 (2018).
[Crossref]

Adv. Opt. Mater. (1)

M. Atighilorestani, H. Jiang, and B. Kaminska, “Electrochromic-polymer-based switchable plasmonic color devices using surface-relief nanostructure pixels,” Adv. Opt. Mater. 6(23), 1801179 (2018).
[Crossref]

J. Mater. Chem. C (1)

S. Zhang, S. Yu, J. Zhou, J. F. Ponder, M. S. Smith, J. R. Reynolds, and V. V. Tsukruk, “Heterogeneous forward and backward scattering modulation by polymer-infused plasmonic nanohole arrays,” J. Mater. Chem. C 7(10), 3090–3099 (2019).
[Crossref]

Langmuir (1)

A. Baba, J. Lübben, K. Tamada, and W. Knoll, “Optical properties of ultrathin poly(3,4-ethylenedioxythiophene) films at several doping levels studied by in situ electrochemical surface plasmon resonance spectroscopy,” Langmuir 19(21), 9058–9064 (2003).
[Crossref]

Nano Lett. (2)

K. Xiong, D. Tordera, G. Emilsson, O. Olsson, U. Linderhed, M. P. Jonsson, and A. B. Dahlin, “Switchable plasmonic metasurfaces with high chromaticity containing only abundant metals,” Nano Lett. 17(11), 7033–7039 (2017).
[Crossref]

Q. Liu, Y. Cui, D. Gardner, X. Li, S. He, and I. I. Smalyukh, “Self-alignment of plasmonic gold nanorods in reconfigurable anisotropic fluids for tunable bulk metamaterial applications,” Nano Lett. 10(4), 1347–1353 (2010).
[Crossref]

Nat. Commun. (2)

T. Xu, Y. K. Wu, X. Luo, and L. J. Guo, “Plasmonic nanoresonators for high-resolution colour filtering and spectral imaging,” Nat. Commun. 1(1), 59 (2010).
[Crossref]

T. Xu, E. C. Walter, A. Agrawal, C. Bohn, J. Velmurugan, W. Zhu, H. J. Lezec, and A. A. Talin, “High-contrast and fast electrochromic switching enabled by plasmonics,” Nat. Commun. 7(1), 10479 (2016).
[Crossref]

Nat. Nanotechnol. (1)

K. Kumar, H. Duan, R. S. Hegde, S. C. W. Koh, J. N. Wei, and J. K. W. Yang, “Printing colour at the optical diffraction limit,” Nat. Nanotechnol. 7(9), 557–561 (2012).
[Crossref]

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A. C. Arsenault, D. P. Puzzo, I. Manners, and G. A. Ozin, “Photonic-crystal full-colour displays,” Nat. Photonics 1(8), 468–472 (2007).
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J. Heikenfeld, K. Zhou, E. Kreit, B. Raj, S. Yang, B. Sun, A. Milarcik, L. Clapp, and R. Schwartz, “Electrofluidic displays using Young–Laplace transposition of brilliant pigment dispersions,” Nat. Photonics 3(5), 292–296 (2009).
[Crossref]

Nature (1)

R. A. Hayes and B. J. Feenstra, “Video-speed electronic paper based on electrowetting,” Nature 425(6956), 383–385 (2003).
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Sci. Adv. (2)

J. Peng, H. H. Jeong, Q. Lin, S. Cormier, H. L. Liang, M. F. L. De Volder, S. Vignolini, and J. J. Baumberg, “Scalable electrochromic nanopixels using plasmonics,” Sci. Adv. 5(5), eaaw2205 (2019).
[Crossref]

C. P. Byers, H. Zhang, D. F. Swearer, M. Yorulmaz, B. S. Hoener, D. Huang, A. Hoggard, W.-S. Chang, P. Mulvaney, E. Ringe, N. J. Halas, P. Nordlander, S. Link, and C. F. Landes, “From tunable core-shell nanoparticles to plasmonic drawbridges: Active control of nanoparticle optical properties,” Sci. Adv. 1(11), e1500988 (2015).
[Crossref]

Small (1)

N. Li, P. Wei, L. Yu, J. Ji, J. Zhao, C. Gao, Y. Li, and Y. Yin, “Dynamically switchable multicolor electrochromic films,” Small 15(7), 1804974 (2019).
[Crossref]

Other (2)

L. Feng, P. Huo, Y. Liang, and T. Xu, “Photonic metamaterial absorbers: Morphology engineering and interdisciplinary applications,” Adv. Mater.1903787 (2019).

A. L. Dyer, A. M. Österholm, D. E. Shen, K. E. Johnson, and J. R. Reynolds, “Conjugated electrochromic polymers: Structure-driven colour and processing control,” Electrochromic Materials and Devices113–184 (2013).

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Figures (3)

Fig. 1.
Fig. 1. (a) Schematic illustration of the fabrication process of the PCGN metasurface. (b) and (c) SEM images of the Au nanodisk array and the PCGN metasurface, respectively. The scale bars stand for 500 nm. Insets of (b) and (c) are the optical photographs of the Au nanodisk substrate and the PCGN metasurface, the scale bars stand for 2 mm.
Fig. 2.
Fig. 2. (a) Reflection spectra of the Au nanodisk substrate in air, the PCGN metasurface in air, and the PCGN metasurface in the conductive solution. (b) Electrochromic modulation of the PCGN metasurface: Reflection spectra of the PCGN metasurface with different driven voltages. (c) Reflection spectra of PEDOT film on planar Au substrate driven by voltages ranging from −1 to 1 V. (d) Time resolved electrochromic modulation: the resonant wavelength of the PCGN metasurface with the driven varied voltages switching between 1 and −1 V.
Fig. 3.
Fig. 3. Simulated (a) reflection spectra and (b) electric field distribution plots of the Au nanodisk substrate in air, the oxidation-state PCGN metasurface in the conductive solution, and the reduction-state PCGN in the conductive solution.

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