Abstract

Chalcogenide glasses with a nominal composition of Ga5Ge20Sb10Se(65-x)Tex (x = 0, 10, 20, 25, 30, 32.5, 35, 37.5) were synthesized. Their physico-chemical properties, glass network structure and optical properties are clearly modified via the substitution of selenium by tellurium. Based on a detailed study of the Ga5Ge20Sb10Se(65-x)Tex bulk glasses properties, the Ga5Ge20Sb10Se45Te20 seleno-telluride glass optimal composition has been selected for fiber drawing. The luminescence properties of Tb3+(500 ppm) doped Ga5Ge20Sb10Se65 and Ga5Ge20Sb10Se45Te20 bulk glasses and fibers were studied. Radiative transitions parameters calculated from the Judd-Ofelt theory are compared to the experimental values. Mid-wavelength infrared emission in the range of 4.3-6.0 µm is attributed to the 7F57F6 transition of Tb3+ions with a corresponding experimental lifetime of 8.9 and 7.8 ms for the selenide and seleno-telluride matrix, respectively. The 7F47F6 emission was recorded at 3.1 µm with a good signal-to-noise ratio, evidencing a rather strong emission from the 7F4 manifold. Finally, although it was expected that the phonon energy will be lower for telluride glasses, selenide glasses are still more suitable for mid-wavelength infrared and long wavelength infrared emissions with well-defined emissions from 3.1 to 8 μm.

© 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

Full Article  |  PDF Article
OSA Recommended Articles
Mid-infrared emission properties of Pr3+-doped Ge-Sb-Se-Ga-I chalcogenide glasses

Mingming Li, Yinsheng Xu, Xiaomeng Jia, Lei Yang, Nengbing Long, Zijun Liu, and Shixun Dai
Opt. Mater. Express 8(4) 992-1000 (2018)

7 to 8 µm emission from Sm3+ doped selenide fibers

Florent Starecki, Alain Braud, Nora Abdellaoui, Jean-Louis Doualan, Catherine Boussard-Plédel, Bruno Bureau, Patrice Camy, and Virginie Nazabal
Opt. Express 26(20) 26462-26469 (2018)

Mid-infrared emission in Tb3+-doped selenide glass fiber

L. Sojka, Z. Tang, D. Furniss, H. Sakr, Y. Fang, E. Beres-Pawlik, T. M. Benson, A. B. Seddon, and S. Sujecki
J. Opt. Soc. Am. B 34(3) A70-A79 (2017)

References

  • View by:
  • |
  • |
  • |

  1. S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
    [Crossref] [PubMed]
  2. F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
    [Crossref]
  3. S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
    [Crossref]
  4. S. Cui, C. Boussard-Plédel, J. Troles, and B. Bureau, “Telluride glass single mode fiber for mid and far infrared filtering,” Opt. Mater. Express 6(4), 971–978 (2016).
    [Crossref]
  5. B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
    [Crossref] [PubMed]
  6. V. Shiryaev, M. Churbanov, J.-L. Adam, and X. Zhang, “Chalcogenide waveguide for infrared sensing” in Chalcogenide Glasses (Woodhead Publishing, 2014).
  7. L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.
  8. Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
    [Crossref]
  9. Ł. Sójka, Z. Tang, H. Zhu, E. Bereś-Pawlik, D. Furniss, A. Seddon, T. Benson, and S. Sujecki, “Study of mid-infrared laser action in chalcogenide rare earth doped glass with Dy3+, Pr3+ and Tb3+,” Opt. Mater. Express 2(11), 1632–1640 (2012).
    [Crossref]
  10. M. E. Webber, M. Pushkarsky, and C. K. N. Patel, “Optical detection of chemical warfare agents and toxic industrial chemicals: Simulation,” J. Appl. Phys. 97(11), 113101 (2005).
    [Crossref]
  11. L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
    [Crossref]
  12. F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
    [Crossref] [PubMed]
  13. M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
    [Crossref]
  14. L. Sojka, Z. Tang, D. Furniss, H. Sakr, Y. Fang, E. Beres-Pawlik, T. Benson, A. Seddon, and S. Sujecki, “Mid-infrared emission in Tb3+ doped selenide glass fiber,” J. Opt. Soc. Am. B 34(3), A70–A79 (2017).
    [Crossref]
  15. V. Shiryaev, M. Churbanov, J.-L. Adam, and X. Zhang, “Preparation of high-purity chalcogenide glasses” in Chalcogenide Glasses (Woodhead Publishing, 2014).
  16. R. Hui and M. O’Sullivan, Fiber Optic Measurement Techniques (Academic, 2009), Chap. 4.
  17. I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
    [Crossref]
  18. S. Sugai, “Stochastic random network model in Ge and Si chalcogenide glasses,” Phys. Rev. B Condens. Matter 35(3), 1345–1361 (1987).
    [Crossref] [PubMed]
  19. G. Lucovsky, C. K. Wong, and W. B. Pollard, “Vibrational properties of glasses: Intermediate range order,” J. Non-Cryst. Solids 59–60(Part 2), 839–846 (1983).
    [Crossref]
  20. P. Nemec, B. Frumarová, and M. Frumar, “Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses,” J. Non-Cryst. Solids 270(1-3), 137–146 (2000).
    [Crossref]
  21. K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
    [Crossref]
  22. C. Gonçalves, “Telluride glasses for infrared optics: a structural approach by vibrationnal spectroscopies and NMR,” (Rennes University, 2017).
  23. R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
    [Crossref]
  24. D. R. Goyal and A. S. Maan, “Far-infrared absorption in amorphous Sb15GexSe85 - x glasses,” J. Non-Cryst. Solids 183(1-2), 182–185 (1995).
    [Crossref]
  25. M. D. Rechtin, A. R. Hilton, and D. J. Hayes, “Infrared transmission in GE-SB-SE glasses,” J. Electron. Mater. 4(2), 347–362 (1975).
    [Crossref]
  26. G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
    [Crossref]
  27. V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
    [Crossref]
  28. I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
    [Crossref]
  29. P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
    [Crossref]
  30. S. Sen, E. L. Gjersing, and B. G. Aitken, “Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure,” J. Non-Cryst. Solids 356(41-42), 2083–2088 (2010).
    [Crossref]
  31. A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
    [Crossref]
  32. P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
    [Crossref]
  33. K. S. Andrikopoulos, S. N. Yannopoulos, A. V. Kolobov, P. Fons, and J. Tominaga, Raman Scattering Study of GeTe and Ge2Sb2Te5 Phase-change Materials (Elsevier, 2007).
  34. G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
    [Crossref]
  35. F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
    [Crossref]
  36. Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
    [Crossref]
  37. W. T. Carnall, P. R. Fields, and B. G. Wybourne, “Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. I. Pr3 +, Nd3 +, Er3 +, Tm3 +, and Yb3 +,” J. Chem. Phys. 42(11), 37973 (1965).
    [Crossref]

2018 (2)

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

2017 (1)

2016 (2)

S. Cui, C. Boussard-Plédel, J. Troles, and B. Bureau, “Telluride glass single mode fiber for mid and far infrared filtering,” Opt. Mater. Express 6(4), 971–978 (2016).
[Crossref]

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

2015 (1)

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

2013 (4)

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

2012 (3)

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Ł. Sójka, Z. Tang, H. Zhu, E. Bereś-Pawlik, D. Furniss, A. Seddon, T. Benson, and S. Sujecki, “Study of mid-infrared laser action in chalcogenide rare earth doped glass with Dy3+, Pr3+ and Tb3+,” Opt. Mater. Express 2(11), 1632–1640 (2012).
[Crossref]

2011 (2)

G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
[Crossref]

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

2010 (2)

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

S. Sen, E. L. Gjersing, and B. G. Aitken, “Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure,” J. Non-Cryst. Solids 356(41-42), 2083–2088 (2010).
[Crossref]

2009 (1)

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

2006 (1)

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

2005 (1)

M. E. Webber, M. Pushkarsky, and C. K. N. Patel, “Optical detection of chemical warfare agents and toxic industrial chemicals: Simulation,” J. Appl. Phys. 97(11), 113101 (2005).
[Crossref]

2003 (1)

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

2001 (1)

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

2000 (2)

P. Nemec, B. Frumarová, and M. Frumar, “Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses,” J. Non-Cryst. Solids 270(1-3), 137–146 (2000).
[Crossref]

A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
[Crossref]

1999 (1)

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

1995 (1)

D. R. Goyal and A. S. Maan, “Far-infrared absorption in amorphous Sb15GexSe85 - x glasses,” J. Non-Cryst. Solids 183(1-2), 182–185 (1995).
[Crossref]

1987 (1)

S. Sugai, “Stochastic random network model in Ge and Si chalcogenide glasses,” Phys. Rev. B Condens. Matter 35(3), 1345–1361 (1987).
[Crossref] [PubMed]

1983 (1)

G. Lucovsky, C. K. Wong, and W. B. Pollard, “Vibrational properties of glasses: Intermediate range order,” J. Non-Cryst. Solids 59–60(Part 2), 839–846 (1983).
[Crossref]

1975 (1)

M. D. Rechtin, A. R. Hilton, and D. J. Hayes, “Infrared transmission in GE-SB-SE glasses,” J. Electron. Mater. 4(2), 347–362 (1975).
[Crossref]

1967 (1)

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

1965 (1)

W. T. Carnall, P. R. Fields, and B. G. Wybourne, “Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. I. Pr3 +, Nd3 +, Er3 +, Tm3 +, and Yb3 +,” J. Chem. Phys. 42(11), 37973 (1965).
[Crossref]

Abdellaoui, N.

Adam, J. L.

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Aggarwal, I. D.

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

Aggawal, I. D.

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Aitken, B. G.

S. Sen, E. L. Gjersing, and B. G. Aitken, “Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure,” J. Non-Cryst. Solids 356(41-42), 2083–2088 (2010).
[Crossref]

Akalin, E.

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

Akola, J.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Akyuz, S.

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

Belin, S.

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Benes, L.

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

Benson, T.

Beres-Pawlik, E.

Bernasconi, M.

G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
[Crossref]

Boussard-Pledel, C.

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

Boussard-Plédel, C.

Bouyrie, Y.

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

Braud, A.

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

Briley, A.

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

Bureau, B.

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

S. Cui, C. Boussard-Plédel, J. Troles, and B. Bureau, “Telluride glass single mode fiber for mid and far infrared filtering,” Opt. Mater. Express 6(4), 971–978 (2016).
[Crossref]

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

Camy, P.

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Caravati, S.

G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
[Crossref]

Carnall, W. T.

W. T. Carnall, P. R. Fields, and B. G. Wybourne, “Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. I. Pr3 +, Nd3 +, Er3 +, Tm3 +, and Yb3 +,” J. Chem. Phys. 42(11), 37973 (1965).
[Crossref]

Chahal, R.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

Charpentier, F.

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Charrier, J.

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Churbanov, M. F.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Cole, B.

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

Cui, S.

S. Cui, C. Boussard-Plédel, J. Troles, and B. Bureau, “Telluride glass single mode fiber for mid and far infrared filtering,” Opt. Mater. Express 6(4), 971–978 (2016).
[Crossref]

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

Danto, S.

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

Darpentigny, J.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

Doualan, J.

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Doualan, J. L.

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

Doualan, J.-L.

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

Dussauze, M.

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

Fang, Y.

Fields, P. R.

W. T. Carnall, P. R. Fields, and B. G. Wybourne, “Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. I. Pr3 +, Nd3 +, Er3 +, Tm3 +, and Yb3 +,” J. Chem. Phys. 42(11), 37973 (1965).
[Crossref]

Frumar, M.

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

P. Nemec, B. Frumarová, and M. Frumar, “Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses,” J. Non-Cryst. Solids 270(1-3), 137–146 (2000).
[Crossref]

Frumarová, B.

P. Nemec, B. Frumarová, and M. Frumar, “Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses,” J. Non-Cryst. Solids 270(1-3), 137–146 (2000).
[Crossref]

Furniss, D.

Galagan, B. I.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Garcia-Garcia, E.

A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
[Crossref]

Gjersing, E. L.

S. Sen, E. L. Gjersing, and B. G. Aitken, “Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure,” J. Non-Cryst. Solids 356(41-42), 2083–2088 (2010).
[Crossref]

Gonzalez-Hernandez, J.

A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
[Crossref]

Goyal, D. R.

D. R. Goyal and A. S. Maan, “Far-infrared absorption in amorphous Sb15GexSe85 - x glasses,” J. Non-Cryst. Solids 183(1-2), 182–185 (1995).
[Crossref]

Grossman, S.

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

Guin, J. P.

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Gulbiten, O.

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

Gutwirth, J.

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Harbison, B.

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Hayes, D. J.

M. D. Rechtin, A. R. Hilton, and D. J. Hayes, “Infrared transmission in GE-SB-SE glasses,” J. Electron. Mater. 4(2), 347–362 (1975).
[Crossref]

Hilton, A. R.

M. D. Rechtin, A. R. Hilton, and D. J. Hayes, “Infrared transmission in GE-SB-SE glasses,” J. Electron. Mater. 4(2), 347–362 (1975).
[Crossref]

Holomb, R.

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

Houizot, P.

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

Ingram, A.

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

Jackson, K.

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

Jiang, S.

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

Jones, R. O.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Jovari, P.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Jóvári, P.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Jurdyc, A. M.

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Keezer, R. C.

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

Kryukova, E. B.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Lhermite, H.

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Lucas, J.

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

Lucas, P.

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

Lucovsky, G.

G. Lucovsky, C. K. Wong, and W. B. Pollard, “Vibrational properties of glasses: Intermediate range order,” J. Non-Cryst. Solids 59–60(Part 2), 839–846 (1983).
[Crossref]

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

Luo, T.

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

Ma, H. L.

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

Maan, A. S.

D. R. Goyal and A. S. Maan, “Far-infrared absorption in amorphous Sb15GexSe85 - x glasses,” J. Non-Cryst. Solids 183(1-2), 182–185 (1995).
[Crossref]

Mazzarello, R.

G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
[Crossref]

Mendoza-Galvan, A.

A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
[Crossref]

Michalik, S.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

Michel, K.

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

Mitsa, V.

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

Moizan, V.

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

Moon, J.

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Mooradian, A.

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

Moreac, A.

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Nazabal, V.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Nemec, P.

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

P. Nemec, B. Frumarová, and M. Frumar, “Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses,” J. Non-Cryst. Solids 270(1-3), 137–146 (2000).
[Crossref]

Patel, C. K. N.

M. E. Webber, M. Pushkarsky, and C. K. N. Patel, “Optical detection of chemical warfare agents and toxic industrial chemicals: Simulation,” J. Appl. Phys. 97(11), 113101 (2005).
[Crossref]

Pederson, M. R.

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

Pethes, I.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

Plotnichenko, V. G.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Pollard, W. B.

G. Lucovsky, C. K. Wong, and W. B. Pollard, “Vibrational properties of glasses: Intermediate range order,” J. Non-Cryst. Solids 59–60(Part 2), 839–846 (1983).
[Crossref]

Porezag, D. V.

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

Prestipino, C.

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

Pushkarsky, M.

M. E. Webber, M. Pushkarsky, and C. K. N. Patel, “Optical detection of chemical warfare agents and toxic industrial chemicals: Simulation,” J. Appl. Phys. 97(11), 113101 (2005).
[Crossref]

Pyrkov, Yu. N.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Quetel, L.

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

Rechtin, M. D.

M. D. Rechtin, A. R. Hilton, and D. J. Hayes, “Infrared transmission in GE-SB-SE glasses,” J. Electron. Mater. 4(2), 347–362 (1975).
[Crossref]

Sakr, H.

Sanghera, J. S.

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Schaafsma, D.

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Scripachev, I. V.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Seddon, A.

Sen, S.

S. Sen, E. L. Gjersing, and B. G. Aitken, “Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure,” J. Non-Cryst. Solids 356(41-42), 2083–2088 (2010).
[Crossref]

Shaw, L. B.

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Shiryaev, V. S.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Shpotyuk, O.

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

Shpotyuk, Ya.

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

Sichka, M.

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

Smektala, F.

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

Smetanin, S. V.

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

Sojka, L.

Sójka, L.

Sosso, G. C.

G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
[Crossref]

Starecki, F.

F. Starecki, N. Abdellaoui, A. Braud, J.-L. Doualan, C. Boussard-Plédel, B. Bureau, P. Camy, and V. Nazabal, “8 μm luminescence from a Tb3+ GaGeSbSe fiber,” Opt. Lett. 43(6), 1211–1214 (2018).
[Crossref] [PubMed]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Sugai, S.

S. Sugai, “Stochastic random network model in Ge and Si chalcogenide glasses,” Phys. Rev. B Condens. Matter 35(3), 1345–1361 (1987).
[Crossref] [PubMed]

Sujecki, S.

Tang, Z.

Taylor, W.

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

Thielen, P. A.

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

Troles, J.

S. Cui, C. Boussard-Plédel, J. Troles, and B. Bureau, “Telluride glass single mode fiber for mid and far infrared filtering,” Opt. Mater. Express 6(4), 971–978 (2016).
[Crossref]

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Vasileiadis, T.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Voleska, I.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Vorobiev, Y. V.

A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
[Crossref]

Wagner, T.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Webber, M. E.

M. E. Webber, M. Pushkarsky, and C. K. N. Patel, “Optical detection of chemical warfare agents and toxic industrial chemicals: Simulation,” J. Appl. Phys. 97(11), 113101 (2005).
[Crossref]

Wong, C. K.

G. Lucovsky, C. K. Wong, and W. B. Pollard, “Vibrational properties of glasses: Intermediate range order,” J. Non-Cryst. Solids 59–60(Part 2), 839–846 (1983).
[Crossref]

Wright, G. B.

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

Wybourne, B. G.

W. T. Carnall, P. R. Fields, and B. G. Wybourne, “Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. I. Pr3 +, Nd3 +, Er3 +, Tm3 +, and Yb3 +,” J. Chem. Phys. 42(11), 37973 (1965).
[Crossref]

Yang, Z.

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

Yannopoulos, S. N.

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

Zhang, S.

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

Zhang, X.

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

Zhang, X. H.

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

Zhu, H.

Adv. Funct. Mater. (1)

S. Danto, P. Houizot, C. Boussard-Pledel, X. Zhang, F. Smektala, and J. Lucas, “A Family of Far-Infrared-Transmitting Glasses in the Ga–Ge–Te System for Space Applications,” Adv. Funct. Mater. 16(14), 1847–1852 (2006).
[Crossref]

IEEE J. Quantum Electron. (1)

L. B. Shaw, B. Cole, P. A. Thielen, J. S. Sanghera, and I. D. Aggarwal, “Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber,” IEEE J. Quantum Electron. 37(9), 1127–1137 (2001).
[Crossref]

J. Amer. Cer. Soc. (1)

Z. Yang, O. Gulbiten, P. Lucas, T. Luo, and S. Jiang, “Long-wave infrared-transmitting optical fibers,” J. Amer. Cer. Soc. 94(6), 1761–1765 (2011).
[Crossref]

J. Appl. Phys. (1)

M. E. Webber, M. Pushkarsky, and C. K. N. Patel, “Optical detection of chemical warfare agents and toxic industrial chemicals: Simulation,” J. Appl. Phys. 97(11), 113101 (2005).
[Crossref]

J. Chem. Phys. (1)

W. T. Carnall, P. R. Fields, and B. G. Wybourne, “Spectral Intensities of the Trivalent Lanthanides and Actinides in Solution. I. Pr3 +, Nd3 +, Er3 +, Tm3 +, and Yb3 +,” J. Chem. Phys. 42(11), 37973 (1965).
[Crossref]

J. Electron. Mater. (1)

M. D. Rechtin, A. R. Hilton, and D. J. Hayes, “Infrared transmission in GE-SB-SE glasses,” J. Electron. Mater. 4(2), 347–362 (1975).
[Crossref]

J. Non-Cryst. Solids (7)

R. Holomb, V. Mitsa, E. Akalin, S. Akyuz, and M. Sichka, “Ab initio and Raman study of medium range ordering in GeSe2 glass,” J. Non-Cryst. Solids 373-374, 51–56 (2013).
[Crossref]

D. R. Goyal and A. S. Maan, “Far-infrared absorption in amorphous Sb15GexSe85 - x glasses,” J. Non-Cryst. Solids 183(1-2), 182–185 (1995).
[Crossref]

S. Sen, E. L. Gjersing, and B. G. Aitken, “Physical properties of GexAs2xTe100-3x glasses and Raman spectroscopic analysis of their short-range structure,” J. Non-Cryst. Solids 356(41-42), 2083–2088 (2010).
[Crossref]

I. Pethes, R. Chahal, V. Nazabal, C. Prestipino, S. Michalik, J. Darpentigny, and P. Jóvári, “Chemical order in Ge-Ga-Sb-Se glasses,” J. Non-Cryst. Solids 484, 49–56 (2018).
[Crossref]

G. Lucovsky, C. K. Wong, and W. B. Pollard, “Vibrational properties of glasses: Intermediate range order,” J. Non-Cryst. Solids 59–60(Part 2), 839–846 (1983).
[Crossref]

P. Nemec, B. Frumarová, and M. Frumar, “Structure and properties of the pure and Pr3+-doped Ge25Ga5Se70 and Ge30Ga5Se65 glasses,” J. Non-Cryst. Solids 270(1-3), 137–146 (2000).
[Crossref]

M. F. Churbanov, I. V. Scripachev, V. S. Shiryaev, V. G. Plotnichenko, S. V. Smetanin, E. B. Kryukova, Yu. N. Pyrkov, and B. I. Galagan, “Chalcogenide glasses doped with Tb, Dy and Pr ions,” J. Non-Cryst. Solids 326–327(1), 301–305 (2003).
[Crossref]

J. Opt. Soc. Am. B (1)

Mater. Chem. Phys. (1)

P. Nemec, V. Nazabal, A. Moreac, J. Gutwirth, L. Benes, and M. Frumar, “Amorphous and crystallized Ge-Sb-Te thin films deposited by pulsed laser: Local structure using Raman scattering spectroscopy,” Mater. Chem. Phys. 136(2-3), 935–941 (2012).
[Crossref]

Mater. Lett. (1)

F. Charpentier, F. Starecki, J. Doualan, P. Jóvári, P. Camy, J. Troles, S. Belin, B. Bureau, and V. Nazabal, “Mid-IR luminescence of Dy3+ and Pr3+ doped Ga5Ge20Sb10S(Se)65 bulk glasses and fibers,” Mater. Lett. 101, 21–24 (2013).
[Crossref]

Microelectron. Eng. (1)

A. Mendoza-Galvan, E. Garcia-Garcia, Y. V. Vorobiev, and J. Gonzalez-Hernandez, “Structural, optical and electrical characterization of amorphous SeTe thin film alloys,” Microelectron. Eng. 51–52, 677–687 (2000).
[Crossref]

Molecules (2)

S. Cui, R. Chahal, C. Boussard-Plédel, V. Nazabal, J. L. Doualan, J. Troles, J. Lucas, and B. Bureau, “From selenium- to tellurium-based glass optical fibers for infrared spectroscopies,” Molecules 18(5), 5373–5388 (2013).
[Crossref] [PubMed]

B. Bureau, C. Boussard-Pledel, P. Lucas, X. Zhang, and J. Lucas, “Forming glasses from Se and Te,” Molecules 14(11), 4337–4350 (2009).
[Crossref] [PubMed]

Opt. Lett. (1)

Opt. Mater. Express (2)

Phys. Rev. B (3)

G. C. Sosso, S. Caravati, R. Mazzarello, and M. Bernasconi, “Raman spectra of cubic and amorphous Ge2Sb2Te5 from first principles,” Phys. Rev. B 83(13), 134201 (2011).
[Crossref]

I. Voleska, J. Akola, P. Jovari, J. Gutwirth, T. Wagner, T. Vasileiadis, S. N. Yannopoulos, and R. O. Jones, “Structure, electronic, and vibrational properties of glassy Ga11Ge11Te78: Experimentally constrained density functional study,” Phys. Rev. B 86(9), 094108 (2012).
[Crossref]

K. Jackson, A. Briley, S. Grossman, D. V. Porezag, and M. R. Pederson, “Raman-active modes of α − GeSe2 and α − GeS2 : A first-principles study, ” Phys. Rev. B 60(22), R14985 (1999).
[Crossref]

Phys. Rev. B Condens. Matter (1)

S. Sugai, “Stochastic random network model in Ge and Si chalcogenide glasses,” Phys. Rev. B Condens. Matter 35(3), 1345–1361 (1987).
[Crossref] [PubMed]

RSC Advances (1)

Ya. Shpotyuk, A. Ingram, O. Shpotyuk, C. Boussard-Pledel, V. Nazabal, and B. Bureau, “Effect of rare-earth doping on the free-volume structure of Ga-modified Te20As30Se50 glass,” RSC Advances 6(27), 22797–22802 (2016).
[Crossref]

Sens. Actuators B Chem. (1)

F. Starecki, F. Charpentier, J.-L. Doualan, L. Quetel, K. Michel, R. Chahal, J. Troles, B. Bureau, A. Braud, P. Camy, V. Moizan, and V. Nazabal, “Mid-IR optical sensor for CO2 detection based on fluorescence absorbance of Dy3+:Ga5Ge20Sb10S65 fibers,” Sens. Actuators B Chem. 207, 518–525 (2015).
[Crossref]

Solid State Commun. (1)

G. Lucovsky, A. Mooradian, W. Taylor, G. B. Wright, and R. C. Keezer, “Identification of fundamental vibrational modes of trigonal alpha-monoclinic and amorphous selenium,” Solid State Commun. 5(2), 113–117 (1967).
[Crossref]

Thin Solid Films (2)

V. Nazabal, P. Nemec, A. M. Jurdyc, S. Zhang, F. Charpentier, H. Lhermite, J. Charrier, J. P. Guin, A. Moreac, M. Frumar, and J. L. Adam, “Optical waveguide based on amorphous Er3+-doped Ga-Ge-Sb-S(Se) pulsed laser deposited thin films,” Thin Solid Films 518(17), 4941–4947 (2010).
[Crossref]

P. Nemec, V. Nazabal, M. Dussauze, H. L. Ma, Y. Bouyrie, and X. H. Zhang, “Ga-Ge-Te amorphous thin films fabricated by pulsed laser deposition,” Thin Solid Films 531, 454–459 (2013).
[Crossref]

Other (6)

V. Shiryaev, M. Churbanov, J.-L. Adam, and X. Zhang, “Preparation of high-purity chalcogenide glasses” in Chalcogenide Glasses (Woodhead Publishing, 2014).

R. Hui and M. O’Sullivan, Fiber Optic Measurement Techniques (Academic, 2009), Chap. 4.

C. Gonçalves, “Telluride glasses for infrared optics: a structural approach by vibrationnal spectroscopies and NMR,” (Rennes University, 2017).

K. S. Andrikopoulos, S. N. Yannopoulos, A. V. Kolobov, P. Fons, and J. Tominaga, Raman Scattering Study of GeTe and Ge2Sb2Te5 Phase-change Materials (Elsevier, 2007).

V. Shiryaev, M. Churbanov, J.-L. Adam, and X. Zhang, “Chalcogenide waveguide for infrared sensing” in Chalcogenide Glasses (Woodhead Publishing, 2014).

L. B. Shaw, D. Schaafsma, J. Moon, B. Harbison, J. S. Sanghera, and I. D. Aggawal, “Evaluation of the IR transitions in rare-earth-doped chalcogenide glass,” in Proc. Conf. Lasers and Electro-Optics (OSA), Washington, DC, 1997, p. 255.

Cited By

OSA participates in Crossref's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Figures (7)

Fig. 1
Fig. 1 (a) X-ray diffraction pattern of Ga5Ge20Sb10Se27.5Te37.5 glass-ceramic sample with crystallites of Ga2Te3, GeSb2Te4 and Te, (b) density ( ± 0.01) and Tg ( ± 5°C) versus Te content inGa5Ge20Sb10Se65-xTex glasses.
Fig. 2
Fig. 2 (a) Absorption coefficient α for the 700-2500 nm wavelength domain; inset shows the cut-off wavelength defined at α = 10 cm−1 (b) absorption coefficient in 5-20 µm spectral range.
Fig. 3
Fig. 3 (a) Far-infrared absorption spectra and (b) Raman scattering spectra of bulk Ga5Ge20Sb10Se65-xTexglasses
Fig. 4
Fig. 4 Refractive index dispersion of bulk Ga5Ge20Sb10Se65-xTex glasses
Fig. 5
Fig. 5 Attenuation curves of 500 ppm Tb3+ doped Ga5Ge20Sb10Se65 (blue curve) and Ga5Ge20Sb10Se45Te20 fibers (black curve).
Fig. 6
Fig. 6 (a) Absorption coefficient of 500 ppm Tb3+ doped Ga5Ge20Sb10Se65 andGa5Ge20Sb10Se45Te20 bulk glass and (b) the simplified energy level diagram of Tb3+ ion with expected MWIR and LWIR luminescence transitions.
Fig. 7
Fig. 7 Emission spectra of 500 ppm Tb3+ doped Ga5Ge20Sb10Se65 and Ga5Ge20Sb10Se45Te20 fibers under excitation at λ = 2.05µm: (a) 7F47F6 (3.1 µm) transition; (b) 7F57F6 (4.7 µm) transition; (c) 7F47F5 (8.0 µm); (d) Tb3+ low-lying manifolds energy diagram corresponding to the measured (a), (b) and (c) spectrums.

Tables (2)

Tables Icon

Table 1 Chemical composition of Ga5Ge20Sb10Se(65-x)Tex (x = 0 - 37.5) undoped samples and Ga5Ge20Sb10Se(65-x)Tex (x = 0, 20) doped with Tb3+ (500 ppm), Se-H concentration (ppm) and glass stability criterion ∆T(°C).

Tables Icon

Table 2 Calculated radiative properties of infrared transitions in 500 ppm Tb3+ doped Ga5Ge20Sb10Se65/Ga5Ge20Sb10Se45Te20 glasses for observed emissions centered at wavelength λ, with quantum efficiency η. AEDand AMD stand for spontaneous electronic and magnetic emission rates, respectively. βrad are corresponding branching ratios. τrad and τexp represent radiative and experimental lifetimes, respectively.

Metrics