Abstract

To obtain applicable red phosphor for plant lighting, a series of Ca14Zn6-xMgxGa9.86O35:0.14Mn4+ phosphors were synthesized by a conventional high-temperature solid-state method. The XRD, SEM, excitation and emission spectra, temperature-dependent emission spectra, decay time, internal quantum efficiency and luminous efficiency are investigated with the change of the doping concentration of Mg2+. The experiment results suggest that the luminescence properties and quantum efficiency of the phosphor can by improved by replacing Zn2+ with Mg2+ at appropriate doses, while the thermal resistance performance and decay time declined, and the internal quantum efficiency and luminous efficiency reached its maximum, when the Mg2+ concentration is 0.40. Ultimately, the appropriate doping concentration of Mg2+ was determined at x = 0.40, in which case, the phosphor has a promising application in future plant lighting.

© 2018 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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    [Crossref]
  2. Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
    [Crossref]
  3. Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
    [Crossref] [PubMed]
  4. Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
    [Crossref]
  5. H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
    [Crossref]
  6. Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
    [Crossref]
  7. R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
    [Crossref]
  8. T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
    [Crossref]
  9. G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
    [Crossref]
  10. Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
    [Crossref]
  11. J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
    [Crossref]
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    [Crossref]
  13. Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
    [Crossref]
  14. X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
    [Crossref]
  15. J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
    [Crossref]
  16. L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
    [Crossref]
  17. J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
    [Crossref]
  18. W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
    [Crossref] [PubMed]
  19. T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
    [Crossref]
  20. K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
    [Crossref]
  21. C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
    [Crossref]
  22. Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
    [Crossref]
  23. Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
    [Crossref]
  24. R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
    [Crossref]
  25. J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
    [Crossref]
  26. Y. X. Pan and G. K. Liu, “Influence of Mg2+ on luminescence efficiency and charge compensating mechanism in phosphor CaAl12O19:Mn4+,” J. Lumin. 131(3), 465–468 (2011).
    [Crossref]
  27. J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
    [Crossref] [PubMed]

2018 (6)

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

X. Y. Sun, Z. He, and X. Gu, “Synthesis, deep red emission and warm WLED applications of K2SiF6: Mn4+ phosphors,” J. Photochem. Photobiol. Chem. 350, 69–74 (2018).
[Crossref]

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

2017 (11)

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
[Crossref]

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
[Crossref]

J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
[Crossref]

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

2016 (4)

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

2015 (2)

H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
[Crossref]

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

2014 (2)

K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
[Crossref]

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

2011 (1)

Y. X. Pan and G. K. Liu, “Influence of Mg2+ on luminescence efficiency and charge compensating mechanism in phosphor CaAl12O19:Mn4+,” J. Lumin. 131(3), 465–468 (2011).
[Crossref]

2006 (1)

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Abe, T.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

Ao, H.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Botty, G.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Brik, M. G.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Cao, R.

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Cao, R. P.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Cao, Y.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Chen, D.

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Chen, J.

Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
[Crossref]

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

Chen, T.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

Chen, W.

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

Chen, X.

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Chen, Y.

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

Chen, Z.

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
[Crossref]

Cheng, Y.

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

de With, G.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Delsing, A. C. A.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Deng, J.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

DiSalvo, F. J.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Du, M.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Fu, J.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

Gai, S. J.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Gao, G.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Gao, X.

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

Goldys, E. M.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Gorobez, J.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Gu, X.

X. Y. Sun, Z. He, and X. Gu, “Synthesis, deep red emission and warm WLED applications of K2SiF6: Mn4+ phosphors,” J. Photochem. Photobiol. Chem. 350, 69–74 (2018).
[Crossref]

Guo, B.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

Guo, C.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Guo, S. L.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Guo, Y.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

Hanzawa, H.

H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
[Crossref]

Hasegawa, T.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

He, J.

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

He, Z.

X. Y. Sun, Z. He, and X. Gu, “Synthesis, deep red emission and warm WLED applications of K2SiF6: Mn4+ phosphors,” J. Photochem. Photobiol. Chem. 350, 69–74 (2018).
[Crossref]

Hintzen, H. T.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Horikawa, T.

H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
[Crossref]

Hu, G.

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

Hu, X.

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

Hu, Z. F.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Huang, L.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Huang, S.

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
[Crossref]

Huang, S. X.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Jansen, T.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Ji, Z.

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Jiao, M.

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

Jina, X.

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

Joo, J. S.

J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
[Crossref]

Justel, T.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Khaidukov, N. M.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Kim, H. S.

H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
[Crossref]

Kim, S. W.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

Kirm, M.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Kumagai, S.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

Kwak, M.

J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
[Crossref]

Lei, B.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Li, H.

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

Li, L.

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
[Crossref]

Li, X.

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Li, Y. Q.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Liang, X.

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

Liao, Z.

Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
[Crossref]

Liu, G. K.

Y. X. Pan and G. K. Liu, “Influence of Mg2+ on luminescence efficiency and charge compensating mechanism in phosphor CaAl12O19:Mn4+,” J. Lumin. 131(3), 465–468 (2011).
[Crossref]

Liu, H.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Liu, J.

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

Liu, L.

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

Liu, P.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Liu, Y.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Liu, Z.

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

Long, J.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Lu, X. Y.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Lu, Z. G.

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Lü, W.

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

Luo, Z.

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Lv, W.

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

Ma, C.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Ma, R.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Ma, X.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Machida, K.

H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
[Crossref]

Makhov, V. N.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Meng, Y.

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

Oja, M.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Pan, Y.

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
[Crossref]

Pan, Y. X.

Y. X. Pan and G. K. Liu, “Influence of Mg2+ on luminescence efficiency and charge compensating mechanism in phosphor CaAl12O19:Mn4+,” J. Lumin. 131(3), 465–468 (2011).
[Crossref]

Park, J. Y.

J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
[Crossref]

Peng, Q.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

Qiuc, J.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Quan, G.

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Quan, G. J.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Richards, B. S.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Sato, M.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
[Crossref]

Seki, K.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
[Crossref]

Shao, B.

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

Shi, M.

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

Shi, R.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Shi, Z.

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Shi, Z. H.

R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

Sun, X. Y.

X. Y. Sun, Z. He, and X. Gu, “Synthesis, deep red emission and warm WLED applications of K2SiF6: Mn4+ phosphors,” J. Photochem. Photobiol. Chem. 350, 69–74 (2018).
[Crossref]

Suo, H.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Tang, P.

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Tian, Y.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Toda, K.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
[Crossref]

Uematsu, K.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
[Crossref]

van Krevel, J. W. H.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

van Steen, J. E. J.

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

Vielhauer, S.

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Wan, Y.

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Wang, G. G.

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Wang, J.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Wang, K.

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Wang, L.

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

Wang, N.

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

Wang, Q. F.

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Wang, W.

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Wang, Y.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Q. F. Wang, Y. Liu, Y. Wang, W. Wang, Y. Wan, G. G. Wang, and Z. G. Lu, “Considerable photoluminescence enhancement of LiEu(MoO4)(2) red phosphors via Bi and/or Si doping for white LEDs,” J. Alloys Compd. 625, 355–361 (2015).
[Crossref]

Wang, Z.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Wen, Z.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Wu, M.

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
[Crossref]

Xia, M.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Xia, W.

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

Xiang, W.

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

Xiao, S.

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

Xu, Y.

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

Xuan, T.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

Yamanashi, R.

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

Yang, C.

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

Yang, H. K.

J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
[Crossref]

Yang, X.

X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
[Crossref]

Ye, Y.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

Yi, S.

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

You, H.

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

Yu, J.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

Yu, X.

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
[Crossref]

Yua, C.

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

Yuan, J.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Yuan, X.

J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Yuwen, M.

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

Zhang, H.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Zhang, N.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Zhang, R.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Zhang, X.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

Zhang, Y.

G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
[Crossref]

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
[Crossref]

Zhang, Z.

C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

Zhao, Q.

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
[Crossref] [PubMed]

Zhao, W.

Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
[Crossref]

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
[Crossref]

Zheng, G.

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

Zheng, J.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Zheng, Y.

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
[Crossref]

Zhong, J.

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Zhong, Y.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Zhou, N.

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Zhou, Y.

Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
[Crossref]

Zhou, Z.

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
[Crossref]

Zhu, Y.

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
[Crossref]

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

ACS Appl. Mater. Interfaces (1)

Z. Zhou, J. Zheng, R. Shi, N. Zhang, J. Chen, R. Zhang, H. Suo, E. M. Goldys, and C. Guo, “Abinitiosite occupancy and far-red emission of Mn4+ in cubic-phase La (MgTi)1/2O3 for plant cultivation,” ACS Appl. Mater. Interfaces 9(7), 6177–6185 (2017).
[Crossref] [PubMed]

Ceram. Int. (1)

Z. Liu, M. Yuwen, J. Liu, C. Yua, T. Xuan, and H. Li, “Electrospinning, optical properties and white LED applications of one-dimensional CaAl12O19:Mn4+ nanofiber phosphors,” Ceram. Int. 43(7), 5674–5679 (2017).
[Crossref]

Chem. Lett. (2)

T. Hasegawa, S. W. Kim, T. Abe, S. Kumagai, R. Yamanashi, K. Seki, K. Uematsu, K. Toda, and M. Sato, “Improvement of emission intensity for near-infrared-emitting Ca14Zn6Al10O35:Mn4+ phosphor by oxygen-pressure method,” Chem. Lett. 45(9), 1096–1098 (2016).
[Crossref]

K. Seki, K. Uematsu, K. Toda, and M. Sato, “Novel deep red emitting phosphors Ca14Zn6Al10O35:Mn4+ (M= Al3+ and Ga3+),” Chem. Lett. 43(8), 1213–1215 (2014).
[Crossref]

Dalton Trans. (1)

J. Zhong, D. Chen, X. Chen, K. Wang, X. Li, Y. Zhu, and Z. Ji, “Efficient rare-earth free red-emitting Ca2YSbO6:Mn4+,M(M = Li+, Na+, K+, Mg2+) phosphors for white light-emitting diodes,” Dalton Trans. 47(18), 6528–6537 (2018).
[Crossref] [PubMed]

Dyes Pigments (1)

R. Cao, Y. Ye, Q. Peng, G. Zheng, H. Ao, J. Fu, Y. Guo, and B. Guo, “Synthesis and luminescence characteristics of novel red-emitting Ba2TiGe2O8: Mn4+ phosphor,” Dyes Pigments 146, 14–19 (2017).
[Crossref]

ECS Journal of Solid State Science and Technology (1)

T. Jansen, J. Gorobez, M. Kirm, M. G. Brik, S. Vielhauer, M. Oja, N. M. Khaidukov, V. N. Makhov, and T. Justel, “Narrow Band Deep Red Photoluminescence of Y2Mg3Ge3O12:Mn4+, Li+ Inverse Garnet for High Power Phosphor Converted LED,” ECS Journal of Solid State Science and Technology 7(1), R3086–R3092 (2018).
[Crossref]

Inorg. Chem. (1)

W. Lü, W. Lv, Q. Zhao, M. Jiao, B. Shao, and H. You,”A novel efficient Mn4+ activated Ca14Zn6Al10O35: phosphor: application in red-emitting and white LEDs,” Inorg. Chem. 53(22), 11985–11990 (2014).
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C. Yang, Z. Zhang, G. Hu, R. Cao, X. Liang, and W. Xiang, “A novel deep red phosphor Ca14Zn6Al10O35:Mn4+ as color converter for warm W-LEDs: structure and luminescence properties,” J. Alloys Compd. 694, 1201–1208 (2017).
[Crossref]

Y. Q. Li, J. E. J. van Steen, J. W. H. van Krevel, G. Botty, A. C. A. Delsing, F. J. DiSalvo, G. de With, and H. T. Hintzen, “Luminescence properties of red-emitting M2Si5N8:Eu2+(M = Ca, Sr, Ba) LED conversion phosphors,” J. Alloys Compd. 417(1–2), 273–279 (2006).
[Crossref]

H. S. Kim, K. Machida, T. Horikawa, and H. Hanzawa, “Luminescence properties of CaAlSiN3: Eu2+ phosphor prepared by direct-nitriding method using fine metal hydride powders,” J. Alloys Compd. 633, 97–103 (2015).
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J. Y. Park, J. S. Joo, H. K. Yang, and M. Kwak, “Deep red-emitting Ca14Zn6Al10O35: Mn4+ phosphors for WLED applications,” J. Alloys Compd. 714, 390–396 (2017).
[Crossref]

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R. P. Cao, Z. H. Shi, G. J. Quan, T. Chen, S. L. Guo, Z. F. Hu, and P. Liu, “Preparation and luminescence properties of Li2MgZrO4: Mn4+ red phosphor for plant growth,” J. Lumin. 188, 577–581 (2017).
[Crossref]

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J. Mater. Chem. C (2)

J. Deng, H. Zhang, X. Zhang, Y. Zheng, J. Yuan, H. Liu, Y. Liu, B. Lei, and J. Qiuc, “Ultrastable Red-emitting Phosphor-in-glass for Superior High-power Artificial Plant Growth LEDs,” J. Mater. Chem. C 6(7), 1738–1745 (2018).
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Z. Zhou, M. Xia, Y. Zhong, S. J. Gai, S. X. Huang, Y. Tian, X. Y. Lu, and N. Zhou, “Dy3+@ Mn4+ co-doped Ca14Ga10−mAlmZn6O35 far-red emitting phosphors with high brightness and improved luminescence and energy transfer properties for plant growth LED light,” J. Mater. Chem. C 5(32), 8201–8210 (2017).
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J. Mater. Chem. C Mater. Opt. Electron. Devices (1)

Y. Liu, G. Gao, L. Huang, Y. Zhu, X. Zhang, J. Yu, B. S. Richards, T. Xuan, Z. Wang, and J. Wang, “Co-precipitation synthesis and photoluminescence properties of BaTiF6:Mn4+: an efficient red phosphor for warm white LEDs,” J. Mater. Chem. C Mater. Opt. Electron. Devices 6(1), 127–133 (2018).
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J. Mater. Sci. (1)

J. Chen, W. Zhao, N. Wang, Y. Meng, S. Yi, J. He, and X. Zhang, “Energy transfer properties and temperature-dependent luminescence of Ca14Zn6Al10O35:Dy3+, Mn4+ phosphors,” J. Mater. Sci. 51(9), 4201–4212 (2016).
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J. Mater. Sci. Mater. Electron. (1)

Y. Xu, Y. Zhang, L. Wang, M. Shi, L. Liu, and Y. Chen, “Red emission enhancement for CaAl12O19:Cr3+ and CaAl12O19: Mn4+ phosphors,” J. Mater. Sci. Mater. Electron. 28(16), 12032–12038 (2017).
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G. Hu, X. Hu, W. Chen, Y. Cheng, Z. Liu, Y. Zhang, X. Liang, and W. Xiang, “Luminescence properties and thermal stability of red phosphor Mg2TiO4: Mn4+ additional Zn2+ sensitization for warm W-LEDs,” Mater. Res. Bull. 95, 277–284 (2017).
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Opt. Mater. (1)

R. Cao, Z. Shi, G. Quan, Z. Luo, P. Tang, H. Ao, and X. Yu, “Li3Mg2NbO6: Mn4+ red phosphor for light-emitting diode: Synthesis and luminescence properties,” Opt. Mater. 57, 212–216 (2016).
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RSC Advances (4)

L. Li, Y. Pan, Z. Chen, S. Huang, and M. Wu, “Tunable luminescence and energy transfer properties of Bi3+ and Mn4+ co-doped Ca14Zn6Al10O35 phosphors for agricultural applications,” RSC Advances 7(24), 14868–14875 (2017).
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X. Gao, W. Xia, T. Chen, X. Yang, X. Jina, and S. Xiao, “Conversion of broadband UV-visible light to near infrared emission by Ca14Zn6Al10O35: Mn4+, Nd3+/Yb3+,” RSC Advances 6(9), 7544–7552 (2016).
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J. Long, X. Yuan, C. Ma, M. Du, X. Ma, Z. Wen, R. Ma, Y. Wang, and Y. Cao, “Strongly enhanced luminescence of Sr4Al14O25:Mn4+ phosphor by co-doping B3+ and Na+ ions with red emission for plant growth LEDs,” RSC Advances 8(3), 1469–1476 (2018).
[Crossref]

Y. Zhou, W. Zhao, J. Chen, and Z. Liao, “Highly efficient red emission and multiple energy transfer properties of Dy3+/Mn4+ co-doped Ca14Zn6Al10O35 phosphors,” RSC Advances 7(28), 17244–17253 (2017).
[Crossref]

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Figures (6)

Fig. 1
Fig. 1 (a) XRD patterns of CZMG:Mn4+(x = 0.00, 0.20, 0.40, 0.60, 0.80, 1. 00); (b) Rietveld refinement of the XRD profile CZMG:Mn4+(x = 0.40).
Fig. 2
Fig. 2 SEM image of (a) CZMG:Mn4+ (x = 0.00) and (b) CZMG:Mn4+(x = 0.40).
Fig. 3
Fig. 3 Normalized excitation (a) and emission (b) spectra of CZMG:Mn4+(x = 0.00, 0.20, 0.40, 0.60, 0.80, 1.00).
Fig. 4
Fig. 4 Temperature-dependent emission spectra of (a) CZMG:Mn4+(x = 0.00) and (b) CZMG:Mn4+(x = 0.40) excited at 460 nm, (c) Dependence of ln(I0/IT–1) on 1/kT.
Fig. 5
Fig. 5 Decay curves of CZMG:Mn4+(x = 0.00, 0.20, 0.40, 0.60, 0.80, 1.00) excited at 460 nm.
Fig. 6
Fig. 6 (a). The internal quantum efficiency and luminous efficiency of CZMG:Mn4+ as a function of Mg2+ concentration under 460nm excitation. (b) The electroluminescence spectra of CZMG:Mn4+(x = 0.40) based on 460nm chip under 20 mA current excitation The inset shows the photo of the phosphor coated LED.

Tables (1)

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Table 1 Cell parameters of Ca14Zn6-xMgxGa9.86O35:0.14Mn4+

Equations (4)

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IT=I0[1+cexp(ΔE/kT)]
I=I0exp(t/τ)+A
τ= 1 WR+WNR
ηQE= LS ER ES