Defect-mediated spontaneous emission enhancement of plasmon-coupled CuInS<sub>2</sub> and CuInS<sub>2</sub>/ZnS

Quinton Rice; Sangram Raut; Rahul Chib; Anderson Hayes; Zygmunt Gryczynski; Ignacy Gryczynski; Young-Kuk Kim; Bagher Tabibi; Jaetae Seo

doi:10.1364/OME.6.000566

Defect-mediated spontaneous emission enhancement of plasmon-coupled CuInS₂ and CuInS₂/ZnS

Quinton Rice, Sangram Raut, Rahul Chib, Anderson Hayes, Zygmunt Gryczynski, Ignacy Gryczynski, Young-Kuk Kim, Bagher Tabibi, and Jaetae Seo

Optical Materials Express
Vol. 6,
Issue 2,
pp. 566-577
(2016)
•https://doi.org/10.1364/OME.6.000566

Get Citation
Copy Citation Text
Quinton Rice, Sangram Raut, Rahul Chib, Anderson Hayes, Zygmunt Gryczynski, Ignacy Gryczynski, Young-Kuk Kim, Bagher Tabibi, and Jaetae Seo, "Defect-mediated spontaneous emission enhancement of plasmon-coupled CuInS₂ and CuInS₂/ZnS," Opt. Mater. Express 6, 566-577 (2016)

Export Citation
- BibTex
- Endnote (RIS)
- HTML
- Plain Text
Get PDF (2842 KB)
Set citation alerts
Save article

Related Topics
Table of Contents Category
- Semiconductors
Optics & Photonics Topics
?

The topics in this list come from the OSA Optics and Photonics Topics applied to this article.
Previously assigned OCIS codes
- Optical properties (160.4760)
- Nanomaterials (160.4236)
- Photoluminescence (250.5230)
- Spectroscopy, time-resolved (300.6500)

About this Article
History
- Original Manuscript: August 21, 2015
- Revised Manuscript: October 31, 2015
- Manuscript Accepted: November 18, 2015
- Published: January 21, 2016

Accessible

Open Access

Abstract

The studies of plasmon-coupled excitons at the surface-/interface-, shallow-, and deep-trapped states of copper-indium-disulfide (CIS) with/without zinc-sulfide (ZnS) shell revealed the defect-mediated spontaneous emission enhancement. The PL enhancement with spectral blue-shift of plasmon-coupled excitons in CIS quantum dots (QDs) indicates the large reduction of nonradiative decay at the surface- and shallow-trapped states with strong spectral overlapping. The PL enhancement with spectral red-shift of plasmon-coupled excitons in CIS/ZnS QDs is accredited to the defect-mediated PL enhancement by the higher fractional amplitude at the interface-trapped state around the longer spectral region. The spontaneous emission enhancement of plasmon-coupled CIS QDs were ~2.1, ~2.2, and ~2.8-folds compared to the decay rates of CIS, and those of plasmon-coupled CIS/ZnS QDs were ~24.1, ~32.8, and ~24.9-folds compared to the decay rates of CIS/ZnS at shorter, intermediate, and longer spectral regions due to relatively stable charge carriers and close to the surface plasmon resonance. The PL enhancements of plasmon-coupled CIS at room temperature and 6 K were two-fold and three-fold compared to the integrated CIS PLs, and the PL enhancements of plasmon-coupled CIS/ZnS at room temperature and 6 K were five-fold and eight-fold compared to the integrated CIS/ZnS PLs. The large PL enhancement is attributable to the plasmon-exciton coupling through Coulomb interaction and the local field enhancement. The larger PL enhancement of plasmon-coupled CIS/ZnS compared to that of plasmon-coupled CIS is accredited to the larger spontaneous emission enhancement.

Full Article | PDF Article

OSA Recommended Articles

Hybrid optical materials of plasmon-coupled CdSe/ZnS coreshells for photonic applications

Jaetae Seo, Rafal Fudala, Wan-Joong Kim, Ryan Rich, Bagher Tabibi, Hyoyeong Cho, Zygmunt Gryczynski, Ignacy Gryczynski, and William Yu
Opt. Mater. Express 2(8) 1026-1039 (2012)

Coupling of spontaneous emission from GaN–AlN quantum dots into silver surface plasmons

Arup Neogi, Hadis Morkoç, Takamasa Kuroda, and Atsushi Tackeuchi
Opt. Lett. 30(1) 93-95 (2005)

Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals

Koichi Okamoto, Saurabh Vyawahare, and Axel Scherer
J. Opt. Soc. Am. B 23(8) 1674-1678 (2006)

References

View by:
Article Order
|
Year
|
Author
|
Publication

J. H. Kim and H. Yang, “All-solution-processed, multilayered CuInS₂/ZnS colloidal quantum-dot-based electroluminescent device,” Opt. Lett. 39(17), 5002–5005 (2014).
[Crossref] [PubMed]
W. S. Song, S. H. Lee, and H. Yang, “Fabrication of warm, high CRI white LED using non-cadmium quantum dots,” Opt. Mater. Express 3(9), 1468–1473 (2013).
[Crossref]
J. W. Moon, J. S. Kim, B. G. Min, H. M. Kim, and J. S. Yo, “Optical characteristics and longevity of quantum dot-coated white LED,” Opt. Mater. Express 4(10), 2174–2181 (2014).
[Crossref]
H. Xu, J. Liu, X. Duan, J. Li, J. Xue, X. Sun, Y. Cai, Z. K. Zhou, and X. Wang, “Enhance energy transfer between quantum dots by the surface plasmon of Ag island film,” Opt. Mater. Express 4(12), 2586–2594 (2014).
[Crossref]
J. S. Niezgoda, E. Yap, J. D. Keene, J. R. McBride, and S. J. Rosenthal, “Plasmonic CuxInyS2 quantum dots make better photovoltaics than their nonplasmonic counterparts,” Nano Lett. 14, 3262–3269 (2014).
X. Hu, R. Kang, Y. Zhang, L. Deng, H. Zhong, B. Zou, and L. J. Shi, “Ray-trace simulation of CuInS(Se)₂ quantum dot based luminescent solar concentrators,” Opt. Express 23(15), A858–A867 (2015).
[Crossref] [PubMed]
J. E. Halpert, F. S. F. Morgenstern, B. Ehrler, Y. Vaynzof, D. Credgington, and N. C. Greenham, “Charge dynamics in solution-processed nanocrystalline CuInS2 solar cells,” ACS Nano 9(6), 5857–5867 (2015).
[Crossref] [PubMed]
J. Seo, R. Fudala, W. J. Kim, R. Rich, B. Tabibi, H. Cho, Z. Gryczynski, I. Gryczynski, and W. Yu, “Hybrid optical materials of plasmon-coupled CdSe/ZnS coreshells for photonic applications,” Opt. Mater. Express 2(8), 1026–1039 (2012).
[Crossref] [PubMed]
M. V. Rigo and J. T. Seo, “Probing plasmon polarization-mediated photoluminescence enhancement on metal-semiconductor hybrid optical nanostructures,” Chem. Phys. Lett. 517(4-6), 190–195 (2011).
[Crossref]
I. M. Soganci, S. Nizamoglu, E. Mutlugun, O. Akin, and H. V. Demir, “Localized plasmon-engineered spontaneous emission of CdSe/ZnS nanocrystals closely-packed in the proximity of Ag nanoisland films for controlling emission linewidth, peak, and intensity,” Opt. Express 15(22), 14289–14298 (2007).
[Crossref] [PubMed]
O. Kulakovich, N. Strekal, A. Yaroshevich, S. Maskevich, S. Gaponenko, I. Nabiev, U. Woggon, and M. Artemyev, “Enhanced luminescence of CdSe quantum dots on gold colloids,” Nano Lett. 2(12), 1449–1452 (2002).
[Crossref]
J. H. Song, T. Atay, S. Shi, H. Urabe, and A. V. Nurmikko, “Large enhancement of fluorescence efficiency from CdSe/ZnS quantum dots induced by resonant coupling to spatially controlled surface plasmons,” Nano Lett. 5(8), 1557–1561 (2005).
[Crossref] [PubMed]
K. Okamoto, S. Vyawahare, and A. Scherer, “Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals,” J. Opt. Soc. Am. B 23(8), 1674–1678 (2006).
[Crossref]
Y. Ito, K. Matsuda, and Y. Kanemitsu, “Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,” Phys. Rev. B 75(3), 033309 (2007).
[Crossref]
J. Y. Yan, W. Zhang, S. Duan, X. G. Zhao, and A. O. Govorov, “Optical properties of coupled metal-semiconductor and metal-molecule nanocrystal complexes: Role of multipole effects,” Phys. Rev. B 77(16), 165301 (2008).
[Crossref]
P. Anger, P. Bharadwaj, and L. Novotny, “Enhancement and quenching of single-molecule fluorescence,” Phys. Rev. Lett. 96(11), 113002 (2006).
[Crossref] [PubMed]
W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: Hybrid excitons and the nonlinear Fano Effect,” Phys. Rev. Lett. 97(14), 146804 (2006).
[Crossref] [PubMed]
Y. Wang, T. Yang, M. T. Tuominen, and M. Achermann, “Radiative rate enhancements in ensembles of hybrid metal-semiconductor nanostructures,” Phys. Rev. Lett. 102(16), 163001 (2009).
[Crossref] [PubMed]
J. Seo, S. Raut, M. Abdel-Fattah, Q. Rice, B. Tabibi, R. Rich, R. Fudala, I. Gryczynski, Z. Gryczynski, W. J. Kim, S. Jung, and R. Hyun, “Time-resolved and temperature-dependent photoluminescence of ternary and quaternary nanocrystals of CuInS2 with ZnS capping and cation exchange,” J. Appl. Phys. 114(9), 094310 (2013).
[Crossref]
J. Kolny-Olesiak and H. Weller, “Synthesis and application of colloidal CuInS2 semiconductor nanocrystals,” ACS Appl. Mater. Interfaces 5(23), 12221–12237 (2013).
[Crossref] [PubMed]
Q. Rice, S. Raut, R. Chib, Z. Gryczynski, I. Gryczynski, W. Zhang, X. Zhong, M. Abdel-Fattah, B. Tabibi, and J. Seo, “Fractional contributions of defect-originated photoluminescence from CuInS2/ZnS coreshells for hybrid white LEDs,” J. Nanomater. 2014, 979875 (2014).
[Crossref]
T. Omata, K. Nose, and S. Otsuka-Yao-Matsuo, “Size dependent optical band gap of ternary I-III-VI2 semiconductor nanocrystals,” J. Appl. Phys. 105(7), 073106 (2009).
[Crossref]
D. Li, Y. Zou, and D. Yang, “Controlled synthesis of luminescent CuInS2 nanocrystals and their optical properties,” J. Lumin. 132(2), 313–317 (2012).
[Crossref]
V. K. Komarala, C. Xie, Y. Q. Wang, J. Xu, and M. Xiao, “Time-resolved photoluminescence properties of CuInS2/ZnS nanocrystals: Influence of intrinsic defects and external impurities,” J. Appl. Phys. 111(12), 124314 (2012).
[Crossref]
S. L. Castro, S. G. Bailey, R. P. Raffaelle, K. K. Banger, and A. F. Hepp, “Synthesis and characterization of colloidal CuInS2 nanoparticles from a molecular single-source precursor,” J. Phys. Chem. B 108(33), 12429–12435 (2004).
[Crossref]
H. Y. Ueng and H. L. Hwang, “The defect structure of CuInS2. part I: Intrinsic defects,” J. Phys. Chem. Solids 50(12), 1297–1305 (1989).
[Crossref]
E. M. Purcell, “Spontaneous emission probabilities at radio frequencies,” Phys. Rev. 69, 681 (1946).
J. Kolny-Olesiak and H. Weller, “Synthesis and application of colloidal CuInS2 semiconductor nanocrystals,” ACS Appl. Mater. Interfaces 5(23), 12221–12237 (2013).
[Crossref] [PubMed]
Y. K. Kim, Y. S. Cho, K. Chung, C. J. Choi, and P. W. Shin, “Enhanced luminescence of Cu-In-S nanocrystals by surface modification,” J. Nanosci. Nanotechnol. 12(4), 3438–3442 (2012).
[Crossref] [PubMed]
Y. K. Kim, S. H. Ahn, G. C. Choi, K. Chung, Y. S. Cho, and C. J. Choi, “Photoluminescence of CuInS2/(Cd, Zn)S nanocrystals as a function of shell composition,” Trans. Elec. Electron. Mater. 12(5), 218–221 (2011).
[Crossref]
Y. K. Kim and C. J. Choi, “Tailoring the morphology and the optical properties of semiconductor nanocrystals by alloying,” in Nanocrystal, Dr. Yoshitake Masuda, ed. (InTech, 2011) pp. 373–396.
K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]
J. T. Seo, Q. Yang, W. J. Kim, J. Heo, S. M. Ma, J. Austin, W. S. Yun, S. S. Jung, S. W. Han, B. Tabibi, and D. Temple, “Optical nonlinearities of Au nanoparticles and Au/Ag coreshells,” Opt. Lett. 34(3), 307–309 (2009).
[Crossref] [PubMed]
K. Nose, Y. Soma, T. Omata, and S. Otsuka-Yao-Matsuo, “Synthesis of ternary CuInS2 nanocrystals: Phase determination by complex ligand species,” Chem. Mater. 21(13), 2607–2613 (2009).
[Crossref]
Y. Hamanaka, T. Kuzuya, T. Sofue, T. Kino, K. Ito, and K. Sumiyama, “Defect-induced photoluminescence and third-order nonlinear optical response of chemically synthesized chalcopyrite CuInS2 nanoparticles,” Chem. Phys. Lett. 466(4), 176–180 (2008).
[Crossref]
H. Zhong, Y. Zhou, M. Ye, Y. He, J. Ye, C. He, C. Yang, and Y. Li, “Controlled synthesis and otical properties of colloidal ternary chalcogenide CuInS2 nanocrystals,” Chem. Mater. 20(20), 6434–6443 (2008).
[Crossref]
T. Unold, T. Enzenhofer, and K. Ellmer, “Optical, structural and electronic properties of CuInS2 solar cells deposited by reactive magnetron sputtering,” MRS Proceedings, 865, F16.5 (2005).
[Crossref]
H. Shibata, “Negative thermal quenching curves in photoluminescence of solids,” Jpn. J. Appl. Phys. 37(Part 1), 550–553 (1998).
[Crossref]

2015 (2)

J. E. Halpert, F. S. F. Morgenstern, B. Ehrler, Y. Vaynzof, D. Credgington, and N. C. Greenham, “Charge dynamics in solution-processed nanocrystalline CuInS2 solar cells,” ACS Nano 9(6), 5857–5867 (2015).
[Crossref] [PubMed]

X. Hu, R. Kang, Y. Zhang, L. Deng, H. Zhong, B. Zou, and L. J. Shi, “Ray-trace simulation of CuInS(Se)₂ quantum dot based luminescent solar concentrators,” Opt. Express 23(15), A858–A867 (2015).
[Crossref] [PubMed]

2014 (5)

J. H. Kim and H. Yang, “All-solution-processed, multilayered CuInS₂/ZnS colloidal quantum-dot-based electroluminescent device,” Opt. Lett. 39(17), 5002–5005 (2014).
[Crossref] [PubMed]

J. W. Moon, J. S. Kim, B. G. Min, H. M. Kim, and J. S. Yo, “Optical characteristics and longevity of quantum dot-coated white LED,” Opt. Mater. Express 4(10), 2174–2181 (2014).
[Crossref]

H. Xu, J. Liu, X. Duan, J. Li, J. Xue, X. Sun, Y. Cai, Z. K. Zhou, and X. Wang, “Enhance energy transfer between quantum dots by the surface plasmon of Ag island film,” Opt. Mater. Express 4(12), 2586–2594 (2014).
[Crossref]

J. S. Niezgoda, E. Yap, J. D. Keene, J. R. McBride, and S. J. Rosenthal, “Plasmonic CuxInyS2 quantum dots make better photovoltaics than their nonplasmonic counterparts,” Nano Lett. 14, 3262–3269 (2014).

Q. Rice, S. Raut, R. Chib, Z. Gryczynski, I. Gryczynski, W. Zhang, X. Zhong, M. Abdel-Fattah, B. Tabibi, and J. Seo, “Fractional contributions of defect-originated photoluminescence from CuInS2/ZnS coreshells for hybrid white LEDs,” J. Nanomater. 2014, 979875 (2014).
[Crossref]

2013 (4)

J. Seo, S. Raut, M. Abdel-Fattah, Q. Rice, B. Tabibi, R. Rich, R. Fudala, I. Gryczynski, Z. Gryczynski, W. J. Kim, S. Jung, and R. Hyun, “Time-resolved and temperature-dependent photoluminescence of ternary and quaternary nanocrystals of CuInS2 with ZnS capping and cation exchange,” J. Appl. Phys. 114(9), 094310 (2013).
[Crossref]

J. Kolny-Olesiak and H. Weller, “Synthesis and application of colloidal CuInS2 semiconductor nanocrystals,” ACS Appl. Mater. Interfaces 5(23), 12221–12237 (2013).
[Crossref] [PubMed]

W. S. Song, S. H. Lee, and H. Yang, “Fabrication of warm, high CRI white LED using non-cadmium quantum dots,” Opt. Mater. Express 3(9), 1468–1473 (2013).
[Crossref]

2012 (4)

J. Seo, R. Fudala, W. J. Kim, R. Rich, B. Tabibi, H. Cho, Z. Gryczynski, I. Gryczynski, and W. Yu, “Hybrid optical materials of plasmon-coupled CdSe/ZnS coreshells for photonic applications,” Opt. Mater. Express 2(8), 1026–1039 (2012).
[Crossref] [PubMed]

Y. K. Kim, Y. S. Cho, K. Chung, C. J. Choi, and P. W. Shin, “Enhanced luminescence of Cu-In-S nanocrystals by surface modification,” J. Nanosci. Nanotechnol. 12(4), 3438–3442 (2012).
[Crossref] [PubMed]

D. Li, Y. Zou, and D. Yang, “Controlled synthesis of luminescent CuInS2 nanocrystals and their optical properties,” J. Lumin. 132(2), 313–317 (2012).
[Crossref]

V. K. Komarala, C. Xie, Y. Q. Wang, J. Xu, and M. Xiao, “Time-resolved photoluminescence properties of CuInS2/ZnS nanocrystals: Influence of intrinsic defects and external impurities,” J. Appl. Phys. 111(12), 124314 (2012).
[Crossref]

2011 (2)

Y. K. Kim, S. H. Ahn, G. C. Choi, K. Chung, Y. S. Cho, and C. J. Choi, “Photoluminescence of CuInS2/(Cd, Zn)S nanocrystals as a function of shell composition,” Trans. Elec. Electron. Mater. 12(5), 218–221 (2011).
[Crossref]

M. V. Rigo and J. T. Seo, “Probing plasmon polarization-mediated photoluminescence enhancement on metal-semiconductor hybrid optical nanostructures,” Chem. Phys. Lett. 517(4-6), 190–195 (2011).
[Crossref]

2009 (4)

K. Nose, Y. Soma, T. Omata, and S. Otsuka-Yao-Matsuo, “Synthesis of ternary CuInS2 nanocrystals: Phase determination by complex ligand species,” Chem. Mater. 21(13), 2607–2613 (2009).
[Crossref]

J. T. Seo, Q. Yang, W. J. Kim, J. Heo, S. M. Ma, J. Austin, W. S. Yun, S. S. Jung, S. W. Han, B. Tabibi, and D. Temple, “Optical nonlinearities of Au nanoparticles and Au/Ag coreshells,” Opt. Lett. 34(3), 307–309 (2009).
[Crossref] [PubMed]

T. Omata, K. Nose, and S. Otsuka-Yao-Matsuo, “Size dependent optical band gap of ternary I-III-VI2 semiconductor nanocrystals,” J. Appl. Phys. 105(7), 073106 (2009).
[Crossref]

Y. Wang, T. Yang, M. T. Tuominen, and M. Achermann, “Radiative rate enhancements in ensembles of hybrid metal-semiconductor nanostructures,” Phys. Rev. Lett. 102(16), 163001 (2009).
[Crossref] [PubMed]

2008 (3)

J. Y. Yan, W. Zhang, S. Duan, X. G. Zhao, and A. O. Govorov, “Optical properties of coupled metal-semiconductor and metal-molecule nanocrystal complexes: Role of multipole effects,” Phys. Rev. B 77(16), 165301 (2008).
[Crossref]

Y. Hamanaka, T. Kuzuya, T. Sofue, T. Kino, K. Ito, and K. Sumiyama, “Defect-induced photoluminescence and third-order nonlinear optical response of chemically synthesized chalcopyrite CuInS2 nanoparticles,” Chem. Phys. Lett. 466(4), 176–180 (2008).
[Crossref]

H. Zhong, Y. Zhou, M. Ye, Y. He, J. Ye, C. He, C. Yang, and Y. Li, “Controlled synthesis and otical properties of colloidal ternary chalcogenide CuInS2 nanocrystals,” Chem. Mater. 20(20), 6434–6443 (2008).
[Crossref]

2007 (2)

I. M. Soganci, S. Nizamoglu, E. Mutlugun, O. Akin, and H. V. Demir, “Localized plasmon-engineered spontaneous emission of CdSe/ZnS nanocrystals closely-packed in the proximity of Ag nanoisland films for controlling emission linewidth, peak, and intensity,” Opt. Express 15(22), 14289–14298 (2007).
[Crossref] [PubMed]

Y. Ito, K. Matsuda, and Y. Kanemitsu, “Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,” Phys. Rev. B 75(3), 033309 (2007).
[Crossref]

2006 (3)

P. Anger, P. Bharadwaj, and L. Novotny, “Enhancement and quenching of single-molecule fluorescence,” Phys. Rev. Lett. 96(11), 113002 (2006).
[Crossref] [PubMed]

W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: Hybrid excitons and the nonlinear Fano Effect,” Phys. Rev. Lett. 97(14), 146804 (2006).
[Crossref] [PubMed]

K. Okamoto, S. Vyawahare, and A. Scherer, “Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals,” J. Opt. Soc. Am. B 23(8), 1674–1678 (2006).
[Crossref]

2005 (1)

J. H. Song, T. Atay, S. Shi, H. Urabe, and A. V. Nurmikko, “Large enhancement of fluorescence efficiency from CdSe/ZnS quantum dots induced by resonant coupling to spatially controlled surface plasmons,” Nano Lett. 5(8), 1557–1561 (2005).
[Crossref] [PubMed]

2004 (1)

S. L. Castro, S. G. Bailey, R. P. Raffaelle, K. K. Banger, and A. F. Hepp, “Synthesis and characterization of colloidal CuInS2 nanoparticles from a molecular single-source precursor,” J. Phys. Chem. B 108(33), 12429–12435 (2004).
[Crossref]

2002 (1)

O. Kulakovich, N. Strekal, A. Yaroshevich, S. Maskevich, S. Gaponenko, I. Nabiev, U. Woggon, and M. Artemyev, “Enhanced luminescence of CdSe quantum dots on gold colloids,” Nano Lett. 2(12), 1449–1452 (2002).
[Crossref]

1998 (1)

H. Shibata, “Negative thermal quenching curves in photoluminescence of solids,” Jpn. J. Appl. Phys. 37(Part 1), 550–553 (1998).
[Crossref]

1995 (1)

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]

1989 (1)

H. Y. Ueng and H. L. Hwang, “The defect structure of CuInS2. part I: Intrinsic defects,” J. Phys. Chem. Solids 50(12), 1297–1305 (1989).
[Crossref]

1946 (1)

E. M. Purcell, “Spontaneous emission probabilities at radio frequencies,” Phys. Rev. 69, 681 (1946).

Abdel-Fattah, M.

Achermann, M.

Ahn, S. H.

Akin, O.

Anger, P.

P. Anger, P. Bharadwaj, and L. Novotny, “Enhancement and quenching of single-molecule fluorescence,” Phys. Rev. Lett. 96(11), 113002 (2006).
[Crossref] [PubMed]

Artemyev, M.

Atay, T.

Austin, J.

Bailey, S. G.

Banger, K. K.

Bharadwaj, P.

P. Anger, P. Bharadwaj, and L. Novotny, “Enhancement and quenching of single-molecule fluorescence,” Phys. Rev. Lett. 96(11), 113002 (2006).
[Crossref] [PubMed]

Bryant, G. W.

W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: Hybrid excitons and the nonlinear Fano Effect,” Phys. Rev. Lett. 97(14), 146804 (2006).
[Crossref] [PubMed]

Cai, Y.

Castro, S. L.

Chib, R.

Cho, H.

Cho, Y. S.

Choi, C. J.

Choi, G. C.

Chung, K.

Credgington, D.

Demir, H. V.

Deng, L.

Duan, S.

Duan, X.

Ehrler, B.

Freeman, R. G.

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]

Fudala, R.

Gaponenko, S.

Govorov, A. O.

W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: Hybrid excitons and the nonlinear Fano Effect,” Phys. Rev. Lett. 97(14), 146804 (2006).
[Crossref] [PubMed]

Grabar, K. C.

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]

Greenham, N. C.

Gryczynski, I.

Gryczynski, Z.

Halpert, J. E.

Hamanaka, Y.

Han, S. W.

He, C.

He, Y.

Heo, J.

Hepp, A. F.

Hommer, M. B.

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]

Hu, X.

Hwang, H. L.

H. Y. Ueng and H. L. Hwang, “The defect structure of CuInS2. part I: Intrinsic defects,” J. Phys. Chem. Solids 50(12), 1297–1305 (1989).
[Crossref]

Hyun, R.

Ito, K.

Ito, Y.

Y. Ito, K. Matsuda, and Y. Kanemitsu, “Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,” Phys. Rev. B 75(3), 033309 (2007).
[Crossref]

Jung, S.

Jung, S. S.

Kanemitsu, Y.

Y. Ito, K. Matsuda, and Y. Kanemitsu, “Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,” Phys. Rev. B 75(3), 033309 (2007).
[Crossref]

Kang, R.

Keene, J. D.

Kim, W. J.

Kim, Y. K.

Kino, T.

Kolny-Olesiak, J.

J. Kolny-Olesiak and H. Weller, “Synthesis and application of colloidal CuInS2 semiconductor nanocrystals,” ACS Appl. Mater. Interfaces 5(23), 12221–12237 (2013).
[Crossref] [PubMed]

Komarala, V. K.

Kulakovich, O.

Kuzuya, T.

Lee, S. H.

W. S. Song, S. H. Lee, and H. Yang, “Fabrication of warm, high CRI white LED using non-cadmium quantum dots,” Opt. Mater. Express 3(9), 1468–1473 (2013).
[Crossref]

Li, D.

D. Li, Y. Zou, and D. Yang, “Controlled synthesis of luminescent CuInS2 nanocrystals and their optical properties,” J. Lumin. 132(2), 313–317 (2012).
[Crossref]

Li, J.

Li, Y.

Liu, J.

Ma, S. M.

Maskevich, S.

Matsuda, K.

Y. Ito, K. Matsuda, and Y. Kanemitsu, “Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,” Phys. Rev. B 75(3), 033309 (2007).
[Crossref]

McBride, J. R.

Min, B. G.

J. W. Moon, J. S. Kim, B. G. Min, H. M. Kim, and J. S. Yo, “Optical characteristics and longevity of quantum dot-coated white LED,” Opt. Mater. Express 4(10), 2174–2181 (2014).
[Crossref]

Moon, J. W.

J. W. Moon, J. S. Kim, B. G. Min, H. M. Kim, and J. S. Yo, “Optical characteristics and longevity of quantum dot-coated white LED,” Opt. Mater. Express 4(10), 2174–2181 (2014).
[Crossref]

Morgenstern, F. S. F.

Mutlugun, E.

Nabiev, I.

Natan, M. J.

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]

Niezgoda, J. S.

Nizamoglu, S.

Nose, K.

T. Omata, K. Nose, and S. Otsuka-Yao-Matsuo, “Size dependent optical band gap of ternary I-III-VI2 semiconductor nanocrystals,” J. Appl. Phys. 105(7), 073106 (2009).
[Crossref]

Novotny, L.

P. Anger, P. Bharadwaj, and L. Novotny, “Enhancement and quenching of single-molecule fluorescence,” Phys. Rev. Lett. 96(11), 113002 (2006).
[Crossref] [PubMed]

Nurmikko, A. V.

Okamoto, K.

K. Okamoto, S. Vyawahare, and A. Scherer, “Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals,” J. Opt. Soc. Am. B 23(8), 1674–1678 (2006).
[Crossref]

Omata, T.

T. Omata, K. Nose, and S. Otsuka-Yao-Matsuo, “Size dependent optical band gap of ternary I-III-VI2 semiconductor nanocrystals,” J. Appl. Phys. 105(7), 073106 (2009).
[Crossref]

Otsuka-Yao-Matsuo, S.

T. Omata, K. Nose, and S. Otsuka-Yao-Matsuo, “Size dependent optical band gap of ternary I-III-VI2 semiconductor nanocrystals,” J. Appl. Phys. 105(7), 073106 (2009).
[Crossref]

Purcell, E. M.

E. M. Purcell, “Spontaneous emission probabilities at radio frequencies,” Phys. Rev. 69, 681 (1946).

Raffaelle, R. P.

Raut, S.

Rice, Q.

Rich, R.

Rigo, M. V.

Rosenthal, S. J.

Scherer, A.

K. Okamoto, S. Vyawahare, and A. Scherer, “Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals,” J. Opt. Soc. Am. B 23(8), 1674–1678 (2006).
[Crossref]

Seo, J.

Seo, J. T.

Shi, L. J.

Shi, S.

Shibata, H.

H. Shibata, “Negative thermal quenching curves in photoluminescence of solids,” Jpn. J. Appl. Phys. 37(Part 1), 550–553 (1998).
[Crossref]

Shin, P. W.

Sofue, T.

Soganci, I. M.

Soma, Y.

Song, J. H.

Song, W. S.

W. S. Song, S. H. Lee, and H. Yang, “Fabrication of warm, high CRI white LED using non-cadmium quantum dots,” Opt. Mater. Express 3(9), 1468–1473 (2013).
[Crossref]

Strekal, N.

Sumiyama, K.

Sun, X.

Tabibi, B.

Temple, D.

Tuominen, M. T.

Ueng, H. Y.

H. Y. Ueng and H. L. Hwang, “The defect structure of CuInS2. part I: Intrinsic defects,” J. Phys. Chem. Solids 50(12), 1297–1305 (1989).
[Crossref]

Urabe, H.

Vaynzof, Y.

Vyawahare, S.

K. Okamoto, S. Vyawahare, and A. Scherer, “Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals,” J. Opt. Soc. Am. B 23(8), 1674–1678 (2006).
[Crossref]

Wang, X.

Wang, Y.

Wang, Y. Q.

Weller, H.

J. Kolny-Olesiak and H. Weller, “Synthesis and application of colloidal CuInS2 semiconductor nanocrystals,” ACS Appl. Mater. Interfaces 5(23), 12221–12237 (2013).
[Crossref] [PubMed]

Woggon, U.

Xiao, M.

Xie, C.

Xu, H.

Xu, J.

Xue, J.

Yan, J. Y.

Yang, C.

Yang, D.

D. Li, Y. Zou, and D. Yang, “Controlled synthesis of luminescent CuInS2 nanocrystals and their optical properties,” J. Lumin. 132(2), 313–317 (2012).
[Crossref]

Yang, H.

J. H. Kim and H. Yang, “All-solution-processed, multilayered CuInS₂/ZnS colloidal quantum-dot-based electroluminescent device,” Opt. Lett. 39(17), 5002–5005 (2014).
[Crossref] [PubMed]

W. S. Song, S. H. Lee, and H. Yang, “Fabrication of warm, high CRI white LED using non-cadmium quantum dots,” Opt. Mater. Express 3(9), 1468–1473 (2013).
[Crossref]

Yang, Q.

Yang, T.

Yap, E.

Yaroshevich, A.

Ye, J.

Ye, M.

Yo, J. S.

J. W. Moon, J. S. Kim, B. G. Min, H. M. Kim, and J. S. Yo, “Optical characteristics and longevity of quantum dot-coated white LED,” Opt. Mater. Express 4(10), 2174–2181 (2014).
[Crossref]

Yu, W.

Yun, W. S.

Zhang, W.

W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: Hybrid excitons and the nonlinear Fano Effect,” Phys. Rev. Lett. 97(14), 146804 (2006).
[Crossref] [PubMed]

Zhang, Y.

Zhao, X. G.

Zhong, H.

Zhong, X.

Zhou, Y.

Zhou, Z. K.

Zou, B.

Zou, Y.

D. Li, Y. Zou, and D. Yang, “Controlled synthesis of luminescent CuInS2 nanocrystals and their optical properties,” J. Lumin. 132(2), 313–317 (2012).
[Crossref]

ACS Appl. Mater. Interfaces (2)

J. Kolny-Olesiak and H. Weller, “Synthesis and application of colloidal CuInS2 semiconductor nanocrystals,” ACS Appl. Mater. Interfaces 5(23), 12221–12237 (2013).
[Crossref] [PubMed]

ACS Nano (1)

Anal. Chem. (1)

K. C. Grabar, R. G. Freeman, M. B. Hommer, and M. J. Natan, “Preparation and characterization of Au colloid monolayers,” Anal. Chem. 67(4), 735–743 (1995).
[Crossref]

Chem. Mater. (2)

Chem. Phys. Lett. (2)

J. Appl. Phys. (3)

T. Omata, K. Nose, and S. Otsuka-Yao-Matsuo, “Size dependent optical band gap of ternary I-III-VI2 semiconductor nanocrystals,” J. Appl. Phys. 105(7), 073106 (2009).
[Crossref]

J. Lumin. (1)

D. Li, Y. Zou, and D. Yang, “Controlled synthesis of luminescent CuInS2 nanocrystals and their optical properties,” J. Lumin. 132(2), 313–317 (2012).
[Crossref]

J. Nanomater. (1)

J. Nanosci. Nanotechnol. (1)

J. Opt. Soc. Am. B (1)

K. Okamoto, S. Vyawahare, and A. Scherer, “Surface-plasmon enhanced bright emission from CdSe quantum-dot nanocrystals,” J. Opt. Soc. Am. B 23(8), 1674–1678 (2006).
[Crossref]

J. Phys. Chem. B (1)

J. Phys. Chem. Solids (1)

H. Y. Ueng and H. L. Hwang, “The defect structure of CuInS2. part I: Intrinsic defects,” J. Phys. Chem. Solids 50(12), 1297–1305 (1989).
[Crossref]

Jpn. J. Appl. Phys. (1)

H. Shibata, “Negative thermal quenching curves in photoluminescence of solids,” Jpn. J. Appl. Phys. 37(Part 1), 550–553 (1998).
[Crossref]

Nano Lett. (3)

Opt. Express (2)

Opt. Lett. (2)

J. H. Kim and H. Yang, “All-solution-processed, multilayered CuInS₂/ZnS colloidal quantum-dot-based electroluminescent device,” Opt. Lett. 39(17), 5002–5005 (2014).
[Crossref] [PubMed]

Opt. Mater. Express (4)

J. W. Moon, J. S. Kim, B. G. Min, H. M. Kim, and J. S. Yo, “Optical characteristics and longevity of quantum dot-coated white LED,” Opt. Mater. Express 4(10), 2174–2181 (2014).
[Crossref]

W. S. Song, S. H. Lee, and H. Yang, “Fabrication of warm, high CRI white LED using non-cadmium quantum dots,” Opt. Mater. Express 3(9), 1468–1473 (2013).
[Crossref]

Phys. Rev. (1)

E. M. Purcell, “Spontaneous emission probabilities at radio frequencies,” Phys. Rev. 69, 681 (1946).

Phys. Rev. B (2)

Y. Ito, K. Matsuda, and Y. Kanemitsu, “Mechanism of photoluminescence enhancement in single semiconductor nanocrystals on metal surfaces,” Phys. Rev. B 75(3), 033309 (2007).
[Crossref]

Phys. Rev. Lett. (3)

P. Anger, P. Bharadwaj, and L. Novotny, “Enhancement and quenching of single-molecule fluorescence,” Phys. Rev. Lett. 96(11), 113002 (2006).
[Crossref] [PubMed]

W. Zhang, A. O. Govorov, and G. W. Bryant, “Semiconductor-metal nanoparticle molecules: Hybrid excitons and the nonlinear Fano Effect,” Phys. Rev. Lett. 97(14), 146804 (2006).
[Crossref] [PubMed]

Trans. Elec. Electron. Mater. (1)

Other (2)

Y. K. Kim and C. J. Choi, “Tailoring the morphology and the optical properties of semiconductor nanocrystals by alloying,” in Nanocrystal, Dr. Yoshitake Masuda, ed. (InTech, 2011) pp. 373–396.

T. Unold, T. Enzenhofer, and K. Ellmer, “Optical, structural and electronic properties of CuInS2 solar cells deposited by reactive magnetron sputtering,” MRS Proceedings, 865, F16.5 (2005).
[Crossref]

Cited By

OSA participates in Crossref's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.

Click here to see a list of articles that cite this paper

Fig. 1 (a) Chalcopyrite crystal structure of I-III-VI₂ ternary compound, and its defect structures of CuInS₂ for the shallow- and deep-trapped states; (b) Schematic diagrams of plasmon-exciton coupling and energy transitions and interactions, where ST/IT is the surface trapped/interface trapped states, D_s is the shallow donor state, D_D is the deep donor state, A_S is the shallow acceptor state, and A_D is the deep acceptor state; and (c) Bulk stacks of CIS or CIS/ZnS QDs and Au MNPs ensembles on a micro-glass plate.

Download Full Size | PPT Slide | PDF

Fig. 2 Absorption and PL spectra of (a) CIS and (b) CIS/ZnS, absorption spectrum of plasmonic Au MNPs, and laser excitation spectrum.

Download Full Size | PPT Slide | PDF

Fig. 3 PL intensity decays, residuals, and exponential decay components of CIS and plasmon-coupled CIS on cover glass at (a) 600 nm, (b) 650 nm, and (c) 710 nm. PL intensity decay in logarithm scale at (d) 600 nm, (e) 650 nm, and (f) 710 nm

Download Full Size | PPT Slide | PDF

Fig. 4 PL intensity decays, residuals, and exponential decay components of CIS/ZnS and plasmon-coupled CIS/ZnS on cover glass at (a) 535 nm, (b) 595 nm, and (c) 650 nm. PL intensity decays in logarithm scale at (d) 535 nm, (e) 595 nm, and (f) 650 nm.

Download Full Size | PPT Slide | PDF

Fig. 5 Temperature-dependent PL spectra of CIS and Au-CIS. The red dash line marks around the PL peaks, and the blue dash line indicates the PL peak changes as the temperature changes. Inset: Integrated PL intensity in logarithm scale as a function of the inverse temperature.

Download Full Size | PPT Slide | PDF

Fig. 6 Temperature-dependent PL spectra of CIS/ZnS and Au-CIS/ZnS. The red dash line marks around the PL peaks. Inset: Integrated PL intensity in logarithm scale as a function of the inverse temperature.

Download Full Size | PPT Slide | PDF

Tables (2)

Table 1 PL lifetimes of CIS and plasmon-coupled CIS with three-exponential decays, averaged lifetimes, and their fractional amplitudes at the three spectral regions

View Table | View all tables in this article

Table 2 PL lifetimes of CIS/ZnS and plasmon-coupled CIS/ZnS with three-exponential decays, averaged lifetimes, and their fractional amplitudes at the three spectral regions

View Table | View all tables in this article

Equations (1)

Equations on this page are rendered with MathJax. Learn more.

I_{P L} ~ \frac{1}{1 + T^{3 / 2} \sum_{i} C_{i} \exp (- E_{a c t, i} / k_{B} T)}

CIS	600 nm	650 nm	710 nm
τ₁	4.7 ns (61.0%)	6.8 ns (51.4%)	15.0 ns (24.9%)
τ₁ w/Au	1.7 ns (63.85%)	3.2 ns (57.5%)	5.5 ns (48.3%)
τ₂	19.1 ns (34.8%)	33.4 ns (38.6%)	59.8 ns (44.2%)
τ₂ w/Au	8.5 ns (32.0%)	17.2 ns (35.5%)	32.5 ns (39.1%)
τ₃	86.6 ns (4.3%)	134.0 ns (10.1%)	201.2 ns (30.9%)
τ₃ w/Au	49.9 ns (3.2%)	80.0 ns (7.0%)	137.1 ns (12.6%)
τ_ave	13.2 ns	29.8 ns	92.3 ns
τ_ave w/Au	5.5 ns	13.6 ns	32.7 ns

CIS/ZnS	535 nm	595 nm	650 nm
τ₁	5.9 ns (47.4%)	7.9 ns (37.9%)	3.5 ns (45.2%)
τ₁ w/Au	0.4 ns (78.4%)	0.6 ns (83.7%)	0.6 ns (85.5%)
τ₂	32.9 ns (41.4%)	54.3 ns (41.0%)	41.0 ns (26.3%)
τ₂ w/Au	2.5 ns (19.8%)	4.0 ns (14.5%)	4.6 ns (12.4%)
τ₃	132.3 ns (11.2%)	176.4 ns (21.2%)	183.1 ns (28.5%)
τ₃ w/Au	22.7 ns (1.8%)	53.2 ns (1.9%)	72.0 ns (2.1%)
τ_ave	31.3 ns	65.5 ns	64.7 ns
τ_{ave w/Au}	1.3 ns	2.0 ns	2.6ns

CIS	600 nm	650 nm	710 nm
τ₁	4.7 ns (61.0%)	6.8 ns (51.4%)	15.0 ns (24.9%)
τ₁ w/Au	1.7 ns (63.85%)	3.2 ns (57.5%)	5.5 ns (48.3%)
τ₂	19.1 ns (34.8%)	33.4 ns (38.6%)	59.8 ns (44.2%)
τ₂ w/Au	8.5 ns (32.0%)	17.2 ns (35.5%)	32.5 ns (39.1%)
τ₃	86.6 ns (4.3%)	134.0 ns (10.1%)	201.2 ns (30.9%)
τ₃ w/Au	49.9 ns (3.2%)	80.0 ns (7.0%)	137.1 ns (12.6%)
τ_ave	13.2 ns	29.8 ns	92.3 ns
τ_ave w/Au	5.5 ns	13.6 ns	32.7 ns

CIS/ZnS	535 nm	595 nm	650 nm
τ₁	5.9 ns (47.4%)	7.9 ns (37.9%)	3.5 ns (45.2%)
τ₁ w/Au	0.4 ns (78.4%)	0.6 ns (83.7%)	0.6 ns (85.5%)
τ₂	32.9 ns (41.4%)	54.3 ns (41.0%)	41.0 ns (26.3%)
τ₂ w/Au	2.5 ns (19.8%)	4.0 ns (14.5%)	4.6 ns (12.4%)
τ₃	132.3 ns (11.2%)	176.4 ns (21.2%)	183.1 ns (28.5%)
τ₃ w/Au	22.7 ns (1.8%)	53.2 ns (1.9%)	72.0 ns (2.1%)
τ_ave	31.3 ns	65.5 ns	64.7 ns
τ_{ave w/Au}	1.3 ns	2.0 ns	2.6ns

Abstract

References

2015 (2)

2014 (5)

2013 (4)

2012 (4)

2011 (2)

2009 (4)

2008 (3)

2007 (2)

2006 (3)

2005 (1)

2004 (1)

2002 (1)

1998 (1)

1995 (1)

1989 (1)

1946 (1)

Abdel-Fattah, M.

Achermann, M.

Ahn, S. H.

Akin, O.

Anger, P.

Artemyev, M.

Atay, T.

Austin, J.

Bailey, S. G.

Banger, K. K.

Bharadwaj, P.

Bryant, G. W.

Cai, Y.

Castro, S. L.

Chib, R.

Cho, H.

Cho, Y. S.

Choi, C. J.

Choi, G. C.

Chung, K.

Credgington, D.

Demir, H. V.

Deng, L.

Duan, S.

Duan, X.

Ehrler, B.

Freeman, R. G.

Fudala, R.

Gaponenko, S.

Govorov, A. O.

Grabar, K. C.

Greenham, N. C.

Gryczynski, I.

Gryczynski, Z.

Halpert, J. E.

Hamanaka, Y.

Han, S. W.

He, C.

He, Y.

Heo, J.

Hepp, A. F.

Hommer, M. B.

Hu, X.

Hwang, H. L.

Hyun, R.

Ito, K.

Ito, Y.

Jung, S.

Jung, S. S.

Kanemitsu, Y.

Kang, R.

Keene, J. D.

Kim, H. M.

Kim, J. H.

Kim, J. S.

Kim, W. J.

Kim, Y. K.

Kino, T.

Kolny-Olesiak, J.

Komarala, V. K.

Kulakovich, O.

Kuzuya, T.