Abstract

Bulk samples of Ge-Sb-S-I chalcoiodide glasses of different compositions were prepared by plasma enhanced chemical vapor deposition (PECVD). GeI4, SbI3 and elemental sulfur were the initial substances. Impurities content, optical, and structural properties of the samples were studied. The data obtained were analyzed and compared with the properties of the bulk samples prepared by interaction of the same initial substances into reactive-distillation column at 650°C. The dependence of optical properties of the glasses on preparation technique was discussed.

© 2016 Optical Society of America

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References

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    [Crossref]
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    [Crossref]

2016 (3)

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
[Crossref]

A. V. Vorotyntsev, L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. I. Mashin, and V. M. Vorotyntsev, “PECVD synthesis of As-S glasses,” Russ. J. Appl. Chem. 89(2), 179–184 (2016).
[Crossref]

X. Hang, X.-F. Peng, S.-X. Dai, X. Dong, P.-Q. Zhang, Y.-S. Xu, L. Xing, and Q.-H. Nie, “Raman gain of Ge-Sb-Se chalcogenide glass,” Wuli Xuebao 65(15), 154 (2016).

2015 (5)

2014 (1)

2011 (1)

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

2009 (2)

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

2007 (1)

S.-S. Chu, S.-F. Wang, H.-Z. Tao, Z.-W. Wang, H. Yang, C.-G. Lin, Q.-H. Gong, and X.-J. Zhao, “Large and ultrafast third-order nonlinear optical properties of Ge-S based chalcogenide glasses,” Chin. Phys. Lett. 24(3), 727–729 (2007).
[Crossref]

2006 (2)

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
[Crossref]

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

2004 (1)

2002 (1)

J. M. Harbold, F. O. Ilday, F. W. Wise, and B. G. Aitken, “Highly nonlinear Ge-As-Se and Ge-As-S-Se glasses for all-optical switching,” IEEE Photonics Technol. Lett. 14(6), 822–824 (2002).
[Crossref]

2000 (1)

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

1998 (1)

K. Tanaka and M. Yamaguchi, “Resonant Raman scattering in GeS2,” J. Non-Cryst. Solids 227–230, 757–760 (1998).
[Crossref]

1997 (1)

V. Krasteva, D. Hensley, and G. Sigel., “The effect of compositional variations on the properties of rare-earth doped Ge-S-I chalcohalide glasses,” J. Non-Cryst. Solids 222, 235–242 (1997).
[Crossref]

1990 (1)

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
[Crossref]

1988 (1)

J. S. Sanghera, J. Heo, and J. D. Mackenzie, “Chalcohalide glasses,” J. Non-Cryst. Solids 103(2-3), 155–178 (1988).
[Crossref]

1975 (1)

S. A. Dembovsky and V. V. Kirilenko, “Glass formation and chemical compounds in the systems AIV–BVI–CVII (AIV=Si, Ge; BVI=S, Se; CVII=Br, I),” Glass Phys. Chem. 3, 225–230 (1975).

1970 (1)

C. H. Perry and D. K. Agrawal, “The Raman spectrum of ferroelectric SbSI,” Solid State Commun. 8(4), 225–230 (1970).
[Crossref]

Adam, J.-L.

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

Adamietz, F.

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

Agarwal, A.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

Aggarwal, I. D.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

Agrawal, D. K.

C. H. Perry and D. K. Agrawal, “The Raman spectrum of ferroelectric SbSI,” Solid State Commun. 8(4), 225–230 (1970).
[Crossref]

Aitken, B. G.

J. M. Harbold, F. O. Ilday, F. W. Wise, and B. G. Aitken, “Highly nonlinear Ge-As-Se and Ge-As-S-Se glasses for all-optical switching,” IEEE Photonics Technol. Lett. 14(6), 822–824 (2002).
[Crossref]

Boidin, R.

Boudebs, G.

M. Olivier, P. Němec, G. Boudebs, R. Boidin, C. Focsa, and V. Nazabal, “Photosensitivity of pulsed laser deposited Ge-Sb-Se thin films,” Opt. Mater. Express 5(4), 781–793 (2015).
[Crossref]

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
[Crossref]

Busse, L. E.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

Carlie, N.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
[Crossref]

Chen, F.

Chen, H.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

Chu, S.-S.

S.-S. Chu, S.-F. Wang, H.-Z. Tao, Z.-W. Wang, H. Yang, C.-G. Lin, Q.-H. Gong, and X.-J. Zhao, “Large and ultrafast third-order nonlinear optical properties of Ge-S based chalcogenide glasses,” Chin. Phys. Lett. 24(3), 727–729 (2007).
[Crossref]

Churbanov, M. F.

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
[Crossref]

Cole, B. C.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

Couzi, M.

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
[Crossref]

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

Dai, S.

Dai, S.-X.

X. Hang, X.-F. Peng, S.-X. Dai, X. Dong, P.-Q. Zhang, Y.-S. Xu, L. Xing, and Q.-H. Nie, “Raman gain of Ge-Sb-Se chalcogenide glass,” Wuli Xuebao 65(15), 154 (2016).

Dembovsky, S. A.

S. A. Dembovsky and V. V. Kirilenko, “Glass formation and chemical compounds in the systems AIV–BVI–CVII (AIV=Si, Ge; BVI=S, Se; CVII=Br, I),” Glass Phys. Chem. 3, 225–230 (1975).

Devyatykh, G. G.

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
[Crossref]

Dianov, E. M.

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
[Crossref]

Dong, X.

X. Hang, X.-F. Peng, S.-X. Dai, X. Dong, P.-Q. Zhang, Y.-S. Xu, L. Xing, and Q.-H. Nie, “Raman gain of Ge-Sb-Se chalcogenide glass,” Wuli Xuebao 65(15), 154 (2016).

Focsa, C.

Gai, X.

Gaylord, S.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

Gong, Q.-H.

S.-S. Chu, S.-F. Wang, H.-Z. Tao, Z.-W. Wang, H. Yang, C.-G. Lin, Q.-H. Gong, and X.-J. Zhao, “Large and ultrafast third-order nonlinear optical properties of Ge-S based chalcogenide glasses,” Chin. Phys. Lett. 24(3), 727–729 (2007).
[Crossref]

Hang, X.

X. Hang, X.-F. Peng, S.-X. Dai, X. Dong, P.-Q. Zhang, Y.-S. Xu, L. Xing, and Q.-H. Nie, “Raman gain of Ge-Sb-Se chalcogenide glass,” Wuli Xuebao 65(15), 154 (2016).

Harbold, J. M.

J. M. Harbold, F. O. Ilday, F. W. Wise, and B. G. Aitken, “Highly nonlinear Ge-As-Se and Ge-As-S-Se glasses for all-optical switching,” IEEE Photonics Technol. Lett. 14(6), 822–824 (2002).
[Crossref]

Harrison, B. B.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

Hensley, D.

V. Krasteva, D. Hensley, and G. Sigel., “The effect of compositional variations on the properties of rare-earth doped Ge-S-I chalcohalide glasses,” J. Non-Cryst. Solids 222, 235–242 (1997).
[Crossref]

Heo, J.

J. S. Sanghera, J. Heo, and J. D. Mackenzie, “Chalcohalide glasses,” J. Non-Cryst. Solids 103(2-3), 155–178 (1988).
[Crossref]

Houizot, P.

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

Hu, J.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

Humeau, A.

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
[Crossref]

Ilday, F. O.

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V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
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L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
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Kitao, M.

Koltashev, V. V.

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

Korytin, A. I.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
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Kostrov, A. V.

L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. V. Kostrov, and V. M. Vorotyntsev, “Preparation of Ge-S-I and Ge-Sb-S-I glasses by Plasma-enhanced Chemical Vapor Deposition,” J. Non-Cryst. Solids 423–424, 76–80 (2015).
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V. Krasteva, D. Hensley, and G. Sigel., “The effect of compositional variations on the properties of rare-earth doped Ge-S-I chalcohalide glasses,” J. Non-Cryst. Solids 222, 235–242 (1997).
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Kudryashov, M. A.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
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Kung, F.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
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Lin, C.-G.

S.-S. Chu, S.-F. Wang, H.-Z. Tao, Z.-W. Wang, H. Yang, C.-G. Lin, Q.-H. Gong, and X.-J. Zhao, “Large and ultrafast third-order nonlinear optical properties of Ge-S based chalcogenide glasses,” Chin. Phys. Lett. 24(3), 727–729 (2007).
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Lobanov, A. S.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
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A. V. Vorotyntsev, L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. I. Mashin, and V. M. Vorotyntsev, “PECVD synthesis of As-S glasses,” Russ. J. Appl. Chem. 89(2), 179–184 (2016).
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L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. V. Kostrov, and V. M. Vorotyntsev, “Preparation of Ge-S-I and Ge-Sb-S-I glasses by Plasma-enhanced Chemical Vapor Deposition,” J. Non-Cryst. Solids 423–424, 76–80 (2015).
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Luther-Davies, B.

Mackenzie, J. D.

J. S. Sanghera, J. Heo, and J. D. Mackenzie, “Chalcohalide glasses,” J. Non-Cryst. Solids 103(2-3), 155–178 (1988).
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Madden, S.

Maeda, S.

Malkov, Yu. A.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
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Mashin, A. I.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
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A. V. Vorotyntsev, L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. I. Mashin, and V. M. Vorotyntsev, “PECVD synthesis of As-S glasses,” Russ. J. Appl. Chem. 89(2), 179–184 (2016).
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Massera, J.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
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Miklos, R.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
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Minakata, M.

Mochalov, L. A.

A. V. Vorotyntsev, L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. I. Mashin, and V. M. Vorotyntsev, “PECVD synthesis of As-S glasses,” Russ. J. Appl. Chem. 89(2), 179–184 (2016).
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D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
[Crossref]

L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. V. Kostrov, and V. M. Vorotyntsev, “Preparation of Ge-S-I and Ge-Sb-S-I glasses by Plasma-enhanced Chemical Vapor Deposition,” J. Non-Cryst. Solids 423–424, 76–80 (2015).
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Mossadegh, R.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
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Murzanev, A. A.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
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Nazabal, V.

Nemec, P.

Nezhdanov, A. V.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
[Crossref]

A. V. Vorotyntsev, L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. I. Mashin, and V. M. Vorotyntsev, “PECVD synthesis of As-S glasses,” Russ. J. Appl. Chem. 89(2), 179–184 (2016).
[Crossref]

L. A. Mochalov, A. S. Lobanov, A. V. Nezhdanov, A. V. Kostrov, and V. M. Vorotyntsev, “Preparation of Ge-S-I and Ge-Sb-S-I glasses by Plasma-enhanced Chemical Vapor Deposition,” J. Non-Cryst. Solids 423–424, 76–80 (2015).
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Nguyen, V. Q.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
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Nie, Q.-H.

X. Hang, X.-F. Peng, S.-X. Dai, X. Dong, P.-Q. Zhang, Y.-S. Xu, L. Xing, and Q.-H. Nie, “Raman gain of Ge-Sb-Se chalcogenide glass,” Wuli Xuebao 65(15), 154 (2016).

Ogusu, K.

Olivier, M.

Peng, X.-F.

X. Hang, X.-F. Peng, S.-X. Dai, X. Dong, P.-Q. Zhang, Y.-S. Xu, L. Xing, and Q.-H. Nie, “Raman gain of Ge-Sb-Se chalcogenide glass,” Wuli Xuebao 65(15), 154 (2016).

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C. H. Perry and D. K. Agrawal, “The Raman spectrum of ferroelectric SbSI,” Solid State Commun. 8(4), 225–230 (1970).
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Petit, L.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
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Plekhovich, A. D.

A. P. Velmuzhov, M. V. Sukhanov, A. D. Plekhovich, A. I. Suchkov, and V. S. Shiryaev, “Thermal decomposition study of GeSI2 and Ge2S3I2 glassy alloys,” J. Non-Cryst. Solids 411, 40–44 (2015).
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Plotnichenko, V. G.

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
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Potapov, A. M.

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

Pureza, P. C.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
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Qiao, B.

Richardson, K.

L. Petit, N. Carlie, H. Chen, S. Gaylord, J. Massera, G. Boudebs, J. Hu, A. Agarwal, L. Kimerling, and K. Richardson, “Compositional dependence of the nonlinear refractive index of new germanium-based chalcogenide glasses,” J. Solid State Chem. 182(10), 2756–2761 (2009).
[Crossref]

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
[Crossref]

Richardson, K. C.

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

Rodriguez, V.

L. Petit, N. Carlie, F. Adamietz, M. Couzi, V. Rodriguez, and K. C. Richardson, “Correlation between physical, optical and structural properties of sulfide glasses in the system Ge–Sb–S,” Mater. Chem. Phys. 97(1), 64–70 (2006).
[Crossref]

Roselle, D.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

Sanghera, J. S.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

J. S. Sanghera, J. Heo, and J. D. Mackenzie, “Chalcohalide glasses,” J. Non-Cryst. Solids 103(2-3), 155–178 (1988).
[Crossref]

Scripachev, I. V.

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
[Crossref]

Shaposhnikov, R. M.

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

Shaw, L. B.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
[Crossref]

Shen, X.

Shipunov, V. A.

G. G. Devyatykh, M. F. Churbanov, I. V. Scripachev, V. A. Shipunov, E. M. Dianov, and V. G. Plotnichenko, ““Heterophase impurity inclusions in chalcogenide glass optical fibers”, Proc. SPIE. 1228 Infrared Fibers II, 116–126 (1990).
[Crossref]

Shiryaev, V. S.

A. P. Velmuzhov, M. V. Sukhanov, A. D. Plekhovich, A. I. Suchkov, and V. S. Shiryaev, “Thermal decomposition study of GeSI2 and Ge2S3I2 glassy alloys,” J. Non-Cryst. Solids 411, 40–44 (2015).
[Crossref]

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

Sibirkin, A. A.

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

Sigel, G.

V. Krasteva, D. Hensley, and G. Sigel., “The effect of compositional variations on the properties of rare-earth doped Ge-S-I chalcohalide glasses,” J. Non-Cryst. Solids 222, 235–242 (1997).
[Crossref]

Stepanov, A. N.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
[Crossref]

Suchkov, A. I.

A. P. Velmuzhov, M. V. Sukhanov, A. D. Plekhovich, A. I. Suchkov, and V. S. Shiryaev, “Thermal decomposition study of GeSI2 and Ge2S3I2 glassy alloys,” J. Non-Cryst. Solids 411, 40–44 (2015).
[Crossref]

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

Sukhanov, M. V.

A. P. Velmuzhov, M. V. Sukhanov, A. D. Plekhovich, A. I. Suchkov, and V. S. Shiryaev, “Thermal decomposition study of GeSI2 and Ge2S3I2 glassy alloys,” J. Non-Cryst. Solids 411, 40–44 (2015).
[Crossref]

Talley, D.

J. S. Sanghera, L. B. Shaw, L. E. Busse, V. Q. Nguyen, P. C. Pureza, B. C. Cole, B. B. Harrison, I. D. Aggarwal, R. Mossadegh, F. Kung, D. Talley, D. Roselle, and R. Miklos, “Development and infrared applications of chalcogenide glass optical fibers,” Fiber Integr. Opt. 19(3), 251–274 (2000).
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Tanaka, K.

K. Tanaka and M. Yamaguchi, “Resonant Raman scattering in GeS2,” J. Non-Cryst. Solids 227–230, 757–760 (1998).
[Crossref]

Tao, H.-Z.

S.-S. Chu, S.-F. Wang, H.-Z. Tao, Z.-W. Wang, H. Yang, C.-G. Lin, Q.-H. Gong, and X.-J. Zhao, “Large and ultrafast third-order nonlinear optical properties of Ge-S based chalcogenide glasses,” Chin. Phys. Lett. 24(3), 727–729 (2007).
[Crossref]

Troles, J.

V. S. Shiryaev, J. Troles, P. Houizot, L. A. Ketkova, M. F. Churbanov, J.-L. Adam, and A. A. Sibirkin, “Preparation of optical fibers based on Ge–Sb–S glass system,” Opt. Mater. 32(2), 362–367 (2009).
[Crossref]

Velmuzhov, A. P.

D. A. Yashunin, A. P. Velmuzhov, A. V. Nezhdanov, A. A. Murzanev, Yu. A. Malkov, M. A. Kudryashov, A. I. Mashin, L. A. Mochalov, A. S. Lobanov, A. I. Korytin, A. V. Vorotyntsev, V. M. Vorotyntsev, and A. N. Stepanov, “Comparative study of nonlinear optical properties of Ge-S-I glasses with different macrocompositions,” J. Non-Cryst. Solids 453, 84–87 (2016).
[Crossref]

A. P. Velmuzhov, M. V. Sukhanov, A. D. Plekhovich, A. I. Suchkov, and V. S. Shiryaev, “Thermal decomposition study of GeSI2 and Ge2S3I2 glassy alloys,” J. Non-Cryst. Solids 411, 40–44 (2015).
[Crossref]

A. P. Velmuzhov, A. A. Sibirkin, V. S. Shiryaev, M. F. Churbanov, A. I. Suchkov, A. M. Potapov, R. M. Shaposhnikov, V. G. Plotnichenko, and V. V. Koltashev, “Preparation of Ge-Sb-S-I glass system via volatile Iodides,” Optoelectron. Adv. Mater. Rapid Commun. 13(8), 936–939 (2011).

Villeneuve, R.

L. Petit, N. Carlie, R. Villeneuve, J. Massera, M. Couzi, A. Humeau, G. Boudebs, and K. Richardson, “Effect of the substitution of S for Se on the structure and non-linear optical properties of the glasses in the system Ge0.18Ga0.05Sb0.07S0.70−xSex,” J. Non-Cryst. Solids 352(50-51), 5413–5420 (2006).
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Vorotyntsev, A. V.

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Figures (4)

Fig. 1
Fig. 1

The Raman spectra of Sb-S-I bulk samples, prepared by PECVD.

Fig. 2
Fig. 2

Raman spectra of Ge-Sb-S-I bulk samples, prepared by thermal method (a) and PECVD method (b).

Fig. 3
Fig. 3

IR spectra of Ge-Sb-S-I bulk samples, prepared by thermal method (a) and PECVD method (b).

Fig. 4
Fig. 4

Chromato-mass-spectroscopic date of the concentration of CO2 in the exhausted gas mixtures (1 – PECVD preparation; 2 – thermal preparation).

Tables (2)

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Table 1 Chemical content of Ge-Sb-S-I glasses, at.%.

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Table 2 Comparison of metal impurity content into bulk samples, prepared by different methods.

Equations (2)

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8S ( ring ) 8S
C + O 2 = CO 2

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