Abstract

A white-light hydrotalcite-like compound (Eu/Tb/Zn-HTlc) fabricated from Eu, Tb, and Zn complexes co-doped into magnesium-aluminum hydrotalcite (MgAl-LDH) was prepared by a simple one-pot chemical method. The structural and luminescent properties of Eu/Tb/Zn-HTlc were investigated. Excited by 370 nm UV light, the simultaneous emission bands of this single-matrix material are located in the red, green, and blue regions, combined to give a pure white emission (CIE x = 0.346 and y = 0.3339). This research represents a new strategy for designing layered organic-inorganic hybrid materials for LED-pumped white light.

© 2012 OSA

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  2. E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
    [CrossRef] [PubMed]
  3. X. M. Zhang, J. Wang, H. Wu, J. H. Zhang, and Q. Su, “One-step synthesis and double emission (Ca1 + x − yEuy)Ga2S4 + x phosphor for white LEDs,” Mater. Lett.63(2), 340–342 (2009).
    [CrossRef]
  4. X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
    [CrossRef]
  5. M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
    [CrossRef] [PubMed]
  6. M. A. Zaitoun and S. Al-Tarawneh, “Effect of varying lanthanide local coordination sphere on luminescence properties illustrated by selected inorganic and organic rare earth complexes synthesized in sol–gel host glasses,” J. Lumin.131(8), 1795–1801 (2011).
    [CrossRef]
  7. B. Kokuoz, C. Kucera, J. R. DiMaio, and J. Ballato, “Organic–inorganic hybrid nanoparticles with enhanced rare-earth emissions,” Opt. Mater.31(9), 1327–1330 (2009).
    [CrossRef]
  8. Y. Zhao and B. Yan, “Photoluminescent properties of novel rare earth organic-inorganic nanocomposite with TiO2 modified silica via double crosslinking units,” Photochem. Photobiol.88(1), 21–31 (2012).
    [CrossRef] [PubMed]
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    [CrossRef]
  10. M. Verónica, B. Graciela, A. Norma, and L. Miguel, “Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor,” Chem. Eng. J.138(1-3), 602–607 (2008).
    [CrossRef]
  11. M. C. Hermosín, I. Pavlovic, M. A. Ulibarri, and J. Cornejo, “Hydrotalcite as sorbent for trinitrophenol: Sorption capacity and mechanism,” Water Res.30(1), 171–177 (1996).
    [CrossRef]
  12. F. Leroux and J.-P. Besse, “Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites,” Chem. Mater.13(10), 3507–3515 (2001).
    [CrossRef]
  13. T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
    [CrossRef] [PubMed]
  14. S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
    [CrossRef]
  15. J. C. Liu, S. X. Lian, A. L. Zhu, Q.H. Li, L.M. Liu, and L.H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chinese J. Lumin.28(1), 67–73 (2007).
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  17. J. Hu, H. Zhao, Q. J. Zhang, and W. D. He, “Synthesis and characterization of submicron PMMA Particles containing rare earth ions on the surface,” J. Appl. Polym. Sci.89(4), 1124–1131 (2003).
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    [CrossRef]
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    [CrossRef]
  20. M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
    [CrossRef]
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    [CrossRef]
  22. J. Das, D. Das, and K. M. Parida, “Preparation and characterization of Mg-Al hydrotalcite-like compounds containing cerium,” J. Colloid Interface Sci.301(2), 569–574 (2006).
    [CrossRef] [PubMed]
  23. W. F. Lee and S. C. Lee, “Effect of hydrotalcite on the swelling and mechanical behaviors for the hybrid nanocomposite hydrogels based on gelatin and hydrotalcite,” J. Appl. Polym. Sci.100(1), 500–507 (2006).
    [CrossRef]
  24. L. Z. Qiu, W. Chen, and B. J. Qu, “Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites,” Polymer (Guildf.)47(3), 922–930 (2006).
    [CrossRef]
  25. F. B. D. Saiah, B.-L. Su, and N. Bettahar, “Removal of Evans Blue by using Nickel-iron layered double hydroxide (LDH) nanoparticles: effect of hydrothermal treatment temperature on textural properties and dye adsorption,” Macromol. Symp.273(1), 125–134 (2008).
    [CrossRef]
  26. S. Gupta, D. D. Agarwal, and S. Banerjee, “Synergistic combination of metal stearates and β-diketones with hydrotalcites in poly(vinyl chloride) stabilization,” J. Appl. Polym. Sci.112(2), 1056–1062 (2009).
    [CrossRef]
  27. M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon, and C. J. Serna, “IR characteristics of hydrotalcite-like compounds,” Phys. Chem. Miner.12(1), 34–38 (1985).
  28. G. J. Gou, P. H. Ma, and M. X. Chu, “Dynamics of intercalation of B4O5 (OH) 2-4 anion into layered double hydroxides intercalated by Cl- anion,” Chem. J. Chin. Univ.26(3), 497–502 (2005).
  29. J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).
  30. W. T. Cheng, S. L. Wang, and S. Y. Lin, “Solid-state interaction study on the captopril/lubricants systems accelerated by grinding process,” J. Phys. Chem. Solids69(4), 1007–1016 (2008).
    [CrossRef]
  31. Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
    [CrossRef]
  32. L. R. Xiao, F. Gao, J. Y. Tang, and W. G. Zhang, “Study on the Eu-containing coordination polymer. structural characterization of Eu (III)- thienyltrifluoroacetone-poly(styrene-acrylic acid),” Spectrosc. Spect. Anal.24(6), 756–761 (2004).
  33. J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
    [CrossRef]
  34. S. P. Newman and W. Jones, “Synthesis, characterization and applications of layered double hydroxides containing organic guests,” New J. Chem.22(2), 105–115 (1998).
    [CrossRef]
  35. R. Trujillano, M. J. Holgado, F. Pigazo, and V. Rives, “Preparation, physicochemical characterisation and magnetic properties of Cu-Al layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer,” Physica B373(2), 267–273 (2006).
    [CrossRef]
  36. M. Milanova, J. Zaharieva, I. Manolov, M. Getzova, and D. Todorovsky, “Lanthanide complexes with β-diketones and coumarin derivates: synthesis, thermal behaviour, optical and pharmacological properties and immobilization,” J. Rare Earths28, 66–74 (2010).
    [CrossRef]
  37. P. S. Bassi, P. C. Kalsi, and C. M. Khajuria, “Thermal decomposition of zinc(II) salicylate dihydrate,” Thermochim. Acta34(1), 183–188 (1979).
    [CrossRef]

2012

Y. Zhao and B. Yan, “Photoluminescent properties of novel rare earth organic-inorganic nanocomposite with TiO2 modified silica via double crosslinking units,” Photochem. Photobiol.88(1), 21–31 (2012).
[CrossRef] [PubMed]

2011

M. A. Zaitoun and S. Al-Tarawneh, “Effect of varying lanthanide local coordination sphere on luminescence properties illustrated by selected inorganic and organic rare earth complexes synthesized in sol–gel host glasses,” J. Lumin.131(8), 1795–1801 (2011).
[CrossRef]

X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

2010

A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
[CrossRef]

M. Milanova, J. Zaharieva, I. Manolov, M. Getzova, and D. Todorovsky, “Lanthanide complexes with β-diketones and coumarin derivates: synthesis, thermal behaviour, optical and pharmacological properties and immobilization,” J. Rare Earths28, 66–74 (2010).
[CrossRef]

2009

P. Gunawan and R. Xu, “Lanthanide-doped layered double hydroxides intercalated with sensitizing anions: efficient energy transfer between host and guest layers,” J. Phys. Chem. C113(39), 17206–17214 (2009).
[CrossRef]

S. Gupta, D. D. Agarwal, and S. Banerjee, “Synergistic combination of metal stearates and β-diketones with hydrotalcites in poly(vinyl chloride) stabilization,” J. Appl. Polym. Sci.112(2), 1056–1062 (2009).
[CrossRef]

M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
[CrossRef] [PubMed]

B. Kokuoz, C. Kucera, J. R. DiMaio, and J. Ballato, “Organic–inorganic hybrid nanoparticles with enhanced rare-earth emissions,” Opt. Mater.31(9), 1327–1330 (2009).
[CrossRef]

X. M. Zhang, J. Wang, H. Wu, J. H. Zhang, and Q. Su, “One-step synthesis and double emission (Ca1 + x − yEuy)Ga2S4 + x phosphor for white LEDs,” Mater. Lett.63(2), 340–342 (2009).
[CrossRef]

2008

M. Verónica, B. Graciela, A. Norma, and L. Miguel, “Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor,” Chem. Eng. J.138(1-3), 602–607 (2008).
[CrossRef]

F. B. D. Saiah, B.-L. Su, and N. Bettahar, “Removal of Evans Blue by using Nickel-iron layered double hydroxide (LDH) nanoparticles: effect of hydrothermal treatment temperature on textural properties and dye adsorption,” Macromol. Symp.273(1), 125–134 (2008).
[CrossRef]

W. T. Cheng, S. L. Wang, and S. Y. Lin, “Solid-state interaction study on the captopril/lubricants systems accelerated by grinding process,” J. Phys. Chem. Solids69(4), 1007–1016 (2008).
[CrossRef]

2007

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

J. C. Liu, S. X. Lian, A. L. Zhu, Q.H. Li, L.M. Liu, and L.H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chinese J. Lumin.28(1), 67–73 (2007).

S. Sun and W. G. Hou, “The photoluminescence of Co-Al-layered double hydroxide,” Chin. Chem. Lett.18(11), 1371–1373 (2007).
[CrossRef]

J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).

2006

R. Trujillano, M. J. Holgado, F. Pigazo, and V. Rives, “Preparation, physicochemical characterisation and magnetic properties of Cu-Al layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer,” Physica B373(2), 267–273 (2006).
[CrossRef]

J. Das, D. Das, and K. M. Parida, “Preparation and characterization of Mg-Al hydrotalcite-like compounds containing cerium,” J. Colloid Interface Sci.301(2), 569–574 (2006).
[CrossRef] [PubMed]

W. F. Lee and S. C. Lee, “Effect of hydrotalcite on the swelling and mechanical behaviors for the hybrid nanocomposite hydrogels based on gelatin and hydrotalcite,” J. Appl. Polym. Sci.100(1), 500–507 (2006).
[CrossRef]

L. Z. Qiu, W. Chen, and B. J. Qu, “Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites,” Polymer (Guildf.)47(3), 922–930 (2006).
[CrossRef]

2005

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
[CrossRef]

G. J. Gou, P. H. Ma, and M. X. Chu, “Dynamics of intercalation of B4O5 (OH) 2-4 anion into layered double hydroxides intercalated by Cl- anion,” Chem. J. Chin. Univ.26(3), 497–502 (2005).

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

2004

L. R. Xiao, F. Gao, J. Y. Tang, and W. G. Zhang, “Study on the Eu-containing coordination polymer. structural characterization of Eu (III)- thienyltrifluoroacetone-poly(styrene-acrylic acid),” Spectrosc. Spect. Anal.24(6), 756–761 (2004).

2003

J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
[CrossRef]

C. Feldmann, T. Jüstel, C. R. Ronda, and P. J. Schmidt, “Inorganic luminescent materials: 100 years of research and application,” Adv. Funct. Mater.13(7), 511–516 (2003).
[CrossRef]

J. Hu, H. Zhao, Q. J. Zhang, and W. D. He, “Synthesis and characterization of submicron PMMA Particles containing rare earth ions on the surface,” J. Appl. Polym. Sci.89(4), 1124–1131 (2003).
[CrossRef]

2001

F. Leroux and J.-P. Besse, “Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites,” Chem. Mater.13(10), 3507–3515 (2001).
[CrossRef]

1999

J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
[CrossRef]

1998

S. P. Newman and W. Jones, “Synthesis, characterization and applications of layered double hydroxides containing organic guests,” New J. Chem.22(2), 105–115 (1998).
[CrossRef]

1996

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

M. C. Hermosín, I. Pavlovic, M. A. Ulibarri, and J. Cornejo, “Hydrotalcite as sorbent for trinitrophenol: Sorption capacity and mechanism,” Water Res.30(1), 171–177 (1996).
[CrossRef]

1991

F. Cavani, F. Trifirò, and A. Vaccari, “Hydrotalcite-type anionic clays: preparation, properties and applications,” Catal. Today11(2), 173–301 (1991).
[CrossRef]

1985

M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon, and C. J. Serna, “IR characteristics of hydrotalcite-like compounds,” Phys. Chem. Miner.12(1), 34–38 (1985).

1979

P. S. Bassi, P. C. Kalsi, and C. M. Khajuria, “Thermal decomposition of zinc(II) salicylate dihydrate,” Thermochim. Acta34(1), 183–188 (1979).
[CrossRef]

Agarwal, D. D.

S. Gupta, D. D. Agarwal, and S. Banerjee, “Synergistic combination of metal stearates and β-diketones with hydrotalcites in poly(vinyl chloride) stabilization,” J. Appl. Polym. Sci.112(2), 1056–1062 (2009).
[CrossRef]

Al-Tarawneh, S.

M. A. Zaitoun and S. Al-Tarawneh, “Effect of varying lanthanide local coordination sphere on luminescence properties illustrated by selected inorganic and organic rare earth complexes synthesized in sol–gel host glasses,” J. Lumin.131(8), 1795–1801 (2011).
[CrossRef]

Arvia, A. J.

J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
[CrossRef]

Ballato, J.

B. Kokuoz, C. Kucera, J. R. DiMaio, and J. Ballato, “Organic–inorganic hybrid nanoparticles with enhanced rare-earth emissions,” Opt. Mater.31(9), 1327–1330 (2009).
[CrossRef]

Banerjee, S.

S. Gupta, D. D. Agarwal, and S. Banerjee, “Synergistic combination of metal stearates and β-diketones with hydrotalcites in poly(vinyl chloride) stabilization,” J. Appl. Polym. Sci.112(2), 1056–1062 (2009).
[CrossRef]

Bassi, P. S.

P. S. Bassi, P. C. Kalsi, and C. M. Khajuria, “Thermal decomposition of zinc(II) salicylate dihydrate,” Thermochim. Acta34(1), 183–188 (1979).
[CrossRef]

Bazin, D.

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

Bellotto, M.

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

Besse, J.-P.

F. Leroux and J.-P. Besse, “Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites,” Chem. Mater.13(10), 3507–3515 (2001).
[CrossRef]

Bettahar, N.

F. B. D. Saiah, B.-L. Su, and N. Bettahar, “Removal of Evans Blue by using Nickel-iron layered double hydroxide (LDH) nanoparticles: effect of hydrothermal treatment temperature on textural properties and dye adsorption,” Macromol. Symp.273(1), 125–134 (2008).
[CrossRef]

Cafferata, L. F. R.

J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
[CrossRef]

Cai, L.-Z.

M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
[CrossRef] [PubMed]

Carlos, L. D.

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Cavani, F.

F. Cavani, F. Trifirò, and A. Vaccari, “Hydrotalcite-type anionic clays: preparation, properties and applications,” Catal. Today11(2), 173–301 (1991).
[CrossRef]

Chen, W.

L. Z. Qiu, W. Chen, and B. J. Qu, “Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites,” Polymer (Guildf.)47(3), 922–930 (2006).
[CrossRef]

Chen, X.

X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

Cheng, W. T.

W. T. Cheng, S. L. Wang, and S. Y. Lin, “Solid-state interaction study on the captopril/lubricants systems accelerated by grinding process,” J. Phys. Chem. Solids69(4), 1007–1016 (2008).
[CrossRef]

Cheng, Z. Y.

Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
[CrossRef]

Chu, M. X.

G. J. Gou, P. H. Ma, and M. X. Chu, “Dynamics of intercalation of B4O5 (OH) 2-4 anion into layered double hydroxides intercalated by Cl- anion,” Chem. J. Chin. Univ.26(3), 497–502 (2005).

Clause, O.

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

Cong, Y.

Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
[CrossRef]

Cornejo, J.

M. C. Hermosín, I. Pavlovic, M. A. Ulibarri, and J. Cornejo, “Hydrotalcite as sorbent for trinitrophenol: Sorption capacity and mechanism,” Water Res.30(1), 171–177 (1996).
[CrossRef]

Curtius, H.

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

Dardenne, K.

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

Das, D.

J. Das, D. Das, and K. M. Parida, “Preparation and characterization of Mg-Al hydrotalcite-like compounds containing cerium,” J. Colloid Interface Sci.301(2), 569–574 (2006).
[CrossRef] [PubMed]

Das, J.

J. Das, D. Das, and K. M. Parida, “Preparation and characterization of Mg-Al hydrotalcite-like compounds containing cerium,” J. Colloid Interface Sci.301(2), 569–574 (2006).
[CrossRef] [PubMed]

DiMaio, J. R.

B. Kokuoz, C. Kucera, J. R. DiMaio, and J. Ballato, “Organic–inorganic hybrid nanoparticles with enhanced rare-earth emissions,” Opt. Mater.31(9), 1327–1330 (2009).
[CrossRef]

Egbewatt, N.

J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
[CrossRef]

Elkaim, E. A.

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

Fanghänel, T.

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

Feldmann, C.

C. Feldmann, T. Jüstel, C. R. Ronda, and P. J. Schmidt, “Inorganic luminescent materials: 100 years of research and application,” Adv. Funct. Mater.13(7), 511–516 (2003).
[CrossRef]

Fu, J.

Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
[CrossRef]

Gago, S.

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Gao, F.

L. R. Xiao, F. Gao, J. Y. Tang, and W. G. Zhang, “Study on the Eu-containing coordination polymer. structural characterization of Eu (III)- thienyltrifluoroacetone-poly(styrene-acrylic acid),” Spectrosc. Spect. Anal.24(6), 756–761 (2004).

Getzova, M.

M. Milanova, J. Zaharieva, I. Manolov, M. Getzova, and D. Todorovsky, “Lanthanide complexes with β-diketones and coumarin derivates: synthesis, thermal behaviour, optical and pharmacological properties and immobilization,” J. Rare Earths28, 66–74 (2010).
[CrossRef]

Gonçalves, I. S.

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Gou, G. J.

G. J. Gou, P. H. Ma, and M. X. Chu, “Dynamics of intercalation of B4O5 (OH) 2-4 anion into layered double hydroxides intercalated by Cl- anion,” Chem. J. Chin. Univ.26(3), 497–502 (2005).

Graciela, B.

M. Verónica, B. Graciela, A. Norma, and L. Miguel, “Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor,” Chem. Eng. J.138(1-3), 602–607 (2008).
[CrossRef]

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P. Gunawan and R. Xu, “Lanthanide-doped layered double hydroxides intercalated with sensitizing anions: efficient energy transfer between host and guest layers,” J. Phys. Chem. C113(39), 17206–17214 (2009).
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Guo, G.-C.

M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
[CrossRef] [PubMed]

Guo, S.-P.

M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
[CrossRef] [PubMed]

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S. Gupta, D. D. Agarwal, and S. Banerjee, “Synergistic combination of metal stearates and β-diketones with hydrotalcites in poly(vinyl chloride) stabilization,” J. Appl. Polym. Sci.112(2), 1056–1062 (2009).
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Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
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J. Hu, H. Zhao, Q. J. Zhang, and W. D. He, “Synthesis and characterization of submicron PMMA Particles containing rare earth ions on the surface,” J. Appl. Polym. Sci.89(4), 1124–1131 (2003).
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M. C. Hermosín, I. Pavlovic, M. A. Ulibarri, and J. Cornejo, “Hydrotalcite as sorbent for trinitrophenol: Sorption capacity and mechanism,” Water Res.30(1), 171–177 (1996).
[CrossRef]

Hernandez-Moreno, M. J.

M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon, and C. J. Serna, “IR characteristics of hydrotalcite-like compounds,” Phys. Chem. Miner.12(1), 34–38 (1985).

Holgado, M. J.

R. Trujillano, M. J. Holgado, F. Pigazo, and V. Rives, “Preparation, physicochemical characterisation and magnetic properties of Cu-Al layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer,” Physica B373(2), 267–273 (2006).
[CrossRef]

Hou, W. G.

S. Sun and W. G. Hou, “The photoluminescence of Co-Al-layered double hydroxide,” Chin. Chem. Lett.18(11), 1371–1373 (2007).
[CrossRef]

Hu, J.

J. Hu, H. Zhao, Q. J. Zhang, and W. D. He, “Synthesis and characterization of submicron PMMA Particles containing rare earth ions on the surface,” J. Appl. Polym. Sci.89(4), 1124–1131 (2003).
[CrossRef]

Jones, W.

S. P. Newman and W. Jones, “Synthesis, characterization and applications of layered double hydroxides containing organic guests,” New J. Chem.22(2), 105–115 (1998).
[CrossRef]

Jüstel, T.

C. Feldmann, T. Jüstel, C. R. Ronda, and P. J. Schmidt, “Inorganic luminescent materials: 100 years of research and application,” Adv. Funct. Mater.13(7), 511–516 (2003).
[CrossRef]

Kalsi, P. C.

P. S. Bassi, P. C. Kalsi, and C. M. Khajuria, “Thermal decomposition of zinc(II) salicylate dihydrate,” Thermochim. Acta34(1), 183–188 (1979).
[CrossRef]

Khajuria, C. M.

P. S. Bassi, P. C. Kalsi, and C. M. Khajuria, “Thermal decomposition of zinc(II) salicylate dihydrate,” Thermochim. Acta34(1), 183–188 (1979).
[CrossRef]

Kim, J. K.

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

Kokuoz, B.

B. Kokuoz, C. Kucera, J. R. DiMaio, and J. Ballato, “Organic–inorganic hybrid nanoparticles with enhanced rare-earth emissions,” Opt. Mater.31(9), 1327–1330 (2009).
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Kucera, C.

B. Kokuoz, C. Kucera, J. R. DiMaio, and J. Ballato, “Organic–inorganic hybrid nanoparticles with enhanced rare-earth emissions,” Opt. Mater.31(9), 1327–1330 (2009).
[CrossRef]

Lambi, J. N.

J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
[CrossRef]

Lee, S. C.

W. F. Lee and S. C. Lee, “Effect of hydrotalcite on the swelling and mechanical behaviors for the hybrid nanocomposite hydrogels based on gelatin and hydrotalcite,” J. Appl. Polym. Sci.100(1), 500–507 (2006).
[CrossRef]

Lee, W. F.

W. F. Lee and S. C. Lee, “Effect of hydrotalcite on the swelling and mechanical behaviors for the hybrid nanocomposite hydrogels based on gelatin and hydrotalcite,” J. Appl. Polym. Sci.100(1), 500–507 (2006).
[CrossRef]

Leroux, F.

F. Leroux and J.-P. Besse, “Polymer interleaved layered double hydroxide: a new emerging class of nanocomposites,” Chem. Mater.13(10), 3507–3515 (2001).
[CrossRef]

Li, C. Z.

X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

Li, J.

Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
[CrossRef]

Li, Q. H.

J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).

Li, Q.H.

J. C. Liu, S. X. Lian, A. L. Zhu, Q.H. Li, L.M. Liu, and L.H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chinese J. Lumin.28(1), 67–73 (2007).

Li, Y.

M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
[CrossRef] [PubMed]

Lian, S. X.

X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

J. C. Liu, S. X. Lian, A. L. Zhu, Q.H. Li, L.M. Liu, and L.H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chinese J. Lumin.28(1), 67–73 (2007).

J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).

Lin, J.

Y. Cong, J. Fu, Z. Y. Cheng, J. Li, Y. C. Han, and J. Lin, “Self-organization and luminescent properties of nanostructured europium (III)-block copolymer complex thin films,” J. Polym. Sci., B, Polym. Phys.43(16), 2181–2189 (2005).
[CrossRef]

Lin, S. Y.

W. T. Cheng, S. L. Wang, and S. Y. Lin, “Solid-state interaction study on the captopril/lubricants systems accelerated by grinding process,” J. Phys. Chem. Solids69(4), 1007–1016 (2008).
[CrossRef]

Liu, J. C.

J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).

J. C. Liu, S. X. Lian, A. L. Zhu, Q.H. Li, L.M. Liu, and L.H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chinese J. Lumin.28(1), 67–73 (2007).

Liu, L. M.

J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).

Liu, L.M.

J. C. Liu, S. X. Lian, A. L. Zhu, Q.H. Li, L.M. Liu, and L.H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chinese J. Lumin.28(1), 67–73 (2007).

Lynch, J.

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

Ma, P. H.

G. J. Gou, P. H. Ma, and M. X. Chu, “Dynamics of intercalation of B4O5 (OH) 2-4 anion into layered double hydroxides intercalated by Cl- anion,” Chem. J. Chin. Univ.26(3), 497–502 (2005).

Manolov, I.

M. Milanova, J. Zaharieva, I. Manolov, M. Getzova, and D. Todorovsky, “Lanthanide complexes with β-diketones and coumarin derivates: synthesis, thermal behaviour, optical and pharmacological properties and immobilization,” J. Rare Earths28, 66–74 (2010).
[CrossRef]

Martin, D. J.

A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
[CrossRef]

Miguel, L.

M. Verónica, B. Graciela, A. Norma, and L. Miguel, “Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor,” Chem. Eng. J.138(1-3), 602–607 (2008).
[CrossRef]

Milanova, M.

M. Milanova, J. Zaharieva, I. Manolov, M. Getzova, and D. Todorovsky, “Lanthanide complexes with β-diketones and coumarin derivates: synthesis, thermal behaviour, optical and pharmacological properties and immobilization,” J. Rare Earths28, 66–74 (2010).
[CrossRef]

Minchin, R. F.

A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
[CrossRef]

Musumeci, A. W.

A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
[CrossRef]

Newman, S. P.

S. P. Newman and W. Jones, “Synthesis, characterization and applications of layered double hydroxides containing organic guests,” New J. Chem.22(2), 105–115 (1998).
[CrossRef]

Norma, A.

M. Verónica, B. Graciela, A. Norma, and L. Miguel, “Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor,” Chem. Eng. J.138(1-3), 602–607 (2008).
[CrossRef]

Nsehyuka, A. T.

J. N. Lambi, A. T. Nsehyuka, N. Egbewatt, L. F. R. Cafferata, and A. J. Arvia, “Synthesis, spectral properties and thermal behaviour of zinc(II) acetylsalicylate,” Thermochim. Acta398(1-2), 145–151 (2003).
[CrossRef]

Parida, K. M.

J. Das, D. Das, and K. M. Parida, “Preparation and characterization of Mg-Al hydrotalcite-like compounds containing cerium,” J. Colloid Interface Sci.301(2), 569–574 (2006).
[CrossRef] [PubMed]

Pavlovic, I.

M. C. Hermosín, I. Pavlovic, M. A. Ulibarri, and J. Cornejo, “Hydrotalcite as sorbent for trinitrophenol: Sorption capacity and mechanism,” Water Res.30(1), 171–177 (1996).
[CrossRef]

Pigazo, F.

R. Trujillano, M. J. Holgado, F. Pigazo, and V. Rives, “Preparation, physicochemical characterisation and magnetic properties of Cu-Al layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer,” Physica B373(2), 267–273 (2006).
[CrossRef]

Pillinger, M.

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Qiu, L. Z.

L. Z. Qiu, W. Chen, and B. J. Qu, “Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites,” Polymer (Guildf.)47(3), 922–930 (2006).
[CrossRef]

Qu, B. J.

L. Z. Qiu, W. Chen, and B. J. Qu, “Morphology and thermal stabilization mechanism of LLDPE/MMT and LLDPE/LDH nanocomposites,” Polymer (Guildf.)47(3), 922–930 (2006).
[CrossRef]

Rebours, B.

M. Bellotto, B. Rebours, O. Clause, J. Lynch, D. Bazin, and E. A. Elkaim, “A reexamination of hydrotalcite crystal chemistry,” J. Phys. Chem.100(20), 8527–8534 (1996).
[CrossRef]

Rendon, J. L.

M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon, and C. J. Serna, “IR characteristics of hydrotalcite-like compounds,” Phys. Chem. Miner.12(1), 34–38 (1985).

Rives, V.

R. Trujillano, M. J. Holgado, F. Pigazo, and V. Rives, “Preparation, physicochemical characterisation and magnetic properties of Cu-Al layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer,” Physica B373(2), 267–273 (2006).
[CrossRef]

Ronda, C. R.

C. Feldmann, T. Jüstel, C. R. Ronda, and P. J. Schmidt, “Inorganic luminescent materials: 100 years of research and application,” Adv. Funct. Mater.13(7), 511–516 (2003).
[CrossRef]

Rong, C. Y.

X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

Sá Ferreira, R. A.

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Saiah, F. B. D.

F. B. D. Saiah, B.-L. Su, and N. Bettahar, “Removal of Evans Blue by using Nickel-iron layered double hydroxide (LDH) nanoparticles: effect of hydrothermal treatment temperature on textural properties and dye adsorption,” Macromol. Symp.273(1), 125–134 (2008).
[CrossRef]

Santos, T. M.

S. Gago, M. Pillinger, R. A. Sá Ferreira, L. D. Carlos, T. M. Santos, and I. S. Gonçalves, “Immobilization of lanthanide ions in a pillared layered double hydroxide,” Chem. Mater.17(23), 5803–5809 (2005).
[CrossRef]

Schmidt, P. J.

C. Feldmann, T. Jüstel, C. R. Ronda, and P. J. Schmidt, “Inorganic luminescent materials: 100 years of research and application,” Adv. Funct. Mater.13(7), 511–516 (2003).
[CrossRef]

Schubert, E. F.

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

Serna, C. J.

M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon, and C. J. Serna, “IR characteristics of hydrotalcite-like compounds,” Phys. Chem. Miner.12(1), 34–38 (1985).

Smith, S. V.

A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
[CrossRef]

Stumpf, T.

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

Su, B.-L.

F. B. D. Saiah, B.-L. Su, and N. Bettahar, “Removal of Evans Blue by using Nickel-iron layered double hydroxide (LDH) nanoparticles: effect of hydrothermal treatment temperature on textural properties and dye adsorption,” Macromol. Symp.273(1), 125–134 (2008).
[CrossRef]

Su, Q.

X. M. Zhang, J. Wang, H. Wu, J. H. Zhang, and Q. Su, “One-step synthesis and double emission (Ca1 + x − yEuy)Ga2S4 + x phosphor for white LEDs,” Mater. Lett.63(2), 340–342 (2009).
[CrossRef]

Sun, J. T.

J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
[CrossRef]

Sun, S.

S. Sun and W. G. Hou, “The photoluminescence of Co-Al-layered double hydroxide,” Chin. Chem. Lett.18(11), 1371–1373 (2007).
[CrossRef]

Tang, J. Y.

L. R. Xiao, F. Gao, J. Y. Tang, and W. G. Zhang, “Study on the Eu-containing coordination polymer. structural characterization of Eu (III)- thienyltrifluoroacetone-poly(styrene-acrylic acid),” Spectrosc. Spect. Anal.24(6), 756–761 (2004).

Todorovsky, D.

M. Milanova, J. Zaharieva, I. Manolov, M. Getzova, and D. Todorovsky, “Lanthanide complexes with β-diketones and coumarin derivates: synthesis, thermal behaviour, optical and pharmacological properties and immobilization,” J. Rare Earths28, 66–74 (2010).
[CrossRef]

Trifirò, F.

F. Cavani, F. Trifirò, and A. Vaccari, “Hydrotalcite-type anionic clays: preparation, properties and applications,” Catal. Today11(2), 173–301 (1991).
[CrossRef]

Trujillano, R.

R. Trujillano, M. J. Holgado, F. Pigazo, and V. Rives, “Preparation, physicochemical characterisation and magnetic properties of Cu-Al layered double hydroxides with CO32- and anionic surfactants with different alkyl chains in the interlayer,” Physica B373(2), 267–273 (2006).
[CrossRef]

Ufer, K.

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

Ulibarri, M. A.

M. C. Hermosín, I. Pavlovic, M. A. Ulibarri, and J. Cornejo, “Hydrotalcite as sorbent for trinitrophenol: Sorption capacity and mechanism,” Water Res.30(1), 171–177 (1996).
[CrossRef]

M. J. Hernandez-Moreno, M. A. Ulibarri, J. L. Rendon, and C. J. Serna, “IR characteristics of hydrotalcite-like compounds,” Phys. Chem. Miner.12(1), 34–38 (1985).

Vaccari, A.

F. Cavani, F. Trifirò, and A. Vaccari, “Hydrotalcite-type anionic clays: preparation, properties and applications,” Catal. Today11(2), 173–301 (1991).
[CrossRef]

Verónica, M.

M. Verónica, B. Graciela, A. Norma, and L. Miguel, “Ethanol steam reforming using Ni(II)-Al(III) layered double hydroxide as catalyst precursor,” Chem. Eng. J.138(1-3), 602–607 (2008).
[CrossRef]

Walther, C.

T. Stumpf, H. Curtius, C. Walther, K. Dardenne, K. Ufer, and T. Fanghänel, “Incorporation of Eu(III) into hydrotalcite: a TRLFS and EXAFS study,” Environ. Sci. Technol.41(9), 3186–3191 (2007).
[CrossRef] [PubMed]

Wang, J.

X. M. Zhang, J. Wang, H. Wu, J. H. Zhang, and Q. Su, “One-step synthesis and double emission (Ca1 + x − yEuy)Ga2S4 + x phosphor for white LEDs,” Mater. Lett.63(2), 340–342 (2009).
[CrossRef]

Wang, M.-S.

M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
[CrossRef] [PubMed]

Wang, Q. G.

J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
[CrossRef]

Wang, S. L.

W. T. Cheng, S. L. Wang, and S. Y. Lin, “Solid-state interaction study on the captopril/lubricants systems accelerated by grinding process,” J. Phys. Chem. Solids69(4), 1007–1016 (2008).
[CrossRef]

Wu, H.

X. M. Zhang, J. Wang, H. Wu, J. H. Zhang, and Q. Su, “One-step synthesis and double emission (Ca1 + x − yEuy)Ga2S4 + x phosphor for white LEDs,” Mater. Lett.63(2), 340–342 (2009).
[CrossRef]

Xiao, L. R.

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Xie, W.

J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
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M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
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A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
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[CrossRef]

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J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
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J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
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Zhang, X. M.

X. M. Zhang, J. Wang, H. Wu, J. H. Zhang, and Q. Su, “One-step synthesis and double emission (Ca1 + x − yEuy)Ga2S4 + x phosphor for white LEDs,” Mater. Lett.63(2), 340–342 (2009).
[CrossRef]

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J. Hu, H. Zhao, Q. J. Zhang, and W. D. He, “Synthesis and characterization of submicron PMMA Particles containing rare earth ions on the surface,” J. Appl. Polym. Sci.89(4), 1124–1131 (2003).
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X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

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Y. Zhao and B. Yan, “Photoluminescent properties of novel rare earth organic-inorganic nanocomposite with TiO2 modified silica via double crosslinking units,” Photochem. Photobiol.88(1), 21–31 (2012).
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M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
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J. C. Liu, S. X. Lian, A. L. Zhu, Q. H. Li, L. M. Liu, and L. H. Zeng, “Luminescent properties and selectivity IR adsorption of Eu-doped hydrotalcite like compounds,” Chi. J. Lumin.28(1), 67–73 (2007).

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M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
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Environ. Sci. Technol.

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M.-S. Wang, S.-P. Guo, Y. Li, L.-Z. Cai, J.-P. Zou, G. Xu, W.-W. Zhou, F.-K. Zheng, and G.-C. Guo, “A direct white-light-emitting metal-organic framework with tunable yellow-to-white photoluminescence by variation of excitation light,” J. Am. Chem. Soc.131(38), 13572–13573 (2009).
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J. Appl. Polym. Sci.

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X. Chen, J. F. Zhao, L. P. Yu, C. Y. Rong, C. Z. Li, and S. X. Lian, “A white light emitting phosphor Sr1.5Ca0.5SiO4:Eu3+,Tb3+,Eu2+for LED-based near-UV chip: preparation, characterization and luminescent mechanism,” J. Lumin.131(12), 2697–2702 (2011).
[CrossRef]

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A. W. Musumeci, Z. P. Xu, S. V. Smith, R. F. Minchin, and D. J. Martin, “Layered double hydroxide nanoparticles incorporating terbium: applicability as a fluorescent probe and morphology modifier,” J. Nanopart. Res.12(1), 111–120 (2010).
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Mater. Sci. Eng.

J. T. Sun, W. Xie, L. J. Yuan, K. L. Zhang, and Q. G. Wang, “Preparation and luminescence properties of Tb3+-doped zinc salicylates,” Mater. Sci. Eng.64(3), 157–160 (1999).
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Figures (7)

Fig. 1
Fig. 1

(a) Excitation spectra (λem = 613nm), and (b) emission spectra (λex = 370nm) of Eu/Tb/Zn-HTlc (solid) and MgAlEuTbZn-LDH sample (dash).

Fig. 2
Fig. 2

CIE chromaticity of Eu/Tb/Zn-HTlc sample.

Fig. 3
Fig. 3

XRD patterns of MgAl-LDHs(a), MgAlEuTbZn-LDHs (b), MgAlEuTbZn-stearate anions-LDHs (c), and Eu/Tb/Zn-HTlc (d). (The inset is the small-angle XRD)

Fig. 4
Fig. 4

TEM, HRTEM images of MgAl-LDHs (a), (b) and TEM, HRTEM images of Eu/Tb/Zn-HTlc (c), (d).

Fig. 5
Fig. 5

Schematic illustration of the mechanism of fabricated Eu/Tb/Zn-HTlc.

Fig. 6
Fig. 6

FT-IR spectra of MgAl-LDHs, MgAlEuTbZn-LDHs and Eu/Tb/Zn-HTlc.

Fig. 7
Fig. 7

TG-DSC patterns of MgAl-LDH(a) and Eu/Tb/Zn-HTlc(b) samples.

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