Abstract

We report results of the optical properties of Dy-doped CsPbCl3 and KPb2Cl5 bulk crystals for potential applications in yellow solid-state laser development. The crystals were synthesized from purified starting materials and melt-grown by vertical Bridgman technique. Optical transmission measurements revealed characteristic absorption bands from intra-4f transitions of Dy3+ ions. Direct optical excitation at 455 nm (6H15/24I15/2) resulted in dominant yellow emission bands at ∼575 nm from the 4F9/2 excited state of Dy3+ ions. In addition, both crystals exhibited weaker emission lines in the blue (∼483 nm) and red (∼670 nm) regions. The peak emission-cross sections for the yellow transition (4F9/26H13/2) were determined to be ∼0.22 × 10−20 cm2 for Dy: CsPbCl3peak = 576.5 nm) and ∼0.59 × 10−20 cm2 for Dy: KPb2Cl5peak = 574.5 nm). The spectral properties and decay dynamics of the 4F9/2 excited state were evaluated within the Judd-Ofelt theory to predict total radiative decay rates, branching ratios, and emission quantum efficiencies.

© 2020 Optical Society of America under the terms of the OSA Open Access Publishing Agreement

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    [Crossref]

2020 (1)

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

2019 (3)

E. Cavalli, “Optical spectroscopy of Dy3+ in crystalline hosts: General aspects, personal considerations and some news,” Opt. Mater. X 1, 100014 (2019).
[Crossref]

N. Pandey, A. Kumar, and S. Chakrabarti, “Investigation of the structural, electronic, and optical properties of Mn-doped CsPbCl3: theory and experiment,” RSC Adv. 9(51), 29556–29565 (2019).
[Crossref]

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

2018 (3)

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
[Crossref]

R. Babu, L. Giribabu, and S. P. Singh, “Recent Advances in Halide-Based Perovskite Crystals and Their Optoelectronic Applications,” Cryst. Growth Des. 18(4), 2645–2664 (2018).
[Crossref]

H. H. Ma, M. Imran, Z. Dang, and Z. Hu, “Growth of Metal Halide Perovskite, from Nanocrystal to Micron-Scale Crystal: A Review,” Crystals 8(5), 182 (2018).
[Crossref]

2017 (1)

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

2016 (2)

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
[Crossref]

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
[Crossref]

2014 (1)

2013 (1)

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

2012 (1)

2010 (1)

S. Bigotta, M. Tonelli, E. Cavalli, and A. Belletti, “Optical spectra of Dy3+ in KY3F10 and LiLuF4 crystalline fibers,” J. Lumin. 130(1), 13–17 (2010).
[Crossref]

2008 (1)

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
[Crossref]

2007 (1)

2005 (1)

2003 (1)

G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
[Crossref]

2002 (1)

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

2001 (1)

2000 (1)

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
[Crossref]

1997 (1)

C. K. Jayasankar and E. Rukmini, “Spectroscopic investigation of Dy3+ ions in borosulphate glasses,” Phys. B 240(3), 273–288 (1997).
[Crossref]

Asada, H.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
[Crossref]

Asai, K.

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
[Crossref]

Babu, R.

R. Babu, L. Giribabu, and S. P. Singh, “Recent Advances in Halide-Based Perovskite Crystals and Their Optoelectronic Applications,” Cryst. Growth Des. 18(4), 2645–2664 (2018).
[Crossref]

Bagaev S, N.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

Bagayev, S.

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
[Crossref]

Belletti, A.

S. Bigotta, M. Tonelli, E. Cavalli, and A. Belletti, “Optical spectra of Dy3+ in KY3F10 and LiLuF4 crystalline fibers,” J. Lumin. 130(1), 13–17 (2010).
[Crossref]

Beregi, E.

G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
[Crossref]

Bigotta, S.

S. Bigotta, M. Tonelli, E. Cavalli, and A. Belletti, “Optical spectra of Dy3+ in KY3F10 and LiLuF4 crystalline fibers,” J. Lumin. 130(1), 13–17 (2010).
[Crossref]

Bolognesi, G.

Bowman, S. R.

Brown, E.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

Burger, A.

Butvina, L. N.

Calonico, D.

Cavalli, E.

E. Cavalli, “Optical spectroscopy of Dy3+ in crystalline hosts: General aspects, personal considerations and some news,” Opt. Mater. X 1, 100014 (2019).
[Crossref]

S. Bigotta, M. Tonelli, E. Cavalli, and A. Belletti, “Optical spectra of Dy3+ in KY3F10 and LiLuF4 crystalline fibers,” J. Lumin. 130(1), 13–17 (2010).
[Crossref]

Chakrabarti, S.

N. Pandey, A. Kumar, and S. Chakrabarti, “Investigation of the structural, electronic, and optical properties of Mn-doped CsPbCl3: theory and experiment,” RSC Adv. 9(51), 29556–29565 (2019).
[Crossref]

Chasapis, T. C.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Chen, B.

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

Chen, H.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

Cheniukh, I.

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
[Crossref]

Chung, D. Y.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Condon, N. J.

Costanzo, G. A.

Dang, Z.

H. H. Ma, M. Imran, Z. Dang, and Z. Hu, “Growth of Metal Halide Perovskite, from Nanocrystal to Micron-Scale Crystal: A Review,” Crystals 8(5), 182 (2018).
[Crossref]

Dianov, E. M.

Dirin, D. N.

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
[Crossref]

Dominiak-Dzik, G.

G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
[Crossref]

Duan, G.

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
[Crossref]

Dunina E, B.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

Fang, L.

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

Feeman, A. J.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Fujimoti, Y.

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
[Crossref]

Giribabu, L.

R. Babu, L. Giribabu, and S. P. Singh, “Recent Advances in Halide-Based Perovskite Crystals and Their Optoelectronic Applications,” Cryst. Growth Des. 18(4), 2645–2664 (2018).
[Crossref]

Gruber J, B.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

Hart, D.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

He, M.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

Heuman, E.

Hing, Y.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

Hommerich, U.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

Hömmerich, U.

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
[Crossref]

Hu, Z.

H. H. Ma, M. Imran, Z. Dang, and Z. Hu, “Growth of Metal Halide Perovskite, from Nanocrystal to Micron-Scale Crystal: A Review,” Crystals 8(5), 182 (2018).
[Crossref]

Huber, G.

Im, J.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Imran, M.

H. H. Ma, M. Imran, Z. Dang, and Z. Hu, “Growth of Metal Halide Perovskite, from Nanocrystal to Micron-Scale Crystal: A Review,” Crystals 8(5), 182 (2018).
[Crossref]

Isaenko, L.

L. Isaenko, A. Yelisseyev, A. Tkachuk, and S. Ivanova, (2008) New Monocrystals with Low Phonon Energy for Mid-IR Lasers, In: M. Ebrahim-Zadeh and I. T. Sorokina, eds. Mid-Infrared Coherent Sources and Applications. NATO Science for Peace and Security Series B: Physics and Biophysics, Springer, Dordrecht.

Isaenko, L. I.

Ivanova, S.

L. Isaenko, A. Yelisseyev, A. Tkachuk, and S. Ivanova, (2008) New Monocrystals with Low Phonon Energy for Mid-IR Lasers, In: M. Ebrahim-Zadeh and I. T. Sorokina, eds. Mid-Infrared Coherent Sources and Applications. NATO Science for Peace and Security Series B: Physics and Biophysics, Springer, Dordrecht.

Jayasankar, C. K.

C. K. Jayasankar and E. Rukmini, “Spectroscopic investigation of Dy3+ ions in borosulphate glasses,” Phys. B 240(3), 273–288 (1997).
[Crossref]

Jin, F.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

Kabir, A.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
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A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
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A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
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Kanatzidis, M. G.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
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Klevtsova R, F.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
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Kobayashi, M.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
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Kondo, S.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
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Kornienko A, A.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
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Koshimizu, M.

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
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Kovacs, L.

G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
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Kovalenko, M. V.

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
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Krankel, C.

Krupke, W. F.

Kumar, A.

N. Pandey, A. Kumar, and S. Chakrabarti, “Investigation of the structural, electronic, and optical properties of Mn-doped CsPbCl3: theory and experiment,” RSC Adv. 9(51), 29556–29565 (2019).
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Kuroiwa, T.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
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Kuznetsov F, A.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
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Levi, F.

Li, J.

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
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Li, S.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
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Lichkova, N. V.

Liu, Z.

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
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Lui, Z.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
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H. H. Ma, M. Imran, Z. Dang, and Z. Hu, “Growth of Metal Halide Perovskite, from Nanocrystal to Micron-Scale Crystal: A Review,” Crystals 8(5), 182 (2018).
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C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
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Nostrand, M. C.

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Omata, K.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
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Page, R. H.

Pandey, N.

N. Pandey, A. Kumar, and S. Chakrabarti, “Investigation of the structural, electronic, and optical properties of Mn-doped CsPbCl3: theory and experiment,” RSC Adv. 9(51), 29556–29565 (2019).
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Parisi, D.

Pavlyuk A, A.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
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Pavlyulk, A. A.

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
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Peters, J. A.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
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Rukmini, E.

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G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
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Sebastian, M.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
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Seo, J. T.

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
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Seo J, T.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
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Shestakov, A.

Shestakova, I. A.

Shynkarenko, Y.

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
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Singh, S. P.

R. Babu, L. Giribabu, and S. P. Singh, “Recent Advances in Halide-Based Perovskite Crystals and Their Optoelectronic Applications,” Cryst. Growth Des. 18(4), 2645–2664 (2018).
[Crossref]

Solarz, P.

G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
[Crossref]

Song, H.

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

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C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Sugimoto, S.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
[Crossref]

Takeuchi, H.

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
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M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
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Temple, D.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
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Tkachuk, A.

L. Isaenko, A. Yelisseyev, A. Tkachuk, and S. Ivanova, (2008) New Monocrystals with Low Phonon Energy for Mid-IR Lasers, In: M. Ebrahim-Zadeh and I. T. Sorokina, eds. Mid-Infrared Coherent Sources and Applications. NATO Science for Peace and Security Series B: Physics and Biophysics, Springer, Dordrecht.

Tonelli, M.

G. Bolognesi, D. Parisi, D. Calonico, G. A. Costanzo, F. Levi, P. W. Metz, C. Krankel, G. Huber, and M. Tonelli, “Yellow laser performance of Dy3+ in co-doped Dy, Tb: LiLuF4,” Opt. Lett. 39(23), 6628–6631 (2014).
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S. Bigotta, M. Tonelli, E. Cavalli, and A. Belletti, “Optical spectra of Dy3+ in KY3F10 and LiLuF4 crystalline fibers,” J. Lumin. 130(1), 13–17 (2010).
[Crossref]

Trivedi, S. B.

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

Ueda, K.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
[Crossref]

Wang, W.

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
[Crossref]

Watanabe, K.

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
[Crossref]

Wessels, B. C.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Wibowo, A. C.

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Xia, H.

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

Xu, M.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

Yakunin, S.

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
[Crossref]

Yanagida, T.

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
[Crossref]

Yang, Y.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

Yelisseyev, A.

L. Isaenko, A. Yelisseyev, A. Tkachuk, and S. Ivanova, (2008) New Monocrystals with Low Phonon Energy for Mid-IR Lasers, In: M. Ebrahim-Zadeh and I. T. Sorokina, eds. Mid-Infrared Coherent Sources and Applications. NATO Science for Peace and Security Series B: Physics and Biophysics, Springer, Dordrecht.

Yelisseyev, A. P.

Zagorodney, V. N.

Zandi, B.

A. Kaminskii A, B. Gruber J, N. Bagaev S, K. Ueda, U. Hommerich, T. Seo J, D. Temple, B. Zandi, A. Kornienko A, B. Dunina E, A. Pavlyuk A, F. Klevtsova R, and A. Kuznetsov F, “Optical spectroscopy and visible stimulated emission of Dy3+ ions in monoclinic KY(WO4)2 and KGd(WO4)2 crystals,” Phys. Rev. B 65(12), 125108 (2002).
[Crossref]

Zhang, J.

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

Zhang, L.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

Zhang, S.

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

Zhang, Z.

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
[Crossref]

Zhao, W.

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
[Crossref]

Zhou, X.

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

Chem. Mater. (1)

D. N. Dirin, I. Cheniukh, S. Yakunin, Y. Shynkarenko, and M. V. Kovalenko, “Solution-Grown CsPbBr3 Perovskite Single Crystals for Photon Detection,” Chem. Mater. 28(23), 8470–8474 (2016).
[Crossref]

Cryst. Growth Des. (2)

R. Babu, L. Giribabu, and S. P. Singh, “Recent Advances in Halide-Based Perovskite Crystals and Their Optoelectronic Applications,” Cryst. Growth Des. 18(4), 2645–2664 (2018).
[Crossref]

C. C. Stoumpos, C. D. Malliakas, J. A. Peters, Z. Lui, M. Sebastian, J. Im, T. C. Chasapis, A. C. Wibowo, D. Y. Chung, A. J. Feeman, B. C. Wessels, and M. G. Kanatzidis, “Crystal Growth of the Perovskite Semiconductor CsPbBr3: A new Material for High-Energy Radiation Detection,” Cryst. Growth Des. 13(7), 2722–2727 (2013).
[Crossref]

Crystals (1)

H. H. Ma, M. Imran, Z. Dang, and Z. Hu, “Growth of Metal Halide Perovskite, from Nanocrystal to Micron-Scale Crystal: A Review,” Crystals 8(5), 182 (2018).
[Crossref]

IOP Conf. Ser.: Mater. Sci. Eng. (1)

Z. Zhang, J. Li, W. Wang, G. Duan, W. Zhao, and Z. Liu, “Luminescence Properties of Dy3+ doped Gd2(WO4)3 Phosphor Prepared by Hydrothermal Method,” IOP Conf. Ser.: Mater. Sci. Eng. 389, 012019 (2018).
[Crossref]

J. Alloys Compd. (1)

G. Dominiak-Dzik, P. Solarz, W. Ryba-Romanowski, E. Beregi, and L. Kovacs, “Dysprosium-doped YAl3(BO3)4 (YAB) crystals: an investigation of radiative and non-radiative processes,” J. Alloys Compd. 359(1-2), 51–58 (2003).
[Crossref]

J. Cryst. Growth (1)

U. Hommerich, E. Brown, A. Kabir, D. Hart, S. B. Trivedi, F. Jin, and H. Chen, “Crystal growth and characterization of undoped and Dy-doped TlPb2Br5 for infrared lasers and nuclear radiation detection,” J. Cryst. Growth 479, 89–92 (2017).
[Crossref]

J. Lumin. (2)

S. Bigotta, M. Tonelli, E. Cavalli, and A. Belletti, “Optical spectra of Dy3+ in KY3F10 and LiLuF4 crystalline fibers,” J. Lumin. 130(1), 13–17 (2010).
[Crossref]

Y. Yang, L. Zhang, S. Li, S. Zhang, M. He, M. Xu, and Y. Hing, “Crystal growth and 570 nm emission of Dy3+ doped CeF3 single crystal,” J. Lumin. 215, 116707 (2019).
[Crossref]

J. Mater. Sci.: Mater. Electron. (1)

L. Fang, X. Zhou, J. Zhang, H. Xia, B. Chen, and H. Song, “Control of white light emission via co-doping of Dy3+ and Tb3+ ions in LiLuF4 single crystals under UV excitation,” J. Mater. Sci.: Mater. Electron. 31(4), 3405–3414 (2020).
[Crossref]

J. Opt. Soc. Am. B (2)

Jap. J. Appl. Phys. (1)

A. A. Kaminskii, U. Hömmerich, D. Temple, J. T. Seo, K. Ueda, S. Bagayev, and A. A. Pavlyulk, “Visible Laser Action of Dy3+ in Monoclinic KY(WO4)2 and KGd(WO4)2 crystal under Xe-flashlamp pumping,” Jap. J. Appl. Phys. 39(Part 2, No. 3A/B), L208–L211 (2000).
[Crossref]

Jpn. J. Appl. Phys. (1)

K. Watanabe, M. Koshimizu, T. Yanagida, Y. Fujimoti, and K. Asai, “Luminescence and scintillation properties of La-and La,Ag-doped CsPbCl3 single crystals,” Jpn. J. Appl. Phys. 55(2S), 02BC20 (2016).
[Crossref]

Nucl. Instrum. Methods Phys. Res., Sect. A (1)

M. Kobayashi, K. Omata, S. Sugimoto, Y. Tamagawa, T. Kuroiwa, H. Asada, H. Takeuchi, and S. Kondo, “Scintillation characteristics of CsPbCl3 single crystals,” Nucl. Instrum. Methods Phys. Res., Sect. A 592(3), 369–373 (2008).
[Crossref]

Opt. Express (1)

Opt. Lett. (2)

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E. Cavalli, “Optical spectroscopy of Dy3+ in crystalline hosts: General aspects, personal considerations and some news,” Opt. Mater. X 1, 100014 (2019).
[Crossref]

Phys. B (1)

C. K. Jayasankar and E. Rukmini, “Spectroscopic investigation of Dy3+ ions in borosulphate glasses,” Phys. B 240(3), 273–288 (1997).
[Crossref]

Phys. Rev. B (1)

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[Crossref]

RSC Adv. (1)

N. Pandey, A. Kumar, and S. Chakrabarti, “Investigation of the structural, electronic, and optical properties of Mn-doped CsPbCl3: theory and experiment,” RSC Adv. 9(51), 29556–29565 (2019).
[Crossref]

Other (2)

L. Isaenko, A. Yelisseyev, A. Tkachuk, and S. Ivanova, (2008) New Monocrystals with Low Phonon Energy for Mid-IR Lasers, In: M. Ebrahim-Zadeh and I. T. Sorokina, eds. Mid-Infrared Coherent Sources and Applications. NATO Science for Peace and Security Series B: Physics and Biophysics, Springer, Dordrecht.

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Figures (6)

Fig. 1.
Fig. 1. Room temperature transmission spectra and pictures (a) Dy:CPC and (b) Dy: KPC.
Fig. 2.
Fig. 2. Room temperature absorption coefficient spectra for (a) Dy: CPC and (b) Dy: KPC. IR transitions originating from the 6H15/2 ground state of Dy3+ are indicated in the figure and are shown in (c).
Fig. 3.
Fig. 3. Room temperature emission spectra under 455 nm excitation for (a) Dy: CPC and (b) Dy: KPC. An energy level diagram showing the relevant emission lines from the 4F9/2 excited states for Dy: CPC is depict under (c). All emission data are summarized in Table 2.
Fig. 4.
Fig. 4. Excitation spectra for (a) Dy: CPC and (b) Dy: KPC. The emission was monitored at ∼575 nm. The bandedge energies of both crystals are indicated in the figures.
Fig. 5.
Fig. 5. Room temperature yellow emission lifetime (4F9/26H13/2) under 455 nm excitation for (a) Dy: CPC and (b) Dy: KPC. The emission was monitored at ∼575 nm.
Fig. 6.
Fig. 6. Yellow emission cross-section spectra for the (4F9/26H13/2) transition (a) Dy: CPC and (b) Dy: KPC.

Tables (3)

Tables Icon

Table 1. Absorption transitions, average absorption wavelengths, integrated absorption coefficients, experimental line strengths, and calculated line strengths values for Dy: CPC.

Tables Icon

Table 2. Observed peak emission wavelengths (λp), calculated radiative decay rates (A) and branching ratios (β) for the 4F9/2 excited state of Dy3+ in CsPbCl3 and KPb2Cl5. Calculated (τrad) and measured (τexp) lifetimes are also given in the table. The reduced matrix elements for JO-analysis were taken from Ref. [22].

Tables Icon

Table 3. Peak emission wavelength (λp), peak emission cross-section (σp), emission lifetime (τ), emission quantum efficiency (η), and branching ratio (β) for different Dy doped crystals at 300 K.

Equations (2)

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τ a v g = t I ( t ) d t / I ( t ) d t
σ p = λ p e a k 4 β 8 π n 2 c τ r a d Δ λ e f f