Abstract

Rotationally resolved infrared–ultraviolet double-resonance effects have been observed in D2CO vapor by using pulsed radiation from a The infrared laser pumps CO2 laser and a tunable dye laser. D2CO molecules in the ν4 rovibrational band, and subsequent excitation by the dye laser in the 365-nm 410 vibronic band is detected by fluorescence at 420 nm. The results consolidate assignments from high-resolution absorption spectra and yield estimates of rotational-relaxation rates.

© 1980 Optical Society of America

PDF Article

References

  • View by:
  • |
  • |
  • |

  1. J. I. Steinfeld, P. L. Houston, “Double-resonance spectroscopy,” in Laser and Coherence Spectroscopy, J. I. Steinfeld, ed. (Plenum, New York, 1978), pp. 1–123.
  2. A. Yogev, Y Haas, Chem. Phys. Lett. 21, 544 (1973).
    [CrossRef]
  3. B. J. Orr, Chem. Phys. Lett. 43, 446 (1976).
    [CrossRef]
  4. I. Burak, T. J. Quelly, J. I. Steinfeld, J. Chem. Phys. 70, 334 (1979).
    [CrossRef]
  5. D. Coffey, C. Yamada, E. Hirota, J. Mol. Spectrosc. 64, 98 (1977).
    [CrossRef]
  6. T. Nakagawa, University of Tokyo, Tokyo, Japan, personal communication (1976).
  7. B. J. Orr, J. W. C. Johns, unpublished infrared absorption spectrum of D2CO vapor, recorded with a resolution of ~0.05 cm−1 in the 9–11-μm spectral region.
  8. B. J. Orr, Spectrochim. Acta 30A, 1275 (1975).
  9. J. C. D. Brand, J. Chem. Soc. 858 (1956).
  10. E. S. Yeung, C. B. Moore, J. Chem. Phys. 58, 3988 (1973).
    [CrossRef]
  11. R. G. Miller, E. K. C. Lee, Chem. Phys. Lett. 41, 52 (1976); J. Chem. Phys. 68, 4448 (1978).
    [CrossRef]
  12. D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
    [CrossRef]
  13. E. S. Yeung, C. B. Moore, Appl. Phys. Lett. 21, 109 (1972); R. V. Ambartsumyan, V. M. Apatin, V. S. Letokhov, V. I. Mishin, Sov. J. Quantum Electron. 5, 191 (1975); J. Marling, J. Chem. Phys. 66, 4200 (1977).
    [CrossRef]
  14. G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
    [CrossRef]
  15. We use the notation JKaKc for the rotational levels of a near-prolate asymmetric rotor.
  16. T. Oka, J. Chem. Phys. 47, 13 (1967); Adv. At. Mol. Phys. 9, 127 (1973).
    [CrossRef]
  17. M. Takami, K. Shimoda, Jpn. J. Appl. Phys. 11, 1648 (1972).
    [CrossRef]
  18. V. Prakash, J. E. Boggs, J. Chem. Phys. 57, 2599 (1972).
    [CrossRef]

1979 (1)

I. Burak, T. J. Quelly, J. I. Steinfeld, J. Chem. Phys. 70, 334 (1979).
[CrossRef]

1977 (2)

D. Coffey, C. Yamada, E. Hirota, J. Mol. Spectrosc. 64, 98 (1977).
[CrossRef]

D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
[CrossRef]

1976 (3)

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

B. J. Orr, Chem. Phys. Lett. 43, 446 (1976).
[CrossRef]

R. G. Miller, E. K. C. Lee, Chem. Phys. Lett. 41, 52 (1976); J. Chem. Phys. 68, 4448 (1978).
[CrossRef]

1975 (1)

B. J. Orr, Spectrochim. Acta 30A, 1275 (1975).

1973 (2)

E. S. Yeung, C. B. Moore, J. Chem. Phys. 58, 3988 (1973).
[CrossRef]

A. Yogev, Y Haas, Chem. Phys. Lett. 21, 544 (1973).
[CrossRef]

1972 (3)

E. S. Yeung, C. B. Moore, Appl. Phys. Lett. 21, 109 (1972); R. V. Ambartsumyan, V. M. Apatin, V. S. Letokhov, V. I. Mishin, Sov. J. Quantum Electron. 5, 191 (1975); J. Marling, J. Chem. Phys. 66, 4200 (1977).
[CrossRef]

M. Takami, K. Shimoda, Jpn. J. Appl. Phys. 11, 1648 (1972).
[CrossRef]

V. Prakash, J. E. Boggs, J. Chem. Phys. 57, 2599 (1972).
[CrossRef]

1967 (1)

T. Oka, J. Chem. Phys. 47, 13 (1967); Adv. At. Mol. Phys. 9, 127 (1973).
[CrossRef]

1956 (1)

J. C. D. Brand, J. Chem. Soc. 858 (1956).

Bellet, J.

D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
[CrossRef]

Boggs, J. E.

V. Prakash, J. E. Boggs, J. Chem. Phys. 57, 2599 (1972).
[CrossRef]

Brand, J. C. D.

J. C. D. Brand, J. Chem. Soc. 858 (1956).

Burak, I.

I. Burak, T. J. Quelly, J. I. Steinfeld, J. Chem. Phys. 70, 334 (1979).
[CrossRef]

Coffey, D.

D. Coffey, C. Yamada, E. Hirota, J. Mol. Spectrosc. 64, 98 (1977).
[CrossRef]

Dangoisse, D.

D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
[CrossRef]

Deldalle, A.

D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
[CrossRef]

Haas, Y

A. Yogev, Y Haas, Chem. Phys. Lett. 21, 544 (1973).
[CrossRef]

Hirota, E.

D. Coffey, C. Yamada, E. Hirota, J. Mol. Spectrosc. 64, 98 (1977).
[CrossRef]

Houston, P. L.

J. I. Steinfeld, P. L. Houston, “Double-resonance spectroscopy,” in Laser and Coherence Spectroscopy, J. I. Steinfeld, ed. (Plenum, New York, 1978), pp. 1–123.

Johns, J. W. C.

B. J. Orr, J. W. C. Johns, unpublished infrared absorption spectrum of D2CO vapor, recorded with a resolution of ~0.05 cm−1 in the 9–11-μm spectral region.

Koren, G.

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

Lee, E. K. C.

R. G. Miller, E. K. C. Lee, Chem. Phys. Lett. 41, 52 (1976); J. Chem. Phys. 68, 4448 (1978).
[CrossRef]

Miller, R. G.

R. G. Miller, E. K. C. Lee, Chem. Phys. Lett. 41, 52 (1976); J. Chem. Phys. 68, 4448 (1978).
[CrossRef]

Moore, C. B.

E. S. Yeung, C. B. Moore, J. Chem. Phys. 58, 3988 (1973).
[CrossRef]

E. S. Yeung, C. B. Moore, Appl. Phys. Lett. 21, 109 (1972); R. V. Ambartsumyan, V. M. Apatin, V. S. Letokhov, V. I. Mishin, Sov. J. Quantum Electron. 5, 191 (1975); J. Marling, J. Chem. Phys. 66, 4200 (1977).
[CrossRef]

Nakagawa, T.

T. Nakagawa, University of Tokyo, Tokyo, Japan, personal communication (1976).

Oka, T.

T. Oka, J. Chem. Phys. 47, 13 (1967); Adv. At. Mol. Phys. 9, 127 (1973).
[CrossRef]

Okon, M.

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

Oppenheim, U. P.

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

Orr, B. J.

B. J. Orr, Chem. Phys. Lett. 43, 446 (1976).
[CrossRef]

B. J. Orr, Spectrochim. Acta 30A, 1275 (1975).

B. J. Orr, J. W. C. Johns, unpublished infrared absorption spectrum of D2CO vapor, recorded with a resolution of ~0.05 cm−1 in the 9–11-μm spectral region.

Prakash, V.

V. Prakash, J. E. Boggs, J. Chem. Phys. 57, 2599 (1972).
[CrossRef]

Quelly, T. J.

I. Burak, T. J. Quelly, J. I. Steinfeld, J. Chem. Phys. 70, 334 (1979).
[CrossRef]

Shimoda, K.

M. Takami, K. Shimoda, Jpn. J. Appl. Phys. 11, 1648 (1972).
[CrossRef]

Splingard, J. P.

D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
[CrossRef]

Steinfeld, J. I.

I. Burak, T. J. Quelly, J. I. Steinfeld, J. Chem. Phys. 70, 334 (1979).
[CrossRef]

J. I. Steinfeld, P. L. Houston, “Double-resonance spectroscopy,” in Laser and Coherence Spectroscopy, J. I. Steinfeld, ed. (Plenum, New York, 1978), pp. 1–123.

Takami, M.

M. Takami, K. Shimoda, Jpn. J. Appl. Phys. 11, 1648 (1972).
[CrossRef]

Tal, D.

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

Weil, R.

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

Yamada, C.

D. Coffey, C. Yamada, E. Hirota, J. Mol. Spectrosc. 64, 98 (1977).
[CrossRef]

Yeung, E. S.

E. S. Yeung, C. B. Moore, J. Chem. Phys. 58, 3988 (1973).
[CrossRef]

E. S. Yeung, C. B. Moore, Appl. Phys. Lett. 21, 109 (1972); R. V. Ambartsumyan, V. M. Apatin, V. S. Letokhov, V. I. Mishin, Sov. J. Quantum Electron. 5, 191 (1975); J. Marling, J. Chem. Phys. 66, 4200 (1977).
[CrossRef]

Yogev, A.

A. Yogev, Y Haas, Chem. Phys. Lett. 21, 544 (1973).
[CrossRef]

Appl. Phys. Lett. (2)

E. S. Yeung, C. B. Moore, Appl. Phys. Lett. 21, 109 (1972); R. V. Ambartsumyan, V. M. Apatin, V. S. Letokhov, V. I. Mishin, Sov. J. Quantum Electron. 5, 191 (1975); J. Marling, J. Chem. Phys. 66, 4200 (1977).
[CrossRef]

G. Koren, U. P. Oppenheim, D. Tal, M. Okon, R. Weil, Appl. Phys. Lett. 29, 40 (1976); G. Koren, M. Okon, U. P. Oppenheim, Opt. Commun. 22, 351 (1977); G. Koren, U. P. Oppenheim, “Multiphoton dissociation in formaldehyde,” in Laser-Induced Processes in Molecules, K. L. Kompa, S. D.Smith Smith, eds. (Springer-Verlag, Berlin, 1979), pp. 209–212.
[CrossRef]

Chem. Phys. Lett. (3)

R. G. Miller, E. K. C. Lee, Chem. Phys. Lett. 41, 52 (1976); J. Chem. Phys. 68, 4448 (1978).
[CrossRef]

A. Yogev, Y Haas, Chem. Phys. Lett. 21, 544 (1973).
[CrossRef]

B. J. Orr, Chem. Phys. Lett. 43, 446 (1976).
[CrossRef]

IEEE J. Quantum Electron. (1)

D. Dangoisse, A. Deldalle, J. P. Splingard, J. Bellet, IEEE J. Quantum Electron. Q-E 13, 730 (1977).
[CrossRef]

J. Chem. Phys. (4)

T. Oka, J. Chem. Phys. 47, 13 (1967); Adv. At. Mol. Phys. 9, 127 (1973).
[CrossRef]

V. Prakash, J. E. Boggs, J. Chem. Phys. 57, 2599 (1972).
[CrossRef]

I. Burak, T. J. Quelly, J. I. Steinfeld, J. Chem. Phys. 70, 334 (1979).
[CrossRef]

E. S. Yeung, C. B. Moore, J. Chem. Phys. 58, 3988 (1973).
[CrossRef]

J. Chem. Soc. (1)

J. C. D. Brand, J. Chem. Soc. 858 (1956).

J. Mol. Spectrosc. (1)

D. Coffey, C. Yamada, E. Hirota, J. Mol. Spectrosc. 64, 98 (1977).
[CrossRef]

Jpn. J. Appl. Phys. (1)

M. Takami, K. Shimoda, Jpn. J. Appl. Phys. 11, 1648 (1972).
[CrossRef]

Spectrochim. Acta (1)

B. J. Orr, Spectrochim. Acta 30A, 1275 (1975).

Other (4)

J. I. Steinfeld, P. L. Houston, “Double-resonance spectroscopy,” in Laser and Coherence Spectroscopy, J. I. Steinfeld, ed. (Plenum, New York, 1978), pp. 1–123.

T. Nakagawa, University of Tokyo, Tokyo, Japan, personal communication (1976).

B. J. Orr, J. W. C. Johns, unpublished infrared absorption spectrum of D2CO vapor, recorded with a resolution of ~0.05 cm−1 in the 9–11-μm spectral region.

We use the notation JKaKc for the rotational levels of a near-prolate asymmetric rotor.

Cited By

OSA participates in CrossRef's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Metrics