Abstract

The development of coherent Fourier transform two-dimensional electronic-vibrational (2D EV) spectroscopy with acousto-optic pulse-shaper-generated near-UV pump pulses and an octave-spanning broadband mid-IR probe pulse is detailed. A 2D EV spectrum of a silicon wafer demonstrates the full experimental capability of this experiment, and a 2D EV spectrum of dissolved hexacyanoferrate establishes the viability of our 2D EV experiment for studying condensed phase molecular ensembles.

© 2016 Optical Society of America

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References

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2016 (1)

N. H. C. Lewis and G. R. Fleming, J. Phys. Chem. Lett. 7, 831 (2016).
[Crossref]

2015 (5)

P. Goyal, C. A. Schwerdtfeger, A. V. Soudackov, and S. Hammes-Schiffer, J. Phys. Chem. B 119, 2758 (2015).
[Crossref]

N. H. C. Lewis, H. Dong, T. A. A. Oliver, and G. R. Fleming, J. Chem. Phys. 142, 174202 (2015).
[Crossref]

T. L. Courtney, Z. W. Fox, K. M. Slenkamp, and M. Khalil, J. Chem. Phys. 143, 154201 (2015).
[Crossref]

T. L. Courtney, Z. W. Fox, L. Estergreen, and M. Khalil, J. Phys. Chem. Lett. 6, 1286 (2015).
[Crossref]

T. A. A. Oliver and G. R. Fleming, J. Phys. Chem. B 119, 11428 (2015).
[Crossref]

2014 (2)

T. A. A. Oliver, N. H. C. Lewis, and G. R. Fleming, Proc. Natl. Acad. Sci. USA 111, 10061 (2014).
[Crossref]

A. Mandal, K. Ramasesha, L. De Marco, and A. Tokmakoff, J. Chem. Phys. 140, 204508 (2014).
[Crossref]

2013 (4)

N. Krebs, I. Pugliesi, J. Hauer, and E. Riedle, New J. Phys. 15, 085016 (2013).
[Crossref]

B. A. West, J. M. Womick, and A. M. Moran, J. Phys. Chem. A 117, 5865 (2013).
[Crossref]

S. Luber, K. Adamczyk, E. T. J. Nibbering, and V. S. Batista, J. Phys. Chem. A 117, 5269 (2013).
[Crossref]

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

2012 (4)

B. A. West and A. M. Moran, J. Phys. Chem. Lett. 3, 2575 (2012).
[Crossref]

W. K. Zhang, M. B. Ji, Z. Sun, and K. J. Gaffney, J. Am. Chem. Soc. 134, 2581 (2012).
[Crossref]

M. Cheng, A. Reynolds, H. Widgren, and M. Khalil, Opt. Lett. 37, 1787 (2012).
[Crossref]

C. Calabrese, A. M. Stingel, L. Shen, and P. B. Petersen, Opt. Lett. 37, 2265 (2012).
[Crossref]

2010 (3)

2009 (1)

2008 (1)

2006 (1)

2003 (3)

G. Cerullo and S. De Silvestri, Rev. Sci. Instrum. 74, 1 (2003).
[Crossref]

M. Khalil, N. Demirdoven, and A. Tokmakoff, J. Phys. Chem. A 107, 5258 (2003).
[Crossref]

D. M. Jonas, Annu. Rev. Phys. Chem. 54, 425 (2003).
[Crossref]

2001 (1)

J. D. Hybl, A. A. Ferro, and D. M. Jonas, J. Chem. Phys. 115, 6606 (2001).
[Crossref]

2000 (1)

S. Mukamel, Annu. Rev. Phys. Chem. 51, 691 (2000).
[Crossref]

1995 (1)

Adamczyk, K.

S. Luber, K. Adamczyk, E. T. J. Nibbering, and V. S. Batista, J. Phys. Chem. A 117, 5269 (2013).
[Crossref]

Balasubramanian, M.

M. Balasubramanian, T. L. Courtney, J. D. Gaynor, and M. Khalil (in preparation) (2016).

Barthelemy, M.

S. Weber, M. Barthelemy, and B. Chatel, Appl. Phys. B 98, 323 (2010).
[Crossref]

Batista, V. S.

S. Luber, K. Adamczyk, E. T. J. Nibbering, and V. S. Batista, J. Phys. Chem. A 117, 5269 (2013).
[Crossref]

Bowlan, P.

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

Brixner, T.

Calabrese, C.

Cerullo, G.

G. Cerullo and S. De Silvestri, Rev. Sci. Instrum. 74, 1 (2003).
[Crossref]

Chatel, B.

S. Weber, M. Barthelemy, and B. Chatel, Appl. Phys. B 98, 323 (2010).
[Crossref]

Cheng, M.

Coudreau, S.

Courtney, T. L.

T. L. Courtney, Z. W. Fox, K. M. Slenkamp, and M. Khalil, J. Chem. Phys. 143, 154201 (2015).
[Crossref]

T. L. Courtney, Z. W. Fox, L. Estergreen, and M. Khalil, J. Phys. Chem. Lett. 6, 1286 (2015).
[Crossref]

M. Balasubramanian, T. L. Courtney, J. D. Gaynor, and M. Khalil (in preparation) (2016).

De Marco, L.

A. Mandal, K. Ramasesha, L. De Marco, and A. Tokmakoff, J. Chem. Phys. 140, 204508 (2014).
[Crossref]

De Silvestri, S.

G. Cerullo and S. De Silvestri, Rev. Sci. Instrum. 74, 1 (2003).
[Crossref]

Demirdoven, N.

M. Khalil, N. Demirdoven, and A. Tokmakoff, J. Phys. Chem. A 107, 5258 (2003).
[Crossref]

Dong, H.

N. H. C. Lewis, H. Dong, T. A. A. Oliver, and G. R. Fleming, J. Chem. Phys. 142, 174202 (2015).
[Crossref]

Elsaesser, T.

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

Estergreen, L.

T. L. Courtney, Z. W. Fox, L. Estergreen, and M. Khalil, J. Phys. Chem. Lett. 6, 1286 (2015).
[Crossref]

Ferro, A. A.

J. D. Hybl, A. A. Ferro, and D. M. Jonas, J. Chem. Phys. 115, 6606 (2001).
[Crossref]

Fleming, G. R.

N. H. C. Lewis and G. R. Fleming, J. Phys. Chem. Lett. 7, 831 (2016).
[Crossref]

T. A. A. Oliver and G. R. Fleming, J. Phys. Chem. B 119, 11428 (2015).
[Crossref]

N. H. C. Lewis, H. Dong, T. A. A. Oliver, and G. R. Fleming, J. Chem. Phys. 142, 174202 (2015).
[Crossref]

T. A. A. Oliver, N. H. C. Lewis, and G. R. Fleming, Proc. Natl. Acad. Sci. USA 111, 10061 (2014).
[Crossref]

Foerster, M.

Fox, Z. W.

T. L. Courtney, Z. W. Fox, L. Estergreen, and M. Khalil, J. Phys. Chem. Lett. 6, 1286 (2015).
[Crossref]

T. L. Courtney, Z. W. Fox, K. M. Slenkamp, and M. Khalil, J. Chem. Phys. 143, 154201 (2015).
[Crossref]

Gaffney, K. J.

W. K. Zhang, M. B. Ji, Z. Sun, and K. J. Gaffney, J. Am. Chem. Soc. 134, 2581 (2012).
[Crossref]

Gaynor, J. D.

M. Balasubramanian, T. L. Courtney, J. D. Gaynor, and M. Khalil (in preparation) (2016).

Goyal, P.

P. Goyal, C. A. Schwerdtfeger, A. V. Soudackov, and S. Hammes-Schiffer, J. Phys. Chem. B 119, 2758 (2015).
[Crossref]

Hammes-Schiffer, S.

P. Goyal, C. A. Schwerdtfeger, A. V. Soudackov, and S. Hammes-Schiffer, J. Phys. Chem. B 119, 2758 (2015).
[Crossref]

Hauer, J.

N. Krebs, I. Pugliesi, J. Hauer, and E. Riedle, New J. Phys. 15, 085016 (2013).
[Crossref]

Hybl, J. D.

J. D. Hybl, A. A. Ferro, and D. M. Jonas, J. Chem. Phys. 115, 6606 (2001).
[Crossref]

Ji, M. B.

W. K. Zhang, M. B. Ji, Z. Sun, and K. J. Gaffney, J. Am. Chem. Soc. 134, 2581 (2012).
[Crossref]

Jonas, D. M.

D. M. Jonas, Annu. Rev. Phys. Chem. 54, 425 (2003).
[Crossref]

J. D. Hybl, A. A. Ferro, and D. M. Jonas, J. Chem. Phys. 115, 6606 (2001).
[Crossref]

Kaplan, D.

Khalil, M.

T. L. Courtney, Z. W. Fox, L. Estergreen, and M. Khalil, J. Phys. Chem. Lett. 6, 1286 (2015).
[Crossref]

T. L. Courtney, Z. W. Fox, K. M. Slenkamp, and M. Khalil, J. Chem. Phys. 143, 154201 (2015).
[Crossref]

M. Cheng, A. Reynolds, H. Widgren, and M. Khalil, Opt. Lett. 37, 1787 (2012).
[Crossref]

M. Khalil, N. Demirdoven, and A. Tokmakoff, J. Phys. Chem. A 107, 5258 (2003).
[Crossref]

M. Balasubramanian, T. L. Courtney, J. D. Gaynor, and M. Khalil (in preparation) (2016).

Krebs, N.

N. Krebs, I. Pugliesi, J. Hauer, and E. Riedle, New J. Phys. 15, 085016 (2013).
[Crossref]

Kuehn, W.

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

Langhojer, F.

Lewis, K. L. M.

Lewis, N. H. C.

N. H. C. Lewis and G. R. Fleming, J. Phys. Chem. Lett. 7, 831 (2016).
[Crossref]

N. H. C. Lewis, H. Dong, T. A. A. Oliver, and G. R. Fleming, J. Chem. Phys. 142, 174202 (2015).
[Crossref]

T. A. A. Oliver, N. H. C. Lewis, and G. R. Fleming, Proc. Natl. Acad. Sci. USA 111, 10061 (2014).
[Crossref]

Luber, S.

S. Luber, K. Adamczyk, E. T. J. Nibbering, and V. S. Batista, J. Phys. Chem. A 117, 5269 (2013).
[Crossref]

Mandal, A.

A. Mandal, K. Ramasesha, L. De Marco, and A. Tokmakoff, J. Chem. Phys. 140, 204508 (2014).
[Crossref]

Matsika, S.

Meyerhofer, D. D.

Moran, A. M.

B. A. West, J. M. Womick, and A. M. Moran, J. Phys. Chem. A 117, 5865 (2013).
[Crossref]

B. A. West and A. M. Moran, J. Phys. Chem. Lett. 3, 2575 (2012).
[Crossref]

Mukamel, S.

S. Mukamel, Annu. Rev. Phys. Chem. 51, 691 (2000).
[Crossref]

Myers, J. A.

Nibbering, E. T. J.

S. Luber, K. Adamczyk, E. T. J. Nibbering, and V. S. Batista, J. Phys. Chem. A 117, 5269 (2013).
[Crossref]

Nuernberger, P.

Ogilvie, J. P.

Oliver, T. A. A.

N. H. C. Lewis, H. Dong, T. A. A. Oliver, and G. R. Fleming, J. Chem. Phys. 142, 174202 (2015).
[Crossref]

T. A. A. Oliver and G. R. Fleming, J. Phys. Chem. B 119, 11428 (2015).
[Crossref]

T. A. A. Oliver, N. H. C. Lewis, and G. R. Fleming, Proc. Natl. Acad. Sci. USA 111, 10061 (2014).
[Crossref]

Petersen, P. B.

Pugliesi, I.

N. Krebs, I. Pugliesi, J. Hauer, and E. Riedle, New J. Phys. 15, 085016 (2013).
[Crossref]

Ramasesha, K.

A. Mandal, K. Ramasesha, L. De Marco, and A. Tokmakoff, J. Chem. Phys. 140, 204508 (2014).
[Crossref]

Reimann, K.

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

Reynolds, A.

Riedle, E.

N. Krebs, I. Pugliesi, J. Hauer, and E. Riedle, New J. Phys. 15, 085016 (2013).
[Crossref]

Schleussner, C. F.

Schwerdtfeger, C. A.

P. Goyal, C. A. Schwerdtfeger, A. V. Soudackov, and S. Hammes-Schiffer, J. Phys. Chem. B 119, 2758 (2015).
[Crossref]

Selig, U.

Shen, L.

Slenkamp, K. M.

T. L. Courtney, Z. W. Fox, K. M. Slenkamp, and M. Khalil, J. Chem. Phys. 143, 154201 (2015).
[Crossref]

Soudackov, A. V.

P. Goyal, C. A. Schwerdtfeger, A. V. Soudackov, and S. Hammes-Schiffer, J. Phys. Chem. B 119, 2758 (2015).
[Crossref]

Stingel, A. M.

Sun, Z.

W. K. Zhang, M. B. Ji, Z. Sun, and K. J. Gaffney, J. Am. Chem. Soc. 134, 2581 (2012).
[Crossref]

Tekavec, P. F.

Tokmakoff, A.

A. Mandal, K. Ramasesha, L. De Marco, and A. Tokmakoff, J. Chem. Phys. 140, 204508 (2014).
[Crossref]

P. B. Petersen and A. Tokmakoff, Opt. Lett. 35, 1962 (2010).
[Crossref]

M. Khalil, N. Demirdoven, and A. Tokmakoff, J. Phys. Chem. A 107, 5258 (2003).
[Crossref]

Tournois, P.

Tseng, C. H.

Weber, S.

S. Weber, M. Barthelemy, and B. Chatel, Appl. Phys. B 98, 323 (2010).
[Crossref]

Weinacht, T. C.

West, B. A.

B. A. West, J. M. Womick, and A. M. Moran, J. Phys. Chem. A 117, 5865 (2013).
[Crossref]

B. A. West and A. M. Moran, J. Phys. Chem. Lett. 3, 2575 (2012).
[Crossref]

Widgren, H.

Woerner, M.

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

Womick, J. M.

B. A. West, J. M. Womick, and A. M. Moran, J. Phys. Chem. A 117, 5865 (2013).
[Crossref]

Zhang, W. K.

W. K. Zhang, M. B. Ji, Z. Sun, and K. J. Gaffney, J. Am. Chem. Soc. 134, 2581 (2012).
[Crossref]

Zheng, L.

Annu. Rev. Phys. Chem. (2)

S. Mukamel, Annu. Rev. Phys. Chem. 51, 691 (2000).
[Crossref]

D. M. Jonas, Annu. Rev. Phys. Chem. 54, 425 (2003).
[Crossref]

Appl. Phys. B (1)

S. Weber, M. Barthelemy, and B. Chatel, Appl. Phys. B 98, 323 (2010).
[Crossref]

J. Am. Chem. Soc. (1)

W. K. Zhang, M. B. Ji, Z. Sun, and K. J. Gaffney, J. Am. Chem. Soc. 134, 2581 (2012).
[Crossref]

J. Chem. Phys. (4)

A. Mandal, K. Ramasesha, L. De Marco, and A. Tokmakoff, J. Chem. Phys. 140, 204508 (2014).
[Crossref]

J. D. Hybl, A. A. Ferro, and D. M. Jonas, J. Chem. Phys. 115, 6606 (2001).
[Crossref]

N. H. C. Lewis, H. Dong, T. A. A. Oliver, and G. R. Fleming, J. Chem. Phys. 142, 174202 (2015).
[Crossref]

T. L. Courtney, Z. W. Fox, K. M. Slenkamp, and M. Khalil, J. Chem. Phys. 143, 154201 (2015).
[Crossref]

J. Phys. Chem. A (3)

B. A. West, J. M. Womick, and A. M. Moran, J. Phys. Chem. A 117, 5865 (2013).
[Crossref]

S. Luber, K. Adamczyk, E. T. J. Nibbering, and V. S. Batista, J. Phys. Chem. A 117, 5269 (2013).
[Crossref]

M. Khalil, N. Demirdoven, and A. Tokmakoff, J. Phys. Chem. A 107, 5258 (2003).
[Crossref]

J. Phys. Chem. B (2)

P. Goyal, C. A. Schwerdtfeger, A. V. Soudackov, and S. Hammes-Schiffer, J. Phys. Chem. B 119, 2758 (2015).
[Crossref]

T. A. A. Oliver and G. R. Fleming, J. Phys. Chem. B 119, 11428 (2015).
[Crossref]

J. Phys. Chem. Lett. (3)

N. H. C. Lewis and G. R. Fleming, J. Phys. Chem. Lett. 7, 831 (2016).
[Crossref]

T. L. Courtney, Z. W. Fox, L. Estergreen, and M. Khalil, J. Phys. Chem. Lett. 6, 1286 (2015).
[Crossref]

B. A. West and A. M. Moran, J. Phys. Chem. Lett. 3, 2575 (2012).
[Crossref]

New J. Phys. (2)

N. Krebs, I. Pugliesi, J. Hauer, and E. Riedle, New J. Phys. 15, 085016 (2013).
[Crossref]

M. Woerner, W. Kuehn, P. Bowlan, K. Reimann, and T. Elsaesser, New J. Phys. 15, 025039 (2013).
[Crossref]

Opt. Express (2)

Opt. Lett. (6)

Proc. Natl. Acad. Sci. USA (1)

T. A. A. Oliver, N. H. C. Lewis, and G. R. Fleming, Proc. Natl. Acad. Sci. USA 111, 10061 (2014).
[Crossref]

Rev. Sci. Instrum. (1)

G. Cerullo and S. De Silvestri, Rev. Sci. Instrum. 74, 1 (2003).
[Crossref]

Other (1)

M. Balasubramanian, T. L. Courtney, J. D. Gaynor, and M. Khalil (in preparation) (2016).

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Figures (3)

Fig. 1.
Fig. 1.

(a) Optical table schematic; the Ti:sapphire output is split into the broadband mid-IR (BBIR) probe pulse (solid green), an 800 nm characterization pulse (dashed red), and the pump pulse (solid blue). The BBIR is generated via filamentation of the 800 nm fundamental and its second harmonic in gaseous media and compressed with material compensation (2 mm Ge) and a deformable mirror compressor (DMC). The pump pulse is chopped (500 Hz) and shaped in an acousto-optic programmable dispersive filter (AOPDF). The orientation of all beams before focusing to the sample (S) is shown, and filled circles indicate beams that generate 2D EV signal. The signal (Sig, purple) and reference (Ref, dashed green) are both dispersed in a spectrometer (Spec) and detected in a 2 × 64 HgCdTe-pixel array (MCT) detector. λ / 2 , half-wave plate; Pol, polarizer; 2 1 , down-collimating telescope. (b) 2D EV experimental pulse sequence. (c) Spectral interferogram of two pump pulses, k 1 and k 2 , at τ 1 = 200    fs (solid black), with the pump pulse spectrum overlaid (dashed black). (d) Extracted phase difference between pump pulses, Δ φ 12 (black dots), is plotted for the center frequency ( ω 0 = 25,000    cm 1 ) over experimental time, t.

Fig. 2.
Fig. 2.

2D EV spectrum of Si at τ 2 = 200    fs . The real part of the FT is plotted as Δ T with red = positive ( green = 0 , blue = negative ) contours plotted from 1 to 1 every 10%. The highest contour corresponds to a change in absorbance of + 0.05 OD. Savitzky–Golay filtering is used to remove the effect of atmospheric water absorption in the BBIR spectra. The top and side panels show pump and probe spectra, respectively.

Fig. 3.
Fig. 3.

2D EV spectrum of K 3 [ Fe ( CN ) 6 ] in FA plotted as Δ T at τ 2 = 500    f s . The spectrum is normalized to the absolute maximum value in the 2D plot and plotted from 1 to 1; the contour separation = 10 % . The maximum contour corresponds to a change in absorbance of 0.004 OD. Top panel: 400 nm pump (dashed gray) and UV/Vis absorption (solid black) spectra. Side panel: BBIR probe (dashed gray) and transient-IR (solid black) spectra; 2D EV projection (dotted black).

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