Abstract

A mid-infrared saturable absorber mirror is successfully fabricated by transferring the mechanically exfoliated black phosphorus onto the gold-coated mirror. With the as-prepared black phosphorus saturable absorber mirror, a continuous-wave passively mode-locked Er:ZBLAN fiber laser is demonstrated at the wavelength of 2.8 μm, which delivers a maximum average output power of 613 mW, a repetition rate of 24 MHz, and a pulse duration of 42 ps. To the best of our knowledge, this is the first time a black phosphorus mode-locked laser at 2.8 μm wavelength has been demonstrated. Our results demonstrate the feasibility of black phosphorus flake as a new two-dimensional material for application in mid-infrared ultrafast photonics.

© 2015 Optical Society of America

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T. Hu, D. D. Hudson, and S. D. Jackson, Opt. Lett. 39, 2133 (2014).
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A. Haboucha, V. Fortin, M. Bernier, J. Genest, Y. Messaddeq, and R. Vallée, Opt. Lett. 39, 3294 (2014).
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2012 (4)

2011 (3)

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
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2010 (1)

J. E. Moore, Nature 464, 194 (2010).
[Crossref]

2009 (2)

H. Zhang, C. Liu, X. Qi, X. Dai, Z. Fang, and S. Zhang, Nat. Phys. 5, 438 (2009).
[Crossref]

A. K. Geim, Science 324, 1530 (2009).
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2008 (1)

J. M. Dawlaty, S. Shivaraman, M. Chandrashekhar, F. Rana, and M. G. Spencer, Appl. Phys. Lett. 92, 042116 (2008).
[Crossref]

2007 (1)

A. Ayari, E. Cobas, O. Ogundadegbe, and M. S. Fuhrer, J. Appl. Phys. 101, 014507 (2007).
[Crossref]

2004 (1)

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
[Crossref]

1997 (1)

Y. Akahama, M. Kobayashi, and H. Kawamura, Solid State Commun. 104, 311 (1997).
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1994 (1)

1972 (1)

A. A. Al-Hilli and B. L. Evans, J. Cryst. Growth 15, 93 (1972).
[Crossref]

Abramsi, K. M.

J. Sotor, G. Sobon, W. Macherzynski, P. Paletko, and K. M. Abramsi, Appl. Phys. Lett. 107, 051108 (2015).
[Crossref]

Abramski, K. M.

Agger, C.

Akahama, Y.

Y. Akahama, M. Kobayashi, and H. Kawamura, Solid State Commun. 104, 311 (1997).
[Crossref]

Al-Hilli, A. A.

A. A. Al-Hilli and B. L. Evans, J. Cryst. Growth 15, 93 (1972).
[Crossref]

Ayari, A.

A. Ayari, E. Cobas, O. Ogundadegbe, and M. S. Fuhrer, J. Appl. Phys. 101, 014507 (2007).
[Crossref]

Bang, O.

Bao, H.

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

Bao, Q.

Y. Chen, G. Jiang, S. Chen, Z. Guo, X. Yu, C. Zhao, H. Zhang, Q. Bao, S. Wen, D. Tang, and D. Fan, Opt. Express 23, 12823 (2015).
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H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

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B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, and A. Kis, Nat. Nanotechnol. 6, 147 (2011).
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Chandrashekhar, M.

J. M. Dawlaty, S. Shivaraman, M. Chandrashekhar, F. Rana, and M. G. Spencer, Appl. Phys. Lett. 92, 042116 (2008).
[Crossref]

Chen, S.

Chen, X.

D. Li, H. Jussila, L. Karvonen, G. Ye, H. Lipsanen, X. Chen, and Z. Sun, “Ultrafast pulse generation with black phosphorus,” arXiv: 1505.00480 (2015).

Chen, X. H.

L. Li, Y. Yu, G. J. Ye, Q. Ge, X. Ou, H. Wu, D. Feng, X. H. Chen, and Y. Zhang, Nat. Nanotechnol. 9, 372 (2014).
[Crossref]

Chen, Y.

Y. Chen, G. Jiang, S. Chen, Z. Guo, X. Yu, C. Zhao, H. Zhang, Q. Bao, S. Wen, D. Tang, and D. Fan, Opt. Express 23, 12823 (2015).
[Crossref]

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

Cheng, X.

T. Jiang, K. Yin, X. Zheng, H. Yu, and X. Cheng, “Black phosphorus as a new broadband saturable absorber for infrared passively Q-switched fiber laser,” arXiv: 1504.07341 (2015).

K. Yin, T. Jiang, H. Yu, X. Zheng, X. Cheng, and J. Hou, “Mid-infrared ultra-short mode-locked fiber laser utilizing topological insulator Bi2Te3 nano-sheets as the saturable absorber,” arXiv: 1505.06322 (2015).

Cobas, E.

A. Ayari, E. Cobas, O. Ogundadegbe, and M. S. Fuhrer, J. Appl. Phys. 101, 014507 (2007).
[Crossref]

Dai, X.

H. Zhang, C. Liu, X. Qi, X. Dai, Z. Fang, and S. Zhang, Nat. Phys. 5, 438 (2009).
[Crossref]

Dawlaty, J. M.

J. M. Dawlaty, S. Shivaraman, M. Chandrashekhar, F. Rana, and M. G. Spencer, Appl. Phys. Lett. 92, 042116 (2008).
[Crossref]

Deng, Y.

H. Liu, Y. Du, Y. Deng, and P. D. Ye, Chem. Soc. Rev. 44, 2732 (2015).
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Du, Y.

H. Liu, Y. Du, Y. Deng, and P. D. Ye, Chem. Soc. Rev. 44, 2732 (2015).
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Dubonos, S. V.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
[Crossref]

Dupont, S.

Duval, S.

Echtermeyer, T. J.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
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Evans, B. L.

A. A. Al-Hilli and B. L. Evans, J. Cryst. Growth 15, 93 (1972).
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Fan, D.

Y. Chen, G. Jiang, S. Chen, Z. Guo, X. Yu, C. Zhao, H. Zhang, Q. Bao, S. Wen, D. Tang, and D. Fan, Opt. Express 23, 12823 (2015).
[Crossref]

J. Ma, S. Lu, Z. Guo, X. Xu, H. Zhang, D. Tang, and D. Fan, Opt. Express 23, 22643 (2015).
[Crossref]

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

Fan, D. Y.

Fang, Z.

H. Zhang, C. Liu, X. Qi, X. Dai, Z. Fang, and S. Zhang, Nat. Phys. 5, 438 (2009).
[Crossref]

Feng, D.

L. Li, Y. Yu, G. J. Ye, Q. Ge, X. Ou, H. Wu, D. Feng, X. H. Chen, and Y. Zhang, Nat. Nanotechnol. 9, 372 (2014).
[Crossref]

Ferrari, A. C.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
[Crossref]

Firsov, V. V.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
[Crossref]

Fortin, V.

Fuhrer, M. S.

A. Ayari, E. Cobas, O. Ogundadegbe, and M. S. Fuhrer, J. Appl. Phys. 101, 014507 (2007).
[Crossref]

Gan, F.

Gao, W. L.

Ge, Q.

L. Li, Y. Yu, G. J. Ye, Q. Ge, X. Ou, H. Wu, D. Feng, X. H. Chen, and Y. Zhang, Nat. Nanotechnol. 9, 372 (2014).
[Crossref]

Geim, A. K.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
[Crossref]

A. K. Geim, Science 324, 1530 (2009).
[Crossref]

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
[Crossref]

Genest, J.

Geng, B.

M. Liu, X. Yin, E. Ulin-Avila, B. Geng, T. Zentgraf, L. Ju, F. Wang, and X. Zhang, Nature 474, 64 (2011).
[Crossref]

Giacometti, V.

B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, and A. Kis, Nat. Nanotechnol. 6, 147 (2011).
[Crossref]

Gorbachev, R. V.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
[Crossref]

Grigorenko, A. N.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
[Crossref]

Grigorieva, I. V.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
[Crossref]

Guo, Z.

Guo, Z. N.

Haboucha, A.

He, J.

Hou, J.

K. Yin, T. Jiang, H. Yu, X. Zheng, X. Cheng, and J. Hou, “Mid-infrared ultra-short mode-locked fiber laser utilizing topological insulator Bi2Te3 nano-sheets as the saturable absorber,” arXiv: 1505.06322 (2015).

Hu, T.

Hudson, D. D.

Jackson, S. D.

Jasnos, P. K.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
[Crossref]

Jiang, D.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
[Crossref]

Jiang, G.

Jiang, T.

K. Yin, T. Jiang, H. Yu, X. Zheng, X. Cheng, and J. Hou, “Mid-infrared ultra-short mode-locked fiber laser utilizing topological insulator Bi2Te3 nano-sheets as the saturable absorber,” arXiv: 1505.06322 (2015).

T. Jiang, K. Yin, X. Zheng, H. Yu, and X. Cheng, “Black phosphorus as a new broadband saturable absorber for infrared passively Q-switched fiber laser,” arXiv: 1504.07341 (2015).

Jiang, X.

Ju, L.

M. Liu, X. Yin, E. Ulin-Avila, B. Geng, T. Zentgraf, L. Ju, F. Wang, and X. Zhang, Nature 474, 64 (2011).
[Crossref]

Jussila, H.

D. Li, H. Jussila, L. Karvonen, G. Ye, H. Lipsanen, X. Chen, and Z. Sun, “Ultrafast pulse generation with black phosphorus,” arXiv: 1505.00480 (2015).

Karvonen, L.

D. Li, H. Jussila, L. Karvonen, G. Ye, H. Lipsanen, X. Chen, and Z. Sun, “Ultrafast pulse generation with black phosphorus,” arXiv: 1505.00480 (2015).

Kawamura, H.

Y. Akahama, M. Kobayashi, and H. Kawamura, Solid State Commun. 104, 311 (1997).
[Crossref]

Keiding, S. R.

Kis, A.

B. Radisavljevic, A. Radenovic, J. Brivio, V. Giacometti, and A. Kis, Nat. Nanotechnol. 6, 147 (2011).
[Crossref]

Kobayashi, M.

Y. Akahama, M. Kobayashi, and H. Kawamura, Solid State Commun. 104, 311 (1997).
[Crossref]

Kong, L.

L. Kong, Z. Qin, G. Xie, Z. Guo, H. Zhang, P. Yuan, and L. Qian, “Multiplayer black phosphorus as broadband saturable absorber for puled lasers from 1  μm to 2.7  μm wavelength,” arXiv: 1508.04510 (2015).

Kowalczyk, M.

Lau, S. P.

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

Li, D.

D. Li, H. Jussila, L. Karvonen, G. Ye, H. Lipsanen, X. Chen, and Z. Sun, “Ultrafast pulse generation with black phosphorus,” arXiv: 1505.00480 (2015).

Li, J.

Li, L.

L. Li, Y. Yu, G. J. Ye, Q. Ge, X. Ou, H. Wu, D. Feng, X. H. Chen, and Y. Zhang, Nat. Nanotechnol. 9, 372 (2014).
[Crossref]

Li, P.

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

Liang, Y.

V. Tran, R. Soklaski, Y. Liang, and L. Yang, Phys. Rev. B 89, 235319 (2014).
[Crossref]

Lin, S.

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

Lipsanen, H.

D. Li, H. Jussila, L. Karvonen, G. Ye, H. Lipsanen, X. Chen, and Z. Sun, “Ultrafast pulse generation with black phosphorus,” arXiv: 1505.00480 (2015).

Liu, C.

H. Zhang, C. Liu, X. Qi, X. Dai, Z. Fang, and S. Zhang, Nat. Phys. 5, 438 (2009).
[Crossref]

Liu, H.

H. Liu, Y. Du, Y. Deng, and P. D. Ye, Chem. Soc. Rev. 44, 2732 (2015).
[Crossref]

Liu, J.

Liu, M.

Z. Luo, M. Liu, Z. Guo, X. Jiang, A. Luo, C. Zhao, X. Yu, W. Xu, and H. Zhang, Opt. Express 23, 20030 (2015).
[Crossref]

M. Liu, X. Yin, E. Ulin-Avila, B. Geng, T. Zentgraf, L. Ju, F. Wang, and X. Zhang, Nature 474, 64 (2011).
[Crossref]

Liu, Y.

Liu, Z.

R. Zhang, Y. Zhang, H. Yu, H. Zhang, R. Yang, B. Yang, Z. Liu, and J. Wang, “Broadband black phosphorus optical modulator in visible to mid-infrared spectral range,” arXiv: 1505.05992 (2015).

Lombardo, A.

T. J. Echtermeyer, L. Britnell, P. K. Jasnos, A. Lombardo, R. V. Gorbachev, A. N. Grigorenko, A. K. Geim, A. C. Ferrari, and K. S. Novoselov, Nat. Commun. 2, 458 (2011).
[Crossref]

Lou, F.

Lu, S.

Lu, S. B.

Luo, A.

Luo, Z.

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Appl. Opt. (1)

Appl. Phys. Lett. (2)

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J. Opt. Soc. Am. B (1)

Nat. Commun. (1)

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Nat. Phys. (1)

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J. E. Moore, Nature 464, 194 (2010).
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Opt. Express (5)

Opt. Lett. (9)

Optica (1)

Phys. Rev. B (1)

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Science (2)

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and V. V. Firsov, Science 306, 666 (2004).
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Other (6)

T. Jiang, K. Yin, X. Zheng, H. Yu, and X. Cheng, “Black phosphorus as a new broadband saturable absorber for infrared passively Q-switched fiber laser,” arXiv: 1504.07341 (2015).

K. Yin, T. Jiang, H. Yu, X. Zheng, X. Cheng, and J. Hou, “Mid-infrared ultra-short mode-locked fiber laser utilizing topological insulator Bi2Te3 nano-sheets as the saturable absorber,” arXiv: 1505.06322 (2015).

H. Mu, S. Lin, Z. Wang, S. Xiao, P. Li, Y. Chen, H. Zhang, H. Bao, S. P. Lau, C. Pan, D. Fan, and Q. Bao, “Black phosphorus-polymer composites for pulsed lasers,” arXiv: 1506.06896 (2015).

L. Kong, Z. Qin, G. Xie, Z. Guo, H. Zhang, P. Yuan, and L. Qian, “Multiplayer black phosphorus as broadband saturable absorber for puled lasers from 1  μm to 2.7  μm wavelength,” arXiv: 1508.04510 (2015).

R. Zhang, Y. Zhang, H. Yu, H. Zhang, R. Yang, B. Yang, Z. Liu, and J. Wang, “Broadband black phosphorus optical modulator in visible to mid-infrared spectral range,” arXiv: 1505.05992 (2015).

D. Li, H. Jussila, L. Karvonen, G. Ye, H. Lipsanen, X. Chen, and Z. Sun, “Ultrafast pulse generation with black phosphorus,” arXiv: 1505.00480 (2015).

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Figures (6)

Fig. 1.
Fig. 1. (a) Raman spectrum of BP the flake sample. (b) Morphology of the BP flake measured by the scanning electron microscopy (SEM). (c) Three-dimensional morphology of the BP flake scanned by atomic force microscopy (AFM). (d) Thickness of the BP flake.
Fig. 2.
Fig. 2. Saturable absorption measurement of BP SAM at 2.8 μm. Inset: experimental setup for saturable absorption measurement.
Fig. 3.
Fig. 3. Schematic of the mode-locked Er:ZBLAN fiber laser. DM, dichroic mirror; ROC, radius of curvature; BP SAM, black phosphorus saturable absorber mirror.
Fig. 4.
Fig. 4. Output average power versus incident pump power in different regimes. CW, continuous-wave; QML, Q-switched mode locking; CWML, continuous-wave mode locking.
Fig. 5.
Fig. 5. (a) CW mode-locked pulse trains in nanosecond and microsecond time scales. (b) RF spectrum of the mode-locked pulse trains with a span of 0.6 MHz. Inset: the wide-span RF spectrum from 10 to 250 MHz.
Fig. 6.
Fig. 6. (a) Autocorrelation trace of the mode-locked pulses. (b) The corresponding mode-locked pulse spectrum.

Tables (1)

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Table 1. Summary of 3-μm Mode-Locked Fiber Lasers

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