Abstract
Femtosecond transient difference absorption (fs TA) measurements, together with a series of open-aperture scans at picosecond and nanosecond pulse widths and a variety of pulse energies, were performed on a 1,10-phenanthrolinyl iridium(III) complex bearing ligands containing a benzothiazolylfluorenyl motif. An analysis of decay data from the fs TA experiment yields a value of for the singlet excited-state lifetime of the complex. By fitting the scans to a five-level dynamic model incorporating the independently measured value of and previously reported values of the complex’s triplet quantum yield (0.13) and triplet excited-state lifetime (230 ns), we obtain values of (singlet) and (triplet) for the excited-state absorption cross-sections of the complex in toluene solution at 532 nm; the latter value represents one of the largest triplet excited-state absorption cross-sections ever reported at this wavelength. The ratio of the triplet excited-state cross-section to the ground-state absorption cross-section exceeds 3800.
© 2015 Optical Society of America
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