Abstract

Luminescent properties of Sb3+/Mn2+ co-doped borosilicate glasses containing no rare earth ions were systematically investigated through absorption, excitation, emission spectra, and decay curves. Upon 250–340 nm light excitation, the glasses exhibit broad blue emission at 400 nm (Sb3+) and red emission at 615 nm (Mn2+). The varied emitted color from blue through white and eventually to red can be obtained by properly tuning the content of Mn2+ ions due to energy transfer from Sb3+ to Mn2+. Our investigation shows that Sb3+/Mn2+ co-doped glasses may provide a new platform to design and fabricate luminescent materials for UV LED chips in the future.

© 2012 Optical Society of America

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[CrossRef]

H. Guo, R. F. Wei, and X. Y. Liu, Opt. Lett. 37, 1670 (2012).
[CrossRef]

C. H. Hsu, S. Das, and C. H. Lu, J. Electrochem. Soc. 159, J193 (2012).
[CrossRef]

2011

S. Nigam, V. Sudarsan, and R. K. Vatsa, Opt. Mater. 33, 558 (2011).
[CrossRef]

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

H. Masai, T. Fujiwara, S. Matsumoto, Y. Takahashi, K. Iwasaki, Y. Tokuda, and T. Yoko, Opt. Lett. 36, 2868 (2011).
[CrossRef]

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Y. Yu, Z. Liu, N. Dai, Y. Sheng, H. Luan, J. Peng, Z. Jiang, H. Li, J. Li, and L. Yang, Opt. Express 19, 19473 (2011).
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C. H. Huang and T. M. Chen, J. Phys. Chem. C. 115, 2349 (2011).
[CrossRef]

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
[CrossRef]

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang, J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

2010

2009

2005

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

2002

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

1988

E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, Phys. Rev. B 37, 18 (1988).
[CrossRef]

Blasse, G.

E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, Phys. Rev. B 37, 18 (1988).
[CrossRef]

Chen, D.

Chen, J. S.

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

Chen, T. M.

C. H. Huang and T. M. Chen, J. Phys. Chem. C. 115, 2349 (2011).
[CrossRef]

Cheng, Z. Y.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Da, N.

Dai, N.

Das, S.

C. H. Hsu, S. Das, and C. H. Lu, J. Electrochem. Soc. 159, J193 (2012).
[CrossRef]

Ding, H.

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

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M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
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Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
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Fan, X. P.

Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
[CrossRef]

Fujiwara, T.

Gao, G.

Geng, D. L.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Guan, M.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Guo, H.

H. Guo, F. Li, R. Wei, H. Zhang, and C. Ma, J. Am. Ceram. Soc. 95, 1178 (2012).
[CrossRef]

H. Guo, R. F. Wei, and X. Y. Liu, Opt. Lett. 37, 1670 (2012).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang, J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

H. Guo, H. Zhang, J. J. Li, and F. Li, Opt. Express 18, 27257 (2010).
[CrossRef]

Guo, N.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Hao, Z. D.

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

Hsu, C. H.

C. H. Hsu, S. Das, and C. H. Lu, J. Electrochem. Soc. 159, J193 (2012).
[CrossRef]

Huang, C. H.

C. H. Huang and T. M. Chen, J. Phys. Chem. C. 115, 2349 (2011).
[CrossRef]

Huang, P.

Huang, Y. J.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Huo, H.

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

Iskandar, F.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

Iwasaki, K.

Jiang, Z.

Kaihatsu, Y.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

Kim, J. K.

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

Li, F.

H. Guo, F. Li, R. Wei, H. Zhang, and C. Ma, J. Am. Ceram. Soc. 95, 1178 (2012).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang, J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

H. Guo, H. Zhang, J. J. Li, and F. Li, Opt. Express 18, 27257 (2010).
[CrossRef]

Li, G. G.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Li, H.

Li, J.

Li, J. J.

Lin, G.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Lin, H.

Lin, J.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Liu, X. Y.

Liu, Z.

Lu, C. H.

C. H. Hsu, S. Das, and C. H. Lu, J. Electrochem. Soc. 159, J193 (2012).
[CrossRef]

Luan, H.

Luo, Q.

Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
[CrossRef]

Luo, Y. S.

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

Ma, C.

H. Guo, F. Li, R. Wei, H. Zhang, and C. Ma, J. Am. Ceram. Soc. 95, 1178 (2012).
[CrossRef]

Masai, H.

Matsumoto, S.

Nigam, S.

S. Nigam, V. Sudarsan, and R. K. Vatsa, Opt. Mater. 33, 558 (2011).
[CrossRef]

Ogi, T.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

Okuyama, K.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

Oomen, E. W. J. L.

E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, Phys. Rev. B 37, 18 (1988).
[CrossRef]

Parmentier, A. B.

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

Peng, C.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Peng, J.

Poelman, D.

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

Qiao, X. S.

Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
[CrossRef]

Qiu, J.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Rademann, K.

M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
[CrossRef]

Reibstein, S.

Schubert, E. F.

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

Shan, Z.

Shang, M. M.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

Sheng, Y.

Smedskjr, M. M.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Smet, P. F.

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

Smit, W. M. A.

E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, Phys. Rev. B 37, 18 (1988).
[CrossRef]

Song, Y. H.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Sudarsan, V.

S. Nigam, V. Sudarsan, and R. K. Vatsa, Opt. Mater. 33, 558 (2011).
[CrossRef]

Takahashi, Y.

Tokuda, Y.

Vatsa, R. K.

S. Nigam, V. Sudarsan, and R. K. Vatsa, Opt. Mater. 33, 558 (2011).
[CrossRef]

Wang, W. N.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

Wang, X.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Wang, Y.

Wei, R.

H. Guo, F. Li, R. Wei, H. Zhang, and C. Ma, J. Am. Ceram. Soc. 95, 1178 (2012).
[CrossRef]

Wei, R. F.

Wen, F. S.

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

Weng, F.

Wondraczek, L.

Xie, J.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Yang, L.

Yang, M.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Yoko, T.

You, H. P.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Yu, J. Y.

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

Yu, Y.

Zhang, H.

H. Guo, F. Li, R. Wei, H. Zhang, and C. Ma, J. Am. Ceram. Soc. 95, 1178 (2012).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang, J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

H. Guo, H. Zhang, J. J. Li, and F. Li, Opt. Express 18, 27257 (2010).
[CrossRef]

Zhang, J. H.

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

Zhang, X.

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

Zhang, X. H.

Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
[CrossRef]

Zhao, X.

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

Zheng, Y. H.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Zhuang, Y.

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

Adv. Funct. Mater.

M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
[CrossRef]

Chem. Commun.

J. Y. Yu, Z. D. Hao, X. Zhang, Y. S. Luo, and J. H. Zhang, Chem. Commun. 47, 12376 (2011).
[CrossRef]

J. Am. Ceram. Soc.

Q. Luo, X. S. Qiao, X. P. Fan, B. Fan, and X. H. Zhang, J. Am. Ceram. Soc. 94, 1670 (2011).
[CrossRef]

H. Guo, F. Li, R. Wei, H. Zhang, and C. Ma, J. Am. Ceram. Soc. 95, 1178 (2012).
[CrossRef]

J. Electrochem. Soc.

H. Guo, J. Li, F. Li, and H. Zhang, J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

M. Guan, X. Wang, Y. Zhuang, G. Lin, J. Xie, M. M. Smedskjr, and J. Qiu, J. Electrochem. Soc. 158, G151 (2011).
[CrossRef]

C. H. Hsu, S. Das, and C. H. Lu, J. Electrochem. Soc. 159, J193 (2012).
[CrossRef]

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

J. Mater. Chem.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, J. Mater. Chem. 21, 13334 (2011).
[CrossRef]

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, J. Mater. Chem. 21, 5183 (2011).
[CrossRef]

F. S. Wen, X. Zhao, H. Ding, H. Huo, and J. S. Chen, J. Mater. Chem. 12, 3761 (2002).
[CrossRef]

J. Phys. Chem. C.

C. H. Huang and T. M. Chen, J. Phys. Chem. C. 115, 2349 (2011).
[CrossRef]

Opt. Express

Opt. Lett.

Opt. Mater.

S. Nigam, V. Sudarsan, and R. K. Vatsa, Opt. Mater. 33, 558 (2011).
[CrossRef]

Phys. Chem. Chem. Phys.

N. Guo, Y. J. Huang, M. Yang, Y. H. Song, Y. H. Zheng, and H. P. You, Phys. Chem. Chem. Phys. 13, 15077 (2011).
[CrossRef]

Phys. Rev. B

E. W. J. L. Oomen, W. M. A. Smit, and G. Blasse, Phys. Rev. B 37, 18 (1988).
[CrossRef]

Science

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

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Figures (2)

Fig. 1.
Fig. 1.

(a) Transmission spectra of the G-host, GS2, and GSMy samples. (b) Excitation and emission spectra of GSx samples. (c) Spectral overlap between excitation of the GM1.2 and emission of GS2 samples, emission spectra of GM1.2 sample. (d) Emission spectra of the G-host, GM1.2, and GSMy samples.

Fig. 2.
Fig. 2.

(a) Decay curves of Sb 3 + emission in GSMy ( y = 0 , 0.2, 0.5, 0.8, 1.2, 2, 3, 4, 5, 6) samples. (b) Energy-level diagram of Sb 3 + and Mn 2 + and possible ET process. (c) The CIE chromaticity diagram corresponding to the emission of the GSMy samples less than 300 nm in excitation. (d) Photos of the GS2, GSM1.2, GSM2, and GSM6 samples excited by 300 nm light.

Equations (2)

Equations on this page are rendered with MathJax. Learn more.

τ ¯ y = 0 t I ( t ) d t / 0 I ( t ) d t ,
η ET = 1 τ ¯ y / τ ¯ 0 .

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