Abstract

Luminescent properties of (Cu+)2, Eu3+ single-doped and codoped sodium silicate glasses were systematically investigated by excitation spectra, emission spectra, and decay curves. Due to the efficient energy transfer from (Cu+)2 pairs to Eu3+, varied hues from green to yellowish white and eventually to orange were generated by tuning the content of Eu3+. A perfect white-light emission with CIE coordinates (X=0.336,Y=0.346) was realized in (Cu+)2, Eu3+ and Ce3+ codoped samples. Our research indicates the potential application of (Cu+)2, Eu3+ codoped sodium silicate glasses for converting phosphors for UV LED chips to generate white LEDs.

© 2012 Optical Society of America

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References

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    [CrossRef]
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2012 (1)

R. F. Wei, H. Zhang, F. Li, and H. Guo, J. Am. Ceram. Soc. 95, 34 (2012).
[CrossRef]

2011 (6)

H. Guo, J. Li, F. Li, and H. Zhang. J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

D. Y. Wang, C. H. Huang, Y. C. Wu, and T. M. Chen, J. Mater. Chem. 21, 10818 (2011).
[CrossRef]

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

C. Ming, F. Song, C. Li, Y. Yu, G. Zhang, H. Yu, T. Sun, and J. Tian, Opt. Lett. 36, 2242 (2011).
[CrossRef]

K. M. Deng, T. Gong, Y. H. Chen, C. K. Duan, and M. Yin, Opt. Lett. 36, 4470 (2011).
[CrossRef]

2010 (2)

2009 (5)

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

D. Chen, Y. Yu, H. Lin, P. Huang, F. Weng, Z. Shan, and Y. Wang, Opt. Lett. 34, 2882 (2009).
[CrossRef]

X. Liu, Y. Teng, Y. Zhuang, J. Xie, Y. Qiao, G. Dong, D. Chen, and J. Qiu, Opt. Lett. 34, 3565 (2009).
[CrossRef]

M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
[CrossRef]

2005 (1)

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

1999 (1)

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

1991 (1)

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

1989 (1)

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, J. Phys. Chem. 93, 3958 (1989).
[CrossRef]

Barrie, J. D.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, J. Phys. Chem. 93, 3958 (1989).
[CrossRef]

Boutinaud, P.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Chayahara, A.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Chen, D.

Chen, G.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Chen, J.

Chen, Q.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Chen, S.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

Chen, T. M.

D. Y. Wang, C. H. Huang, Y. C. Wu, and T. M. Chen, J. Mater. Chem. 21, 10818 (2011).
[CrossRef]

Chen, Y. H.

Cheng, Z.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Deng, K. M.

Dong, G.

X. Liu, Y. Teng, Y. Zhuang, J. Xie, Y. Qiao, G. Dong, D. Chen, and J. Qiu, Opt. Lett. 34, 3565 (2009).
[CrossRef]

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Duan, C. K.

Duloisy, E.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Dunn, B.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, J. Phys. Chem. 93, 3958 (1989).
[CrossRef]

Eichelbaum, M.

M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
[CrossRef]

Fujii, K.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Fukumi, K.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Geng, D.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Gong, T.

Guo, H.

R. F. Wei, H. Zhang, F. Li, and H. Guo, J. Am. Ceram. Soc. 95, 34 (2012).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang. J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

H. Guo, X. Wang, J. Chen, and F. Li, Opt. Express 18, 18900 (2010).
[CrossRef]

H. Guo, H. Zhang, J. J. Li, and F. Li, Opt. Express 18, 27257 (2010).
[CrossRef]

Hayakaya, J.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Hollingsworth, G.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, J. Phys. Chem. 93, 3958 (1989).
[CrossRef]

Horino, Y.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Huang, C. H.

D. Y. Wang, C. H. Huang, Y. C. Wu, and T. M. Chen, J. Mater. Chem. 21, 10818 (2011).
[CrossRef]

Huang, P.

Kim, J. K.

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

Kitamura, N.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Le Flem, G.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Li, C.

Li, F.

R. F. Wei, H. Zhang, F. Li, and H. Guo, J. Am. Ceram. Soc. 95, 34 (2012).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang. J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

H. Guo, X. Wang, J. Chen, and F. Li, Opt. Express 18, 18900 (2010).
[CrossRef]

H. Guo, H. Zhang, J. J. Li, and F. Li, Opt. Express 18, 27257 (2010).
[CrossRef]

Li, G.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Li, J.

H. Guo, J. Li, F. Li, and H. Zhang. J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

Li, J. J.

Lin, H.

Lin, J.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Liu, X.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

X. Liu, Y. Teng, Y. Zhuang, J. Xie, Y. Qiao, G. Dong, D. Chen, and J. Qiu, Opt. Lett. 34, 3565 (2009).
[CrossRef]

Makihara, M.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Ming, C.

Moine, B.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Ohno, N.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Ohora, K.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Parent, C.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Parmentier, A. B.

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

Pedrini, C.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Peng, C.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Poelman, D.

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

Qiao, Y.

Qiu, J.

X. Liu, Y. Teng, Y. Zhuang, J. Xie, Y. Qiao, G. Dong, D. Chen, and J. Qiu, Opt. Lett. 34, 3565 (2009).
[CrossRef]

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Rademann, K.

M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
[CrossRef]

Schubert, E. F.

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

Shan, Z.

Shang, M.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Sheng, J.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

Smet, P. F.

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

Song, F.

Sun, T.

Teng, Y.

Tian, J.

Wang, D. Y.

D. Y. Wang, C. H. Huang, Y. C. Wu, and T. M. Chen, J. Mater. Chem. 21, 10818 (2011).
[CrossRef]

Wang, X.

Wang, Y.

Wei, R. F.

R. F. Wei, H. Zhang, F. Li, and H. Guo, J. Am. Ceram. Soc. 95, 34 (2012).
[CrossRef]

Weng, F.

Wu, Y. C.

D. Y. Wang, C. H. Huang, Y. C. Wu, and T. M. Chen, J. Mater. Chem. 21, 10818 (2011).
[CrossRef]

Xie, J.

Yin, M.

Yu, H.

Yu, J.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

Yu, Y.

Zhang, G.

C. Ming, F. Song, C. Li, Y. Yu, G. Zhang, H. Yu, T. Sun, and J. Tian, Opt. Lett. 36, 2242 (2011).
[CrossRef]

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Zhang, H.

R. F. Wei, H. Zhang, F. Li, and H. Guo, J. Am. Ceram. Soc. 95, 34 (2012).
[CrossRef]

H. Guo, J. Li, F. Li, and H. Zhang. J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

H. Guo, H. Zhang, J. J. Li, and F. Li, Opt. Express 18, 27257 (2010).
[CrossRef]

Zhang, J.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

Zhang, Q.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Zhang, Y.

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

Zhou, Q.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Zhuang, Y.

Zink, J. I.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, J. Phys. Chem. 93, 3958 (1989).
[CrossRef]

Adv. Funct. Mater. (1)

M. Eichelbaum and K. Rademann, Adv. Funct. Mater. 19, 2045 (2009).
[CrossRef]

Chem. Phys. Lett. (1)

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, Chem. Phys. Lett. 482, 228 (2009).
[CrossRef]

Int. J. Hydrogen Energy (1)

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, Int. J. Hydrogen Energy 34, 1119 (2009).
[CrossRef]

J. Am. Ceram. Soc. (1)

R. F. Wei, H. Zhang, F. Li, and H. Guo, J. Am. Ceram. Soc. 95, 34 (2012).
[CrossRef]

J. Electrochem. Soc. (2)

H. Guo, J. Li, F. Li, and H. Zhang. J. Electrochem. Soc. 158, J165 (2011).
[CrossRef]

P. F. Smet, A. B. Parmentier, and D. Poelman, J. Electrochem. Soc. 158, R37 (2011).
[CrossRef]

J. Mater. Chem. (1)

D. Y. Wang, C. H. Huang, Y. C. Wu, and T. M. Chen, J. Mater. Chem. 21, 10818 (2011).
[CrossRef]

J. Phys. Chem. (1)

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, J. Phys. Chem. 93, 3958 (1989).
[CrossRef]

J. Phys. Chem. C (1)

G. Li, D. Geng, M. Shang, Y. Zhang, C. Peng, Z. Cheng, and J. Lin, J. Phys. Chem. C 115, 21882 (2011).
[CrossRef]

J. Solid State Chem. (1)

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, J. Solid State Chem. 94, 236 (1991).
[CrossRef]

Nucl. Instr. Methods B (1)

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, Nucl. Instr. Methods B 149, 77 (1999).
[CrossRef]

Opt. Express (2)

Opt. Lett. (4)

Science (1)

E. F. Schubert and J. K. Kim, Science 308, 1274 (2005).
[CrossRef]

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Figures (3)

Fig. 1.
Fig. 1.

(a) Transmission spectra of G-host and GCux samples (x=0.2, 0.5, 1, 2, 3, 4). (b) Excitation and (c) emission spectra of GCux samples. (d) Spectral overlap between excitation of GEu1 and emission of GCu2 samples.

Fig. 2.
Fig. 2.

(a) Emission and (b) excitation spectra of G-host, GEu1, and GCuEuy samples (y=0, 0.5, 1, 2, 3, 4, 5, 6). (c) Decay curves of (Cu+)2 pairs emission in GCuEuy samples (y=0, 1, 3, 5). (d) Energy-level diagram of (Cu+)2 pairs and Eu3+ ions and possible ET process.

Fig. 3.
Fig. 3.

The CIE chromaticity diagram corresponding to emission of GCuEuy (y=0, 0.2, 0.5, 1, 2, 3, 4, 5, 6), GCe, and GCuEuCe samples under 330 nm excitation. The insert shows photos of GCu2, GCuEu2, GCuEu6, and GCuEuCe samples excited by 330 nm light.

Equations (2)

Equations on this page are rendered with MathJax. Learn more.

η=1ICu/Isum,
τ¯=0tI(t)dt/0I(t)dt,

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