Optical transitions of Eu<sup>3+</sup> and Dy<sup>3+</sup> ions in lead phosphate glasses

Wojciech A. Pisarski; Lidia Żur; Joanna Pisarska

doi:10.1364/OL.36.000990

Optical transitions of ${Eu}^{3 +}$ and ${Dy}^{3 +}$ ions in lead phosphate glasses

Wojciech A. Pisarski, Lidia Żur, and Joanna Pisarska

Optics Letters
Vol. 36,
Issue 6,
pp. 990-992
(2011)
•https://doi.org/10.1364/OL.36.000990

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Wojciech A. Pisarski, Lidia Żur, and Joanna Pisarska, "Optical transitions of Eu³⁺ and Dy³⁺ ions in lead phosphate glasses," Opt. Lett. 36, 990-992 (2011)

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- Materials
Optics & Photonics Topics
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The topics in this list come from the OSA Optics and Photonics Topics applied to this article.
Previously assigned OCIS codes
- Fluorescent and luminescent materials (160.2540)
- Glass and other amorphous materials (160.2750)
- Rare-earth-doped materials (160.5690)

About this Article
History
- Original Manuscript: December 2, 2010
- Revised Manuscript: February 10, 2011
- Manuscript Accepted: February 10, 2011
- Published: March 14, 2011

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Abstract

Lead phosphate glasses containing ${Eu}^{3 +}$ and ${Dy}^{3 +}$ have been studied. Local structure was verified using Fourier transform (FT)-IR spectroscopy. Emission bands of ${Eu}^{3 +}$ and ${Dy}^{3 +}$ ions in lead phosphate glasses are observed in the visible spectral range, which correspond to ${}^{5}{D_{0}} \to {}^{7}{F_{J}}$ ( $J = 0, 1, 2, 4$ ) and ${}^{4}{F_{9 / 2}} \to {}^{6}{H_{J / 2}}$ ( $J = 15, 13, 11$ ) transitions, respectively. Shorter luminescence decays from excited states of ${Eu}^{3 +}$ and ${Dy}^{3 +}$ are due to the presence of PbO in phosphate glass.

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${Ln}^{3 +}$	Transition	$λ_{p}$ [nm]	Parameter	$τ_{m}$ [ms]
${Eu}^{3 +}$	${}^{5}{D_{0}} \to {}^{7}{F_{2}}$	611
	${}^{5}{D_{0}} \to {}^{7}{F_{1}}$	590	$R / O = 2.41$	2.02
${Dy}^{3 +}$	${}^{4}{F_{9 / 2}} \to {}^{6}{H_{13 / 2}}$	573
	${}^{4}{F_{9 / 2}} \to {}^{6}{H_{15 / 2}}$	480	$Y / B = 1.32$	0.56

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