Abstract

Spectroscopic properties of optical fibers with a bismuth-doped silicate glass core are explained on the basis of molecular orbital theory and a solution of the Schrödinger equation, which takes into account the exchange, the spin-orbital, and the glass field potential interactions of s, p, and d electron shells of bismuth with s(σ), p(σ), and p(π) orbits of oxygen atoms. The approach can explain the IR luminescence properties of other optical centers formed by other atoms with the same structure of electron shells as the bismuth atom. The model of transitions based on intramolecular charge transfer between molecular orbital and metallic states is proposed.

© 2009 Optical Society of America

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2008 (4)

2007 (2)

V. V. Dvoyrin, V. M. Mashinsky, and E. M. Dianov, Opt. Lett. 32, 451 (2007).
[CrossRef] [PubMed]

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

2006 (1)

2005 (3)

2001 (1)

Y. Fujimoto and M. Nakatsuka, Jpn. J. Appl. Phys. Part 2 40, L279 (2001).
[CrossRef]

1975 (1)

C. Pedrini, J. Chem. Phys. 63, 3085 (1975).
[CrossRef]

Alfano, R. R.

Bigot, L.

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Bouwmans, G.

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Bufetov, I. A.

Bulatov, L. I.

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. F. Kustov, L. I. Bulatov, V. V. Dvoyrin, and V. M. Mashinsky, in The Third EPS-QEOD Europhoton Conference on Solid-State, Fiber and Waveguided Light Sources (2008), paper THoE.7.

Bykov, A. B.

Chen, D.

Dianov, E. M.

I. A. Bufetov, K. M. Golant, S. V. Firstov, A. V. Kholodkov, A. V. Shubin, and E. M. Dianov, Appl. Opt. 47, 4940 (2008).
[CrossRef] [PubMed]

V. O. Sokolov, V. G. Plotnichenko, and E. M. Dianov, Opt. Lett. 33, 1488 (2008).
[CrossRef] [PubMed]

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, and E. M. Dianov, Opt. Lett. 32, 451 (2007).
[CrossRef] [PubMed]

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

E. M. Dianov, S. V. Firstov, O. I. Medvedkov, I. A. Bufetov, V. F. Khopin, and A. N. Guryanov, in Optical Fiber Communication Conference, 2009 OSA Technical Digest Series (Optical Society of America, 2009), paper OWT3.

Douay, M.

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Dvoyrin, V. V.

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, and E. M. Dianov, Opt. Lett. 32, 451 (2007).
[CrossRef] [PubMed]

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

E. F. Kustov, L. I. Bulatov, V. V. Dvoyrin, and V. M. Mashinsky, in The Third EPS-QEOD Europhoton Conference on Solid-State, Fiber and Waveguided Light Sources (2008), paper THoE.7.

Favre, A.

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Firstov, S. V.

I. A. Bufetov, K. M. Golant, S. V. Firstov, A. V. Kholodkov, A. V. Shubin, and E. M. Dianov, Appl. Opt. 47, 4940 (2008).
[CrossRef] [PubMed]

E. M. Dianov, S. V. Firstov, O. I. Medvedkov, I. A. Bufetov, V. F. Khopin, and A. N. Guryanov, in Optical Fiber Communication Conference, 2009 OSA Technical Digest Series (Optical Society of America, 2009), paper OWT3.

Fujimoto, Y.

Y. Fujimoto and M. Nakatsuka, Jpn. J. Appl. Phys. Part 2 40, L279 (2001).
[CrossRef]

Golant, K. M.

Guryanov, A. N.

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

E. M. Dianov, S. V. Firstov, O. I. Medvedkov, I. A. Bufetov, V. F. Khopin, and A. N. Guryanov, in Optical Fiber Communication Conference, 2009 OSA Technical Digest Series (Optical Society of America, 2009), paper OWT3.

Gur'yanov, A. N.

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

Jiang, X.

Kholodkov, A. V.

Khopin, V. F.

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. M. Dianov, S. V. Firstov, O. I. Medvedkov, I. A. Bufetov, V. F. Khopin, and A. N. Guryanov, in Optical Fiber Communication Conference, 2009 OSA Technical Digest Series (Optical Society of America, 2009), paper OWT3.

Kustov, E. F.

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. F. Kustov, L. I. Bulatov, V. V. Dvoyrin, and V. M. Mashinsky, in The Third EPS-QEOD Europhoton Conference on Solid-State, Fiber and Waveguided Light Sources (2008), paper THoE.7.

Mashinsky, V. M.

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, and E. M. Dianov, Opt. Lett. 32, 451 (2007).
[CrossRef] [PubMed]

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

E. F. Kustov, L. I. Bulatov, V. V. Dvoyrin, and V. M. Mashinsky, in The Third EPS-QEOD Europhoton Conference on Solid-State, Fiber and Waveguided Light Sources (2008), paper THoE.7.

Medvedkov, O. I.

E. M. Dianov, S. V. Firstov, O. I. Medvedkov, I. A. Bufetov, V. F. Khopin, and A. N. Guryanov, in Optical Fiber Communication Conference, 2009 OSA Technical Digest Series (Optical Society of America, 2009), paper OWT3.

Melkumov, M. A.

Meng, X.

Nakatsuka, M.

Y. Fujimoto and M. Nakatsuka, Jpn. J. Appl. Phys. Part 2 40, L279 (2001).
[CrossRef]

Pedrini, C.

C. Pedrini, J. Chem. Phys. 63, 3085 (1975).
[CrossRef]

Peng, M.

Petricevic, V.

Plotnichenko, V. G.

Pureur, V.

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Qiu, J.

Razdobreev, I.

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Sharonov, M. Yu.

Shubin, A. V.

Sokolov, V. O.

Sukhorukov, A. P.

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

Umnikov, A. A.

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

Yashkov, M. V.

V. V. Dvoyrin, V. M. Mashinsky, L. I. Bulatov, I. A. Bufetov, A. V. Shubin, M. A. Melkumov, E. F. Kustov, E. M. Dianov, A. A. Umnikov, V. F. Khopin, M. V. Yashkov, and A. N. Guryanov, Opt. Lett. 31, 2966 (2006).
[CrossRef] [PubMed]

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

Zhao, Q.

Zhu, C.

Appl. Opt. (1)

Appl. Phys. Lett. (1)

I. Razdobreev, L. Bigot, V. Pureur, A. Favre, G. Bouwmans, and M. Douay, Appl. Phys. Lett. 90, 031103 (2007).
[CrossRef]

Bull. Russ. Acad. Sci. Phys. (1)

L. I. Bulatov, V. M. Mashinsky, V. V. Dvoyrin, E. F. Kustov, E. M. Dianov, and A. P. Sukhorukov, Bull. Russ. Acad. Sci. Phys. 72, 1655 (2008).
[CrossRef]

J. Chem. Phys. (1)

C. Pedrini, J. Chem. Phys. 63, 3085 (1975).
[CrossRef]

Jpn. J. Appl. Phys. Part 2 (1)

Y. Fujimoto and M. Nakatsuka, Jpn. J. Appl. Phys. Part 2 40, L279 (2001).
[CrossRef]

Opt. Express (1)

Opt. Lett. (5)

Quantum Electron. (1)

E. M. Dianov, V. V. Dvoyrin, V. M. Mashinsky, A. A. Umnikov, M. V. Yashkov, and A. N. Gur'yanov, Quantum Electron. 35, 1083 (2005).
[CrossRef]

Other (3)

E. F. Kustov, L. I. Bulatov, V. V. Dvoyrin, and V. M. Mashinsky, in The Third EPS-QEOD Europhoton Conference on Solid-State, Fiber and Waveguided Light Sources (2008), paper THoE.7.

E. M. Dianov, S. V. Firstov, O. I. Medvedkov, I. A. Bufetov, V. F. Khopin, and A. N. Guryanov, in Optical Fiber Communication Conference, 2009 OSA Technical Digest Series (Optical Society of America, 2009), paper OWT3.

V. V. Dvoyrin, V. M. Mashinsky, E. M. Dianov, A. A. Umnikov, M. V. Yashkov, and A. N. Guryanov, in Proceedings of the 31st European Conference on Optical Communicaation (2005), Vol. 4, pp. 949-950.

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Figures (3)

Fig. 1
Fig. 1

MO diagram of the ( n 1 ) d and n ( s , p ) states of the M atom and p ( π ) , p ( σ ) , and s ( σ ) ligand orbitals for fourfold oxygen coordination. The vertical arrows indicate transitions corresponding to absorption and emission bands in the framework of the intramolecular charge transfer effect.

Fig. 2
Fig. 2

(a) Transition structure of MO-Bi configurations (numbers near the arrows denote the calculated wavelengths of the absorption and luminescence transitions) and (b) absorption and luminescence spectra of Bi-doped aluminosilicate fiber (the luminescence excitation wavelength was of 514 nm). For luminescence at 540–554 nm excitation wavelength was 193 nm [13].

Fig. 3
Fig. 3

Electron transitions of IMCT effect with excitation at 500 nm. The wavelengths are given for Bi atom.

Equations (1)

Equations on this page are rendered with MathJax. Learn more.

H = E 0 ( d ) + E 0 ( p ) + g 2 ( d ) G 2 + g 1 ( p ) G 1 + ξ d a d ( d ) + ξ p a p ( p ) + a 4 c ( d ) A 4 A + a 2 f A 2 F + a 4 f A 4 F ,

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