Abstract

A new red phosphor, Ba2Mg(BO3)2:Eu,Mn, was synthesized by the solid-state reaction method and its photoluminescence properties were investigated by excitation and emission spectra and decay curves. Its excitation band is extending from 250450nm, which is adaptable to the emission band of near-ultraviolet LED chips (350420nm). Upon the excitation of 365nm light, the phosphor exhibits strong red emission centered at 615nm. The relationship between Eu2+ and Mn2+ dopants was studied from the viewpoint of a crystal structure and by photoluminescence spectra and decay curves. The results show that the characteristic Eu2+ emission predominate in the emission band and Mn2+ promote the redistribution of Eu2+ at the cation sites of the host crystal.

© 2008 Optical Society of America

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  1. T. Nishida, T. Ban, and N. Kobayashi, Appl. Phys. Lett. 82, 3817 (2003).
    [CrossRef]
  2. N. Kimura, S. Ken, and S. Hirafune, Appl. Phys. Lett. 90, 051109 (2007).
    [CrossRef]
  3. Y. S. Hu, W. D. Zhuang, and H. Q. Ye, J. Alloys Compd. 390, 226 (2005).
    [CrossRef]
  4. X. X. Wang, J. Wang, and J. X. Shi, Mater. Res. Bull. 42, 1669 (2007).
    [CrossRef]
  5. Y. Gao, C. S. Shi, and Y. Wu, Mater. Res. Bull. 31, 439 (1996).
    [CrossRef]
  6. Y. Wang, X. Guo, and T. Endo, J. Solid State Chem. 177, 2242 (2004).
    [CrossRef]
  7. Y. H. Wang, K. Uheda, and H. Takizawa, J. Electrochem. Soc. 148, G430 (2001).
    [CrossRef]
  8. A. Akella and D. A. Keszler, Mater. Res. Bull. 30, 105 (1995).
    [CrossRef]
  9. H. Lin, H. Liang, and Z. Tian, Mater. Res. Bull. 21, 864 (2006).
  10. G. Blasse and B. C. Grabmaier, Luminescent Materials (Springer-Verlag, 1994), p. 96.
  11. S. Shigeo and M. Y. William, Phosphor Handbook (Phosphor Research Society, 1998), p.173.
  12. Y. H. Tseng, B. S. Chiou, and C. C. Peng, Thin Solid Films 330, 173 (1998).
    [CrossRef]

2007 (2)

N. Kimura, S. Ken, and S. Hirafune, Appl. Phys. Lett. 90, 051109 (2007).
[CrossRef]

X. X. Wang, J. Wang, and J. X. Shi, Mater. Res. Bull. 42, 1669 (2007).
[CrossRef]

2006 (1)

H. Lin, H. Liang, and Z. Tian, Mater. Res. Bull. 21, 864 (2006).

2005 (1)

Y. S. Hu, W. D. Zhuang, and H. Q. Ye, J. Alloys Compd. 390, 226 (2005).
[CrossRef]

2004 (1)

Y. Wang, X. Guo, and T. Endo, J. Solid State Chem. 177, 2242 (2004).
[CrossRef]

2003 (1)

T. Nishida, T. Ban, and N. Kobayashi, Appl. Phys. Lett. 82, 3817 (2003).
[CrossRef]

2001 (1)

Y. H. Wang, K. Uheda, and H. Takizawa, J. Electrochem. Soc. 148, G430 (2001).
[CrossRef]

1998 (1)

Y. H. Tseng, B. S. Chiou, and C. C. Peng, Thin Solid Films 330, 173 (1998).
[CrossRef]

1996 (1)

Y. Gao, C. S. Shi, and Y. Wu, Mater. Res. Bull. 31, 439 (1996).
[CrossRef]

1995 (1)

A. Akella and D. A. Keszler, Mater. Res. Bull. 30, 105 (1995).
[CrossRef]

Akella, A.

A. Akella and D. A. Keszler, Mater. Res. Bull. 30, 105 (1995).
[CrossRef]

Ban, T.

T. Nishida, T. Ban, and N. Kobayashi, Appl. Phys. Lett. 82, 3817 (2003).
[CrossRef]

Blasse, G.

G. Blasse and B. C. Grabmaier, Luminescent Materials (Springer-Verlag, 1994), p. 96.

Chiou, B. S.

Y. H. Tseng, B. S. Chiou, and C. C. Peng, Thin Solid Films 330, 173 (1998).
[CrossRef]

Endo, T.

Y. Wang, X. Guo, and T. Endo, J. Solid State Chem. 177, 2242 (2004).
[CrossRef]

Gao, Y.

Y. Gao, C. S. Shi, and Y. Wu, Mater. Res. Bull. 31, 439 (1996).
[CrossRef]

Grabmaier, B. C.

G. Blasse and B. C. Grabmaier, Luminescent Materials (Springer-Verlag, 1994), p. 96.

Guo, X.

Y. Wang, X. Guo, and T. Endo, J. Solid State Chem. 177, 2242 (2004).
[CrossRef]

Hirafune, S.

N. Kimura, S. Ken, and S. Hirafune, Appl. Phys. Lett. 90, 051109 (2007).
[CrossRef]

Hu, Y. S.

Y. S. Hu, W. D. Zhuang, and H. Q. Ye, J. Alloys Compd. 390, 226 (2005).
[CrossRef]

Ken, S.

N. Kimura, S. Ken, and S. Hirafune, Appl. Phys. Lett. 90, 051109 (2007).
[CrossRef]

Keszler, D. A.

A. Akella and D. A. Keszler, Mater. Res. Bull. 30, 105 (1995).
[CrossRef]

Kimura, N.

N. Kimura, S. Ken, and S. Hirafune, Appl. Phys. Lett. 90, 051109 (2007).
[CrossRef]

Kobayashi, N.

T. Nishida, T. Ban, and N. Kobayashi, Appl. Phys. Lett. 82, 3817 (2003).
[CrossRef]

Liang, H.

H. Lin, H. Liang, and Z. Tian, Mater. Res. Bull. 21, 864 (2006).

Lin, H.

H. Lin, H. Liang, and Z. Tian, Mater. Res. Bull. 21, 864 (2006).

Nishida, T.

T. Nishida, T. Ban, and N. Kobayashi, Appl. Phys. Lett. 82, 3817 (2003).
[CrossRef]

Peng, C. C.

Y. H. Tseng, B. S. Chiou, and C. C. Peng, Thin Solid Films 330, 173 (1998).
[CrossRef]

Shi, C. S.

Y. Gao, C. S. Shi, and Y. Wu, Mater. Res. Bull. 31, 439 (1996).
[CrossRef]

Shi, J. X.

X. X. Wang, J. Wang, and J. X. Shi, Mater. Res. Bull. 42, 1669 (2007).
[CrossRef]

Shigeo, S.

S. Shigeo and M. Y. William, Phosphor Handbook (Phosphor Research Society, 1998), p.173.

Takizawa, H.

Y. H. Wang, K. Uheda, and H. Takizawa, J. Electrochem. Soc. 148, G430 (2001).
[CrossRef]

Tian, Z.

H. Lin, H. Liang, and Z. Tian, Mater. Res. Bull. 21, 864 (2006).

Tseng, Y. H.

Y. H. Tseng, B. S. Chiou, and C. C. Peng, Thin Solid Films 330, 173 (1998).
[CrossRef]

Uheda, K.

Y. H. Wang, K. Uheda, and H. Takizawa, J. Electrochem. Soc. 148, G430 (2001).
[CrossRef]

Wang, J.

X. X. Wang, J. Wang, and J. X. Shi, Mater. Res. Bull. 42, 1669 (2007).
[CrossRef]

Wang, X. X.

X. X. Wang, J. Wang, and J. X. Shi, Mater. Res. Bull. 42, 1669 (2007).
[CrossRef]

Wang, Y.

Y. Wang, X. Guo, and T. Endo, J. Solid State Chem. 177, 2242 (2004).
[CrossRef]

Wang, Y. H.

Y. H. Wang, K. Uheda, and H. Takizawa, J. Electrochem. Soc. 148, G430 (2001).
[CrossRef]

William, M. Y.

S. Shigeo and M. Y. William, Phosphor Handbook (Phosphor Research Society, 1998), p.173.

Wu, Y.

Y. Gao, C. S. Shi, and Y. Wu, Mater. Res. Bull. 31, 439 (1996).
[CrossRef]

Ye, H. Q.

Y. S. Hu, W. D. Zhuang, and H. Q. Ye, J. Alloys Compd. 390, 226 (2005).
[CrossRef]

Zhuang, W. D.

Y. S. Hu, W. D. Zhuang, and H. Q. Ye, J. Alloys Compd. 390, 226 (2005).
[CrossRef]

Appl. Phys. Lett. (2)

T. Nishida, T. Ban, and N. Kobayashi, Appl. Phys. Lett. 82, 3817 (2003).
[CrossRef]

N. Kimura, S. Ken, and S. Hirafune, Appl. Phys. Lett. 90, 051109 (2007).
[CrossRef]

J. Alloys Compd. (1)

Y. S. Hu, W. D. Zhuang, and H. Q. Ye, J. Alloys Compd. 390, 226 (2005).
[CrossRef]

J. Electrochem. Soc. (1)

Y. H. Wang, K. Uheda, and H. Takizawa, J. Electrochem. Soc. 148, G430 (2001).
[CrossRef]

J. Solid State Chem. (1)

Y. Wang, X. Guo, and T. Endo, J. Solid State Chem. 177, 2242 (2004).
[CrossRef]

Mater. Res. Bull. (4)

A. Akella and D. A. Keszler, Mater. Res. Bull. 30, 105 (1995).
[CrossRef]

H. Lin, H. Liang, and Z. Tian, Mater. Res. Bull. 21, 864 (2006).

X. X. Wang, J. Wang, and J. X. Shi, Mater. Res. Bull. 42, 1669 (2007).
[CrossRef]

Y. Gao, C. S. Shi, and Y. Wu, Mater. Res. Bull. 31, 439 (1996).
[CrossRef]

Thin Solid Films (1)

Y. H. Tseng, B. S. Chiou, and C. C. Peng, Thin Solid Films 330, 173 (1998).
[CrossRef]

Other (2)

G. Blasse and B. C. Grabmaier, Luminescent Materials (Springer-Verlag, 1994), p. 96.

S. Shigeo and M. Y. William, Phosphor Handbook (Phosphor Research Society, 1998), p.173.

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Figures (6)

Fig. 1
Fig. 1

XRD spectra of samples.

Fig. 2
Fig. 2

Emission spectra of samples under 365 nm excitation.

Fig. 3
Fig. 3

Excitation spectra under 615 nm emission peak beside S0 under 595 nm emission.

Fig. 4
Fig. 4

PL decay curves excited at 365 nm (a) monitored at 625 nm , (b) monitored at 540 nm .

Fig. 5
Fig. 5

Observed (solid curve) and fitted (dotted curve) emission spectra and decomposed Gaussian components (dashed curve) of S4.

Fig. 6
Fig. 6

Intensity ratio among emission peaks.

Tables (1)

Tables Icon

Table 1 Composition and Color Coordinate of Samples

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