Abstract

The singlet excited-state lifetime of a terpyridyl platinum(II) pentynyl complex was determined to be 268±87ps by fitting femtosecond transient absorption data, the triplet excited-state lifetime was found to be 62ns by fitting nanosecond transient absorption decay data, and the triplet quantum yield was measured to be 0.16. A ground-state absorption cross section of 2.5×1019cm2 at 532nm was deduced from UV-vis absorption data. Excited-state absorption cross sections of 3.5×1017cm2 (singlet) and 4.5×1017cm2 (triplet) were obtained by using a five-level dynamic model to fit open-aperture Z scans at picosecond and nanosecond pulse widths and a variety of pulse energies.

© 2008 Optical Society of America

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  1. F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
    [Crossref] [PubMed]
  2. W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
    [Crossref]
  3. T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.
  4. F. Guo and W. Sun, J. Phys. Chem. B 110, 15029 (2006).
    [Crossref] [PubMed]
  5. W. Sun, H.-J. Zhu, and P. M. Barron, Chem. Mater. 18, 2602 (2006).
    [Crossref]
  6. W. Sun and F. Guo, Chin. Opt. Lett. S3, S34 (2005).
  7. P. Shao, Y. Li, and W. Sun, J. Phys. Chem. A 112, 1172 (2008).
    [Crossref] [PubMed]
  8. P. Shao and W. Sun, Inorg. Chem. 46, 8603 (2007).
    [Crossref] [PubMed]
  9. S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
    [Crossref]
  10. V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
    [Crossref]
  11. K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
    [Crossref]
  12. E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
    [Crossref] [PubMed]
  13. Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
    [Crossref] [PubMed]
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    [Crossref]
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    [Crossref]
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    [Crossref]

2008 (1)

P. Shao, Y. Li, and W. Sun, J. Phys. Chem. A 112, 1172 (2008).
[Crossref] [PubMed]

2007 (3)

P. Shao and W. Sun, Inorg. Chem. 46, 8603 (2007).
[Crossref] [PubMed]

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

2006 (2)

F. Guo and W. Sun, J. Phys. Chem. B 110, 15029 (2006).
[Crossref] [PubMed]

W. Sun, H.-J. Zhu, and P. M. Barron, Chem. Mater. 18, 2602 (2006).
[Crossref]

2005 (2)

W. Sun and F. Guo, Chin. Opt. Lett. S3, S34 (2005).

F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
[Crossref] [PubMed]

2004 (1)

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

2003 (1)

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

2002 (1)

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

2001 (1)

V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
[Crossref]

1999 (1)

S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
[Crossref]

1990 (1)

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

1986 (1)

I. Carmichael and G. L. Hug, J. Phys. Chem. Ref. Data 15, 1 (1986).
[Crossref]

1978 (1)

R. Bensasson, C. R. Goldschmidt, E. J. Land, and T. G. Truscott, Photochem. Photobiol. 28, 277 (1978).
[Crossref]

Barron, P. M.

W. Sun, H.-J. Zhu, and P. M. Barron, Chem. Mater. 18, 2602 (2006).
[Crossref]

Bensasson, R.

R. Bensasson, C. R. Goldschmidt, E. J. Land, and T. G. Truscott, Photochem. Photobiol. 28, 277 (1978).
[Crossref]

Camerel, F.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Carmichael, I.

I. Carmichael and G. L. Hug, J. Phys. Chem. Ref. Data 15, 1 (1986).
[Crossref]

Castellano, F. N.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Chan, M. C. W.

S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
[Crossref]

Che, C.-M.

S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
[Crossref]

Cheung, K.-K.

V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
[Crossref]

S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
[Crossref]

Chu, B.W.-K.

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

Danilov, E. O.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Ferry, M. J.

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

Goldschmidt, C. R.

R. Bensasson, C. R. Goldschmidt, E. J. Land, and T. G. Truscott, Photochem. Photobiol. 28, 277 (1978).
[Crossref]

Guo, F.

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

F. Guo and W. Sun, J. Phys. Chem. B 110, 15029 (2006).
[Crossref] [PubMed]

F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
[Crossref] [PubMed]

W. Sun and F. Guo, Chin. Opt. Lett. S3, S34 (2005).

Hagen, D. J.

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

Hug, G. L.

I. Carmichael and G. L. Hug, J. Phys. Chem. Ref. Data 15, 1 (1986).
[Crossref]

Kinayyigit, S.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Lai, S.-W.

S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
[Crossref]

Land, E. J.

R. Bensasson, C. R. Goldschmidt, E. J. Land, and T. G. Truscott, Photochem. Photobiol. 28, 277 (1978).
[Crossref]

Li, Y.

P. Shao, Y. Li, and W. Sun, J. Phys. Chem. A 112, 1172 (2008).
[Crossref] [PubMed]

Liu, Y.

F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
[Crossref] [PubMed]

Mott, A. G.

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

Pomestchenko, I. E.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Pritchett, T. M.

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

Retaileau, P.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Said, A. A.

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

Schanze, K.

F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
[Crossref] [PubMed]

Shao, P.

P. Shao, Y. Li, and W. Sun, J. Phys. Chem. A 112, 1172 (2008).
[Crossref] [PubMed]

P. Shao and W. Sun, Inorg. Chem. 46, 8603 (2007).
[Crossref] [PubMed]

Sheik-Bahae, M.

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

Shikhova, E.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Stryland, E. W. V.

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

Sun, W.

P. Shao, Y. Li, and W. Sun, J. Phys. Chem. A 112, 1172 (2008).
[Crossref] [PubMed]

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

P. Shao and W. Sun, Inorg. Chem. 46, 8603 (2007).
[Crossref] [PubMed]

F. Guo and W. Sun, J. Phys. Chem. B 110, 15029 (2006).
[Crossref] [PubMed]

W. Sun, H.-J. Zhu, and P. M. Barron, Chem. Mater. 18, 2602 (2006).
[Crossref]

F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
[Crossref] [PubMed]

W. Sun and F. Guo, Chin. Opt. Lett. S3, S34 (2005).

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

Tang, R.P.-L.

V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
[Crossref]

Tang, W.-S.

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

Tregubov, A. D.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Truscott, T. G.

R. Bensasson, C. R. Goldschmidt, E. J. Land, and T. G. Truscott, Photochem. Photobiol. 28, 277 (1978).
[Crossref]

Tung, C.-H.

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

Wei, T.-H.

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

Wong, K.M.-C.

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
[Crossref]

Wu, L.-Z.

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

Wu, Z.-X.

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

Yam, V.W.-W.

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
[Crossref]

Yang, Q.-Z.

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

Zhang, B.

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

Zhang, L.-P.

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

Zhu, H.-J.

W. Sun, H.-J. Zhu, and P. M. Barron, Chem. Mater. 18, 2602 (2006).
[Crossref]

Zhu, N.

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

Ziessel, R.

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Appl. Phys. Lett. (1)

W. Sun, Z.-X. Wu, Q.-Z. Yang, L.-Z. Wu, and C.-H. Tung, Appl. Phys. Lett. 82, 850 (2003).
[Crossref]

Chem. Mater. (1)

W. Sun, H.-J. Zhu, and P. M. Barron, Chem. Mater. 18, 2602 (2006).
[Crossref]

Chin. Opt. Lett. (1)

W. Sun and F. Guo, Chin. Opt. Lett. S3, S34 (2005).

IEEE J. Quantum Electron. (1)

M. Sheik-Bahae, A. A. Said, T.-H. Wei, D. J. Hagen, and E. W. V. Stryland, IEEE J. Quantum Electron. 26, 760 (1990).
[Crossref]

Inorg. Chem. (5)

E. Shikhova, E. O. Danilov, S. Kinayyigit, I. E. Pomestchenko, A. D. Tregubov, F. Camerel, P. Retaileau, R. Ziessel, and F. N. Castellano, Inorg. Chem. 46, 3038 (2007).
[Crossref] [PubMed]

Q.-Z. Yang, L.-Z. Wu, Z.-X. Wu, L.-P. Zhang, and C.-H. Tung, Inorg. Chem. 41, 5653 (2002).
[Crossref] [PubMed]

F. Guo, W. Sun, Y. Liu, and K. Schanze, Inorg. Chem. 44, 4055 (2005).
[Crossref] [PubMed]

P. Shao and W. Sun, Inorg. Chem. 46, 8603 (2007).
[Crossref] [PubMed]

S.-W. Lai, M. C. W. Chan, K.-K. Cheung, and C.-M. Che, Inorg. Chem. 38, 4262 (1999).
[Crossref]

J. Phys. Chem. A (1)

P. Shao, Y. Li, and W. Sun, J. Phys. Chem. A 112, 1172 (2008).
[Crossref] [PubMed]

J. Phys. Chem. B (1)

F. Guo and W. Sun, J. Phys. Chem. B 110, 15029 (2006).
[Crossref] [PubMed]

J. Phys. Chem. Ref. Data (1)

I. Carmichael and G. L. Hug, J. Phys. Chem. Ref. Data 15, 1 (1986).
[Crossref]

Organometallics (2)

V.W.-W. Yam, R.P.-L. Tang, K.M.-C. Wong, and K.-K. Cheung, Organometallics 20, 4476 (2001).
[Crossref]

K.M.-C. Wong, W.-S. Tang, B.W.-K. Chu, N. Zhu, and V.W.-W. Yam, Organometallics 23, 3459 (2004).
[Crossref]

Photochem. Photobiol. (1)

R. Bensasson, C. R. Goldschmidt, E. J. Land, and T. G. Truscott, Photochem. Photobiol. 28, 277 (1978).
[Crossref]

Other (1)

T. M. Pritchett, M. J. Ferry, A. G. Mott, F. Guo, B. Zhang, and W. Sun, in Nonlinear Optics: Materials, Fundamentals and Applications, OSA Technical Digest (CD) (Optical Society of America, 2007), paper WE11.

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Figures (4)

Fig. 1
Fig. 1

UV-vis absorption spectrum of ttpy- Pt in acetonitrile.

Fig. 2
Fig. 2

Femtosecond transient difference absorption spectra of ttpy- Pt in acetonitrile in 2 mm cell.

Fig. 3
Fig. 3

Picosecond Z scans of ttpy- Pt in acetonitrile.

Fig. 4
Fig. 4

Nanosecond Z scans of ttpy- Pt in acetonitrile.

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