Experimental study on a nonlinear photonics process of Er(0.5)Yb(3):FOV oxyfluoride nanophase vitroceramics

Xiaobo Chen; Zengfu Song; Lili Hu; Junjie Zhang; Lei Wen

doi:10.1364/OL.32.002019

Optics Letters
Vol. 32,
Issue 14,
pp. 2019-2021
(2007)
•https://doi.org/10.1364/OL.32.002019

Experimental study on a nonlinear photonics process of Er(0.5)Yb(3):FOV oxyfluoride nanophase vitroceramics

Xiaobo Chen, Zengfu Song, Lili Hu, Junjie Zhang, and Lei Wen

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Xiaobo Chen, Zengfu Song, Lili Hu, Junjie Zhang, and Lei Wen, "Experimental study on a nonlinear photonics process of Er(0.5)Yb(3):FOV oxyfluoride nanophase vitroceramics," Opt. Lett. 32, 2019-2021 (2007)

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Abstract

We study the nonlinear photonics of rare-earth-doped oxyfluoride nanophase vitroceramics (FOV), oxyfluoride glass (FOG), and ZBLAN fluoride glass. We found that an interesting fluorescence intensity inversion phenomenon between red and green fluorescence occurs from Er(0.5)Yb(3):FOV. The dynamic range ∑ of the intensity inversion between red and green fluorescence of Er(0.5)Yb(3):FOV is about $5.753 \times 10^{2}$ , which is 100 to 1000 times larger than those of other materials. One of the applications of this phenomenon is double-wavelength fluorescence falsification-preventing technology, which is proved to possess the novel antifriction loss and antiscribble properties.

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Samples	$F [{}^{4}S_{3 ∕ 2}]$ $({}^{4}G_{11 ∕ 2})$	$F [{}^{4}F_{9 ∕ 2}]$ $({}^{4}G_{11 ∕ 2})$	γ	$F [{}^{4}S_{3 ∕ 2}]$ $({}^{4}F_{7 ∕ 2})$	$F [{}^{4}F_{9 ∕ 2}]$ $({}^{4}F_{7 ∕ 2})$	α	$\sum = γ \times α$
(1) Er(0.5)Yb(3):FOV	$1.246 \times 10^{7}$	$1.444 \times 10^{8}$	$1.159 \times 10^{1}$	$1.848 \times 10^{7}$	$3.211 \times 10^{5}$	$4.964 \times 10^{1}$	$5.753 \times 10^{2}$
$(1 b) Er (0.5) Yb (3) : FOV + QB 21$	$9.814 \times 10^{6}$	$6.430 \times 10^{6}$	$6.552 \times 10^{- 1}$	$1.677 \times 10^{7}$	$1.850 \times 10^{4}$	$9.064 \times 10^{2}$	$5.938 \times 10^{2}$
(2) Er(0.5)Yb(1):FOV	$5.541 \times 10^{7}$	$2.781 \times 10^{6}$	$5.019 \times 10^{- 2}$	$1.537 \times 10^{7}$	$4.624 \times 10^{5}$	$3.325 \times 10^{1}$	1.669
$(2 b) Er (0.5) Yb (1) : FOV + QB 21$	$6.246 \times 10^{7}$	$1.699 \times 10^{5}$	$2.720 \times 10^{- 3}$	$2.019 \times 10^{7}$	$3.295 \times 10^{4}$	$6.127 \times 10^{2}$	1.667
(3) Er(0.5):FOV	$6.456 \times 10^{7}$	$7.377 \times 10^{5}$	$1.142 \times 10^{- 2}$	$1.643 \times 10^{7}$	$2.512 \times 10^{5}$	$6.539 \times 10^{1}$	$7.468 \times 10^{- 1}$
(4) Er(0.5)Yb(3):FOG	$3.493 \times 10^{7}$	$6.095 \times 10^{6}$	$1.745 \times 10^{- 1}$	$8.576 \times 10^{6}$	$2.695 \times 10^{5}$	$3.182 \times 10^{1}$	5.553
(5)Er(0.5)Yb(1):FOG	$5.813 \times 10^{7}$	$1.533 \times 10^{6}$	$2.638 \times 10^{- 2}$	$1.453 \times 10^{7}$	$4.321 \times 10^{5}$	$3.364 \times 10^{1}$	$8.874 \times 10^{- 1}$
(6)Er(0.5):FOG	$6.461 \times 10^{7}$	$7.661 \times 10^{5}$	$1.186 \times 10^{- 2}$	$1.747 \times 10^{7}$	$2.587 \times 10^{5}$	$6.754 \times 10^{1}$	$8.010 \times 10^{- 1}$
(7) Er(0.3)Yb(3):ZBLAN	$4.052 \times 10^{8}$	$1.243 \times 10^{7}$	$3.067 \times 10^{- 2}$	$9.134 \times 10^{7}$	$2.754 \times 10^{6}$	$3.317 \times 10^{1}$	1.017
$(7 b) Er (0.3) Yb (3) : ZBLAN + QB 21$	$5.867 \times 10^{8}$	$9.696 \times 10^{5}$	$1.653 \times 10^{- 3}$	$1.449 \times 10^{8}$	$2.381 \times 10^{5}$	$6.083 \times 10^{2}$	1.005
(8) Er(0.3):ZBLAN	$3.673 \times 10^{8}$	$4.960 \times 10^{6}$	$1.350 \times 10^{- 2}$	$7.641 \times 10^{7}$	$1.164 \times 10^{6}$	$6.564 \times 10^{1}$	$8.862 \times 10^{- 1}$

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