An antimony–germanium- (Sb–Ge-) codoped fiber specially designed for the fabrication of fiber Bragg gratings (FBGs) with high temperature sustainability has been developed. The photosensitivity and the high-temperature sustainability of FBGs that have been written into this fiber were tested. The results obtained showed that the FBG written into this fiber has a very high temperature sustainability of 900 °C. A decay mechanism that involves cation hopping is presented to explain the observed high temperature sustainability of the grating written into this fiber.
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