Abstract

Infrared radio-frequency double-resonance spectroscopy has been carried out for 13CH3OH. Four K-type doublet transitions have been observed below 1 GHz, using the 9P(10) and 9P(12) CO2 laser lines. The results confirm previously proposed assignments of infrared absorption transitions and far-infrared laser emission lines observed in this molecule. Measurements of the A-state splittings have permitted the determination of the asymmetry splitting parameters SO(K) and SCO(K) for (n, K) = (0, 4) and (1, 3).

© 1987 Optical Society of America

Full Article  |  PDF Article

References

  • View by:
  • |
  • |
  • |

  1. J. P. Sattler, T. L. Worchesky, W. A. Riessler, Infrared Phys. 19, 217 (1979).
    [CrossRef]
  2. W. H. Weber, P. D. Maker, J. Mol. Spectrosc. 93, 131 (1982).
    [CrossRef]
  3. G. Moruzzi, F. Strumia, F. Colao, Infrared Phys. 25, 251 (1985).
    [CrossRef]
  4. R. M. Lees, Proc. Soc. Photo-Opt. Instrum. Eng. 666, 158 (1986).
  5. F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
    [CrossRef]
  6. J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
    [CrossRef]
  7. R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
    [CrossRef]
  8. G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
    [CrossRef]
  9. E. Arimondo, M. Inguscio, A. Moretti, M. Pellegrino, F. Strumia, Opt. Lett. 5, 496 (1980).
    [CrossRef] [PubMed]
  10. J. O. Henningsen, in Infrared and Millimeter Waves, K. J. Button, ed. (Academic, New York, 1982), Vol. 5, Chap. 2.
  11. J. O. Henningse, Int. J. Infrared Millimeter Waves 7, 1605 (1986).
    [CrossRef]
  12. E. V. Ivash, D. M. Dennison, J. Chem. Phys. 21, 1804 (1953).
    [CrossRef]
  13. J. O. Henningson, J. C. Petersen, postdeadline paper presented at the International Conference on Infrared Millimeter Waves, Pisa, Italy, October 20–24, 1986.
  14. H. Dreizler, W. Schrepp, R. Schwarz, Z. Naturforsch. 34a, 571 (1979).
  15. W. Fawzy, R. H. Schwendeman, J. Mol. Spectrosc. 120, 317 (1986).
    [CrossRef]
  16. J. O. Henningsen, J. C. Petersen, Infrared Phys. 18, 475 (1978).
    [CrossRef]
  17. N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
    [CrossRef]
  18. J. O. Henningsen, J. Mol. Spectrosc. 102, 399 (1983).
    [CrossRef]

1986 (3)

R. M. Lees, Proc. Soc. Photo-Opt. Instrum. Eng. 666, 158 (1986).

J. O. Henningse, Int. J. Infrared Millimeter Waves 7, 1605 (1986).
[CrossRef]

W. Fawzy, R. H. Schwendeman, J. Mol. Spectrosc. 120, 317 (1986).
[CrossRef]

1985 (1)

G. Moruzzi, F. Strumia, F. Colao, Infrared Phys. 25, 251 (1985).
[CrossRef]

1984 (2)

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
[CrossRef]

1983 (1)

J. O. Henningsen, J. Mol. Spectrosc. 102, 399 (1983).
[CrossRef]

1982 (1)

W. H. Weber, P. D. Maker, J. Mol. Spectrosc. 93, 131 (1982).
[CrossRef]

1980 (2)

E. Arimondo, M. Inguscio, A. Moretti, M. Pellegrino, F. Strumia, Opt. Lett. 5, 496 (1980).
[CrossRef] [PubMed]

F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
[CrossRef]

1979 (4)

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
[CrossRef]

J. P. Sattler, T. L. Worchesky, W. A. Riessler, Infrared Phys. 19, 217 (1979).
[CrossRef]

H. Dreizler, W. Schrepp, R. Schwarz, Z. Naturforsch. 34a, 571 (1979).

1978 (1)

J. O. Henningsen, J. C. Petersen, Infrared Phys. 18, 475 (1978).
[CrossRef]

1953 (1)

E. V. Ivash, D. M. Dennison, J. Chem. Phys. 21, 1804 (1953).
[CrossRef]

Arimondo, E.

Colao, F.

G. Moruzzi, F. Strumia, F. Colao, Infrared Phys. 25, 251 (1985).
[CrossRef]

Dennison, D. M.

E. V. Ivash, D. M. Dennison, J. Chem. Phys. 21, 1804 (1953).
[CrossRef]

Dreizler, H.

H. Dreizler, W. Schrepp, R. Schwarz, Z. Naturforsch. 34a, 571 (1979).

Duxbury, G.

G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
[CrossRef]

Evenson, K. M.

F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
[CrossRef]

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

Fawzy, W.

W. Fawzy, R. H. Schwendeman, J. Mol. Spectrosc. 120, 317 (1986).
[CrossRef]

Henningse, J. O.

J. O. Henningse, Int. J. Infrared Millimeter Waves 7, 1605 (1986).
[CrossRef]

Henningsen, J. O.

J. O. Henningsen, J. Mol. Spectrosc. 102, 399 (1983).
[CrossRef]

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

J. O. Henningsen, J. C. Petersen, Infrared Phys. 18, 475 (1978).
[CrossRef]

J. O. Henningsen, in Infrared and Millimeter Waves, K. J. Button, ed. (Academic, New York, 1982), Vol. 5, Chap. 2.

Henningson, J. O.

J. O. Henningson, J. C. Petersen, postdeadline paper presented at the International Conference on Infrared Millimeter Waves, Pisa, Italy, October 20–24, 1986.

Inguscio, M.

Ioli, N.

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

Ivash, E. V.

E. V. Ivash, D. M. Dennison, J. Chem. Phys. 21, 1804 (1953).
[CrossRef]

Jennings, D. A.

F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
[CrossRef]

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

Kato, H.

G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
[CrossRef]

Lees, R. M.

R. M. Lees, Proc. Soc. Photo-Opt. Instrum. Eng. 666, 158 (1986).

R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
[CrossRef]

LeLerre, M. L.

G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
[CrossRef]

Maker, P. D.

W. H. Weber, P. D. Maker, J. Mol. Spectrosc. 93, 131 (1982).
[CrossRef]

Moretti, A.

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

E. Arimondo, M. Inguscio, A. Moretti, M. Pellegrino, F. Strumia, Opt. Lett. 5, 496 (1980).
[CrossRef] [PubMed]

Moruzzi, G.

G. Moruzzi, F. Strumia, F. Colao, Infrared Phys. 25, 251 (1985).
[CrossRef]

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

Oliver, B. A.

R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
[CrossRef]

Pellegrino, M.

Petersen, F. R.

F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
[CrossRef]

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

Petersen, J. C.

G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
[CrossRef]

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

J. O. Henningsen, J. C. Petersen, Infrared Phys. 18, 475 (1978).
[CrossRef]

J. O. Henningson, J. C. Petersen, postdeadline paper presented at the International Conference on Infrared Millimeter Waves, Pisa, Italy, October 20–24, 1986.

Riessler, W. A.

J. P. Sattler, T. L. Worchesky, W. A. Riessler, Infrared Phys. 19, 217 (1979).
[CrossRef]

Rosselli, P.

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

Sattler, J. P.

J. P. Sattler, T. L. Worchesky, W. A. Riessler, Infrared Phys. 19, 217 (1979).
[CrossRef]

Scalabrin, A.

F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
[CrossRef]

Schrepp, W.

H. Dreizler, W. Schrepp, R. Schwarz, Z. Naturforsch. 34a, 571 (1979).

Schwarz, R.

H. Dreizler, W. Schrepp, R. Schwarz, Z. Naturforsch. 34a, 571 (1979).

Schwendeman, R. H.

W. Fawzy, R. H. Schwendeman, J. Mol. Spectrosc. 120, 317 (1986).
[CrossRef]

Strumia, F.

G. Moruzzi, F. Strumia, F. Colao, Infrared Phys. 25, 251 (1985).
[CrossRef]

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

E. Arimondo, M. Inguscio, A. Moretti, M. Pellegrino, F. Strumia, Opt. Lett. 5, 496 (1980).
[CrossRef] [PubMed]

Van der Linde, J.

R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
[CrossRef]

Weber, W. H.

W. H. Weber, P. D. Maker, J. Mol. Spectrosc. 93, 131 (1982).
[CrossRef]

Worchesky, T. L.

J. P. Sattler, T. L. Worchesky, W. A. Riessler, Infrared Phys. 19, 217 (1979).
[CrossRef]

Young, C.

R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
[CrossRef]

IEEE J. Quantum Electron. (1)

F. R. Petersen, K. M. Evenson, D. A. Jennings, A. Scalabrin, IEEE J. Quantum Electron. QE-16, 319 (1980).
[CrossRef]

Infrared Phys. (3)

J. P. Sattler, T. L. Worchesky, W. A. Riessler, Infrared Phys. 19, 217 (1979).
[CrossRef]

G. Moruzzi, F. Strumia, F. Colao, Infrared Phys. 25, 251 (1985).
[CrossRef]

J. O. Henningsen, J. C. Petersen, Infrared Phys. 18, 475 (1978).
[CrossRef]

Int. J. Infrared Millimeter Waves (1)

J. O. Henningse, Int. J. Infrared Millimeter Waves 7, 1605 (1986).
[CrossRef]

J. Chem. Phys. (1)

E. V. Ivash, D. M. Dennison, J. Chem. Phys. 21, 1804 (1953).
[CrossRef]

J. Mol. Spectrosc. (7)

W. Fawzy, R. H. Schwendeman, J. Mol. Spectrosc. 120, 317 (1986).
[CrossRef]

N. Ioli, A. Moretti, G. Moruzzi, P. Rosselli, F. Strumia, J. Mol. Spectrosc. 105, 284 (1984).
[CrossRef]

J. O. Henningsen, J. Mol. Spectrosc. 102, 399 (1983).
[CrossRef]

W. H. Weber, P. D. Maker, J. Mol. Spectrosc. 93, 131 (1982).
[CrossRef]

J. O. Henningsen, J. C. Petersen, F. R. Petersen, D. A. Jennings, K. M. Evenson, J. Mol. Spectrosc. 77, 298 (1979).
[CrossRef]

R. M. Lees, C. Young, J. Van der Linde, B. A. Oliver, J. Mol. Spectrosc. 75, 161 (1979).
[CrossRef]

G. Duxbury, J. C. Petersen, H. Kato, M. L. LeLerre, J. Mol. Spectrosc. 107, 261 (1984).
[CrossRef]

Opt. Lett. (1)

Proc. Soc. Photo-Opt. Instrum. Eng. (1)

R. M. Lees, Proc. Soc. Photo-Opt. Instrum. Eng. 666, 158 (1986).

Z. Naturforsch. (1)

H. Dreizler, W. Schrepp, R. Schwarz, Z. Naturforsch. 34a, 571 (1979).

Other (2)

J. O. Henningson, J. C. Petersen, postdeadline paper presented at the International Conference on Infrared Millimeter Waves, Pisa, Italy, October 20–24, 1986.

J. O. Henningsen, in Infrared and Millimeter Waves, K. J. Button, ed. (Academic, New York, 1982), Vol. 5, Chap. 2.

Cited By

OSA participates in CrossRef's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Figures (4)

Fig. 1
Fig. 1

Experimental apparatus. BS, beam splitter; PSD, phase-sensitive detector; Att.'s, attenuators.

Fig. 2
Fig. 2

Energy-level scheme showing the transition pumped by the 9P(10) CO2 laser line. a, b, and c, Previously observed FIR transitions. The double arrows indicate the RF transitions observed.

Fig. 3
Fig. 3

Energy-level scheme showing the transition pumped by the 9P(12) CO2 laser line. The letters a, b, and c denote previously observed FIR transitions. The double arrows indicate the RF transitions observed.

Fig. 4
Fig. 4

Double-resonance signal observed with the 9P(10) line of the CO2 laser. The laser power was 200 mW, the RF power 300 mW, and the sample pressure was 40 mTorr. A time constant of 100 msec was used.

Tables (2)

Tables Icon

Table 1 Observed Asymmetry Splittings in13CH3OH

Tables Icon

Table 2 Asymmetry-Splitting Parameters for 13CH3OH (MHz)

Equations (1)

Equations on this page are rendered with MathJax. Learn more.

S ( J , K ) = S ( K ) ( J + K ) ! ( J K ) ! ,

Metrics