Abstract

We report 2D Fourier transform electronic spectroscopy obtained in the pump–probe geometry using a continuum probe. An acousto-optic pulse shaper placed in the pump arm of a standard pump-continuum probe experiment permits 2D spectroscopy that probes a broad spectral range. We demonstrate the method on a simple dye system exhibiting vibrational wavepacket dynamics that modulate the peak shapes of the 2D spectra. The broad spectral range of the continuum probe allows us to observe vibronic cross peaks in the 2D spectra.

© 2009 Optical Society of America

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    [CrossRef] [PubMed]
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    [CrossRef]
  8. M. L. Cowan, J. P. Ogilvie, and R. J. D. Miller, Chem. Phys. Lett. 386, 184 (2004).
    [CrossRef]
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    [CrossRef] [PubMed]
  10. W. Xiong and M. T. Zanni, Opt. Lett. 33, 1371 (2008).
    [CrossRef] [PubMed]
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    [CrossRef]
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    [CrossRef]
  13. S. A. Kovalenko, N. P. Ernsting, and J. Ruthmann, Chem. Phys. Lett. 258, 445 (1996).
    [CrossRef]
  14. D. Egorova, M. F. Gelin, and W. Domcke, J. Chem. Phys. 126, 074314 (2007).
    [CrossRef] [PubMed]

2008

2007

D. Egorova, M. F. Gelin, and W. Domcke, J. Chem. Phys. 126, 074314 (2007).
[CrossRef] [PubMed]

L. P. DeFlores, R. A. Nicodemus, and A. Tokmakoff, Opt. Lett. 32, 2966 (2007).
[CrossRef] [PubMed]

S. H. Shim, D. B. Strasfeld, Y. L. Ling, and M. T. Zanni, Proc. Natl. Acad. Sci. USA 104, 14197 (2007).
[CrossRef] [PubMed]

E. M. Grumstrup, S. H. Shim, M. A. Montgomery, N. H. Damrauer, and M. T. Zanni, Opt. Express 15, 16681 (2007).
[CrossRef] [PubMed]

2004

M. L. Cowan, J. P. Ogilvie, and R. J. D. Miller, Chem. Phys. Lett. 386, 184 (2004).
[CrossRef]

T. Brixner, T. Mancal, I. V. Stiopkin, and G. R. Fleming, J. Chem. Phys. 121, 4221 (2004).
[CrossRef] [PubMed]

2003

D. M. Jonas, Annu. Rev. Phys. Chem. 54, 425 (2003).
[CrossRef] [PubMed]

2001

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

1999

S. M. G. Faeder and D. M. Jonas, J. Phys. Chem. A 103, 10489 (1999).
[CrossRef]

1997

1996

S. A. Kovalenko, N. P. Ernsting, and J. Ruthmann, Chem. Phys. Lett. 258, 445 (1996).
[CrossRef]

Brixner, T.

T. Brixner, T. Mancal, I. V. Stiopkin, and G. R. Fleming, J. Chem. Phys. 121, 4221 (2004).
[CrossRef] [PubMed]

Cowan, M. L.

M. L. Cowan, J. P. Ogilvie, and R. J. D. Miller, Chem. Phys. Lett. 386, 184 (2004).
[CrossRef]

Cyrier, M.

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

Damrauer, N. H.

DeFlores, L. P.

Domcke, W.

D. Egorova, M. F. Gelin, and W. Domcke, J. Chem. Phys. 126, 074314 (2007).
[CrossRef] [PubMed]

Egorova, D.

D. Egorova, M. F. Gelin, and W. Domcke, J. Chem. Phys. 126, 074314 (2007).
[CrossRef] [PubMed]

Ernsting, N. P.

S. A. Kovalenko, N. P. Ernsting, and J. Ruthmann, Chem. Phys. Lett. 258, 445 (1996).
[CrossRef]

Faeder, S. M. G.

S. M. G. Faeder and D. M. Jonas, J. Phys. Chem. A 103, 10489 (1999).
[CrossRef]

Fleming, G. R.

T. Brixner, T. Mancal, I. V. Stiopkin, and G. R. Fleming, J. Chem. Phys. 121, 4221 (2004).
[CrossRef] [PubMed]

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

Gelin, M. F.

D. Egorova, M. F. Gelin, and W. Domcke, J. Chem. Phys. 126, 074314 (2007).
[CrossRef] [PubMed]

Grumstrup, E. M.

Jonas, D. M.

D. M. Jonas, Annu. Rev. Phys. Chem. 54, 425 (2003).
[CrossRef] [PubMed]

S. M. G. Faeder and D. M. Jonas, J. Phys. Chem. A 103, 10489 (1999).
[CrossRef]

Kauffmann, H. F.

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

Kovalenko, S. A.

S. A. Kovalenko, N. P. Ernsting, and J. Ruthmann, Chem. Phys. Lett. 258, 445 (1996).
[CrossRef]

Larsen, D. S.

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

Lewis, K. L. M.

Ling, Y. L.

S. H. Shim, D. B. Strasfeld, Y. L. Ling, and M. T. Zanni, Proc. Natl. Acad. Sci. USA 104, 14197 (2007).
[CrossRef] [PubMed]

Lukes, V.

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

Mancal, T.

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

T. Brixner, T. Mancal, I. V. Stiopkin, and G. R. Fleming, J. Chem. Phys. 121, 4221 (2004).
[CrossRef] [PubMed]

Miller, R. J. D.

M. L. Cowan, J. P. Ogilvie, and R. J. D. Miller, Chem. Phys. Lett. 386, 184 (2004).
[CrossRef]

Milota, F.

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

Montgomery, M. A.

Myers, J. A.

Nemeth, A.

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

Nicodemus, R. A.

Ogilvie, J. P.

J. A. Myers, K. L. M. Lewis, P. F. Tekavec, and J. P. Ogilvie, Opt. Express 16, 17420 (2008).
[CrossRef] [PubMed]

M. L. Cowan, J. P. Ogilvie, and R. J. D. Miller, Chem. Phys. Lett. 386, 184 (2004).
[CrossRef]

Ohta, K.

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

Piel, J.

Riedle, E.

Ruthmann, J.

S. A. Kovalenko, N. P. Ernsting, and J. Ruthmann, Chem. Phys. Lett. 258, 445 (1996).
[CrossRef]

Shim, S. H.

S. H. Shim, D. B. Strasfeld, Y. L. Ling, and M. T. Zanni, Proc. Natl. Acad. Sci. USA 104, 14197 (2007).
[CrossRef] [PubMed]

E. M. Grumstrup, S. H. Shim, M. A. Montgomery, N. H. Damrauer, and M. T. Zanni, Opt. Express 15, 16681 (2007).
[CrossRef] [PubMed]

Sperling, J.

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

Stiopkin, I. V.

T. Brixner, T. Mancal, I. V. Stiopkin, and G. R. Fleming, J. Chem. Phys. 121, 4221 (2004).
[CrossRef] [PubMed]

Strasfeld, D. B.

S. H. Shim, D. B. Strasfeld, Y. L. Ling, and M. T. Zanni, Proc. Natl. Acad. Sci. USA 104, 14197 (2007).
[CrossRef] [PubMed]

Tekavec, P. F.

Tokmakoff, A.

Wilhelm, T.

Xiong, W.

Xu, Q. H.

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

Zanni, M. T.

Annu. Rev. Phys. Chem.

D. M. Jonas, Annu. Rev. Phys. Chem. 54, 425 (2003).
[CrossRef] [PubMed]

Chem. Phys. Lett.

M. L. Cowan, J. P. Ogilvie, and R. J. D. Miller, Chem. Phys. Lett. 386, 184 (2004).
[CrossRef]

A. Nemeth, F. Milota, T. Mancal, V. Lukes, H. F. Kauffmann, and J. Sperling, Chem. Phys. Lett. 459, 94 (2008).
[CrossRef]

S. A. Kovalenko, N. P. Ernsting, and J. Ruthmann, Chem. Phys. Lett. 258, 445 (1996).
[CrossRef]

J. Chem. Phys.

D. Egorova, M. F. Gelin, and W. Domcke, J. Chem. Phys. 126, 074314 (2007).
[CrossRef] [PubMed]

D. S. Larsen, K. Ohta, Q. H. Xu, M. Cyrier, and G. R. Fleming, J. Chem. Phys. 114, 8008 (2001).
[CrossRef]

T. Brixner, T. Mancal, I. V. Stiopkin, and G. R. Fleming, J. Chem. Phys. 121, 4221 (2004).
[CrossRef] [PubMed]

J. Phys. Chem. A

S. M. G. Faeder and D. M. Jonas, J. Phys. Chem. A 103, 10489 (1999).
[CrossRef]

Opt. Express

Opt. Lett.

Proc. Natl. Acad. Sci. USA

S. H. Shim, D. B. Strasfeld, Y. L. Ling, and M. T. Zanni, Proc. Natl. Acad. Sci. USA 104, 14197 (2007).
[CrossRef] [PubMed]

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Figures (3)

Fig. 1
Fig. 1

Experimental setup for 2D spectroscopy with a pulse shaper and a continuum probe. (b) Absorption (solid curve) and emission (dotted curve) spectra of PERY showing the pump (dashed curve) and continuum (dashed–dotted curve) spectra.

Fig. 2
Fig. 2

Pump–probe data at 535 and 579 nm , showing oscillations with a period of 240 fs . The temporal offset between the two traces is caused by linear chirp on the continuum probe. Arrows indicate the t 2 times at which the 2D spectra in Fig. 3 were recorded.

Fig. 3
Fig. 3

(a) Absorptive 2D spectra for PERY in DMSO at different waiting times t 2 indicated by the arrows in Fig. 2 (b) Ratio of diagonal to antidiagonal widths for the central peak (solid blue curve), lower peak (dashed red curve), and upper peak (dotted green curve), showing modulation with a 240 fs period. The angle of the nodal line in the central peak (dashed–dotted purple curve) in the imaginary 2D spectrum (not shown) exhibits similar modulation.

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