Abstract

The nonlinear optical property of few-layered MoS2 nanoplatelets synthesized by the hydrothermal exfoliation method was investigated from the visible to the near-infrared band using lasers. Both open-aperture Z-scan and balanced-detector measurement techniques were used to demonstrate the broadband saturable absorption property of few-layered MoS2. To explore its potential applications in ultrafast photonics, we fabricated a passive mode locker for ytterbium-doped fibre laser by depositing few-layered MoS2 onto the end facet of optical fiber by means of an optical trapping approach. Our laser experiment shows that few-layer MoS2-based mode locker allows for the generation of stable mode-locked laser pulse, centered at 1054.3 nm, with a 3-dB spectral bandwidth of 2.7 nm and a pulse duration of 800 ps. Our finding suggests that few-layered MoS2 nanoplatelets can be useful nonlinear optical material for laser photonics devices, such as passive laser mode locker, Q-switcher, optical limiter, optical switcher and so on.

© 2014 Optical Society of America

1. Introduction

Since graphene was first isolated from graphite, its electronic and optical properties have been studied extensively and applied in various fields [14]. The success of graphene applications motivates the exploration of other graphene-like two-dimensional (2D) materials in which strong intra-layer covalent bonding and weak inter-layer van der Waals forces exist [5, 6]. But the photonic applications of 2D crystals remain much less actively investigated. Although saturable absorption in molybdenum disulfide (MoS2) has been reported [7], ultrafast pulse generation has yet to be demonstrated. Single-layer transition metal dichalcogenides (TMDs) display surprisingly strong bulk-like photon absorption and exciton generation owing to Van Hove singularities [8] and possibly band nesting [9]. MoS2 is a typical TMD, in which hexagonal layers of molybdenum atoms are sandwiched between two layers of chalcogen atoms (S) [10, 11]. As with graphene, layered materials must be exfoliated into thin sheets to reveal their extraordinary properties. The optical properties of MoS2 show interesting layer dependence. The excitonic transition at the K point in the Brillouin zone of MoS2 remains direct regardless of layer thickness, whereas the indirect band-gap energy between the Γ and K points increases as layer thickness decreases. The indirect-to-direct transition occurs as MoS2 is exfoliated into monolayer sheets, resulting in the dramatic enhancement of photoluminescence [12, 13]. This exotic optical-electrical property makes few-layered MoS2 a potential optical material for use in optoelectronics.

Optical materials with different nonlinear optical responses (optical limiting and saturable absorption) are widely used for photonic devices such as optical limiters, mode-lockers, and Q-switchers [14, 15]. Graphene has been shown to exhibit broadband optical saturable absorption property and has been applied successfully in passive mode locking or Q-switching of both fibre and solid-state lasers [1417]. Very recently, Wang et al. reported that MoS2 dispersions with large populations of single and few layers produced by liquid-phase exfoliation exhibit significant saturable absorption under femtosecond laser excitation at 800 nm and show better saturable absorption response than does graphene [7]. The potential photonics applications of solution-processed 2-dimenional layered materials, such as MoS2, WS2, Bi2Se3, and Bi2Te3, had been summarized by Bonaccorso et al. [18]. Recently, we demonstrated the high-yield exfoliation of 2D chalcogenides by reduction with sodium naphthalenide; the solution-dispersible flakes can be easily manipulated and provide an opportunity to study the ultrafast photonics of 2D chalcogenide films [19].

In this contribution, we experimentally confirm that MoS2 shows broadband saturable absorption response from the visible to the near-infrared band and demonstrate the first ultrafast photonics application of MoS2 saturable absorber for passive laser mode-locking operation. To take advantage of its near-infrared saturable absorption property, we have developed a MoS2-based optical fibre saturable absorber device with operation wavelength suitable for an ytterbium-doped fibre laser and experimentally generated nanosecond pulses, indicating that the MoS2 saturable absorber possesses excellent mode-locking ability comparable with other saturable absorbers such as graphene.

2. Experimental preparation and setup

2.1. Preparation of MoS2 nanoplatelets

Hydrothermal intercalation/exfoliation [13, 20], a convenient and cost-effective approach for the synthesis of MoS2 flakes applied in this work, is shown schematically in Fig. 1.Typically, MoS2 bulk crystals (0.1 g, 99.999%, Alfa Aesar) were placed into a 50-mL Teflon-lined autoclave filled with 30 mL ethylene glycol and 0.32 g lithium hydroxide. The autoclave was heated at 200°C for 72 hours to achieve the complete intercalation of MoS2 through the lithium ions (Li+) dissolved in the solution. After the Li-ion intercalation, the dispersions in the solution were collected by filtration and rinsed with acetone to eliminate the residual ethylene glycol solution and lithium hydroxide. Colloidal suspensions of MoS2 nanoplatelets (NPs) were prepared by hydrating the lithiated MoS2 powder in deionised water. The NPs were filtered through porous polyvinylidene fluoride (0.45-lm nominal pore size) membranes, then dried at 60°C to form MoS2 NPs membranes. All samples for the material characterization and nonlinear optical measurement were dispersed in isopropyl alcohol with a concentration of 0.5 mg/mL.

 figure: Fig. 1

Fig. 1 Schematic diagram of the formation of MoS2 NPs.

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The characterizations of the MoS2 NP samples are shown in Fig. 2.Figure 2(a) shows the scanning electron microscopy image of the as-prepared MoS2 NPs, where the layered structure can be identified at the edge of the NPs. The XRD results of exfoliated MoS2 NPs in Fig. 2(b) are in good agreement with the hexagonal structure of MoS2 (PDF Card 04-0880). Atomic force microscopy was used to determine the sample thickness, as shown in Fig. 2(c). The height difference between the quartz substrate and the sample surface is approximately 9.2 nm. Figure 2(d) shows typical UV-Vis spectra of few-layered MoS2 NPs dispersed in isopropyl alcohol solution and dropped on quarts with a spectrophotometer (Lambda 950). Two peaks around 630 nm and 680 nm arise from the direct-gap transition, which is due to the energy split from valence band and spin-orbit coupling [12, 21]. The broadband absorption in Fig. 2(d) may be related to the presence of both 1T (metallic) and 2H (semiconducting) phases in the as-exfoliated MoS2 NPs [19]. The 1T phase is known to predominate due to doping by impurities. This means that the saturable absorption properties we study here can be dominated by the metallic phase.

 figure: Fig. 2

Fig. 2 Characterisation of MoS2 NPs for Z-scan measurement. (a) Scanning electron microscopy image, (b) XRD diffraction pattern, (c) Atomic force microscopy image and (d) UV-Vis spectra of as-grown MoS2 NPs.

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To confirm that the bulk MoS2 has been successfully exfoliated into few-layer structure, we performed Raman spectroscopy on exfoliated MoS2 and bulk MoS2, as shown in Fig. 3.The characteristic peaks of the two samples at 380 and 407 cm−1 are assigned to the E12g and A1g modes of MoS2, respectively. The E12g mode is correlated with an in-plane motion of Mo and S atoms, while the A1g mode is caused by an out-of-plane vibration of Mo and S [22].Notably, the E12g is the shear mode, which is attributed to the relative motion between the adjacent two mono-layers. By comparing the E12g mode of bulk MoS2, one could observe an obvious red shift in the Raman spectra due to the interlayer dependence of the shear modes, which agrees with that of MoS2 with thicknesses in the range of 1-3 layers [23].

 figure: Fig. 3

Fig. 3 Raman spectra of the bulk and the exfoliated MoS2

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2.2. Experimental setup

The laser Z-scan technique, which was used as an effective tool to measure the nonlinear refractive index of graphene in [24], was used to study the nonlinear optical absorption of the as-prepared MoS2 NPs. The experimental setup is shown schematically in Fig. 4. The Z-scan measurements were performed by a mode-locked Ti:sapphire oscillator-seeded regenerative amplifier, from which a train of optical pulses (centre wavelength: 800 nm, pulse duration: 100 fs, 3-dB spectral width: 15 nm and repetition rate: 1 kHz) are emitted. A piece of BBO crystal is used to double the frequency of the incident laser pulse at 800 nm through SHG, delivering laser pulses at 400 nm. This technique allows for measurement at different wavelengths.

 figure: Fig. 4

Fig. 4 Schematic diagram of the Z-scan experimental setup.

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At first, the MoS2 dispersion was contained within a 1-mm-thick cuvette for measurement by the incident laser beam (800 nm), which was focused by an objective lens (focal length: 500 mm). The incident beam waist was measured to be about 30 μm by a CCD. By using an optical attenuator, we could adjust the average optical power to below 10 mW, which corresponded to a peak input fluence of 350 mJ/cm2. The solution cuvette was perpendicularly oriented towards the beam axis and translated along the Z-axis through a linear motorised stage. Computer-controlled power meters were used to simultaneously monitor the referenced and output optical power. To confirm the precision of the experimental setup, the CS2 solution contained in the cuvette was used for calibration. A typical valley-like Z-scan trace could be observed. This allowed the nonlinear optical absorption coefficient of CS2 to be determined as 4.35 × 10−11 cm/W, which is in good agreement with the 5 × 10−11 cm/W value reported previously [25]. This result demonstrates the reliability of our Z-scan measurement platform.

3. Nonlinear optics results and discussion

The ultrafast nonlinear absorption properties of MoS2 NPs were investigated by the Z-scan technique. Figures 5(a) and 5(b) show the excitation fluence-dependent open-aperture Z-scan measurement results of MoS2 NP dispersions at both 400 and 800 nm. The sharp and narrow peaks and valleys at the focus point clearly show the characteristics of nonlinear absorption. At the low incident fluence (400 nm), the optical transmittance increases as the sample is translated across the focus point [Fig. 5(a)]. The response is typical of saturable absorption, in which the optical absorbance decreases with the increase of the incident laser flux and becomes saturated above a certain threshold. With the increase of the input fluence, the peaks of the saturable absorption also increase correspondingly. This can be clearly seen from the experimental data at 18 mJ/cm2 and 35 mJ/cm2 in Fig. 5(a). However, reverse saturable absorption (RSA) like curve also occurs at a peak intensity of 70 mJ/cm2. Figure 5(b) shows similar saturable absorption and RSA like behaviour at 800 nm. However, a higher excitation fluence is required to achieve the transition from saturable absorption to RSA at 800 nm than at 400 nm.

 figure: Fig. 5

Fig. 5 The open-aperture Z-scan measurements of MoS2 dispersions in a 1-mm cuvette at (a) 400 nm and (b) 800 nm with different input fluences.

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The saturable absorption at 400 nm under low incident fluence can be attributed to valence-conduction inter-band transition. The band gaps of few-layered MoS2 NPs are rather inhomogeneous due to the mixture of the 1T (metallic) and 2H (semiconducting) phases in the as-exfoliated material [19]. As the input fluence increases, electrons in the valence band can be easily pumped to fill the conduction band. Due to the direct band structure and the Pauli blocking principle, the optical absorption saturates at a higher intensity. At higher excitation fluence, nonlinear scattering starts to dominate and leads to the emergence of RSA-like curves, similar to that reported previously [26]. In addition, the origin of the RSA at 800 nm under high input fluence might come from two-photon absorption (TPA) or nonlinear scattering, or a combination of both.

We fitted the experimental Z-scan data with the saturable model that includes both the saturable absorption and TPA effects [27, 28]:

α(I)=α01+I/Is+βI
where α(I) is the total absorption coefficient, α0is the linear absorption coefficient, Iis the input intensity, Is is the saturable intensity and β is the TPA coefficient. Normally, however, we use the normalized transmittance in the Z-scan measurement:
T=(1α0L1+I/IsβIL)/(1α0L)
where L is the sample length. Otherwise, we can use peak intensityI0and the diffraction length of the beam Z0 to determine the intensity:
I(z)=I0(1+z2/z02).
Thus, we can use the following modified equation to fit the Z-scan experimental data:
T=[1α0LIsIs+I0/(1+z2/z02)βLI0/(1+z2/z02)]/(1α0L).
From the fitting curves, we can see that the saturable absorption data fits perfectly; the saturable intensity Is and modulation depth α0L are about 136.1 ± 20 GW/cm2 and 10% at 400 nm and 279.6 ± 60 GW/cm2 and 34% at 800 nm, respectively. The TPA β coefficients at the two bands are approximately negligible. The RSA data do not fit very well with the model, possibly due to the multiple origins of the RSA behavior.

To further investigate the nonlinear absorption change at 800 nm, the balanced twin-detector method was used to characterize the nonlinear response of MoS2 dispersions, as shown in Fig. 6(a).A femtosecond laser pulse at 800 nm was used to perpendicularly illuminate the dispersion sample. The optical power through the dispersion was monitored by detector 1 (D1) while the back-scattering light collected by the lens was monitored by detector 2 (D2). By gradually increasing the input power, we could identify the changes occurring in the transmittance and back-scattering power under different input fluences. The transmittance curve is shown in Fig. 6(b), and we can see that the transmittance peak increases as the input fluence increases up to 60 mJ/cm2 and then becomes saturated at an incident fluence of 60~105 mJ/cm2 and suddenly drops at 120 mJ/cm2. At the same time, the scattering power linearly increases with the input fluence up to 105 mJ/cm2 and then significantly increases around 120 mJ/cm2. We found that the sudden transmittance change was caused by laser-induced microbubbles at an input fluence above 120 mJ/cm2. On the basis of these findings, we can conclude that the sudden transmittance decrease of MoS2 dispersion originates from the back scattering of microbubbles within the solution, which can induce the transition from saturable absorption to RSA under femtosecond laser pulse excitation. The transmittance data can be well fitted by the saturable model above, and the saturable intensity and modulation depth are inferred to be about 337.9 GW/cm2 and 33%, respectively.

 figure: Fig. 6

Fig. 6 (a) Schematic diagram of twin-detector measurement; (b) and (c) show the nonlinear transmittance and scattering power, respectively, of MoS2 dispersions under different input fluences at 800 nm.

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To suppress the nonlinear scattering effect that arises from laser-induced microbubbles, MoS2 NPs were cast as a thin film on quartz plate and open-aperture Z-scan measurements were performed on it. The sample was made by spin coating MoS2 dispersions onto a 1-mm-thick quartz plate and then drying it in an oven. The average thickness of the sample was measured to be about 10 nm. Through the performance of similar Z-scan measurements, the saturable absorption of MoS2 film was also experimentally identified under different excitation fluence. Figure 7(a), which shows typical saturable absorption curves at different input intensities, indicates the clear dependence of the transmittance peak on the input intensity. To further ensure that the detected sample was free of optical damage, the reproducibility of the transmission curves was tested by cycling the laser fluence up and down. By either increasing the incident laser from low to high power or vice-versa, the measured nonlinear optics curves could be well reproduced at different powers.

 figure: Fig. 7

Fig. 7 (a) The open-aperture Z-scan measurement of MoS2 NPs on quartz at different input influences at 800 nm; (b) the relation between normalized transmittance and input intensity.

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To verify whether the quartz substrate contributes to the nonlinear optics response, pure quartz substrate without sample was used as the control, and there was no response even after irradiation at high laser power. The corresponding saturable absorption curves are shown in Fig. 7(b), from which the saturation intensity and modulation depth are determined to be 1.85 GW/cm2 and 15.9%, respectively. Unlike the experiments with the dispersion solution, nonlinear scattering has been mitigated here, which does not allow for the emergence of the RSA effect. Consequently, we can safely conclude that the observed saturable absorption response should only originate from the intrinsic absorption in MoS2, whereas micro bubble-induced nonlinear scattering can produce the optical limiting effect in the MoS2 dispersion solution.

To check whether the MoS2 NPs also show saturable absorption at other wavelengths, the film sample was also measured at 1064 nm. We used a passively mode-locked ytterbium-doped fibre laser (centre wavelength: 1064 nm, repetition rate: 7 MHz and pulse duration: 0.8 ns) as the laser source. After collimation and focusing, the incident beam waist was estimated to be about 18.4 μm at the focus point. The open-aperture Z-scan technique was performed, and the saturable absorption curves were found at different input intensities, as shown in Fig. 8(a).The twin-detector method was also used to check the nonlinear absorption at different points on the sample, and we could also observe very strong saturable absorption response, as shown in Figs. 8(b) and 8(c). From the nonlinear optics curves, the saturable intensity and modulation depth are fitted to be 8.7 MW/m2 and 4.6%, respectively. Based on both the open-aperture Z-scan and balanced twin-detector measurements, it can be concluded that similar to graphene, MoS2 can act as a broadband saturable absorber in the visible to the near-infrared band.

 figure: Fig. 8

Fig. 8 (a) The open-aperture Z-scan measurement of MoS2 NPs on quartz at different input intensities at 1064 nm. (b) and (c) The twin-detector measurement of the film sample at 1064 nm: the incident power is increased (with respect to decreased) from low (with respect to high) to high (with respect to low) intensity.

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4. Ultrafast photonics applications

The optical saturable absorption of MoS2 for the passive mode locking of a fibre laser was also investigated. To make the absorber more compatible with the fibre laser cavity, the optical trapping method was used to deposit MoS2 flakes onto the optical fibre facet. Under laser illumination, thermal convection flow and thermal diffusion can occur. These will allow for the movement of nano-particles (herein MoS2 flake) along the temperature gradient towards the fiber surface. In the experiment, the end of the output port of a continuous wave laser at 975nm was immersed into a Dimethyl Formamide (DMF) solution of few-layer MoS2. Polymethyl methacrylate (PMMA) solution was used to coat the fiber pigtail for protection. By controlling the pump power and deposition time, a suitable fiber pigtailed saturable absorber device can be fabricated for our fiber laser. The fibre laser cavity is schematically shown in Fig. 9.We used a piece of 0.65-m highly ytterbium-doped ðbre (YDF, LIEKKI Yb1200-4/125) with a group velocity dispersion of –20 ps2/km as the gain medium, and a single-mode fibre with a total length of 22.4 m fibre and group velocity dispersion of –23 ps2/km as the other fibre component. The net cavity dispersion was normal and was estimated to be –3.09 ps2. The laser was forward pumped by a 975-nm laser diode through a 975/1060 WDM and then emitted outside the laser cavity by a 10/90 optical coupler. Unidirectional operation can be ensured by an in-cavity polarisation-independent isolator (PII-ISO). The cavity polarisation and cavity birefringence can be adjusted by the polarisation controllers to further optimise the laser mode-locking performance. The as-fabricated MoS2 saturable absorber device was then spliced inside the laser cavity between the PC and the PII-ISO. The output laser pulse train was monitored by an oscilloscope (Tektronix TDS3054B) and a radiofrequency analyser, and the optical spectrum and pulse duration were measured by an optical spectrum analyser (Ando AQ-6317B) with a spectral resolution of 0.015 nm.

 figure: Fig. 9

Fig. 9 Schematic of the ytterbium-doped ðbre laser passively mode locked by the MoS2 saturable absorber. WDM (wavelength division multiplexer), YDF (ytterbium-doped fibre), PC (polarisation controller), PI-ISO (polarisation-independent isolator), SMF (single-mode fibre) and MoS2-saturable absorber.

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Figure 10 summarizes the nonlinear optical property of the fibre-pigtailed MoS2 saturable absorber as well as the performance of the ytterbium-doped ðbre laser passively mode locked by the fibre-pigtailed MoS2 saturable absorber. Figure 10(a) shows the measurement of SA curve of fibre-pigtailed MoS2 saturable absorber. The modulation depth and the saturable intensity are inferred to be 9.3% and 15.9 MW/m2, respectively. The mode-locking operation self-starts once the pump power exceeds 60 mW. The oscilloscope tracings of output pulses are shown in Figs. 10(b) and 10(c). Figure 10(d) shows a typical mode-locking spectrum, which has a bandwidth of 2.7 nm and a central wavelength of 1054.3 nm. Given that the total cavity dispersion is normal, it allows the generation of dissipative solitons characterised by sharp steep spectral edges in the optical spectrum [29]. Unlike the operation of conventional soliton fibre lasers, where transform-limited optical pulses (with pulse duration of hundreds of femtoseconds) can be readily generated with per-pulse energy limited at the level of tens of pico-joules, the operation of a dissipative soliton ytterbium-doped fiber laser can generate larger energy optical pulses with heavy chirp. Correspondingly, the generated optical pulse is measured to be as broad as 800 ps. However, limited by our detection system (the detector bandwidth is about 5 GHz), we are unable to probe the fine structure of the mode-locked pulses. The pulse repetition rate is about 152 nanoseconds, which corresponds to the cavity round-trip time. With continuously increasing pump power, the single-pulse operation state is maintained while the output power is increased until it reaches the maximum value of 9.3 mW. Under high pumping, the mode-locking state becomes unstable and gradually loses its stability. The corresponding radiofrequency spectrum shows that in the stable mode-locking state, the fundamental frequency has a high signal-to-noise ratio (up to 50 dB).

 figure: Fig. 10

Fig. 10 The laser mode-locking performance by the MoS2 saturable absorber: (a) the SA response fibre-pigtailed MoS2 saturable absorber; (b) & (c) the oscilloscope tracings; (d) the optical spectrum; (e) the radiofrequency spectral profile; (f) wideband RF spectrum.

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We note that the dissipative soliton operation of a fibre laser has been enabled by different types of saturable absorbers, including SWCNTs [30] and graphene [3134]. The present work demonstrates the first dissipative soliton fibre laser passively mode locked by MoS2 saturable absorber. Due to the strongly chirped feature of dissipative solitons, it can be easily amplified. After further pulse compression technology, ultrashort pulses with very large energy can be generated. The generation of dissipative solitons demonstrates that the MoS2 saturable absorber can be used to generate large energy laser pulses.

It is worth commenting on the broadband performance of graphene and MoS2. The broadband performance of graphene is intrinsic, due to its gapless nature. However, it is more complex in the exfoliated MoS2 NPs sample we used due to the mixture of 1T (metallic) and 2H (semiconducting) phases present [19]. The 1T phases usually predominate in as-exfoliated samples due to doping by impurities, giving rise to similar broadband performance as graphene. If the MoS2 can be rendered predeominantly 2H, its absorption at resonance energy will be stronger. This means that at specific wavelength that is in resonance with the band gap, we expect that MoS2 saturable absorber can potentially give stronger saturable absorption response than graphene in view of its strong bulk-like photon absorption and exciton generation owing to Van Hove singularities.

5. Conclusion

In conclusion, we have characterised the broadband saturable absorption properties of few-layered MoS2 from the visible band to the near-infrared band. Our measurements of the nonlinear absorption of solution-dispersed MoS2 yielded saturation intensity and normalized modulation depth of 136.1 ± 20 GW/cm2 and 10% at 400-nm femtosecond laser excitation and 279.6 ± 60 GW/cm2 and 34% at 800-nm excitation, respectively. However, a higher incident laser flux leads to RSA, which arises from the laser-induced microbubbles in the solution. In the case of few-layered MoS2 thin film, even under very high laser fluence of 100 mJ/cm2, only saturable absorption with a saturation intensity of 1.85 GW/cm2 and modulation depth of 15.9% is observed.

To take advantage of the saturable absorption properties of MoS2 at the near-infrared band, we fabricated a new type of MoS2-based optical fibre saturable absorber device that fits the mode-locking operation of an ytterbium-doped fibre laser and experimentally achieved the generation of a nanosecond dissipative soliton pulse at 1054 nm. The demonstrated pulsed laser performance includes a 3-dB spectral bandwidth of 2.7 nm and pulse duration of 800 ps, which indicates that the MoS2 saturable absorber also possesses mode-locking ability that is at least comparable with that of conventional saturable absorbers such as graphene.

Acknowledgments

This work is partially supported by the National 973 Program of China (Grant No. 2012CB315701). K.P.L. offers thanks for the MOE Tier 1 grant “Two dimensional crystals as platforms for optoelectronics (R-143-000-556-112)” and also the NRF-CRP project “Novel 2D materials with tailored properties: beyond graphene (R-144-000-295-281)”. H. Z. offers thanks for the MOE grant (Grant No. NCET 11-0135) and National Natural Science Fund (Grant No. 61222505). The authors would like to thank Dr. Xiang Qi at Xiangtan University for providing the Raman characterization data.

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19. J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014). [CrossRef]   [PubMed]  

20. L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012). [CrossRef]  

21. A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010). [CrossRef]   [PubMed]  

22. P. Tonndorf, R. Schmidt, P. Böttger, X. Zhang, J. Börner, A. Liebig, M. Albrecht, C. Kloc, O. Gordan, D. R. T. Zahn, S. Michaelis de Vasconcellos, and R. Bratschitsch, “Photoluminescence emission and Raman response of monolayer MoS₂, MoSe₂, and WSe₂,” Opt. Express 21(4), 4908–4916 (2013). [CrossRef]   [PubMed]  

23. H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012). [CrossRef]  

24. H. Zhang, S. Virally, Q. Bao, L. K. Ping, S. Massar, N. Godbout, and P. Kockaert, “Z-scan measurement of the nonlinear refractive index of graphene,” Opt. Lett. 37(11), 1856–1858 (2012). [CrossRef]   [PubMed]  

25. R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004). [CrossRef]  

26. K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006). [CrossRef]   [PubMed]  

27. J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009). [CrossRef]  

28. E. Garmire, “Resonant optical nonlinearities in semiconductors,” IEEE J. Sel. Top. Quantum Electron. 6(6), 1094–1110 (2000). [CrossRef]  

29. P. Grelu and N. Akhmediev, “Dissipative solitons for mode-locked lasers,” Nat. Photonics 6(2), 84–92 (2012). [CrossRef]  

30. K. Kieu and F. W. Wise, “All-fiber normal-dispersion femtosecond laser,” Opt. Express 16(15), 11453–11458 (2008). [CrossRef]   [PubMed]  

31. H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010). [CrossRef]  

32. G. Sobon, J. Sotor, J. Jagiello, R. Kozinski, Ma. Zdrojek, M. Holdynski, P. Paletko, J. Boguslawski, L. Lipinska, and K. M. Abramski, “Graphene oxide vs. reduced graphene oxide as saturable absorbers for Er-doped passively mode-locked fibre laser,” Opt. Express 20(17), 19463–19473 (2012).

33. A. Martinez, K. Fuse, B. Xu, and S. Yamashita, “Optical deposition of graphene and carbon nanotubes in a fiber ferrule for passive mode-locked lasing,” Opt. Express 18(22), 23054–23061 (2010). [CrossRef]   [PubMed]  

34. P. L. Huang, S. C. Lin, C. Y. Yeh, H. H. Kuo, S. H. Huang, G. R. Lin, L. J. Li, C. Y. Su, and W. H. Cheng, “Stable mode-locked fiber laser based on CVD fabricated graphene saturable absorber,” Opt. Express 20(3), 2460–2465 (2012). [CrossRef]   [PubMed]  

References

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  1. K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
    [Crossref] [PubMed]
  2. A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
    [Crossref]
  3. F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
    [Crossref]
  4. S. Yamashita, “A tutorial on nonlinear photonic applications of carbon nanotube and graphene,” J. Lightwave Technol. 30(4), 427–447 (2012).
    [Crossref]
  5. A. H. Castro Neto and K. Novoselov, “Two dimensional crystals: beyond graphene,” Mater. Express 1(1), 10–17 (2011).
    [Crossref]
  6. M. S. Xu, T. Liang, M. Shi, and H. Z. Chen, “Graphene-like two-dimensional materials,” Chem. Rev. 113(5), 3766–3798 (2013).
    [Crossref] [PubMed]
  7. K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
    [Crossref] [PubMed]
  8. L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
    [Crossref] [PubMed]
  9. A. Carvalho, R. M. Ribeiro, and A. H. Castro Neto, “Band nesting and the optical response of two-dimensional semiconducting transition metal dichalcogenides,” Phys. Rev. B 88(11), 115205 (2013).
    [Crossref]
  10. Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
    [Crossref] [PubMed]
  11. C. Ataca, H. Şahin, and S. Ciraci, “Stable, single-layer MX2 transition-metal oxides and dichalcogenides in a honeycomb-like structure,” J. Phys. Chem. C 116(16), 8983–8999 (2012).
    [Crossref]
  12. K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
    [Crossref] [PubMed]
  13. J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
    [Crossref] [PubMed]
  14. Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
    [Crossref]
  15. H. Zhang, D. Y. Tang, L. M. Zhao, Q. L. Bao, and K. P. Loh, “Large energy mode locking of an erbium-doped fiber laser with atomic layer graphene,” Opt. Express 17(20), 17630–17635 (2009).
    [Crossref] [PubMed]
  16. Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
    [Crossref] [PubMed]
  17. Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
    [Crossref]
  18. F. Bonaccorso and Z. Sun, “Solution processing of graphene, topological insulators and other 2d crystals for ultrafast photonics,” Opt. Mater. Express 4(1), 63–78 (2014).
    [Crossref]
  19. J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
    [Crossref] [PubMed]
  20. L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
    [Crossref]
  21. A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
    [Crossref] [PubMed]
  22. P. Tonndorf, R. Schmidt, P. Böttger, X. Zhang, J. Börner, A. Liebig, M. Albrecht, C. Kloc, O. Gordan, D. R. T. Zahn, S. Michaelis de Vasconcellos, and R. Bratschitsch, “Photoluminescence emission and Raman response of monolayer MoS₂, MoSe₂, and WSe₂,” Opt. Express 21(4), 4908–4916 (2013).
    [Crossref] [PubMed]
  23. H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
    [Crossref]
  24. H. Zhang, S. Virally, Q. Bao, L. K. Ping, S. Massar, N. Godbout, and P. Kockaert, “Z-scan measurement of the nonlinear refractive index of graphene,” Opt. Lett. 37(11), 1856–1858 (2012).
    [Crossref] [PubMed]
  25. R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
    [Crossref]
  26. K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006).
    [Crossref] [PubMed]
  27. J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
    [Crossref]
  28. E. Garmire, “Resonant optical nonlinearities in semiconductors,” IEEE J. Sel. Top. Quantum Electron. 6(6), 1094–1110 (2000).
    [Crossref]
  29. P. Grelu and N. Akhmediev, “Dissipative solitons for mode-locked lasers,” Nat. Photonics 6(2), 84–92 (2012).
    [Crossref]
  30. K. Kieu and F. W. Wise, “All-fiber normal-dispersion femtosecond laser,” Opt. Express 16(15), 11453–11458 (2008).
    [Crossref] [PubMed]
  31. H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
    [Crossref]
  32. G. Sobon, J. Sotor, J. Jagiello, R. Kozinski, Ma. Zdrojek, M. Holdynski, P. Paletko, J. Boguslawski, L. Lipinska, and K. M. Abramski, “Graphene oxide vs. reduced graphene oxide as saturable absorbers for Er-doped passively mode-locked fibre laser,” Opt. Express 20(17), 19463–19473 (2012).
  33. A. Martinez, K. Fuse, B. Xu, and S. Yamashita, “Optical deposition of graphene and carbon nanotubes in a fiber ferrule for passive mode-locked lasing,” Opt. Express 18(22), 23054–23061 (2010).
    [Crossref] [PubMed]
  34. P. L. Huang, S. C. Lin, C. Y. Yeh, H. H. Kuo, S. H. Huang, G. R. Lin, L. J. Li, C. Y. Su, and W. H. Cheng, “Stable mode-locked fiber laser based on CVD fabricated graphene saturable absorber,” Opt. Express 20(3), 2460–2465 (2012).
    [Crossref] [PubMed]

2014 (2)

F. Bonaccorso and Z. Sun, “Solution processing of graphene, topological insulators and other 2d crystals for ultrafast photonics,” Opt. Mater. Express 4(1), 63–78 (2014).
[Crossref]

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
[Crossref] [PubMed]

2013 (5)

M. S. Xu, T. Liang, M. Shi, and H. Z. Chen, “Graphene-like two-dimensional materials,” Chem. Rev. 113(5), 3766–3798 (2013).
[Crossref] [PubMed]

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
[Crossref] [PubMed]

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

A. Carvalho, R. M. Ribeiro, and A. H. Castro Neto, “Band nesting and the optical response of two-dimensional semiconducting transition metal dichalcogenides,” Phys. Rev. B 88(11), 115205 (2013).
[Crossref]

P. Tonndorf, R. Schmidt, P. Böttger, X. Zhang, J. Börner, A. Liebig, M. Albrecht, C. Kloc, O. Gordan, D. R. T. Zahn, S. Michaelis de Vasconcellos, and R. Bratschitsch, “Photoluminescence emission and Raman response of monolayer MoS₂, MoSe₂, and WSe₂,” Opt. Express 21(4), 4908–4916 (2013).
[Crossref] [PubMed]

2012 (9)

H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
[Crossref]

H. Zhang, S. Virally, Q. Bao, L. K. Ping, S. Massar, N. Godbout, and P. Kockaert, “Z-scan measurement of the nonlinear refractive index of graphene,” Opt. Lett. 37(11), 1856–1858 (2012).
[Crossref] [PubMed]

P. Grelu and N. Akhmediev, “Dissipative solitons for mode-locked lasers,” Nat. Photonics 6(2), 84–92 (2012).
[Crossref]

G. Sobon, J. Sotor, J. Jagiello, R. Kozinski, Ma. Zdrojek, M. Holdynski, P. Paletko, J. Boguslawski, L. Lipinska, and K. M. Abramski, “Graphene oxide vs. reduced graphene oxide as saturable absorbers for Er-doped passively mode-locked fibre laser,” Opt. Express 20(17), 19463–19473 (2012).

P. L. Huang, S. C. Lin, C. Y. Yeh, H. H. Kuo, S. H. Huang, G. R. Lin, L. J. Li, C. Y. Su, and W. H. Cheng, “Stable mode-locked fiber laser based on CVD fabricated graphene saturable absorber,” Opt. Express 20(3), 2460–2465 (2012).
[Crossref] [PubMed]

Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
[Crossref] [PubMed]

C. Ataca, H. Şahin, and S. Ciraci, “Stable, single-layer MX2 transition-metal oxides and dichalcogenides in a honeycomb-like structure,” J. Phys. Chem. C 116(16), 8983–8999 (2012).
[Crossref]

S. Yamashita, “A tutorial on nonlinear photonic applications of carbon nanotube and graphene,” J. Lightwave Technol. 30(4), 427–447 (2012).
[Crossref]

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
[Crossref]

2011 (2)

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

A. H. Castro Neto and K. Novoselov, “Two dimensional crystals: beyond graphene,” Mater. Express 1(1), 10–17 (2011).
[Crossref]

2010 (7)

K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
[Crossref] [PubMed]

Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
[Crossref] [PubMed]

Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
[Crossref]

A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
[Crossref] [PubMed]

H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
[Crossref]

A. Martinez, K. Fuse, B. Xu, and S. Yamashita, “Optical deposition of graphene and carbon nanotubes in a fiber ferrule for passive mode-locked lasing,” Opt. Express 18(22), 23054–23061 (2010).
[Crossref] [PubMed]

F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
[Crossref]

2009 (4)

J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
[Crossref]

Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
[Crossref]

H. Zhang, D. Y. Tang, L. M. Zhao, Q. L. Bao, and K. P. Loh, “Large energy mode locking of an erbium-doped fiber laser with atomic layer graphene,” Opt. Express 17(20), 17630–17635 (2009).
[Crossref] [PubMed]

A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
[Crossref]

2008 (1)

2006 (1)

K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006).
[Crossref] [PubMed]

2004 (2)

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
[Crossref]

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
[Crossref] [PubMed]

2000 (1)

E. Garmire, “Resonant optical nonlinearities in semiconductors,” IEEE J. Sel. Top. Quantum Electron. 6(6), 1094–1110 (2000).
[Crossref]

Abramski, K. M.

Akhmediev, N.

P. Grelu and N. Akhmediev, “Dissipative solitons for mode-locked lasers,” Nat. Photonics 6(2), 84–92 (2012).
[Crossref]

Albrecht, M.

Arora, S. K.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Ataca, C.

C. Ataca, H. Şahin, and S. Ciraci, “Stable, single-layer MX2 transition-metal oxides and dichalcogenides in a honeycomb-like structure,” J. Phys. Chem. C 116(16), 8983–8999 (2012).
[Crossref]

Baba, M.

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
[Crossref]

Bae, M.

Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
[Crossref]

Baillargeat, D.

H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
[Crossref]

Bao, Q.

H. Zhang, S. Virally, Q. Bao, L. K. Ping, S. Massar, N. Godbout, and P. Kockaert, “Z-scan measurement of the nonlinear refractive index of graphene,” Opt. Lett. 37(11), 1856–1858 (2012).
[Crossref] [PubMed]

H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
[Crossref]

Bao, Q. L.

H. Zhang, D. Y. Tang, L. M. Zhao, Q. L. Bao, and K. P. Loh, “Large energy mode locking of an erbium-doped fiber laser with atomic layer graphene,” Opt. Express 17(20), 17630–17635 (2009).
[Crossref] [PubMed]

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Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
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Belle, B. D.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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Bergin, S. D.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Blau, W. J.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
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Boguslawski, J.

Boland, J. J.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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F. Bonaccorso and Z. Sun, “Solution processing of graphene, topological insulators and other 2d crystals for ultrafast photonics,” Opt. Mater. Express 4(1), 63–78 (2014).
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Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
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F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
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Börner, J.

Böttger, P.

Bratschitsch, R.

Britnell, L.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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A. Carvalho, R. M. Ribeiro, and A. H. Castro Neto, “Band nesting and the optical response of two-dimensional semiconducting transition metal dichalcogenides,” Phys. Rev. B 88(11), 115205 (2013).
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L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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Castro Neto, A. H.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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A. Carvalho, R. M. Ribeiro, and A. H. Castro Neto, “Band nesting and the optical response of two-dimensional semiconducting transition metal dichalcogenides,” Phys. Rev. B 88(11), 115205 (2013).
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A. H. Castro Neto and K. Novoselov, “Two dimensional crystals: beyond graphene,” Mater. Express 1(1), 10–17 (2011).
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A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
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Chen, H. Z.

M. S. Xu, T. Liang, M. Shi, and H. Z. Chen, “Graphene-like two-dimensional materials,” Chem. Rev. 113(5), 3766–3798 (2013).
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Chen, W. Z.

K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006).
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Cheng, W. H.

Chim, C. Y.

A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
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C. Ataca, H. Şahin, and S. Ciraci, “Stable, single-layer MX2 transition-metal oxides and dichalcogenides in a honeycomb-like structure,” J. Phys. Chem. C 116(16), 8983–8999 (2012).
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Coleman, J. N.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
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J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
[Crossref]

De, S.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Donegan, J. F.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Dong, S.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
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Dubonos, S. V.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
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Duesberg, G. S.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Eckmann, A.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
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Fan, J.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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Feng, Y.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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Ferrari, A. C.

F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
[Crossref]

Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
[Crossref] [PubMed]

Firsov, A. A.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
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Fox, D.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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Fuse, K.

Galli, G.

A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
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Ganeev, R. A.

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
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J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Geim, A. K.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
[Crossref]

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
[Crossref] [PubMed]

Georgiou, T.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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Godbout, N.

Gorbachev, R. V.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
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Gordan, O.

Grelu, P.

P. Grelu and N. Akhmediev, “Dissipative solitons for mode-locked lasers,” Nat. Photonics 6(2), 84–92 (2012).
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Grieveson, E. M.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Grigorenko, A. N.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

Grigorieva, I. V.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
[Crossref] [PubMed]

Grunlan, J. C.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Guinea, F.

A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
[Crossref]

Hallam, T.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Han, W.

Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
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Hao, G.

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
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Hasan, T.

Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
[Crossref] [PubMed]

F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
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K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
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Hernandez, Y.

J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
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Holdynski, M.

Hone, J.

K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
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Huang, P. L.

Huang, S. H.

Huang, Z.

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
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Ishizawa, N.

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
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Jagiello, J.

Jalil, R.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

Jang, S.

Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
[Crossref]

Jeong, H. Y.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
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Ji, W.

K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006).
[Crossref] [PubMed]

Jiang, B.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
[Crossref] [PubMed]

Jiang, D.

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
[Crossref] [PubMed]

Kalantar-Zadeh, K.

Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
[Crossref] [PubMed]

Khan, U.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Kieu, K.

Kim, G. T.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Kim, H. Y.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Kim, J.

A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
[Crossref] [PubMed]

Kim, Y.-J.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

King, P. J.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Kis, A.

Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
[Crossref] [PubMed]

Kloc, C.

Knize, R. J.

H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
[Crossref]

Kockaert, P.

Kozinski, R.

Kuo, H. H.

Kuroda, H.

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
[Crossref]

Lee, C.

K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
[Crossref] [PubMed]

Lee, K.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Li, H.

H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
[Crossref]

Li, J.

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
[Crossref]

Li, L. J.

Li, T.

A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
[Crossref] [PubMed]

Liang, T.

M. S. Xu, T. Liang, M. Shi, and H. Z. Chen, “Graphene-like two-dimensional materials,” Chem. Rev. 113(5), 3766–3798 (2013).
[Crossref] [PubMed]

Liebig, A.

Lin, G. R.

Lin, S. C.

Lipinska, L.

Liu, B.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
[Crossref] [PubMed]

Liu, Y.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
[Crossref] [PubMed]

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
[Crossref]

Loh, K. P.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
[Crossref] [PubMed]

H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
[Crossref]

H. Zhang, D. Y. Tang, L. M. Zhao, Q. L. Bao, and K. P. Loh, “Large energy mode locking of an erbium-doped fiber laser with atomic layer graphene,” Opt. Express 17(20), 17630–17635 (2009).
[Crossref] [PubMed]

Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
[Crossref]

K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006).
[Crossref] [PubMed]

Lotya, M.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
[Crossref] [PubMed]

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
[Crossref]

Mak, K. F.

K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
[Crossref] [PubMed]

Martinez, A.

Massar, S.

McComb, D. W.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Michaelis de Vasconcellos, S.

Mishchenko, A.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

Moriarty, G.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Morozov, S. V.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
[Crossref] [PubMed]

Nai, C. T.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
[Crossref] [PubMed]

Nellist, P. D.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Ni, Z.

Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
[Crossref]

Nicholls, R. J.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Nicolosi, V.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Novoselov, K.

A. H. Castro Neto and K. Novoselov, “Two dimensional crystals: beyond graphene,” Mater. Express 1(1), 10–17 (2011).
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Novoselov, K. S.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
[Crossref]

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
[Crossref] [PubMed]

O’Neill, A.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
[Crossref] [PubMed]

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Olivier, A.

H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
[Crossref]

Paletko, P.

Peres, N. M. R.

A. H. Castro Neto, F. Guinea, N. M. R. Peres, K. S. Novoselov, and A. K. Geim, “The electronic properties of graphene,” Rev. Mod. Phys. 81(1), 109–162 (2009).
[Crossref]

Perkins, J. M.

J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
[Crossref] [PubMed]

Ping, L. K.

Popa, D.

Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
[Crossref] [PubMed]

Privitera, G.

Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
[Crossref] [PubMed]

Qi, X.

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
[Crossref]

Ren, L.

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
[Crossref]

Ribeiro, R. M.

L. Britnell, R. M. Ribeiro, A. Eckmann, R. Jalil, B. D. Belle, A. Mishchenko, Y.-J. Kim, R. V. Gorbachev, T. Georgiou, S. V. Morozov, A. N. Grigorenko, A. K. Geim, C. Casiraghi, A. H. Castro Neto, and K. S. Novoselov, “Strong light-matter interactions in heterostructures of atomically thin films,” Science 340(6138), 1311–1314 (2013).
[Crossref] [PubMed]

A. Carvalho, R. M. Ribeiro, and A. H. Castro Neto, “Band nesting and the optical response of two-dimensional semiconducting transition metal dichalcogenides,” Phys. Rev. B 88(11), 115205 (2013).
[Crossref]

Ryasnyansky, A. I.

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
[Crossref]

Sahin, H.

C. Ataca, H. Şahin, and S. Ciraci, “Stable, single-layer MX2 transition-metal oxides and dichalcogenides in a honeycomb-like structure,” J. Phys. Chem. C 116(16), 8983–8999 (2012).
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Sakakibara, S.

R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
[Crossref]

Schmidt, R.

Shan, J.

K. F. Mak, C. Lee, J. Hone, J. Shan, and T. F. Heinz, “Atomically thin MoS₂: a new direct-gap semiconductor,” Phys. Rev. Lett. 105(13), 136805 (2010).
[Crossref] [PubMed]

Shen, Z. X.

Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
[Crossref]

Shi, M.

M. S. Xu, T. Liang, M. Shi, and H. Z. Chen, “Graphene-like two-dimensional materials,” Chem. Rev. 113(5), 3766–3798 (2013).
[Crossref] [PubMed]

Shin, H. S.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
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Shmeliov, A.

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J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
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J. N. Coleman, M. Lotya, A. O’Neill, S. D. Bergin, P. J. King, U. Khan, K. Young, A. Gaucher, S. De, R. J. Smith, I. V. Shvets, S. K. Arora, G. Stanton, H. Y. Kim, K. Lee, G. T. Kim, G. S. Duesberg, T. Hallam, J. J. Boland, J. J. Wang, J. F. Donegan, J. C. Grunlan, G. Moriarty, A. Shmeliov, R. J. Nicholls, J. M. Perkins, E. M. Grieveson, K. Theuwissen, D. W. McComb, P. D. Nellist, and V. Nicolosi, “Two-dimensional nanosheets produced by liquid exfoliation of layered materials,” Science 331(6017), 568–571 (2011).
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A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
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F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
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R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
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H. Zhang, D. Y. Tang, L. M. Zhao, Q. L. Bao, and K. P. Loh, “Large energy mode locking of an erbium-doped fiber laser with atomic layer graphene,” Opt. Express 17(20), 17630–17635 (2009).
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Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
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H. Zhang, D. Y. Tang, L. M. Zhao, Q. L. Bao, and K. P. Loh, “Large energy mode locking of an erbium-doped fiber laser with atomic layer graphene,” Opt. Express 17(20), 17630–17635 (2009).
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Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
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H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
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Zhang, Y.

A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
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H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
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Zhao, Q.

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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Zheng, J.

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
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Zhong, J.

L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
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L. Ren, X. Qi, Y. Liu, G. Hao, Z. Huang, X. Zou, L. Yang, J. Li, and J. Zhong, “Large-scale production of ultrathin topological insulator bismuth telluride nanosheets by a hydrothermal intercalation and exfoliation route,” J. Mater. Chem. 22(11), 4921–4926 (2012).
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ACS Nano (2)

K. Wang, J. Wang, J. Fan, M. Lotya, A. O’Neill, D. Fox, Y. Feng, X. Zhang, B. Jiang, Q. Zhao, H. Zhang, J. N. Coleman, L. Zhang, and W. J. Blau, “Ultrafast saturable absorption of two-dimensional MoS2 nanosheets,” ACS Nano 7(10), 9260–9267 (2013).
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Z. Sun, T. Hasan, F. Torrisi, D. Popa, G. Privitera, F. Wang, F. Bonaccorso, D. M. Basko, and A. C. Ferrari, “Graphene mode-locked ultrafast laser,” ACS Nano 4(2), 803–810 (2010).
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Adv. Funct. Mater. (2)

Q. L. Bao, H. Zhang, Y. Wang, Z. Ni, Y. Yan, Z. X. Shen, K. P. Loh, and D. Y. Tang, “Atomic-layer graphene as a saturable absorber for ultrafast pulsed lasers,” Adv. Funct. Mater. 19(19), 3077–3083 (2009).
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H. Li, Q. Zhang, C. C. R. Yap, B. K. Tay, T. H. T. Edwin, A. Olivier, and D. Baillargeat, “From bulk to monolayer MoS2: evolution of Raman scattering,” Adv. Funct. Mater. 22(7), 1385–1390 (2012).
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Adv. Mater. (1)

J. Wang, Y. Hernandez, M. Lotya, J. N. Coleman, and W. J. Blau, “Broadband nonlinear optical response of graphene dispersions,” Adv. Mater. 21(23), 2430–2435 (2009).
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Appl. Phys. Lett. (2)

H. Zhang, D. Tang, R. J. Knize, L. Zhao, Q. Bao, and K. P. Loh, “Graphene mode-locked, wavelength-tunable, dissipative soliton fibre laser,” Appl. Phys. Lett. 96(11), 111112 (2010).
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Y. Song, S. Jang, W. Han, and M. Bae, “Graphene mode-lockers for fiber lasers functioned with evanescent field interaction,” Appl. Phys. Lett. 96(5), 051122 (2010).
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Chem. Rev. (1)

M. S. Xu, T. Liang, M. Shi, and H. Z. Chen, “Graphene-like two-dimensional materials,” Chem. Rev. 113(5), 3766–3798 (2013).
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J. Phys. Chem. B (1)

K. P. Loh, H. Zhang, W. Z. Chen, and W. Ji, “Templated deposition of MoS2 nanotubules using single source precursor and studies of their optical limiting properties,” J. Phys. Chem. B 110(3), 1235–1239 (2006).
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A. Splendiani, L. Sun, Y. Zhang, T. Li, J. Kim, C. Y. Chim, G. Galli, and F. Wang, “Emerging photoluminescence in monolayer MoS2.,” Nano Lett. 10(4), 1271–1275 (2010).
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Nat. Commun. (1)

J. Zheng, H. Zhang, S. Dong, Y. Liu, C. T. Nai, H. S. Shin, H. Y. Jeong, B. Liu, and K. P. Loh, “High yield exfoliation of two-dimensional chalcogenides using sodium naphthalenide,” Nat. Commun. 5, 2995 (2014).
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Nat. Nanotechnol. (1)

Q. H. Wang, K. Kalantar-Zadeh, A. Kis, J. N. Coleman, and M. S. Strano, “Electronics and optoelectronics of two-dimensional transition metal dichalcogenides,” Nat. Nanotechnol. 7(11), 699–712 (2012).
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Nat. Photonics (2)

F. Bonaccorso, Z. Sun, T. Hasan, and A. C. Ferrari, “Graphene photonics and optoelectronics,” Nat. Photonics 4(9), 611–622 (2010).
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R. A. Ganeev, A. I. Ryasnyansky, N. Ishizawa, M. Baba, M. Suzuki, M. Turu, S. Sakakibara, and H. Kuroda, “Two- and three-photon absorption in CS2,” Opt. Commun. 231(1–6), 431–436 (2004).
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Opt. Mater. Express (1)

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Science (3)

K. S. Novoselov, A. K. Geim, S. V. Morozov, D. Jiang, Y. Zhang, S. V. Dubonos, I. V. Grigorieva, and A. A. Firsov, “Electric field effect in atomically thin carbon films,” Science 306(5696), 666–669 (2004).
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[Crossref] [PubMed]

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Figures (10)

Fig. 1
Fig. 1 Schematic diagram of the formation of MoS2 NPs.
Fig. 2
Fig. 2 Characterisation of MoS2 NPs for Z-scan measurement. (a) Scanning electron microscopy image, (b) XRD diffraction pattern, (c) Atomic force microscopy image and (d) UV-Vis spectra of as-grown MoS2 NPs.
Fig. 3
Fig. 3 Raman spectra of the bulk and the exfoliated MoS2
Fig. 4
Fig. 4 Schematic diagram of the Z-scan experimental setup.
Fig. 5
Fig. 5 The open-aperture Z-scan measurements of MoS2 dispersions in a 1-mm cuvette at (a) 400 nm and (b) 800 nm with different input fluences.
Fig. 6
Fig. 6 (a) Schematic diagram of twin-detector measurement; (b) and (c) show the nonlinear transmittance and scattering power, respectively, of MoS2 dispersions under different input fluences at 800 nm.
Fig. 7
Fig. 7 (a) The open-aperture Z-scan measurement of MoS2 NPs on quartz at different input influences at 800 nm; (b) the relation between normalized transmittance and input intensity.
Fig. 8
Fig. 8 (a) The open-aperture Z-scan measurement of MoS2 NPs on quartz at different input intensities at 1064 nm. (b) and (c) The twin-detector measurement of the film sample at 1064 nm: the incident power is increased (with respect to decreased) from low (with respect to high) to high (with respect to low) intensity.
Fig. 9
Fig. 9 Schematic of the ytterbium-doped ðbre laser passively mode locked by the MoS2 saturable absorber. WDM (wavelength division multiplexer), YDF (ytterbium-doped fibre), PC (polarisation controller), PI-ISO (polarisation-independent isolator), SMF (single-mode fibre) and MoS2-saturable absorber.
Fig. 10
Fig. 10 The laser mode-locking performance by the MoS2 saturable absorber: (a) the SA response fibre-pigtailed MoS2 saturable absorber; (b) & (c) the oscilloscope tracings; (d) the optical spectrum; (e) the radiofrequency spectral profile; (f) wideband RF spectrum.

Equations (4)

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α(I)= α 0 1+I/ I s +βI
T=(1 α 0 L 1+I/ I s βIL)/(1 α 0 L)
I(z)= I 0 (1+ z 2 / z 0 2 ) .
T=[ 1 α 0 L I s I s + I 0 /(1+ z 2 / z 0 2 ) βL I 0 /(1+ z 2 / z 0 2 ) ]/(1 α 0 L).

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