Abstract

We describe both theoretically and experimentally the existence and excitation of confined modes in planar arrays of gold nanodisks. Ordered 2D lattices of monodispersive nanoparticles are manufactured, embedded in a silica matrix, and exposed to evanescent prism-coupling illumination, leading to dark features in the reflectivity, which signal the presence of confined modes guided along the arrays. We find remarkable agreement between theory and experiment in the frequency-momentum dispersion of the resonances. Direct excitation of these modes reveals long propagation distances and deep extinction features. This combined experimental and theoretical characterization of guided modes shows a good understanding of the optical response of metallic particles arrays, which can be beneficial in future designs of optical-signal and distant-sensing applications.

© 2012 OSA

Metal nanoparticles are capable of producing high levels of confinement and enhancement of incident light [1]. These appealing properties make them useful for sensing (e.g., through detection of plasmon-resonance shifts [26] and surface-enhanced Raman scattering [711]), cancer therapy [12, 13], drug delivery [14], improved photovoltaics [15, 16], and catalysis [17, 18]. These applications have attracted a considerable degree of interest on the optical properties of nanoparticles, which strongly depend on size, morphology, and composition [1921]. The interaction between neighboring particles can also produce changes in their optical behavior, which are dramatic when small particle gaps are involved [2224]. Additionally, long-range interactions lead to collective modes in ordered [25, 26] and disordered [27] particle arrangements, which have been proposed for waveguiding in both 1D [28, 29] and 2D [25, 30] configurations.

In particular, lattice resonances in 2D ordered particle arrays act as an effective way of creating guided modes [31] that are strongly dependent on the choice of materials, particle size and shape, and lattice parameters, leading to distinct TE and TM modes [25, 32]. This configures a versatile platform for applications to distant sensing and waveguiding, which deserve a detailed characterization of the arrays. Direct far-field sampling of quasi-bounded modes in 2D arrays through diffracted orders have been extensively reported [3338]. Additionally, theoretical descriptions are available [39], which become particularly intuitive when assuming dipole inter-particle interactions [25, 31]. However, guided modes in metal particle arrays have not been yet directly sampled (i.e., sampled without the assistance of diffraction to couple to far-field radiation), and a detailed experimental study of their optical behavior is still missing.

In this Letter, we report direct observation of guided modes in ordered gold-particle arrays through dips in their evanescent-field reflection using the Otto configuration [40, 41]. Gold nanodisks have been fabricated by imprint lithography [42] and embedded in a symmetric silica environment [Fig. 1(a,b)]. A high-index prism is then used for evanescent coupling of incident light [Fig. 1(c)]. The reflected signal unambiguously shows the presence of guided modes. We further report electromagnetic simulations for both the guided-mode dispersion relations and the reflectivity under prism illumination. Experiment and theory are in excellent agreement for the dispersion relations and the mode propagation distances. Our results bear some resemblance to guided modes in photonic crystal waveguides [4345] and electromagnetic surface waves in drilled metal films [46].

 

Fig. 1 Images and scheme of the system under consideration. (a) and (b) SEM images of our nanoimprinted arrays. The gold nanodisks are arranged in a square lattice with parameter a = 300nm. The height of the disks is h = 50nm and the diameter is D = 200nm in (a) and D = 250nm in (b). (c) An array of golden disks is embedded in a homogeneous SiO2 environment (refraction index nSiO2 = 1.46) at a distance d = 600nm from a prism interface. This is the Otto configuration, whereby light undergoes total internal reflection inside the prism (nF2 = 1.67) with incident angle θi and parallel wave vector k outside the light cone. Light couples evanescently to the confined modes of the array, thus producing a measurable attenuated total reflection.

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The array modes under study originate in the lattice resonances produced by long-range interaction between the particles close to the onset of different diffraction orders [25]. Under such conditions, there is constructive interference of the fields scattered by the particles, leading to array-confined modes, which are in fact guided modes that propagate along the plane of the array. These modes are intrinsic to the lattice and exist even for non-resonant dielectric particles, as shown in Ref. [25], and show up at frequencies to the red with respect to the light line in a frequency-wavevector diagram [31]. In Fig. 2(a) we show the calculated reflection coefficient of arrays of gold nanodisks placed in a symmetric SiO2 environment. The dispersion diagram is dominated by two types of features: a prominent one arising from the noted lattice resonances; and a weaker one associated with the excitation of localized surface plasmons that are confined at the gaps between neighboring nanoparticles [23] (see below). The reflection coefficient is peaked along a line close to the light cone (solid line), indicating the position of the dispersion relation of the lattice modes. For reference, we also show in the diagram the umklapp folding of the light cone (dashed line), which crosses the light cone at the boundary of the first Brillouin zone (BZ). While the lattice resonance within the first BZ is both too narrow and close to the light line to be resolved in Fig. 2, it is clearly visible withing the second BZ.

 

Fig. 2 Simulations of confined modes in a square array of SiO2-embedded gold nanodisks of D = 200nm in diameter. (a) Dispersion diagram showing the light energy and wave-vector dependence of the array reflection coefficient (color scale). Guided modes show up as bright features. The light cone (solid line) and its first Bragg-reflection (dashed line) are plotted for reference. (b) Electric-field intensity maps over a region of 4 unit cells at a distance D/2 above the array for characteristic points within the dispersion diagram, as shown by labels A–D in both (a) and (b). The nanoparticle contours are represented by a dashed circle. Dipolar patterns are visible when confined modes are excited (A and B), leading to large field enhancement (see color scale). In contrast, lower field enhancement is associated with non-resonant reflection (C and D), although hotspots can localize between particle gaps (see D), leading to an almost dispersionless feature in (a).

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The intensity of the electric field, which is represented in Fig. 2(b) for a unit cell at a distance D/2 from the middle plane of the lattice, clearly shows the collective character of the resonance. Along the dispersion relation of the propagating mode, such at positions A and B, we have large values of the field enhancement spreading all over the plane, with relatively small spatial variations. We also represent the field at the weaker, relatively flat spectral feature below the resonance at point C. Clearly, the latter shows strong localization at the particle gaps, which is consistent with an interpretation in terms of localized gap plasmons between neighboring nanoparticles and explains the observed vanishing group velocity. Under non-resonant incidence conditions (i.e., away from the propagating mode and localized plasmon regions), the enhancement is featureless and weak, as shown for point D.

Arrays embedded in a symmetric environment thus display sharp resonances that can be easily modeled theoretically, but their fabrication and characterization is difficult compared to arrays supported on a substrate. A high degree of asymmetry is known to strongly modify and even prevent the existence of the lattice resonances [25, 39]. In order to reach a compromise between these two extreme situations, we have fabricated gold nanodisk arrays on a SiO2 substrate and added a dielectric capping of the same material [Fig. 1(a)]. This capping of thickness d = 600nm not only ensures the existence of the resonant modes, but also provides protection for the nanostructure in potential device applications.

We have measured the reflectivity spectra of these samples in a rotation stage using a coupling prism of F2 glass. The sample was illuminated with a polarized white laser source (Fyanium) and specular reflection was collected using a computer controlled rotation stage that allows rotating the sample and the fiber-coupled spectrometer independently. When light is reflected at the prism-sample interface under total-internal reflection conditions, it produces an evanescent field that,for values of the parallel momentum matching those of the guided modes, is coupled into the latter. This coupling transfers energy that is dissipated due to losses in the metallic nanoparticles, therefore producing a dip in the reflection spectrum, which is a signature of the excitation of a surface mode [40].

The spectral dependence of this dip can be clearly resolved in Fig. 3, where it shows up to the right of the critical angle (θc ≈ 64). The agreement between theory [Fig. 3(c,d)] and experiment [Fig. 3(a,b)] is excellent in position, intensity, and width of the spectral features for samples with two different particle diameters [D = 200nm in Fig. 3(a,c) and D = 250nm in Fig. 3(b,d)]. Some discrepancies are observed in the features at the left end of the angular region under investigation, which we attribute to systematic errors in the characterization setup, which is optimized for data collection to the right of the critical angle. As expected from the calculations of Fig. 2 for a symmetric environment, the resonance appears close to the light line and nearly parallel to it, specially for the smallest particles. Incidentally, almost perfect coupling takes place, with the reflectance reaching values close to zero.

 

Fig. 3 Experimental (a,b) and theoretical (c,d) energy-angle-dependent reflectance of the combined array-prism system [Fig. 1(a)] for nanodisks of diameter D = 200nm (a,c) and D = 250nm (b,d). The excitation of a guided mode is revealed by a dark (low reflectance) feature at the right of the critical angle (θi ≈ 64deg).

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A more detailed characterization of the modes is presented in Fig. 4. Panel (a) shows excellent agreement between the theoretical (dashed curves) and experimental (solid curves) dispersion relations for both particle sizes. The degree of confinement, indicated by the separation from the light (dotted) line in Fig. 4(a) and also by the penetration of the field intensity outside the array in Fig. 4(b), is also in excellent agreement. Notice that this penetration distance [37] is comparable to the separation of 600 nm between the prism and the particles, but the modes are still well defined and clearly resolvable.

 

Fig. 4 Experiment-theory comparison of the dispersion relation (a), the penetration length outside the array (Lz) (b), and the propagation distance (Lx) (c) for the guided modes. The values shown in this plot are obtained from Lorentzian functions fitted to the dips shown in Fig. 3. From the position of the peak we calculate both the dispersion relation and the penetration length, while the width is related to the propagation length. Theory: dashed curves. Experiment: solid curves, obtained from constant-energy Lorentzian fits of the reflection dip in Fig. 3 [the inset in (a) shows a characteristic example of the Lorentzian fit for the energy 1,74eV signaled with crosses in the main plot]. Black (gray) curves correspond to disks of diameter D = 200nm (D = 250nm).

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Finally, we have calculated the propagation distance along the plane of the array [Fig. 4(c)] by fitting the reflectance dips to Lorentzians [see insets in Fig. 4(a)]. Theory predicts larger propagation length than what is observed in the experiment, and we attribute this discrepancy to imperfections in the shape and position of the particles. Fabrication defects are not so important when observing the dispersion relation, but the propagation distance is strongly influenced by radiative scattering of the mode, which is observed as an increase of attenuation associated with propagation. Actually, the discrepancy between theory and experiment is less pronounced for the largest particles under consideration (gray curves), for which variations in morphology with the same degree of absolute tolerance are relatively smaller. Propagation distances of a few microns (∼ 10 surface-mode wavelengths) are obtained.

In conclusion, we have experimentally demonstrated the existence of confined propagating modes in planar arrays of plasmonic nanoparticles, and we have determined their dispersion relation and characteristic lengths. Our electromagnetic simulations are in excellent agreement with the experiments. These results should trigger further research into the direct spatial mapping of guided modes. Our particle arrays can be potentially used to propagate optical signals. They can also assist distant sensing, whereby the optical signal from the object or substance to be sensed propagates through an array to the position at which the detector is placed. This possibility provides a natural hybrid between plasmon-based sensors and nanoparticle-based waveguiding.

In conclusion, we have experimentally demonstrated the existence of confined propagating modes in planar arrays of plasmonic nanoparticles, and we have determined their dispersion relation and characteristic lengths. Our electromagnetic simulations are in excellent agreement with the experiments. These results should be useful in the design of potential applications to signal processing through metallic particle arrays. They can also assist distant sensing, whereby the optical signal from the object or substance to be sensed propagates through an array to the position at which the detector is placed, thus providing a natural hybrid between plasmon-based sensors and nanoparticle-based waveguiding. We hope that our study stimulates further research in this direction.

This work has been supported in part by the European Union ( NMP4-2006-016881-SPANS, NMP4-SL-2008-213669-ENSEMBLE, FP7-ICT-2009-4-248909-LIMA, and FP7-ICT-2009-4-248855-N4E), the Spanish MEC ( MAT2010-14885 and Consolider Nano-Light.es), and the research program of the Foundation for Fundamental Research on Matter (FOM), which is financially supported by the Netherlands Organization for Fundamental Research (NWO) and is part of an industrial partnership program between Philips and FOM. It is also supported in part by NanoNextNL, a micro and nanotechnology consortium of the Government of the Netherlands and 130 partners. X.M.B. acknowledges a Spanish CSIC-JAE grant.

References and links

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References

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  1. K. R. Li, M. I. Stockman, and D. J. Bergman, “Self-similar chain of metal nanospheres as an efficient nanolens,” Phys. Rev. Lett.91, 227402 (2003).
    [CrossRef] [PubMed]
  2. A. McFarland and R. Van Duyne, “Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity,” Nano Lett.3, 1057–1062 (2003).
    [CrossRef]
  3. A. B. Dahlin, J. O. Tegenfeldt, and F. Höök, “Improving the instrumental resolution of sensors based on localized surface plasmon resonance,” An. Chem.78, 4416–4423 (2006).
    [CrossRef]
  4. K.-S. Lee and M. A. El-Sayed, “Gold and silver nanoparticles in sensing and imaging: Sensitivity of plasmon response to size, shape, and metal composition,” J. Phys. Chem. B110, 19220–19225 (2006).
    [CrossRef] [PubMed]
  5. M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev.108, 494–521 (2008).
    [CrossRef] [PubMed]
  6. J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
    [CrossRef] [PubMed]
  7. S. Nie and S. R. Emory, “Probing single molecules and single nanoparticles by surface-enhanced raman scattering,” Science275, 1102–1106 (1997).
    [CrossRef] [PubMed]
  8. K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett.78, 1667–1670 (1997).
    [CrossRef]
  9. P. Johansson, H. Xu, and M. Käll, “Surface-enhanced raman scattering and fluorescence near metal nanoparticles,” Phys. Rev. B72, 035427 (2005).
    [CrossRef]
  10. C. E. Talley, J. B. Jackson, C. Oubre, N. K. Grady, C. W. Hollars, S. M. Lane, T. R. Huser, P. Nordlander, and N. J. Halas, “Surface-enhanced Raman scattering from individual au nanoparticles and nanoparticle dimer substrates,” Nano Lett.5, 1569–1574 (2005).
    [CrossRef] [PubMed]
  11. L. Rodríguez-Lorenzo, R. A. Álvarez-Puebla, I. Pastoriza-Santos, S. Mazzucco, O. Stéphan, M. Kociak, L. M. Liz-Marzán, and F. J. García de Abajo, “Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering,” J. Am. Chem. Soc.131, 4616–4618 (2009).
    [CrossRef] [PubMed]
  12. X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
    [CrossRef]
  13. L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
    [CrossRef] [PubMed]
  14. Y. L. Luo, Y. S. Shiao, and Y. F. Huang, “Release of photoactivatable drugs from plasmonic nanoparticles for targeted cancer therapy,” ACS Nano5, 7796–7804 (2011).
    [CrossRef] [PubMed]
  15. K. R. Catchpole and A. Polman, “Plasmonic solar cells,” Opt. Express16, 21793–21800 (2008).
    [CrossRef] [PubMed]
  16. H. A. Atwater and A. Polman, “Plasmonics for improved photovoltaic devices,” Nat. Mater.9, 205–213 (2010).
    [CrossRef] [PubMed]
  17. R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science293, 269–271 (2001).
    [CrossRef] [PubMed]
  18. P. V. Kamat, “Photophysical, photochemical and photocatalytic aspects of metal nanoparticles,” J. Phys. Chem. B106, 7729–7744 (2002).
    [CrossRef]
  19. J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
    [CrossRef]
  20. K. L. Kelly, E. Coronado, L. L. Zhao, and G. C. Schatz, “The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment,” J. Phys. Chem. B107, 668–677 (2003).
    [CrossRef]
  21. V. Myroshnychenko, J. Rodríguez-Fernández, I. Pastoriza-Santos, A. M. Funston, C. Novo, P. Mulvaney, L. M. Liz-Marzán, and F. J. García de Abajo, “Modelling the optical response of gold nanoparticles,” Chem. Soc. Rev.37, 1792–1805 (2008).
    [CrossRef] [PubMed]
  22. P. E. Batson, “A new surface plasmon resonance in clusters of small aluminum spheres,” Ultramicroscopy9, 277–282 (1982).
    [CrossRef]
  23. P. Nordlander, C. Oubre, E. Prodan, K. Li, and M. I. Stockman, “Plasmon hybridizaton in nanoparticle dimers,” Nano Lett.4, 899–903 (2004).
    [CrossRef]
  24. I. Romero, J. Aizpurua, G. W. Bryant, and F. J. García de Abajo, “Plasmons in nearly touching metallic nanoparticles: Singular response in the limit of touching dimers,” Opt. Express14, 9988–9999 (2006).
    [CrossRef] [PubMed]
  25. X. M. Bendaña and F. J. García de Abajo, “Confined collective excitations of self-standing and supported planar periodic particle arrays,” Opt. Express17, 18826–18835 (2009).
    [CrossRef]
  26. D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
    [CrossRef] [PubMed]
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2011 (3)

Y. L. Luo, Y. S. Shiao, and Y. F. Huang, “Release of photoactivatable drugs from plasmonic nanoparticles for targeted cancer therapy,” ACS Nano5, 7796–7804 (2011).
[CrossRef] [PubMed]

M. A. Otte, M. C. Estevez, D. Regatos, L. M. Lechuga, and B. Sepulveda, “Guiding light in monolayers of sparse and random plasmonic meta-atoms,” ACS NANO5, 9179–9186 (2011).
[CrossRef] [PubMed]

W. Zhou and T. W. Odom, “Tunable subradiant lattice plasmons by out-of-plane dipolar interactions,” Nat. Nanotech.6, 423–427 (2011).
[CrossRef]

2010 (3)

B. Auguié, X. M. Bendaña, W. L. Barnes, and F. J. García de Abajo, “Diffractive arrays of gold nanoparticles near an interface: Critical role of the substrate,” Phys. Rev. B82, 155447 (2010).
[CrossRef]

D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
[CrossRef] [PubMed]

H. A. Atwater and A. Polman, “Plasmonics for improved photovoltaic devices,” Nat. Mater.9, 205–213 (2010).
[CrossRef] [PubMed]

2009 (4)

L. Rodríguez-Lorenzo, R. A. Álvarez-Puebla, I. Pastoriza-Santos, S. Mazzucco, O. Stéphan, M. Kociak, L. M. Liz-Marzán, and F. J. García de Abajo, “Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering,” J. Am. Chem. Soc.131, 4616–4618 (2009).
[CrossRef] [PubMed]

X. M. Bendaña and F. J. García de Abajo, “Confined collective excitations of self-standing and supported planar periodic particle arrays,” Opt. Express17, 18826–18835 (2009).
[CrossRef]

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Shaping the fluorescent emission by lattice resonances in plasmonic crystals of nanoantennas,” Phys. Rev. Lett.102, 146807 (2009).
[CrossRef] [PubMed]

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Surface modes in plasmonic crystals induced by diffractive coupling of nanoantennas,” Phys. Rev. B80, 201401 (2009).
[CrossRef]

2008 (9)

V. Myroshnychenko, J. Rodríguez-Fernández, I. Pastoriza-Santos, A. M. Funston, C. Novo, P. Mulvaney, L. M. Liz-Marzán, and F. J. García de Abajo, “Modelling the optical response of gold nanoparticles,” Chem. Soc. Rev.37, 1792–1805 (2008).
[CrossRef] [PubMed]

R. Sainidou and F. J. García de Abajo, “Plasmon guided modes in nanoparticle metamaterials,” Opt. Express16, 4499–4506 (2008).
[CrossRef] [PubMed]

B. Auguié and W. L. Barnes, “Collective resonances in gold nanoparticle arrays,” Phys. Rev. Lett.101, 143902 (2008).
[CrossRef] [PubMed]

V. G. Kravets, F. Schedin, and A. N. Grigorenko, “Extremely narrow plasmon resonances based on diffraction coupling of localized plasmons in arrays of metallic nanoparticles,” Phys. Rev. Lett.101, 087403 (2008).
[CrossRef] [PubMed]

Y. Chu, E. Schonbrun, T. Yang, and K. B. Crozier, “Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays,” Appl. Phys. Lett.93, 181108 (2008).
[CrossRef]

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

K. R. Catchpole and A. Polman, “Plasmonic solar cells,” Opt. Express16, 21793–21800 (2008).
[CrossRef] [PubMed]

M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev.108, 494–521 (2008).
[CrossRef] [PubMed]

J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
[CrossRef] [PubMed]

2007 (2)

F. J. García de Abajo, “Colloquium: Light scattering by particle and hole arrays,” Rev. Mod. Phys.79, 1267–1290 (2007).
[CrossRef]

M. A. Verschuuren and H. A. van Sprang, “3d photonic structures by sol-gel imprint lithography,” Mater. Res. Soc. Symp. Proc.1002, 1002-N03-05 (2007).
[CrossRef]

2006 (3)

I. Romero, J. Aizpurua, G. W. Bryant, and F. J. García de Abajo, “Plasmons in nearly touching metallic nanoparticles: Singular response in the limit of touching dimers,” Opt. Express14, 9988–9999 (2006).
[CrossRef] [PubMed]

A. B. Dahlin, J. O. Tegenfeldt, and F. Höök, “Improving the instrumental resolution of sensors based on localized surface plasmon resonance,” An. Chem.78, 4416–4423 (2006).
[CrossRef]

K.-S. Lee and M. A. El-Sayed, “Gold and silver nanoparticles in sensing and imaging: Sensitivity of plasmon response to size, shape, and metal composition,” J. Phys. Chem. B110, 19220–19225 (2006).
[CrossRef] [PubMed]

2005 (2)

P. Johansson, H. Xu, and M. Käll, “Surface-enhanced raman scattering and fluorescence near metal nanoparticles,” Phys. Rev. B72, 035427 (2005).
[CrossRef]

C. E. Talley, J. B. Jackson, C. Oubre, N. K. Grady, C. W. Hollars, S. M. Lane, T. R. Huser, P. Nordlander, and N. J. Halas, “Surface-enhanced Raman scattering from individual au nanoparticles and nanoparticle dimer substrates,” Nano Lett.5, 1569–1574 (2005).
[CrossRef] [PubMed]

2004 (1)

P. Nordlander, C. Oubre, E. Prodan, K. Li, and M. I. Stockman, “Plasmon hybridizaton in nanoparticle dimers,” Nano Lett.4, 899–903 (2004).
[CrossRef]

2003 (5)

K. L. Kelly, E. Coronado, L. L. Zhao, and G. C. Schatz, “The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment,” J. Phys. Chem. B107, 668–677 (2003).
[CrossRef]

S. A. Maier, P. G. Kik, H. A. Atwater, S. Meltzer, E. Harel, B. E. Koel, and A. A. G. Requicha, “Local detection of electromagnetic energy transport below the diffraction limit in metal nanoparticle plasmon waveguides,” Nat. Mater.2, 229–232 (2003).
[CrossRef] [PubMed]

L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
[CrossRef] [PubMed]

K. R. Li, M. I. Stockman, and D. J. Bergman, “Self-similar chain of metal nanospheres as an efficient nanolens,” Phys. Rev. Lett.91, 227402 (2003).
[CrossRef] [PubMed]

A. McFarland and R. Van Duyne, “Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity,” Nano Lett.3, 1057–1062 (2003).
[CrossRef]

2002 (2)

P. V. Kamat, “Photophysical, photochemical and photocatalytic aspects of metal nanoparticles,” J. Phys. Chem. B106, 7729–7744 (2002).
[CrossRef]

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
[CrossRef]

2001 (1)

R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science293, 269–271 (2001).
[CrossRef] [PubMed]

1999 (1)

S. G. Johnson, S. Fan, P. R. Villeneuve, J. D. Joannopoulos, and L. A. Kolodziejski, “Guided modes in photonic crystal slabs,” Phys. Rev. B60, 5751–5758 (1999).
[CrossRef]

1998 (2)

S. Y. Lin, E. Chow, V. Hietala, P. R. Villeneuve, and J. D. Joannopoulos, “Experimental demonstration of guiding and bending of electromagnetic waves in a photonic crystal,” Science282, 274–276 (1998).
[CrossRef] [PubMed]

M. Quinten, A. Leitner, J. R. Krenn, and F. R. Aussenegg, “Electromagnetic energy transport via linear chains of silver nanoparticles,” Opt. Lett.23, 1331–1333 (1998).
[CrossRef]

1997 (3)

S. Nie and S. R. Emory, “Probing single molecules and single nanoparticles by surface-enhanced raman scattering,” Science275, 1102–1106 (1997).
[CrossRef] [PubMed]

K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett.78, 1667–1670 (1997).
[CrossRef]

J. D. Joannopoulos, P. R. Villeneuve, and S. H. Fan, “Photonic crystals: Putting a new twist on light,” Nature386, 143–149 (1997).
[CrossRef]

1982 (1)

P. E. Batson, “A new surface plasmon resonance in clusters of small aluminum spheres,” Ultramicroscopy9, 277–282 (1982).
[CrossRef]

1973 (1)

R. Ulrich and M. Tacke, “Submillimeter waveguiding on periodic metal structure,” Appl. Phys. Lett.22, 251–253 (1973).
[CrossRef]

1967 (1)

A. Otto, “Theory of plasmon excitation in thin films by electrons of non-normal incidence,” Phys. Status Solidi22, 401–406 (1967).
[CrossRef]

Aizpurua, J.

Álvarez-Puebla, R. A.

L. Rodríguez-Lorenzo, R. A. Álvarez-Puebla, I. Pastoriza-Santos, S. Mazzucco, O. Stéphan, M. Kociak, L. M. Liz-Marzán, and F. J. García de Abajo, “Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering,” J. Am. Chem. Soc.131, 4616–4618 (2009).
[CrossRef] [PubMed]

Anderton, C. R.

M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev.108, 494–521 (2008).
[CrossRef] [PubMed]

Anker, J. N.

J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
[CrossRef] [PubMed]

Ansari, D. O.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Aoki, K.

R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science293, 269–271 (2001).
[CrossRef] [PubMed]

Asahi, R.

R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science293, 269–271 (2001).
[CrossRef] [PubMed]

Atwater, H. A.

H. A. Atwater and A. Polman, “Plasmonics for improved photovoltaic devices,” Nat. Mater.9, 205–213 (2010).
[CrossRef] [PubMed]

S. A. Maier, P. G. Kik, H. A. Atwater, S. Meltzer, E. Harel, B. E. Koel, and A. A. G. Requicha, “Local detection of electromagnetic energy transport below the diffraction limit in metal nanoparticle plasmon waveguides,” Nat. Mater.2, 229–232 (2003).
[CrossRef] [PubMed]

Auguié, B.

B. Auguié, X. M. Bendaña, W. L. Barnes, and F. J. García de Abajo, “Diffractive arrays of gold nanoparticles near an interface: Critical role of the substrate,” Phys. Rev. B82, 155447 (2010).
[CrossRef]

B. Auguié and W. L. Barnes, “Collective resonances in gold nanoparticle arrays,” Phys. Rev. Lett.101, 143902 (2008).
[CrossRef] [PubMed]

Aussenegg, F. R.

D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
[CrossRef] [PubMed]

M. Quinten, A. Leitner, J. R. Krenn, and F. R. Aussenegg, “Electromagnetic energy transport via linear chains of silver nanoparticles,” Opt. Lett.23, 1331–1333 (1998).
[CrossRef]

Bankson, J.

L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
[CrossRef] [PubMed]

Barbic, M.

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
[CrossRef]

Barnes, W. L.

B. Auguié, X. M. Bendaña, W. L. Barnes, and F. J. García de Abajo, “Diffractive arrays of gold nanoparticles near an interface: Critical role of the substrate,” Phys. Rev. B82, 155447 (2010).
[CrossRef]

B. Auguié and W. L. Barnes, “Collective resonances in gold nanoparticle arrays,” Phys. Rev. Lett.101, 143902 (2008).
[CrossRef] [PubMed]

Batson, P. E.

P. E. Batson, “A new surface plasmon resonance in clusters of small aluminum spheres,” Ultramicroscopy9, 277–282 (1982).
[CrossRef]

Bendaña, X. M.

B. Auguié, X. M. Bendaña, W. L. Barnes, and F. J. García de Abajo, “Diffractive arrays of gold nanoparticles near an interface: Critical role of the substrate,” Phys. Rev. B82, 155447 (2010).
[CrossRef]

X. M. Bendaña and F. J. García de Abajo, “Confined collective excitations of self-standing and supported planar periodic particle arrays,” Opt. Express17, 18826–18835 (2009).
[CrossRef]

Bergman, D. J.

K. R. Li, M. I. Stockman, and D. J. Bergman, “Self-similar chain of metal nanospheres as an efficient nanolens,” Phys. Rev. Lett.91, 227402 (2003).
[CrossRef] [PubMed]

Berrier, A.

S. R. K. Rodríguez, M. C. Schaafsma, A. Berrier, and J. Gomez-Rivas, “Collective resonances in plasmonic crystals: Size matters,” Phys. B p. DOI: (2012).
[CrossRef]

Bryant, G. W.

Catchpole, K. R.

Chen, G. Z.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Chow, E.

S. Y. Lin, E. Chow, V. Hietala, P. R. Villeneuve, and J. D. Joannopoulos, “Experimental demonstration of guiding and bending of electromagnetic waves in a photonic crystal,” Science282, 274–276 (1998).
[CrossRef] [PubMed]

Chu, Y.

Y. Chu, E. Schonbrun, T. Yang, and K. B. Crozier, “Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays,” Appl. Phys. Lett.93, 181108 (2008).
[CrossRef]

Coronado, E.

K. L. Kelly, E. Coronado, L. L. Zhao, and G. C. Schatz, “The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment,” J. Phys. Chem. B107, 668–677 (2003).
[CrossRef]

Crozier, K. B.

Y. Chu, E. Schonbrun, T. Yang, and K. B. Crozier, “Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays,” Appl. Phys. Lett.93, 181108 (2008).
[CrossRef]

Dahlin, A. B.

A. B. Dahlin, J. O. Tegenfeldt, and F. Höök, “Improving the instrumental resolution of sensors based on localized surface plasmon resonance,” An. Chem.78, 4416–4423 (2006).
[CrossRef]

Dasari, R. R.

K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett.78, 1667–1670 (1997).
[CrossRef]

Ditlbacher, H.

D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
[CrossRef] [PubMed]

El-Sayed, M. A.

K.-S. Lee and M. A. El-Sayed, “Gold and silver nanoparticles in sensing and imaging: Sensitivity of plasmon response to size, shape, and metal composition,” J. Phys. Chem. B110, 19220–19225 (2006).
[CrossRef] [PubMed]

Emory, S. R.

S. Nie and S. R. Emory, “Probing single molecules and single nanoparticles by surface-enhanced raman scattering,” Science275, 1102–1106 (1997).
[CrossRef] [PubMed]

Estevez, M. C.

M. A. Otte, M. C. Estevez, D. Regatos, L. M. Lechuga, and B. Sepulveda, “Guiding light in monolayers of sparse and random plasmonic meta-atoms,” ACS NANO5, 9179–9186 (2011).
[CrossRef] [PubMed]

Fan, S.

S. G. Johnson, S. Fan, P. R. Villeneuve, J. D. Joannopoulos, and L. A. Kolodziejski, “Guided modes in photonic crystal slabs,” Phys. Rev. B60, 5751–5758 (1999).
[CrossRef]

Fan, S. H.

J. D. Joannopoulos, P. R. Villeneuve, and S. H. Fan, “Photonic crystals: Putting a new twist on light,” Nature386, 143–149 (1997).
[CrossRef]

Feld, M. S.

K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett.78, 1667–1670 (1997).
[CrossRef]

Funston, A. M.

V. Myroshnychenko, J. Rodríguez-Fernández, I. Pastoriza-Santos, A. M. Funston, C. Novo, P. Mulvaney, L. M. Liz-Marzán, and F. J. García de Abajo, “Modelling the optical response of gold nanoparticles,” Chem. Soc. Rev.37, 1792–1805 (2008).
[CrossRef] [PubMed]

Galler, N.

D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
[CrossRef] [PubMed]

García de Abajo, F. J.

B. Auguié, X. M. Bendaña, W. L. Barnes, and F. J. García de Abajo, “Diffractive arrays of gold nanoparticles near an interface: Critical role of the substrate,” Phys. Rev. B82, 155447 (2010).
[CrossRef]

L. Rodríguez-Lorenzo, R. A. Álvarez-Puebla, I. Pastoriza-Santos, S. Mazzucco, O. Stéphan, M. Kociak, L. M. Liz-Marzán, and F. J. García de Abajo, “Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering,” J. Am. Chem. Soc.131, 4616–4618 (2009).
[CrossRef] [PubMed]

X. M. Bendaña and F. J. García de Abajo, “Confined collective excitations of self-standing and supported planar periodic particle arrays,” Opt. Express17, 18826–18835 (2009).
[CrossRef]

V. Myroshnychenko, J. Rodríguez-Fernández, I. Pastoriza-Santos, A. M. Funston, C. Novo, P. Mulvaney, L. M. Liz-Marzán, and F. J. García de Abajo, “Modelling the optical response of gold nanoparticles,” Chem. Soc. Rev.37, 1792–1805 (2008).
[CrossRef] [PubMed]

R. Sainidou and F. J. García de Abajo, “Plasmon guided modes in nanoparticle metamaterials,” Opt. Express16, 4499–4506 (2008).
[CrossRef] [PubMed]

F. J. García de Abajo, “Colloquium: Light scattering by particle and hole arrays,” Rev. Mod. Phys.79, 1267–1290 (2007).
[CrossRef]

I. Romero, J. Aizpurua, G. W. Bryant, and F. J. García de Abajo, “Plasmons in nearly touching metallic nanoparticles: Singular response in the limit of touching dimers,” Opt. Express14, 9988–9999 (2006).
[CrossRef] [PubMed]

Giannini, V.

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Surface modes in plasmonic crystals induced by diffractive coupling of nanoantennas,” Phys. Rev. B80, 201401 (2009).
[CrossRef]

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Shaping the fluorescent emission by lattice resonances in plasmonic crystals of nanoantennas,” Phys. Rev. Lett.102, 146807 (2009).
[CrossRef] [PubMed]

Gómez Rivas, J.

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V. G. Kravets, F. Schedin, and A. N. Grigorenko, “Extremely narrow plasmon resonances based on diffraction coupling of localized plasmons in arrays of metallic nanoparticles,” Phys. Rev. Lett.101, 087403 (2008).
[CrossRef] [PubMed]

Schonbrun, E.

Y. Chu, E. Schonbrun, T. Yang, and K. B. Crozier, “Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays,” Appl. Phys. Lett.93, 181108 (2008).
[CrossRef]

Schultz, D. A.

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
[CrossRef]

Schultz, S.

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
[CrossRef]

Sepulveda, B.

M. A. Otte, M. C. Estevez, D. Regatos, L. M. Lechuga, and B. Sepulveda, “Guiding light in monolayers of sparse and random plasmonic meta-atoms,” ACS NANO5, 9179–9186 (2011).
[CrossRef] [PubMed]

Sershen, S.

L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
[CrossRef] [PubMed]

Shah, N. C.

J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
[CrossRef] [PubMed]

Shiao, Y. S.

Y. L. Luo, Y. S. Shiao, and Y. F. Huang, “Release of photoactivatable drugs from plasmonic nanoparticles for targeted cancer therapy,” ACS Nano5, 7796–7804 (2011).
[CrossRef] [PubMed]

Shin, D. M.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Smith, D. R.

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
[CrossRef]

Stafford, R.

L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
[CrossRef] [PubMed]

Stéphan, O.

L. Rodríguez-Lorenzo, R. A. Álvarez-Puebla, I. Pastoriza-Santos, S. Mazzucco, O. Stéphan, M. Kociak, L. M. Liz-Marzán, and F. J. García de Abajo, “Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering,” J. Am. Chem. Soc.131, 4616–4618 (2009).
[CrossRef] [PubMed]

Stewart, M. E.

M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev.108, 494–521 (2008).
[CrossRef] [PubMed]

Stockman, M. I.

P. Nordlander, C. Oubre, E. Prodan, K. Li, and M. I. Stockman, “Plasmon hybridizaton in nanoparticle dimers,” Nano Lett.4, 899–903 (2004).
[CrossRef]

K. R. Li, M. I. Stockman, and D. J. Bergman, “Self-similar chain of metal nanospheres as an efficient nanolens,” Phys. Rev. Lett.91, 227402 (2003).
[CrossRef] [PubMed]

Tacke, M.

R. Ulrich and M. Tacke, “Submillimeter waveguiding on periodic metal structure,” Appl. Phys. Lett.22, 251–253 (1973).
[CrossRef]

Taga, Y.

R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science293, 269–271 (2001).
[CrossRef] [PubMed]

Talley, C. E.

C. E. Talley, J. B. Jackson, C. Oubre, N. K. Grady, C. W. Hollars, S. M. Lane, T. R. Huser, P. Nordlander, and N. J. Halas, “Surface-enhanced Raman scattering from individual au nanoparticles and nanoparticle dimer substrates,” Nano Lett.5, 1569–1574 (2005).
[CrossRef] [PubMed]

Tegenfeldt, J. O.

A. B. Dahlin, J. O. Tegenfeldt, and F. Höök, “Improving the instrumental resolution of sensors based on localized surface plasmon resonance,” An. Chem.78, 4416–4423 (2006).
[CrossRef]

Thompson, L. B.

M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev.108, 494–521 (2008).
[CrossRef] [PubMed]

Trügler, A.

D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
[CrossRef] [PubMed]

Ulrich, R.

R. Ulrich and M. Tacke, “Submillimeter waveguiding on periodic metal structure,” Appl. Phys. Lett.22, 251–253 (1973).
[CrossRef]

Van Duyne, R.

A. McFarland and R. Van Duyne, “Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity,” Nano Lett.3, 1057–1062 (2003).
[CrossRef]

Van Duyne, R. P.

J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
[CrossRef] [PubMed]

van Sprang, H. A.

M. A. Verschuuren and H. A. van Sprang, “3d photonic structures by sol-gel imprint lithography,” Mater. Res. Soc. Symp. Proc.1002, 1002-N03-05 (2007).
[CrossRef]

Vecchi, G.

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Shaping the fluorescent emission by lattice resonances in plasmonic crystals of nanoantennas,” Phys. Rev. Lett.102, 146807 (2009).
[CrossRef] [PubMed]

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Surface modes in plasmonic crystals induced by diffractive coupling of nanoantennas,” Phys. Rev. B80, 201401 (2009).
[CrossRef]

Verschuuren, M. A.

M. A. Verschuuren and H. A. van Sprang, “3d photonic structures by sol-gel imprint lithography,” Mater. Res. Soc. Symp. Proc.1002, 1002-N03-05 (2007).
[CrossRef]

Villeneuve, P. R.

S. G. Johnson, S. Fan, P. R. Villeneuve, J. D. Joannopoulos, and L. A. Kolodziejski, “Guided modes in photonic crystal slabs,” Phys. Rev. B60, 5751–5758 (1999).
[CrossRef]

S. Y. Lin, E. Chow, V. Hietala, P. R. Villeneuve, and J. D. Joannopoulos, “Experimental demonstration of guiding and bending of electromagnetic waves in a photonic crystal,” Science282, 274–276 (1998).
[CrossRef] [PubMed]

J. D. Joannopoulos, P. R. Villeneuve, and S. H. Fan, “Photonic crystals: Putting a new twist on light,” Nature386, 143–149 (1997).
[CrossRef]

Wang, M. D.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Wang, Y.

K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett.78, 1667–1670 (1997).
[CrossRef]

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L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
[CrossRef] [PubMed]

Xu, H.

P. Johansson, H. Xu, and M. Käll, “Surface-enhanced raman scattering and fluorescence near metal nanoparticles,” Phys. Rev. B72, 035427 (2005).
[CrossRef]

Yang, L.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Yang, T.

Y. Chu, E. Schonbrun, T. Yang, and K. B. Crozier, “Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays,” Appl. Phys. Lett.93, 181108 (2008).
[CrossRef]

Yin-Goen, Q.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Young, A. N.

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Zhao, J.

J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
[CrossRef] [PubMed]

Zhao, L. L.

K. L. Kelly, E. Coronado, L. L. Zhao, and G. C. Schatz, “The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment,” J. Phys. Chem. B107, 668–677 (2003).
[CrossRef]

Zhou, W.

W. Zhou and T. W. Odom, “Tunable subradiant lattice plasmons by out-of-plane dipolar interactions,” Nat. Nanotech.6, 423–427 (2011).
[CrossRef]

ACS Nano (1)

Y. L. Luo, Y. S. Shiao, and Y. F. Huang, “Release of photoactivatable drugs from plasmonic nanoparticles for targeted cancer therapy,” ACS Nano5, 7796–7804 (2011).
[CrossRef] [PubMed]

M. A. Otte, M. C. Estevez, D. Regatos, L. M. Lechuga, and B. Sepulveda, “Guiding light in monolayers of sparse and random plasmonic meta-atoms,” ACS NANO5, 9179–9186 (2011).
[CrossRef] [PubMed]

An. Chem. (1)

A. B. Dahlin, J. O. Tegenfeldt, and F. Höök, “Improving the instrumental resolution of sensors based on localized surface plasmon resonance,” An. Chem.78, 4416–4423 (2006).
[CrossRef]

Appl. Phys. Lett. (2)

Y. Chu, E. Schonbrun, T. Yang, and K. B. Crozier, “Experimental observation of narrow surface plasmon resonances in gold nanoparticle arrays,” Appl. Phys. Lett.93, 181108 (2008).
[CrossRef]

R. Ulrich and M. Tacke, “Submillimeter waveguiding on periodic metal structure,” Appl. Phys. Lett.22, 251–253 (1973).
[CrossRef]

Chem. Rev. (1)

M. E. Stewart, C. R. Anderton, L. B. Thompson, J. Maria, S. K. Gray, J. A. Rogers, and R. G. Nuzzo, “Nanostructured plasmonic sensors,” Chem. Rev.108, 494–521 (2008).
[CrossRef] [PubMed]

Chem. Soc. Rev. (1)

V. Myroshnychenko, J. Rodríguez-Fernández, I. Pastoriza-Santos, A. M. Funston, C. Novo, P. Mulvaney, L. M. Liz-Marzán, and F. J. García de Abajo, “Modelling the optical response of gold nanoparticles,” Chem. Soc. Rev.37, 1792–1805 (2008).
[CrossRef] [PubMed]

J. Am. Chem. Soc. (1)

L. Rodríguez-Lorenzo, R. A. Álvarez-Puebla, I. Pastoriza-Santos, S. Mazzucco, O. Stéphan, M. Kociak, L. M. Liz-Marzán, and F. J. García de Abajo, “Zeptomol detection through controlled ultrasensitive surface-enhanced Raman scattering,” J. Am. Chem. Soc.131, 4616–4618 (2009).
[CrossRef] [PubMed]

J. Chem. Phys. (1)

J. J. Mock, M. Barbic, D. R. Smith, D. A. Schultz, and S. Schultz, “Shape effects in plasmon resonance of individual colloidal silver nanoparticles,” J. Chem. Phys.116, 6755–6759 (2002).
[CrossRef]

J. Phys. Chem. B (3)

K. L. Kelly, E. Coronado, L. L. Zhao, and G. C. Schatz, “The optical properties of metal nanoparticles: The influence of size, shape, and dielectric environment,” J. Phys. Chem. B107, 668–677 (2003).
[CrossRef]

P. V. Kamat, “Photophysical, photochemical and photocatalytic aspects of metal nanoparticles,” J. Phys. Chem. B106, 7729–7744 (2002).
[CrossRef]

K.-S. Lee and M. A. El-Sayed, “Gold and silver nanoparticles in sensing and imaging: Sensitivity of plasmon response to size, shape, and metal composition,” J. Phys. Chem. B110, 19220–19225 (2006).
[CrossRef] [PubMed]

Mater. Res. Soc. Symp. Proc. (1)

M. A. Verschuuren and H. A. van Sprang, “3d photonic structures by sol-gel imprint lithography,” Mater. Res. Soc. Symp. Proc.1002, 1002-N03-05 (2007).
[CrossRef]

Nano Lett. (3)

P. Nordlander, C. Oubre, E. Prodan, K. Li, and M. I. Stockman, “Plasmon hybridizaton in nanoparticle dimers,” Nano Lett.4, 899–903 (2004).
[CrossRef]

A. McFarland and R. Van Duyne, “Single silver nanoparticles as real-time optical sensors with zeptomole sensitivity,” Nano Lett.3, 1057–1062 (2003).
[CrossRef]

C. E. Talley, J. B. Jackson, C. Oubre, N. K. Grady, C. W. Hollars, S. M. Lane, T. R. Huser, P. Nordlander, and N. J. Halas, “Surface-enhanced Raman scattering from individual au nanoparticles and nanoparticle dimer substrates,” Nano Lett.5, 1569–1574 (2005).
[CrossRef] [PubMed]

Nat. Biotech. (1)

X. Qian, X. H. Peng, D. O. Ansari, Q. Yin-Goen, G. Z. Chen, D. M. Shin, L. Yang, A. N. Young, M. D. Wang, and S. Nie, “In vivo tumor targeting and spectroscopic detection with surface-enhanced raman nanoparticle tags,” Nat. Biotech.26, 83–90 (2008).
[CrossRef]

Nat. Mater. (3)

H. A. Atwater and A. Polman, “Plasmonics for improved photovoltaic devices,” Nat. Mater.9, 205–213 (2010).
[CrossRef] [PubMed]

J. N. Anker, W. P. Hall, O. Lyandres, N. C. Shah, J. Zhao, and R. P. Van Duyne, “Biosensing with plasmonic nanosensors,” Nat. Mater.7, 442–453 (2008).
[CrossRef] [PubMed]

S. A. Maier, P. G. Kik, H. A. Atwater, S. Meltzer, E. Harel, B. E. Koel, and A. A. G. Requicha, “Local detection of electromagnetic energy transport below the diffraction limit in metal nanoparticle plasmon waveguides,” Nat. Mater.2, 229–232 (2003).
[CrossRef] [PubMed]

Nat. Nanotech. (1)

W. Zhou and T. W. Odom, “Tunable subradiant lattice plasmons by out-of-plane dipolar interactions,” Nat. Nanotech.6, 423–427 (2011).
[CrossRef]

Nature (1)

J. D. Joannopoulos, P. R. Villeneuve, and S. H. Fan, “Photonic crystals: Putting a new twist on light,” Nature386, 143–149 (1997).
[CrossRef]

Opt. Express (4)

Opt. Lett. (1)

Phys. Rev. B (4)

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Surface modes in plasmonic crystals induced by diffractive coupling of nanoantennas,” Phys. Rev. B80, 201401 (2009).
[CrossRef]

S. G. Johnson, S. Fan, P. R. Villeneuve, J. D. Joannopoulos, and L. A. Kolodziejski, “Guided modes in photonic crystal slabs,” Phys. Rev. B60, 5751–5758 (1999).
[CrossRef]

B. Auguié, X. M. Bendaña, W. L. Barnes, and F. J. García de Abajo, “Diffractive arrays of gold nanoparticles near an interface: Critical role of the substrate,” Phys. Rev. B82, 155447 (2010).
[CrossRef]

P. Johansson, H. Xu, and M. Käll, “Surface-enhanced raman scattering and fluorescence near metal nanoparticles,” Phys. Rev. B72, 035427 (2005).
[CrossRef]

Phys. Rev. Lett. (6)

K. Kneipp, Y. Wang, H. Kneipp, L. T. Perelman, I. Itzkan, R. R. Dasari, and M. S. Feld, “Single molecule detection using surface-enhanced Raman scattering (SERS),” Phys. Rev. Lett.78, 1667–1670 (1997).
[CrossRef]

K. R. Li, M. I. Stockman, and D. J. Bergman, “Self-similar chain of metal nanospheres as an efficient nanolens,” Phys. Rev. Lett.91, 227402 (2003).
[CrossRef] [PubMed]

G. Vecchi, V. Giannini, and J. Gómez Rivas, “Shaping the fluorescent emission by lattice resonances in plasmonic crystals of nanoantennas,” Phys. Rev. Lett.102, 146807 (2009).
[CrossRef] [PubMed]

B. Auguié and W. L. Barnes, “Collective resonances in gold nanoparticle arrays,” Phys. Rev. Lett.101, 143902 (2008).
[CrossRef] [PubMed]

V. G. Kravets, F. Schedin, and A. N. Grigorenko, “Extremely narrow plasmon resonances based on diffraction coupling of localized plasmons in arrays of metallic nanoparticles,” Phys. Rev. Lett.101, 087403 (2008).
[CrossRef] [PubMed]

D. M. Koller, U. Hohenester, A. Hohenau, H. Ditlbacher, F. Reil, N. Galler, F. R. Aussenegg, A. Leitner, A. Trügler, and J. R. Krenn, “Superresolution moire mapping of particle plasmon modes,” Phys. Rev. Lett.104, 143901 (2010).
[CrossRef] [PubMed]

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A. Otto, “Theory of plasmon excitation in thin films by electrons of non-normal incidence,” Phys. Status Solidi22, 401–406 (1967).
[CrossRef]

Proc. Natl. Acad. Sci. (1)

L. Hirsch, R. Stafford, J. Bankson, S. Sershen, B. Rivera, R. Price, J. Hazle, N. Halas, and J. West, “Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance,” Proc. Natl. Acad. Sci.100, 13549–13554 (2003).
[CrossRef] [PubMed]

Rev. Mod. Phys. (1)

F. J. García de Abajo, “Colloquium: Light scattering by particle and hole arrays,” Rev. Mod. Phys.79, 1267–1290 (2007).
[CrossRef]

Science (3)

S. Y. Lin, E. Chow, V. Hietala, P. R. Villeneuve, and J. D. Joannopoulos, “Experimental demonstration of guiding and bending of electromagnetic waves in a photonic crystal,” Science282, 274–276 (1998).
[CrossRef] [PubMed]

R. Asahi, T. Morikawa, T. Ohwaki, K. Aoki, and Y. Taga, “Visible-light photocatalysis in nitrogen-doped titanium oxides,” Science293, 269–271 (2001).
[CrossRef] [PubMed]

S. Nie and S. R. Emory, “Probing single molecules and single nanoparticles by surface-enhanced raman scattering,” Science275, 1102–1106 (1997).
[CrossRef] [PubMed]

Ultramicroscopy (1)

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[CrossRef]

Other (2)

S. R. K. Rodríguez, M. C. Schaafsma, A. Berrier, and J. Gomez-Rivas, “Collective resonances in plasmonic crystals: Size matters,” Phys. B p. DOI: (2012).
[CrossRef]

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[CrossRef]

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Figures (4)

Fig. 1
Fig. 1

Images and scheme of the system under consideration. (a) and (b) SEM images of our nanoimprinted arrays. The gold nanodisks are arranged in a square lattice with parameter a = 300nm. The height of the disks is h = 50nm and the diameter is D = 200nm in (a) and D = 250nm in (b). (c) An array of golden disks is embedded in a homogeneous SiO2 environment (refraction index nSiO2 = 1.46) at a distance d = 600nm from a prism interface. This is the Otto configuration, whereby light undergoes total internal reflection inside the prism (nF2 = 1.67) with incident angle θi and parallel wave vector k outside the light cone. Light couples evanescently to the confined modes of the array, thus producing a measurable attenuated total reflection.

Fig. 2
Fig. 2

Simulations of confined modes in a square array of SiO2-embedded gold nanodisks of D = 200nm in diameter. (a) Dispersion diagram showing the light energy and wave-vector dependence of the array reflection coefficient (color scale). Guided modes show up as bright features. The light cone (solid line) and its first Bragg-reflection (dashed line) are plotted for reference. (b) Electric-field intensity maps over a region of 4 unit cells at a distance D/2 above the array for characteristic points within the dispersion diagram, as shown by labels A–D in both (a) and (b). The nanoparticle contours are represented by a dashed circle. Dipolar patterns are visible when confined modes are excited (A and B), leading to large field enhancement (see color scale). In contrast, lower field enhancement is associated with non-resonant reflection (C and D), although hotspots can localize between particle gaps (see D), leading to an almost dispersionless feature in (a).

Fig. 3
Fig. 3

Experimental (a,b) and theoretical (c,d) energy-angle-dependent reflectance of the combined array-prism system [Fig. 1(a)] for nanodisks of diameter D = 200nm (a,c) and D = 250nm (b,d). The excitation of a guided mode is revealed by a dark (low reflectance) feature at the right of the critical angle (θi ≈ 64deg).

Fig. 4
Fig. 4

Experiment-theory comparison of the dispersion relation (a), the penetration length outside the array (Lz) (b), and the propagation distance (Lx) (c) for the guided modes. The values shown in this plot are obtained from Lorentzian functions fitted to the dips shown in Fig. 3. From the position of the peak we calculate both the dispersion relation and the penetration length, while the width is related to the propagation length. Theory: dashed curves. Experiment: solid curves, obtained from constant-energy Lorentzian fits of the reflection dip in Fig. 3 [the inset in (a) shows a characteristic example of the Lorentzian fit for the energy 1,74eV signaled with crosses in the main plot]. Black (gray) curves correspond to disks of diameter D = 200nm (D = 250nm).

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