Abstract

Bulk crystals of Cu2ZnSiTe4 (CZSiTe) have been prepared by modified Bridgman method and have been investigated by single crystal X-ray method, Energy Dispersive X-Ray analysis and Raman scattering techniques. The structural studies revealed that the CZSiTe compounds crystallizes in the tetragonal space group I4¯2m, with a = b = 5.9612(1) Å and c = 11.7887(4) Å at 293 K. The Raman spectrum characteristic of the crystals exhibits nine peaks, with two dominant peaks at approximately 134 cm−1 and 151 cm−1 that can be used as fingerprint peaks for the identification of this compound. The Raman peaks were analyzed on the basis of the derived irreducible representation for the zone center phonons and by comparison with experimental and theoretical data from close related semiconductors as Cu2FeSnS4 and Cu2ZnSnSe4.

© 2014 Optical Society of America

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References

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  1. H. Matsushita, T. Ichikawa, and A. Katsui, “Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds,” J. Mater. Sci. 40(8), 2003–2005 (2005).
    [Crossref]
  2. H. Matsushita and A. Katsui, “Materials design for Cu-based quaternary compounds derived from chalcopyrite-rule,” J. Phys. Chem. Solids 66(11), 1933–1936 (2005).
    [Crossref]
  3. H. Haeuseler, F. W. Ohrendorf, and M. Himmirch, “Zur Kenntnis quaternärer Telluride Cu2M M T e4 mit Tetraederstrukturen,” Z. Naturforsch 46b, 1049–1052 (1991).
  4. K.A. Rosmus and J.A. Aitken, “Cu2ZnSiS4,” Acta Cryst. E67, i28 (2011).
  5. S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
    [Crossref]
  6. M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
    [Crossref]
  7. M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
    [Crossref]
  8. M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
    [Crossref]
  9. K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
    [Crossref]
  10. S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
    [Crossref]
  11. M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
    [Crossref]
  12. M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
    [Crossref]
  13. R. C. Clark and J. S. Reid, “The analytical calculation of absorption in multifaceted crystals,” Acta Crystallogr. A 51(6), 887–897 (1995).
    [Crossref]
  14. G. M. Sheldrick, “A short history of SHELX,” Acta Crystallogr. A 64(1), 112–122 (2008).
    [Crossref] [PubMed]
  15. A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
    [Crossref]
  16. A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
    [PubMed]
  17. D. L. Rousseau, R. P. Bauman, and S. P. S. Porto, “Normal mode determination in crystals,” J. Raman Spectrosc. 10(1), 253–290 (1981).
    [Crossref]
  18. M. Himmrich and H. Haeuseler, “Far infrared studies on stannite and wurtzstannite type compounds,” Spectrochimica Acta 47(7), 933–942 (1991).
    [Crossref]
  19. X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
    [Crossref]
  20. N. B. M. Amiri and A. Postnikov, “Electronic structure and lattice dynamics in kesterite-type Cu2ZnSnSe4 from first-principles calculations,” Phys. Rev. B 82(20), 205204 (2010).
    [Crossref]
  21. T. Gurel, C. Sevik, and T. Cagın, “Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures,” Phys. Rev. B 84(20), 205201 (2011).
    [Crossref]
  22. H. Neumann, “Lattice vibrations in AIBIIICVI2 chalcopyrite compounds,” Helv. Phys. Acta 58, 337–346 (1985).
  23. I. P. Kaminow, E. Buehler, and J. H. Wernick, “Vibrational modes in ZnSiP2,” Phys. Rev. B 2(4), 960–966 (1970).
    [Crossref]

2014 (3)

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

2013 (5)

A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

2012 (2)

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

2011 (2)

T. Gurel, C. Sevik, and T. Cagın, “Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures,” Phys. Rev. B 84(20), 205201 (2011).
[Crossref]

K.A. Rosmus and J.A. Aitken, “Cu2ZnSiS4,” Acta Cryst. E67, i28 (2011).

2010 (2)

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

N. B. M. Amiri and A. Postnikov, “Electronic structure and lattice dynamics in kesterite-type Cu2ZnSnSe4 from first-principles calculations,” Phys. Rev. B 82(20), 205204 (2010).
[Crossref]

2008 (1)

G. M. Sheldrick, “A short history of SHELX,” Acta Crystallogr. A 64(1), 112–122 (2008).
[Crossref] [PubMed]

2005 (2)

H. Matsushita, T. Ichikawa, and A. Katsui, “Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds,” J. Mater. Sci. 40(8), 2003–2005 (2005).
[Crossref]

H. Matsushita and A. Katsui, “Materials design for Cu-based quaternary compounds derived from chalcopyrite-rule,” J. Phys. Chem. Solids 66(11), 1933–1936 (2005).
[Crossref]

1995 (1)

R. C. Clark and J. S. Reid, “The analytical calculation of absorption in multifaceted crystals,” Acta Crystallogr. A 51(6), 887–897 (1995).
[Crossref]

1991 (2)

M. Himmrich and H. Haeuseler, “Far infrared studies on stannite and wurtzstannite type compounds,” Spectrochimica Acta 47(7), 933–942 (1991).
[Crossref]

H. Haeuseler, F. W. Ohrendorf, and M. Himmirch, “Zur Kenntnis quaternärer Telluride Cu2M M T e4 mit Tetraederstrukturen,” Z. Naturforsch 46b, 1049–1052 (1991).

1985 (1)

H. Neumann, “Lattice vibrations in AIBIIICVI2 chalcopyrite compounds,” Helv. Phys. Acta 58, 337–346 (1985).

1981 (1)

D. L. Rousseau, R. P. Bauman, and S. P. S. Porto, “Normal mode determination in crystals,” J. Raman Spectrosc. 10(1), 253–290 (1981).
[Crossref]

1970 (1)

I. P. Kaminow, E. Buehler, and J. H. Wernick, “Vibrational modes in ZnSiP2,” Phys. Rev. B 2(4), 960–966 (1970).
[Crossref]

Aitken, J.A.

K.A. Rosmus and J.A. Aitken, “Cu2ZnSiS4,” Acta Cryst. E67, i28 (2011).

Amiri, N. B. M.

N. B. M. Amiri and A. Postnikov, “Electronic structure and lattice dynamics in kesterite-type Cu2ZnSnSe4 from first-principles calculations,” Phys. Rev. B 82(20), 205204 (2010).
[Crossref]

Arushanov, E.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Bauman, R. P.

D. L. Rousseau, R. P. Bauman, and S. P. S. Porto, “Normal mode determination in crystals,” J. Raman Spectrosc. 10(1), 253–290 (1981).
[Crossref]

Buehler, E.

I. P. Kaminow, E. Buehler, and J. H. Wernick, “Vibrational modes in ZnSiP2,” Phys. Rev. B 2(4), 960–966 (1970).
[Crossref]

Cagin, T.

T. Gurel, C. Sevik, and T. Cagın, “Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures,” Phys. Rev. B 84(20), 205201 (2011).
[Crossref]

Choubrac, L.

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Clark, R. C.

R. C. Clark and J. S. Reid, “The analytical calculation of absorption in multifaceted crystals,” Acta Crystallogr. A 51(6), 887–897 (1995).
[Crossref]

Dermenji, L.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

Du, C. H.

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Dumcenco, D.

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Dumcenco, D. O.

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

Evain, M.

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Fertey, P.

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Fontane, X.

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

Fontané, X.

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Guc, M.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

Guillot-Deudon, C.

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Gurel, T.

T. Gurel, C. Sevik, and T. Cagın, “Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures,” Phys. Rev. B 84(20), 205201 (2011).
[Crossref]

Gurieva, G.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
[Crossref]

Haeuseler, H.

H. Haeuseler, F. W. Ohrendorf, and M. Himmirch, “Zur Kenntnis quaternärer Telluride Cu2M M T e4 mit Tetraederstrukturen,” Z. Naturforsch 46b, 1049–1052 (1991).

M. Himmrich and H. Haeuseler, “Far infrared studies on stannite and wurtzstannite type compounds,” Spectrochimica Acta 47(7), 933–942 (1991).
[Crossref]

Himmirch, M.

H. Haeuseler, F. W. Ohrendorf, and M. Himmirch, “Zur Kenntnis quaternärer Telluride Cu2M M T e4 mit Tetraederstrukturen,” Z. Naturforsch 46b, 1049–1052 (1991).

Himmrich, M.

M. Himmrich and H. Haeuseler, “Far infrared studies on stannite and wurtzstannite type compounds,” Spectrochimica Acta 47(7), 933–942 (1991).
[Crossref]

Huang, Y. S.

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Ichikawa, T.

H. Matsushita, T. Ichikawa, and A. Katsui, “Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds,” J. Mater. Sci. 40(8), 2003–2005 (2005).
[Crossref]

Izquierdo-Roca, V.

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Jobic, S.

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Kaminow, I. P.

I. P. Kaminow, E. Buehler, and J. H. Wernick, “Vibrational modes in ZnSiP2,” Phys. Rev. B 2(4), 960–966 (1970).
[Crossref]

Katsui, A.

H. Matsushita, T. Ichikawa, and A. Katsui, “Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds,” J. Mater. Sci. 40(8), 2003–2005 (2005).
[Crossref]

H. Matsushita and A. Katsui, “Materials design for Cu-based quaternary compounds derived from chalcopyrite-rule,” J. Phys. Chem. Solids 66(11), 1933–1936 (2005).
[Crossref]

Kravtsov, V. Ch.

A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
[Crossref]

Lafond, A.

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Leon, M.

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

Levcenco, S.

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Levcenko, S.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

Lisunov, K. G.

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

Matsushita, H.

H. Matsushita, T. Ichikawa, and A. Katsui, “Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds,” J. Mater. Sci. 40(8), 2003–2005 (2005).
[Crossref]

H. Matsushita and A. Katsui, “Materials design for Cu-based quaternary compounds derived from chalcopyrite-rule,” J. Phys. Chem. Solids 66(11), 1933–1936 (2005).
[Crossref]

Merino, J. M.

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

Morante, J. R.

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Nateprov, A.

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
[Crossref]

Neumann, H.

H. Neumann, “Lattice vibrations in AIBIIICVI2 chalcopyrite compounds,” Helv. Phys. Acta 58, 337–346 (1985).

Ohrendorf, F. W.

H. Haeuseler, F. W. Ohrendorf, and M. Himmirch, “Zur Kenntnis quaternärer Telluride Cu2M M T e4 mit Tetraederstrukturen,” Z. Naturforsch 46b, 1049–1052 (1991).

Pérez Rodríguez, A.

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

Perez-Rodriguez, A.

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

Pérez-Rodríguez, A.

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Porto, S. P. S.

D. L. Rousseau, R. P. Bauman, and S. P. S. Porto, “Normal mode determination in crystals,” J. Raman Spectrosc. 10(1), 253–290 (1981).
[Crossref]

Postnikov, A.

N. B. M. Amiri and A. Postnikov, “Electronic structure and lattice dynamics in kesterite-type Cu2ZnSnSe4 from first-principles calculations,” Phys. Rev. B 82(20), 205204 (2010).
[Crossref]

Reid, J. S.

R. C. Clark and J. S. Reid, “The analytical calculation of absorption in multifaceted crystals,” Acta Crystallogr. A 51(6), 887–897 (1995).
[Crossref]

Rosmus, K.A.

K.A. Rosmus and J.A. Aitken, “Cu2ZnSiS4,” Acta Cryst. E67, i28 (2011).

Rousseau, D. L.

D. L. Rousseau, R. P. Bauman, and S. P. S. Porto, “Normal mode determination in crystals,” J. Raman Spectrosc. 10(1), 253–290 (1981).
[Crossref]

Saucedo, E.

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Schorr, S.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
[Crossref]

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Serna, R.

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

Sevik, C.

T. Gurel, C. Sevik, and T. Cagın, “Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures,” Phys. Rev. B 84(20), 205201 (2011).
[Crossref]

Sheldrick, G. M.

G. M. Sheldrick, “A short history of SHELX,” Acta Crystallogr. A 64(1), 112–122 (2008).
[Crossref] [PubMed]

Syrbu, N. N.

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

Tezlevan, V.

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Tiong, K. K.

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

Valakh, M. Ya.

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Wang, Y. P.

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

Wernick, J. H.

I. P. Kaminow, E. Buehler, and J. H. Wernick, “Vibrational modes in ZnSiP2,” Phys. Rev. B 2(4), 960–966 (1970).
[Crossref]

Wu, J. D.

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

Yukhymchuk, V. O.

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

Acta Cryst. (1)

K.A. Rosmus and J.A. Aitken, “Cu2ZnSiS4,” Acta Cryst. E67, i28 (2011).

Acta Crystallogr B Struct Sci Cryst Eng Mater (1)

A. Lafond, L. Choubrac, C. Guillot-Deudon, P. Fertey, M. Evain, and S. Jobic, “X-ray resonant single-crystal diffraction technique, a powerful tool to investigate the kesterite structure of the photovoltaic Cu2ZnSnS4 compound,” Acta Crystallogr B Struct Sci Cryst Eng Mater 70(Pt 2), 390–394 (2014).
[PubMed]

Acta Crystallogr. A (2)

R. C. Clark and J. S. Reid, “The analytical calculation of absorption in multifaceted crystals,” Acta Crystallogr. A 51(6), 887–897 (1995).
[Crossref]

G. M. Sheldrick, “A short history of SHELX,” Acta Crystallogr. A 64(1), 112–122 (2008).
[Crossref] [PubMed]

Helv. Phys. Acta (1)

H. Neumann, “Lattice vibrations in AIBIIICVI2 chalcopyrite compounds,” Helv. Phys. Acta 58, 337–346 (1985).

J. Alloy. Comp. (3)

X. Fontané, V. Izquierdo-Roca, E. Saucedo, S. Schorr, V. O. Yukhymchuk, M. Ya. Valakh, A. Pérez-Rodríguez, and J. R. Morante, “Vibrational properties of stannite and kesterite type compounds: Raman scattering analysis of Cu2(Fe,Zn)SnS4,” J. Alloy. Comp. 539, 190–194 (2012).
[Crossref]

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Exciton spectra and energy band structure of Cu2ZnSiSe4,” J. Alloy. Comp. 587, 393–397 (2014).
[Crossref]

K. G. Lisunov, M. Guc, S. Levcenko, D. Dumcenco, Y. S. Huang, G. Gurieva, S. Schorr, and E. Arushanov, “Energy spectrum of near-edge holes and conduction mechanisms in Cu2ZnSiSe4 single crystals,” J. Alloy. Comp. 580, 481–486 (2013).
[Crossref]

J. Appl. Phys. (2)

S. Levcenco, D. Dumcenco, Y. S. Huang, E. Arushanov, V. Tezlevan, K. K. Tiong, and C. H. Du, “Near band edge anisotropic optical transitions in wide band gap semiconductor Cu2ZnSiS4,” J. Appl. Phys. 108(7), 073508 (2010).
[Crossref]

M. Guc, S. Levcenko, V. Izquierdo-Roca, X. Fontane, M. Ya. Valakh, E. Arushanov, and A. Perez-Rodrıguez, “Polarized Raman scattering analysis of Cu2ZnSiS4 and Cu2ZnSiSe4 single crystals,” J. Appl. Phys. 114(17), 173507 (2013).
[Crossref]

J. Mater. Sci. (1)

H. Matsushita, T. Ichikawa, and A. Katsui, “Structural, thermodynamical and optical properties of Cu2-II-IV-VI4 quaternary compounds,” J. Mater. Sci. 40(8), 2003–2005 (2005).
[Crossref]

J. Phys. Chem. Solids (1)

H. Matsushita and A. Katsui, “Materials design for Cu-based quaternary compounds derived from chalcopyrite-rule,” J. Phys. Chem. Solids 66(11), 1933–1936 (2005).
[Crossref]

J. Raman Spectrosc. (1)

D. L. Rousseau, R. P. Bauman, and S. P. S. Porto, “Normal mode determination in crystals,” J. Raman Spectrosc. 10(1), 253–290 (1981).
[Crossref]

Mater. Chem. Phys. (1)

M. Leon, S. Levcenko, R. Serna, A. Nateprov, G. Gurieva, J. M. Merino, S. Schorr, and E. Arushanov, “Spectroscopic ellipsometry study of Cu2ZnGeSe4 and Cu2ZnSiSe4 poly-crystals,” Mater. Chem. Phys. 141(1), 58–62 (2013).
[Crossref]

Opt. Mater. (1)

S. Levcenco, D. O. Dumcenco, Y. P. Wang, J. D. Wu, Y. S. Huang, E. Arushanov, V. Tezlevan, and K. K. Tiong, “Photoluminescence and Raman scattering characterization of Cu2ZnSiQ4 (Q = S, Se) single crystals,” Opt. Mater. 34(7), 1072–1076 (2012).
[Crossref]

Phys. Rev. B (3)

N. B. M. Amiri and A. Postnikov, “Electronic structure and lattice dynamics in kesterite-type Cu2ZnSnSe4 from first-principles calculations,” Phys. Rev. B 82(20), 205204 (2010).
[Crossref]

T. Gurel, C. Sevik, and T. Cagın, “Characterization of vibrational and mechanical properties of quaternary compounds Cu2ZnSnS4 and Cu2ZnSnSe4 in kesterite and stannite structures,” Phys. Rev. B 84(20), 205201 (2011).
[Crossref]

I. P. Kaminow, E. Buehler, and J. H. Wernick, “Vibrational modes in ZnSiP2,” Phys. Rev. B 2(4), 960–966 (1970).
[Crossref]

Phys. Status Solidi., C Curr. Top. Solid State Phys. (1)

M. Guc, V. Izquierdo-Roca, A. Pérez Rodríguez, G. Gurieva, S. Levcenko, S. Schorr, and E. Arushanov, “Raman spectra of wurtzstannite quaternary compounds,” Phys. Status Solidi., C Curr. Top. Solid State Phys. 10(7-8), 1075–1078 (2013).
[Crossref]

Solid State Commun. (1)

M. Guc, S. Levcenko, L. Dermenji, G. Gurieva, S. Schorr, N. N. Syrbu, and E. Arushanov, “Excitonic and band-band transitions of Cu2ZnSiS4 determined from reflectivity spectra,” Solid State Commun. 190, 44–48 (2014).
[Crossref]

Spectrochimica Acta (1)

M. Himmrich and H. Haeuseler, “Far infrared studies on stannite and wurtzstannite type compounds,” Spectrochimica Acta 47(7), 933–942 (1991).
[Crossref]

Surf. Eng. Appl. Electron. (1)

A. Nateprov, V. Ch. Kravtsov, G. Gurieva, and S. Schorr, “Single crystal X-ray structure investigation of Cu2ZnSnSe4,” Surf. Eng. Appl. Electron. 49(5), 423–426 (2013).
[Crossref]

Z. Naturforsch (1)

H. Haeuseler, F. W. Ohrendorf, and M. Himmirch, “Zur Kenntnis quaternärer Telluride Cu2M M T e4 mit Tetraederstrukturen,” Z. Naturforsch 46b, 1049–1052 (1991).

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Figures (2)

Fig. 1
Fig. 1 The crystal structure of CZSiTe.
Fig. 2
Fig. 2 Fitting (red line) of CZSiTe Raman spectra (black line) with Lorentzian curves (green line). The breaks in the intensity scale were done to show better the low intensity peaks. The untreated Raman spectrum of CZSiTe crystal is shown in the inset.

Tables (4)

Tables Icon

Table 1 Results of Refinement and Experimental Details of X-ray Measurements.

Tables Icon

Table 2 Atomic Coordinatesa and Equivalent Isotropic Displacement Parametersb.

Tables Icon

Table 3 Irreducible Representations for Atoms of Tetragonal CZSiTe.

Tables Icon

Table 4 Proposed Symmetry Assignment of Raman Active Modes in CZSiTe Compound.

Equations (1)

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ν VI ( 2( α IVI + α IIIVI ) M VI ) 1/2 ,

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