Abstract

A novel single-component warm white light-emitting Sr2Ca0.995MoO6: Sm3+0.005 phosphor was synthesized by solid-state reaction. The photoluminescence excitation spectra ranging from 300 to 450 nm and 460 to 500 nm broadly are observed. Direct full-color warm white light [(x, y) = 0.3221, 0.3525] was realized in this single-phase phosphor with exposure to 380 nm UV light. When this phosphor is pumped by 466 nm radiation we obtained yellow emission with an intense red component, suggesting that this material is also competitive as a blue-pumped yellow phosphor. Thus two approaches to white light are realized simultaneously in Sm3+ doped single-component phosphor for the first time. The quantum yield and the reliability of the as-synthesized phosphors for White LED applications were also investigated.

© 2014 Optical Society of America

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  1. H. A. Höppe, “Recent developments in the field of inorganic phosphors,” Angew. Chem. Int. Ed. Engl. 48(20), 3572–3582 (2009).
    [Crossref] [PubMed]
  2. Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
    [Crossref]
  3. R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7-8), 588–600 (2007).
    [Crossref]
  4. H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
    [Crossref]
  5. J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
    [Crossref]
  6. A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
    [Crossref]
  7. X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
    [Crossref]
  8. X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
    [Crossref]
  9. Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
    [Crossref]
  10. B. Liu, L. J. Kong, and C. S. Shi, “White-light long-lasting phosphor Sr2MgSi2O7: Dy3+,” J. Lumin. 122–123, 121–124 (2007).
    [Crossref]
  11. L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
    [Crossref]
  12. G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
    [Crossref]
  13. Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
    [Crossref]
  14. Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
    [Crossref]
  15. S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
    [Crossref]
  16. L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
    [Crossref]
  17. S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
    [Crossref]
  18. Z. G. Xia and D. M. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc. 93, 1397–1401 (2010).
  19. R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
    [Crossref] [PubMed]

2013 (2)

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

2012 (3)

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
[Crossref]

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

2011 (2)

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
[Crossref]

2010 (2)

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

Z. G. Xia and D. M. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc. 93, 1397–1401 (2010).

2009 (2)

G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
[Crossref]

H. A. Höppe, “Recent developments in the field of inorganic phosphors,” Angew. Chem. Int. Ed. Engl. 48(20), 3572–3582 (2009).
[Crossref] [PubMed]

2008 (4)

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
[Crossref]

2007 (4)

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7-8), 588–600 (2007).
[Crossref]

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

B. Liu, L. J. Kong, and C. S. Shi, “White-light long-lasting phosphor Sr2MgSi2O7: Dy3+,” J. Lumin. 122–123, 121–124 (2007).
[Crossref]

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

Ahn, H. W.

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

Carlos, L. D.

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Chen, D. M.

Z. G. Xia and D. M. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc. 93, 1397–1401 (2010).

Chen, H. Q.

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

Dong, X. P.

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

Ferreira, R. A.

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Gong, M. L.

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

Guo, N.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Han, G. C.

G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
[Crossref]

Han, P. D.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

Han, Y.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

Hannah, M. E.

A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
[Crossref]

Hao, Z. D.

Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
[Crossref]

Happek, U.

A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
[Crossref]

He, Z. X.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Heward, W. J.

A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
[Crossref]

Hintzen, H. T.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Hirosaki, N.

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7-8), 588–600 (2007).
[Crossref]

Höppe, H. A.

H. A. Höppe, “Recent developments in the field of inorganic phosphors,” Angew. Chem. Int. Ed. Engl. 48(20), 3572–3582 (2009).
[Crossref] [PubMed]

Hou, W. G.

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

Huang, Y. J.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Im, W. B.

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

Jang, H. S.

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

Jeon, D. Y.

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

Jia, Y. C.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Jing, X. P.

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

Kim, J. S.

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

Kim, S. S.

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

Kong, L. J.

B. Liu, L. J. Kong, and C. S. Shi, “White-light long-lasting phosphor Sr2MgSi2O7: Dy3+,” J. Lumin. 122–123, 121–124 (2007).
[Crossref]

Lee, C. H.

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

Lee, D. C.

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

Lee, J. H.

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

Lee, J. W.

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

Li, W. W.

X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
[Crossref]

Li, Y. J.

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

Liu, B.

B. Liu, L. J. Kong, and C. S. Shi, “White-light long-lasting phosphor Sr2MgSi2O7: Dy3+,” J. Lumin. 122–123, 121–124 (2007).
[Crossref]

Liu, J.

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

Liu, S. Q.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Liu, Y. N.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Liu, Z. S.

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

Longo, R. L.

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Lu, J.

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

Lu, S. Z.

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

Lu, Z.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

Lv, W. Z.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Malta, O. L.

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Mao, Z. Y.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Nolasco, M.

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Qiao, H.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Roma, A. C.

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Setlur, A. A.

A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
[Crossref]

Shi, C. S.

B. Liu, L. J. Kong, and C. S. Shi, “White-light long-lasting phosphor Sr2MgSi2O7: Dy3+,” J. Lumin. 122–123, 121–124 (2007).
[Crossref]

Sun, K.

X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
[Crossref]

Sun, X. Y.

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

Tian, Z. W.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Wang, C. H.

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

Wang, L. X.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

Wang, N. F.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Wang, X. B.

X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
[Crossref]

Wang, X. J.

Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
[Crossref]

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

Wang, Y. H.

G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
[Crossref]

Woo, E. J.

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

Wu, C. F.

G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
[Crossref]

Wu, Z. C.

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

Xia, Z. G.

Z. G. Xia and D. M. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc. 93, 1397–1401 (2010).

Xie, R. J.

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7-8), 588–600 (2007).
[Crossref]

Xu, J.

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

Yan, X. S.

X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
[Crossref]

Yang, H.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

Yang, Z. M.

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

Ye, S.

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

You, H. P.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Yu, D. C.

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

Zeng, H. H.

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

Zhang, J. C.

G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
[Crossref]

Zhang, J. H.

Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
[Crossref]

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

Zhang, L.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

Zhang, Q. T.

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

Zhang, Q. Y.

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

Zhang, X.

Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
[Crossref]

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

Zhao, Q.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Zheng, Y. H.

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

Zhou, N.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Zhou, X. M.

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

Zhou, Z.

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Angew. Chem. Int. Ed. Engl. (1)

H. A. Höppe, “Recent developments in the field of inorganic phosphors,” Angew. Chem. Int. Ed. Engl. 48(20), 3572–3582 (2009).
[Crossref] [PubMed]

Appl. Phys. B (1)

S. Ye, C. H. Wang, Z. S. Liu, J. Lu, and X. P. Jing, “Photoluminescence and energy transfer of phosphor series Ba2-zSrzCaMo1-yWyO6:Eu,Li for white light UVLED applications,” Appl. Phys. B 91(3-4), 551–557 (2008).
[Crossref]

Chem. Mater. (1)

A. A. Setlur, W. J. Heward, M. E. Hannah, and U. Happek, “Incorporation of Si4+-N3- into Ce3+-doped garnets for warm white LED phosphors,” Chem. Mater. 20(19), 6277–6283 (2008).
[Crossref]

Chemistry (1)

R. A. Ferreira, M. Nolasco, A. C. Roma, R. L. Longo, O. L. Malta, and L. D. Carlos, “Dependence of the lifetime upon the excitation energy and intramolecular energy transfer rates: the 5D0Eu(III) emission case,” Chemistry 18(38), 12130–12139 (2012).
[Crossref] [PubMed]

Ind. Eng. Chem. Res. (1)

J. W. Lee, J. H. Lee, E. J. Woo, H. W. Ahn, J. S. Kim, and C. H. Lee, “Synthesis of nanosized Ce3+,Eu3+-codoped YAG phosphor in a continuous supercritical water system,” Ind. Eng. Chem. Res. 47(16), 5994–6000 (2008).
[Crossref]

J. Alloy. Comp. (2)

Z. C. Wu, J. Liu, W. G. Hou, J. Xu, and M. L. Gong, “A new single-host white-light-emitting BaSrMg(PO4)2: Eu2+ phosphor for white-light-emitting diodes,” J. Alloy. Comp. 498(2), 139–142 (2010).
[Crossref]

L. Zhang, P. D. Han, Y. Han, Z. Lu, H. Yang, L. X. Wang, and Q. T. Zhang, “Structure evolution and tunable luminescence of (Sr0.98−mBamEu0.02)2Ca(Mo1−nWn)O6 phosphor with ultraviolet excitation for white LEDs,” J. Alloy. Comp. 558, 229–235 (2013).
[Crossref]

J. Am. Ceram. Soc. (1)

Z. G. Xia and D. M. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc. 93, 1397–1401 (2010).

J. Appl. Phys. (1)

S. Ye, Y. J. Li, D. C. Yu, Z. M. Yang, and Q. Y. Zhang, “Structural effects on Stokes and anti-Stokes luminescence of double-perovskite (Ba,Sr)2CaMoO6: Yb3+,Eu3+,” J. Appl. Phys. 110(1), 013517 (2011).
[Crossref]

J. Electrochem. Soc. (1)

X. S. Yan, W. W. Li, X. B. Wang, and K. Sun, “Facile synthesis of Ce3+, Eu3+ co-doped YAG nanophosphor for white light-emitting diodes,” J. Electrochem. Soc. 159(2), H195–H200 (2012).
[Crossref]

J. Lumin. (3)

X. Y. Sun, J. H. Zhang, X. Zhang, S. Z. Lu, and X. J. Wang, “A white light phosphor suitable for near ultraviolet excitation,” J. Lumin. 122–123, 955–957 (2007).
[Crossref]

B. Liu, L. J. Kong, and C. S. Shi, “White-light long-lasting phosphor Sr2MgSi2O7: Dy3+,” J. Lumin. 122–123, 121–124 (2007).
[Crossref]

H. S. Jang, W. B. Im, D. C. Lee, D. Y. Jeon, and S. S. Kim, “Enhancement of red spectral emission intensity of Y3Al5O12:Ce3+ phosphor via Pr co-doping and Tb substitution for the application to white LEDs,” J. Lumin. 126(2), 371–377 (2007).
[Crossref]

J. Mater. Chem. (1)

Y. C. Jia, Y. J. Huang, Y. H. Zheng, N. Guo, H. Qiao, Q. Zhao, W. Z. Lv, and H. P. You, “Color point tuning of Y3Al5O12:Ce3+ phosphor via Mn2+-Si4+ incorporation for white light generation,” J. Mater. Chem. 22(30), 15146–15152 (2012).
[Crossref]

J. Phys. D Appl. Phys. (1)

Z. Zhou, N. F. Wang, N. Zhou, Z. X. He, S. Q. Liu, Y. N. Liu, Z. W. Tian, Z. Y. Mao, and H. T. Hintzen, “High colour purity single-phased full colour emitting white LED phosphor Sr2V2O7:Eu3+,” J. Phys. D Appl. Phys. 46(3), 035104 (2013).
[Crossref]

Mater. Lett. (1)

L. Zhang, X. M. Zhou, H. H. Zeng, H. Q. Chen, and X. P. Dong, “White-light long-lasting phosphor Sr2SiO4:Pr3+,” Mater. Lett. 62(16), 2539–2541 (2008).
[Crossref]

Mater. Res. Bull. (1)

G. C. Han, Y. H. Wang, C. F. Wu, and J. C. Zhang, “Hydrothermal synthesis and vacuum ultraviolet-excited luminescence properties of novel Dy3+-doped LaPO4 white light phosphors,” Mater. Res. Bull. 44(12), 2255–2257 (2009).
[Crossref]

Opt. Mater. (1)

Z. D. Hao, J. H. Zhang, X. Zhang, and X. J. Wang, “CaSc2O4:Eu3+: A tunable full-color emitting phosphor for white light emitting diodes,” Opt. Mater. 33(3), 355–358 (2011).
[Crossref]

Sci. Technol. Adv. Mater. (1)

R. J. Xie and N. Hirosaki, “Silicon-based oxynitride and nitride phosphors for white LEDs-A review,” Sci. Technol. Adv. Mater. 8(7-8), 588–600 (2007).
[Crossref]

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Figures (4)

Fig. 1
Fig. 1 XRD pattern of Sr2Ca0.995MoO6: Sm3+0.005 and Sr2CaMoO6 standard pattern. The inset shows its crystal structure.
Fig. 2
Fig. 2 [(a) and (b)] The PLE and PL spectra of Sr2Ca0.995MoO6: Sm3+0.005 and PL spectrum of Sr2CaMoO6. (c) The chromaticity coordinates of Sr2Ca0.995MoO6: Sm3+0.005 under 380 and 466 nm excitation.
Fig. 3
Fig. 3 The PL spectra of Sr2Ca0.995MoO6: Sm3+0.005 at different temperatures from 303 to 473 K under 466 nm excitation.
Fig. 4
Fig. 4 The PL decay curve of Sr2Ca0.995MoO6: Sm3+0.005.

Equations (3)

Equations on this page are rendered with MathJax. Learn more.

I ( t ) = I 0 + A exp ( t / τ )
I ( t ) = I 0 + A 1 exp ( t / τ 1 ) + A 2 exp ( t / τ 2 )
τ = ( A 1 τ 1 2 + A 2 τ 2 2 ) / ( A 1 τ 1 + A 2 τ 2 )

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