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Multi-resonant absorption in ultra-thin silicon solar cells with metallic nanowires

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Abstract

We propose a design to confine light absorption in flat and ultra-thin amorphous silicon solar cells with a one-dimensional silver grating embedded in the front window of the cell. We show numerically that multi-resonant light trapping is achieved in both TE and TM polarizations. Each resonance is analyzed in detail and modeled by Fabry-Perot resonances or guided modes via grating coupling. This approach is generalized to a complete amorphous silicon solar cell, with the additional degrees of freedom provided by the buffer layers. These results could guide the design of resonant structures for optimized ultra-thin solar cells.

© 2013 Optical Society of America

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Figures (6)

Fig. 1
Fig. 1 (a) Schematic of the simplified structure made of a ZnO:Al/a-Si:H/Ag stack. A 1D silver grating (width w, pitch p, metal thickness hm) is deposited on the a-Si:H layer (thickness hs) and embedded in a ZnO:Al anti-reflection coating layer (thickness h1). (b) Spectra of the numerically computed total absorption of the reference structure under TM (orange) and TE (green) polarized light at normal incidence. The parameters of the metallic grating are p=200 nm, w=80 nm and hm=20 nm. The total absorption spectrum of a planar ZnO:Al (50 nm)/a-Si:H (90 nm)/Ag structure is shown with the black dashed curve for the sake of comparison.
Fig. 2
Fig. 2 Study of the short wavelengths resonances (AE) (TE) and (AM) (TM). (a) Sketch of the asymmetric Fabry-Perot resonator model used to fit the numerical calculations. The influence of the metallic grating is neglected. ϕ1 and ϕ2 are the phase shifts induced by reflection at the ZnO:Al/Air and ZnO:Al/a-Si:H interfaces. (b, c) Total light absorption spectrum in the simplified structure depicted in Fig. 1 as a function of the wavelength and the ZnO:Al layer thickness h1. Excitation at normal incidence light in (b) TE and (c) TM polarizations. The position of the absorption bands with low dependence on h1 can be attributed to resonances BE, CE, BM and CM as shown with orange dashed lines. The resonance position h1 = f(λ) given by the Fabry-Perot model (Eq.(1)) is shown with black dashed curves for q = 0, 1.
Fig. 3
Fig. 3 Study of the resonances (BE) (TE) and (BM) (TM).(a) Sketch of the asymmetric Fabry-Perot resonator model used to fit the numerical calculations. The influence of the metallic grating is neglected. ϕ1 and ϕ2 are the phase shifts induced by reflection at the a-Si:H/ZnO:Al and a-Si:H/Ag interfaces. (b, c) Total light absorption spectrum in the simplified structure depicted in Fig. 1 as a function of the wavelength and the absorber layer thickness hs. Excitation at normal incidence light in (b) TE and (c) TM polarizations. The resonance position hs = f(λ) given by the Fabry-Perot model (Eq.(1)) with h1 = hs and n1 = ns, is shown in black dashed lines for q = 0, 1, 2, 3. (d,e) Electric field intensity maps for a 1D silver grating with w= 80 nm, p= 200 nm, hm= 20 nm for an excitation at (d) λBE = 631 nm under TE polarized light and (e) λBM = 649 nm under TM polarized light.
Fig. 4
Fig. 4 Study of the long wavelength (CE) resonance for TE polarization. (a) Total light absorption spectrum as a function of the wavelength and the angle of incidence (plane of incidence perpendicular to the wires). (b) Total light absorption spectrum as a function of the wavelength and the grating period at normal incidence. The absorption bands attributed to resonances AE and BE are shown in orange dashed lines in Figs. 4 (a) and (b). (c) Electric field intensity map for an excitation at λCE = 687 nm for a TE polarization at normal incidence.
Fig. 5
Fig. 5 Numerically computed optical absorption in each material of an ultra-thin a-Si:H solar cell for an excitation under TE (a, left) and TM (b, right) polarizations at normal incidence (red curve: absorption only in a-Si:H; blue curve: absorption in a-Si:H and the ITO and ZnO:Al spacing layers; grey curve: total absorption). The bandgap of amorphous silicon is shown in grey. Inset of Fig. (a): Sketch of the structure investigated: solar cell made of a Si3N4(Ag)/ITO/a-Si:H/ZnO:Al/Ag stack with a 90 nm-thick p-i-n a-Si:H absorber layer. A 1D silver grating (thickness=20 nm, width=80 nm and period=200 nm) is embedded in the front Si3N4 layer. Other geometrical parameters are hSi3N4 =60 nm, hITO=10 nm, hZnO:Al=15 nm.
Fig. 6
Fig. 6 (a) Evolution of the absorption in the a-Si:H layer for the complete cell as a function of the ZnO:Al layer thickness hAZO for a TM polarized light at normal incidence. (b, c) Electric field intensity maps for an excitation at λCM = 770 nm (simplified structure)(b) and λG= 709 nm (complete cell)(c) at normal incidence for a TM polarization.

Tables (1)

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Table 1 Influence of the geometrical parameters of the structure shown in the inset of Fig. 5(a).

Equations (2)

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h 1 = λ 2 n 1 ( q φ 2 π )
2 π λ C E Re ( n eff ) = | 2 π λ C E sin θ + m 2 π p |
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