Abstract

Oxyfluoride glasses containing Ag species and rare earth (RE) ions (Dy3+, Sm3+, Tb3+) were prepared by melt-quenching technique. The type of luminescent species of novel excitation band (230-300 nm peaked at 255 nm) and emission band (300-600 nm peaked at 350 nm) were investigated by absorption, excitation, emission spectra, as well as decay lifetime measurements and can be ascribed to isolated Ag+ ions. Owing to energy transfer from Ag+ to RE ions, significant enhancements of RE ions emission (76 times for Sm3+, 41 times for Dy3+) were observed for non-resonant UV excitation (255 nm). Our research may extend the understanding of interactions between RE ions and Ag species.

© 2012 OSA

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  2. F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
    [PubMed]
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  4. D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).
  5. G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).
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    [PubMed]
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  11. Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).
  12. M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater. 19, 2045–2052 (2009).
  13. M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
    [PubMed]
  14. H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).
  15. H. Guo, X. Wang, J. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express 18(18), 18900–18905 (2010).
    [PubMed]
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    [PubMed]
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  18. E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).
  19. S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).
  20. A. Meijerink, M. van Heek, and G. Blasse, “Luminescence of Ag+ in crystalline and glassy SrB4O7,” J. Phys. Chem. Solids 54, 901–906 (1993).

2012 (2)

R. Wei, H. Zhang, F. Li, and H. Guo, “Blue-White-Green Tunable Luminescence of Ce3+, Tb3+ Co-Doped Sodium Silicate Glasses for White LEDs,” J. Am. Ceram. Soc. 95, 34–36 (2012).

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

2011 (5)

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem. 21, 3156–3161 (2011).

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

2010 (3)

2009 (1)

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater. 19, 2045–2052 (2009).

2008 (1)

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

2007 (1)

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

2005 (1)

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

2003 (1)

S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).

2000 (1)

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

1999 (1)

T. Hayakawa, S. Selvan, and M. Nogami, “Field enhancement effect of small Ag particles on the fluorescence from Eu3+-doped SiO2 glass,” Appl. Phys. Lett. 74, 1513–1515 (1999).

1993 (1)

A. Meijerink, M. van Heek, and G. Blasse, “Luminescence of Ag+ in crystalline and glassy SrB4O7,” J. Phys. Chem. Solids 54, 901–906 (1993).

1985 (1)

O. Malta, P. Santa-Cruz, G. De Sá, and F. Auzel, “Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials,” J. Lumin. 33, 261–272 (1985).

Auzel, F.

O. Malta, P. Santa-Cruz, G. De Sá, and F. Auzel, “Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials,” J. Lumin. 33, 261–272 (1985).

Battaglin, G.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Blasse, G.

A. Meijerink, M. van Heek, and G. Blasse, “Luminescence of Ag+ in crystalline and glassy SrB4O7,” J. Phys. Chem. Solids 54, 901–906 (1993).

Borsella, E.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Chen, D.

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Chen, F.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Chen, J.

Chen, X.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Cruz, P.

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

Dai, S.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Dai, Y.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

De Araújo, C.

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

De Sá, G.

O. Malta, P. Santa-Cruz, G. De Sá, and F. Auzel, “Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials,” J. Lumin. 33, 261–272 (1985).

Deng, R.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Eichelbaum, M.

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater. 19, 2045–2052 (2009).

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Gao, G.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem. 21, 3156–3161 (2011).

García, M.

S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).

García, M. A.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Gonella, F.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Guo, H.

R. Wei, H. Zhang, F. Li, and H. Guo, “Blue-White-Green Tunable Luminescence of Ce3+, Tb3+ Co-Doped Sodium Silicate Glasses for White LEDs,” J. Am. Ceram. Soc. 95, 34–36 (2012).

H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).

H. Guo, H. Zhang, J. Li, and F. Li, “Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light,” Opt. Express 18(26), 27257–27262 (2010).
[PubMed]

H. Guo, X. Wang, J. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express 18(18), 18900–18905 (2010).
[PubMed]

Han, Y.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Hayakawa, T.

T. Hayakawa, S. Selvan, and M. Nogami, “Field enhancement effect of small Ag particles on the fluorescence from Eu3+-doped SiO2 glass,” Appl. Phys. Lett. 74, 1513–1515 (1999).

Hoell, A.

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Hu, X.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Huang, F.

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

Jiang, X.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Jung, H.

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

Kassab, L.

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

Kirilenko, D.

Kuznetsov, A.

Li, F.

R. Wei, H. Zhang, F. Li, and H. Guo, “Blue-White-Green Tunable Luminescence of Ce3+, Tb3+ Co-Doped Sodium Silicate Glasses for White LEDs,” J. Am. Ceram. Soc. 95, 34–36 (2012).

H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).

H. Guo, H. Zhang, J. Li, and F. Li, “Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light,” Opt. Express 18(26), 27257–27262 (2010).
[PubMed]

H. Guo, X. Wang, J. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express 18(18), 18900–18905 (2010).
[PubMed]

Li, J.

H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).

H. Guo, H. Zhang, J. Li, and F. Li, “Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light,” Opt. Express 18(26), 27257–27262 (2010).
[PubMed]

Lin, C.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Liu, X.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Llopis, J.

S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).

Malta, O.

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

O. Malta, P. Santa-Cruz, G. De Sá, and F. Auzel, “Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials,” J. Lumin. 33, 261–272 (1985).

Mazzoldi, P.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Meijerink, A.

A. Meijerink, M. van Heek, and G. Blasse, “Luminescence of Ag+ in crystalline and glassy SrB4O7,” J. Phys. Chem. Solids 54, 901–906 (1993).

Moon, B.

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

Moshchalkov, V. V.

Naranjo, L.

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

Nie, Q.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Nogami, M.

T. Hayakawa, S. Selvan, and M. Nogami, “Field enhancement effect of small Ag particles on the fluorescence from Eu3+-doped SiO2 glass,” Appl. Phys. Lett. 74, 1513–1515 (1999).

Pacchioni, G.

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Paje, S.

S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).

Park, J.

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

Peng, M.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem. 21, 3156–3161 (2011).

Polloni, R.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Qiu, J.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Quaranta, A.

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Rademann, K.

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater. 19, 2045–2052 (2009).

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Reibstein, S.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem. 21, 3156–3161 (2011).

Rodríguez, V. D.

Santa-Cruz, P.

O. Malta, P. Santa-Cruz, G. De Sá, and F. Auzel, “Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials,” J. Lumin. 33, 261–272 (1985).

Seeta Rama Raju, G.

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

Selvan, S.

T. Hayakawa, S. Selvan, and M. Nogami, “Field enhancement effect of small Ag particles on the fluorescence from Eu3+-doped SiO2 glass,” Appl. Phys. Lett. 74, 1513–1515 (1999).

Shen, X.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Stößer, R.

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Tatchev, D. M.

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Tikhomirov, V. K.

van Heek, M.

A. Meijerink, M. van Heek, and G. Blasse, “Luminescence of Ag+ in crystalline and glassy SrB4O7,” J. Phys. Chem. Solids 54, 901–906 (1993).

Van Tendeloo, G.

Villegas, M.

S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).

Wang, C.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Wang, F.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Wang, J.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Wang, Q.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Wang, X.

Wang, Y.

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

Wei, R.

R. Wei, H. Zhang, F. Li, and H. Guo, “Blue-White-Green Tunable Luminescence of Ce3+, Tb3+ Co-Doped Sodium Silicate Glasses for White LEDs,” J. Am. Ceram. Soc. 95, 34–36 (2012).

Weigel, W.

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Wondraczek, L.

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem. 21, 3156–3161 (2011).

Wu, Y.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Xu, T.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Xu, Y.

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

Yang, A.

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

Yu, B.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Yu, J.

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

Yu, Y.

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

Zhang, H.

R. Wei, H. Zhang, F. Li, and H. Guo, “Blue-White-Green Tunable Luminescence of Ce3+, Tb3+ Co-Doped Sodium Silicate Glasses for White LEDs,” J. Am. Ceram. Soc. 95, 34–36 (2012).

H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).

H. Guo, H. Zhang, J. Li, and F. Li, “Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light,” Opt. Express 18(26), 27257–27262 (2010).
[PubMed]

Zhu, C.

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

Zhu, H.

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Adv. Funct. Mater. (1)

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater. 19, 2045–2052 (2009).

Appl. Phys. Lett. (2)

L. Naranjo, C. De Araújo, O. Malta, P. Cruz, and L. Kassab, “Enhancement of Pr3+ luminescence in PbO-GeO2 glasses containing silver nanoparticles,” Appl. Phys. Lett. 87, 241914 (2005).

T. Hayakawa, S. Selvan, and M. Nogami, “Field enhancement effect of small Ag particles on the fluorescence from Eu3+-doped SiO2 glass,” Appl. Phys. Lett. 74, 1513–1515 (1999).

Appl.Phys. A. (1)

E. Borsella, G. Battaglin, M. A. García, F. Gonella, P. Mazzoldi, R. Polloni, and A. Quaranta, “Structural incorporation of silver in soda-lime glass by the ion-exchange process: a photoluminescence spectroscopy study,” Appl.Phys. A. 71, 125–132 (2000).

Chem. Phys. Lett. (1)

Y. Dai, X. Hu, C. Wang, D. Chen, X. Jiang, C. Zhu, B. Yu, and J. Qiu, “Fluorescent Ag nanoclusters in glass induced by an infrared femtosecond laser,” Chem. Phys. Lett. 439, 81–84 (2007).

J. Am. Ceram. Soc. (2)

G. Seeta Rama Raju, J. Yu, J. Park, H. Jung, and B. Moon, “Photoluminescence and cathodoluminescence properties of nanocrystalline Ca2Gd8Si6O26:Sm3+ phosphors,” J. Am. Ceram. Soc. 95, 238–242 (2012).

R. Wei, H. Zhang, F. Li, and H. Guo, “Blue-White-Green Tunable Luminescence of Ce3+, Tb3+ Co-Doped Sodium Silicate Glasses for White LEDs,” J. Am. Ceram. Soc. 95, 34–36 (2012).

J. Electrochem. Soc. (1)

H. Guo, J. Li, F. Li, and H. Zhang, “Origin of white luminescence in Ag-Eu Co-doped oxyfluoride glasses,” J. Electrochem. Soc. 158, J165–J168 (2011).

J. Lumin. (1)

O. Malta, P. Santa-Cruz, G. De Sá, and F. Auzel, “Fluorescence enhancement induced by the presence of small silver particles in Eu3+ doped materials,” J. Lumin. 33, 261–272 (1985).

J. Mater. Chem. (2)

G. Gao, S. Reibstein, M. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem. 21, 3156–3161 (2011).

D. Chen, Y. Yu, F. Huang, A. Yang, and Y. Wang, “Lanthanide activator doped NaYb1-xGdxF4 nanocrystals with tunable down-, up-conversion luminescence and paramagnetic properties,” J. Mater. Chem. 21, 6186–6192 (2011).

J. Non-Cryst. Solids (1)

S. Paje, M. García, J. Llopis, and M. Villegas, “Optical spectroscopy of silver ion-exchanged As-doped glass,” J. Non-Cryst. Solids 318, 239–247 (2003).

J. Phys. Chem. C (1)

Y. Wu, X. Shen, S. Dai, Y. Xu, F. Chen, C. Lin, T. Xu, and Q. Nie, “Silver Nanoparticles Enhanced Upconversion Luminescence in Er3+/Yb3+ Codoped Bismuth-Germanate Glasses,” J. Phys. Chem. C 115, 25040–25045 (2011).

J. Phys. Chem. Solids (1)

A. Meijerink, M. van Heek, and G. Blasse, “Luminescence of Ag+ in crystalline and glassy SrB4O7,” J. Phys. Chem. Solids 54, 901–906 (1993).

Nanotechnology (1)

M. Eichelbaum, K. Rademann, A. Hoell, D. M. Tatchev, W. Weigel, R. Stößer, and G. Pacchioni, “Photoluminescence of atomic gold and silver particles in soda-lime silicate glasses,” Nanotechnology 19(13), 135701 (2008).
[PubMed]

Nat. Mater. (1)

F. Wang, R. Deng, J. Wang, Q. Wang, Y. Han, H. Zhu, X. Chen, and X. Liu, “Tuning upconversion through energy migration in core-shell nanoparticles,” Nat. Mater. 10(12), 968–973 (2011).
[PubMed]

Opt. Express (3)

Other (1)

G. Blasse and B. C. Grabmaier, Luminescent Marerials (Springer, 1994).

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Figures (5)

Fig. 1
Fig. 1

Transmittance spectra of GAg, GDyAg, GSmAg and GTbAg.

Fig. 2
Fig. 2

(color online) Excitation and emission spectra of (a) GDy and GDyAg; (b) GSm and GSmAg; (c) GTb and GTbAg; (d) GAg.

Fig. 3
Fig. 3

Decay curves of 601 nm emission excited by 402 nm (I) and 255 nm (II) light for GSmAg; decay curve of 350 nm emission (λex = 255 nm) for GAg (III).

Fig. 4
Fig. 4

Energy level diagram and energy transfer process.

Fig. 5
Fig. 5

(color online) (a) Emission spectra of GTbSmAg (λex = 255 nm); (b) CIE chromaticity diagram related to white light emission of GDyAg and GTbSmAg (λex = 255 nm).

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