Abstract

The luminescent properties of novel Cu+, Sm3+ single- and co-doped borosilicate glasses were systematically investigated by absorption, excitation, emission spectra and decay curves. Cu+ single-doped glasses emit broad luminescence band covering all the visible range. And their peaks shift to blue with decreasing excitation wavelength from 330 to 280 nm. Cu+, Sm3+ co-doped samples generate the varied hues from blue white to pure white and eventually to yellow white due to an efficient energy transfer from Cu+ to Sm3+. Our research indicates the potential application of Cu+, Sm3+ co-doped borosilicate glasses as converting phosphors for white LEDs pumped by UV LED chips.

© 2012 OSA

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2012 (4)

2011 (6)

Y. Yu, Z. Liu, N. Dai, Y. Sheng, H. Luan, J. Peng, Z. Jiang, H. Li, J. Li, and L. Yang, “Ce-Tb-Mn co-doped white light emitting glasses suitable for long-wavelength UV excitation,” Opt. Express19(20), 19473–19479 (2011).
[CrossRef] [PubMed]

G. J. Gao, S. Reibstein, M. Y. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem.21(9), 3156–3161 (2011).
[CrossRef]

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

P. F. Smet, A. B. Parmentier, and D. Poelman, “Selecting Conversion Phosphors for White Light-Emitting Diodes,” J. Electrochem. Soc.158(6), R37–R54 (2011).
[CrossRef]

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

C. H. Huang and T. M. Chen, “A novel single-composition trichromatic white-light Ca3Y(GaO)3(BO3)4:Ce3+, Mn2+, Tb3+ phosphor for UV-light emitting diodes,” J. Phys. Chem. C115(5), 2349–2355 (2011).
[CrossRef]

2010 (6)

Z. Xia and D. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc.93, 1397–1401 (2010).

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

C. H. Huang, W. R. Liu, and T. M. Chen, “Single-phased white-light phosphors Ca9Gd(PO4)7:Eu2+, Mn2+ under near-ultraviolet excitation,” J. Phys. Chem. C114(43), 18698–18701 (2010).
[CrossRef]

H. Guo, X. Wang, J. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express18(18), 18900–18905 (2010).
[CrossRef] [PubMed]

V. K. Tikhomirov, V. D. Rodríguez, A. Kuznetsov, D. Kirilenko, G. Van Tendeloo, and V. V. Moshchalkov, “Preparation and luminescence of bulk oxyfluoride glasses doped with Ag nanoclusters,” Opt. Express18(21), 22032–22040 (2010).
[CrossRef] [PubMed]

H. Guo, H. Zhang, J. J. Li, and F. Li, “Blue-white-green tunable luminescence from Ba2Gd2Si4O13:Ce3+,Tb3+ phosphors excited by ultraviolet light,” Opt. Express18(26), 27257–27262 (2010).
[CrossRef] [PubMed]

2009 (6)

D. Chen, Y. Yu, H. Lin, P. Huang, F. Weng, Z. Shan, and Y. Wang, “CeF3-based glass ceramic: A potential luminescent host for white-light-emitting diode,” Opt. Lett.34(19), 2882–2884 (2009).
[CrossRef] [PubMed]

X. F. Liu, Y. Teng, Y. X. Zhuang, J. H. Xie, Y. B. Qiao, G. P. Dong, D. P. Chen, and J. R. Qiu, “Broadband conversion of visible light to near-infrared emission by Ce3+, Yb3+-codoped yttrium aluminum garnet,” Opt. Lett.34(22), 3565–3567 (2009).
[CrossRef] [PubMed]

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater.19(13), 2045–2052 (2009).
[CrossRef]

2007 (1)

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

2005 (1)

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

1999 (1)

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

1991 (1)

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

1989 (1)

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, “Optical spectroscopy of copper(I)-doped Na+-β″-alumina,” J. Phys. Chem.93(10), 3958–3963 (1989).
[CrossRef]

Barrie, J. D.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, “Optical spectroscopy of copper(I)-doped Na+-β″-alumina,” J. Phys. Chem.93(10), 3958–3963 (1989).
[CrossRef]

Boutinaud, P.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Chayahara, A.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Chen, D.

Z. Xia and D. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc.93, 1397–1401 (2010).

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

D. Chen, Y. Yu, H. Lin, P. Huang, F. Weng, Z. Shan, and Y. Wang, “CeF3-based glass ceramic: A potential luminescent host for white-light-emitting diode,” Opt. Lett.34(19), 2882–2884 (2009).
[CrossRef] [PubMed]

Chen, D. P.

Chen, G.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Chen, J.

Chen, Q.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Chen, S.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

Chen, T. M.

C. H. Huang and T. M. Chen, “A novel single-composition trichromatic white-light Ca3Y(GaO)3(BO3)4:Ce3+, Mn2+, Tb3+ phosphor for UV-light emitting diodes,” J. Phys. Chem. C115(5), 2349–2355 (2011).
[CrossRef]

C. H. Huang, W. R. Liu, and T. M. Chen, “Single-phased white-light phosphors Ca9Gd(PO4)7:Eu2+, Mn2+ under near-ultraviolet excitation,” J. Phys. Chem. C114(43), 18698–18701 (2010).
[CrossRef]

Cheng, Z.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

Cheng, Z. Y.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

Chibotaru, L. F.

Cuong, N. T.

Dai, N.

Dong, G.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Dong, G. P.

Duloisy, E.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Dunn, B.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, “Optical spectroscopy of copper(I)-doped Na+-β″-alumina,” J. Phys. Chem.93(10), 3958–3963 (1989).
[CrossRef]

Eichelbaum, M.

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater.19(13), 2045–2052 (2009).
[CrossRef]

Fujii, K.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Fukumi, K.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Gao, G. J.

G. J. Gao, S. Reibstein, M. Y. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem.21(9), 3156–3161 (2011).
[CrossRef]

Geng, D.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

Geng, D. L.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

Guo, H.

Guo, N.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Hayakaya, J.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Hollingsworth, G.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, “Optical spectroscopy of copper(I)-doped Na+-β″-alumina,” J. Phys. Chem.93(10), 3958–3963 (1989).
[CrossRef]

Horino, Y.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Huang, C. H.

C. H. Huang and T. M. Chen, “A novel single-composition trichromatic white-light Ca3Y(GaO)3(BO3)4:Ce3+, Mn2+, Tb3+ phosphor for UV-light emitting diodes,” J. Phys. Chem. C115(5), 2349–2355 (2011).
[CrossRef]

C. H. Huang, W. R. Liu, and T. M. Chen, “Single-phased white-light phosphors Ca9Gd(PO4)7:Eu2+, Mn2+ under near-ultraviolet excitation,” J. Phys. Chem. C114(43), 18698–18701 (2010).
[CrossRef]

Huang, P.

Huang, Y. J.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Iskandar, F.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

Jiang, Z.

Kaihatsu, Y.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

Kim, J. K.

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

Kirilenko, D.

Kitamura, N.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Kuznetsov, A.

Kuznetsov, A. S.

Lakshminarayana, G.

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

Le Flem, G.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Li, F.

Li, G.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

Li, G. G.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

Li, H.

Li, J.

Y. Yu, Z. Liu, N. Dai, Y. Sheng, H. Luan, J. Peng, Z. Jiang, H. Li, J. Li, and L. Yang, “Ce-Tb-Mn co-doped white light emitting glasses suitable for long-wavelength UV excitation,” Opt. Express19(20), 19473–19479 (2011).
[CrossRef] [PubMed]

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

Li, J. J.

Liang, X.

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Lin, H.

Lin, J.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

Liu, K.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Liu, W. R.

C. H. Huang, W. R. Liu, and T. M. Chen, “Single-phased white-light phosphors Ca9Gd(PO4)7:Eu2+, Mn2+ under near-ultraviolet excitation,” J. Phys. Chem. C114(43), 18698–18701 (2010).
[CrossRef]

Liu, X.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Liu, X. F.

Liu, X. Y.

Liu, Z.

Luan, H.

Makihara, M.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Moine, B.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Moshchalkov, V. V.

Nguyen, M. T.

Ogi, T.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

Ohno, N.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Ohora, K.

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Okuyama, K.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

Parent, C.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Parmentier, A. B.

P. F. Smet, A. B. Parmentier, and D. Poelman, “Selecting Conversion Phosphors for White Light-Emitting Diodes,” J. Electrochem. Soc.158(6), R37–R54 (2011).
[CrossRef]

Pedrini, C.

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Peng, C.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

Peng, J.

Peng, M. Y.

G. J. Gao, S. Reibstein, M. Y. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem.21(9), 3156–3161 (2011).
[CrossRef]

Poelman, D.

P. F. Smet, A. B. Parmentier, and D. Poelman, “Selecting Conversion Phosphors for White Light-Emitting Diodes,” J. Electrochem. Soc.158(6), R37–R54 (2011).
[CrossRef]

Pring, A.

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Qiao, Y. B.

Qiu, J.

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Qiu, J. R.

Rademann, K.

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater.19(13), 2045–2052 (2009).
[CrossRef]

Reibstein, S.

G. J. Gao, S. Reibstein, M. Y. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem.21(9), 3156–3161 (2011).
[CrossRef]

Rodríguez, V. D.

Schubert, E. F.

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

Shan, Z.

Shang, M.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

Shang, M. M.

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

Sheng, J.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

Sheng, Y.

Smet, P. F.

P. F. Smet, A. B. Parmentier, and D. Poelman, “Selecting Conversion Phosphors for White Light-Emitting Diodes,” J. Electrochem. Soc.158(6), R37–R54 (2011).
[CrossRef]

Song, Y. H.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Teng, Y.

X. F. Liu, Y. Teng, Y. X. Zhuang, J. H. Xie, Y. B. Qiao, G. P. Dong, D. P. Chen, and J. R. Qiu, “Broadband conversion of visible light to near-infrared emission by Ce3+, Yb3+-codoped yttrium aluminum garnet,” Opt. Lett.34(22), 3565–3567 (2009).
[CrossRef] [PubMed]

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

Tikhomirov, V. K.

Van Tendeloo, G.

Velázquez, J. J.

Wang, W. N.

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

Wang, X.

Wang, Y.

Wei, R. F.

Weng, F.

Wondraczek, L.

G. J. Gao, S. Reibstein, M. Y. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem.21(9), 3156–3161 (2011).
[CrossRef]

Xia, F.

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Xia, Z.

Z. Xia and D. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc.93, 1397–1401 (2010).

Xie, J. H.

Yang, D.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

Yang, H.

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

Yang, L.

Yang, M.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Yang, Y.

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

You, H. P.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Yu, J.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

Yu, Y.

Yuan, S.

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Zhang, G.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Zhang, H.

Zhang, H. J.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Zhang, J.

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

Zhang, Q.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Zhang, Y.

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

Zheng, Y. H.

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

Zhou, Q.

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Zhou, S.

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

Zhu, C.

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Zhuang, Y. X.

Zink, J. I.

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, “Optical spectroscopy of copper(I)-doped Na+-β″-alumina,” J. Phys. Chem.93(10), 3958–3963 (1989).
[CrossRef]

Adv. Funct. Mater. (1)

M. Eichelbaum and K. Rademann, “Plasmonic enhancement or energy transfer? on the luminescence of gold-, silver-, and lanthanide-doped silicate glasses and its potential for light-emitting devices,” Adv. Funct. Mater.19(13), 2045–2052 (2009).
[CrossRef]

Appl. Phys. Lett. (1)

X. Liang, Y. Yang, C. Zhu, S. Yuan, G. Chen, A. Pring, and F. Xia, “Luminescence properties of Tb3+ - Sm3+ codoped glasses for white light emitting diodes,” Appl. Phys. Lett.91(9), 091104 (2007).
[CrossRef]

Chem. Phys. Lett. (1)

Q. Zhang, G. Chen, G. Dong, G. Zhang, X. Liu, J. Qiu, Q. Zhou, Q. Chen, and D. Chen, “The reduction of Cu2+ to Cu+ and optical properties of Cu+ ions in Cu-doped and Cu/Al-codoped high silica glasses sintered in an air atmosphere,” Chem. Phys. Lett.482(4-6), 228–233 (2009).
[CrossRef]

Int. J. Hydrogen Energy (1)

J. Sheng, S. Chen, J. Zhang, J. Li, and J. Yu, “UV-light irradiation induced copper nanoclusters in a silicate glass,” Int. J. Hydrogen Energy34(2), 1119–1122 (2009).
[CrossRef]

J. Am. Ceram. Soc. (1)

Z. Xia and D. Chen, “Synthesis and luminescence properties of BaMoO4:Sm3+ phosphors,” J. Am. Ceram. Soc.93, 1397–1401 (2010).

J. Electrochem. Soc. (1)

P. F. Smet, A. B. Parmentier, and D. Poelman, “Selecting Conversion Phosphors for White Light-Emitting Diodes,” J. Electrochem. Soc.158(6), R37–R54 (2011).
[CrossRef]

J. Mater. Chem. (5)

W. N. Wang, T. Ogi, Y. Kaihatsu, F. Iskandar, and K. Okuyama, “Novel rare-earth-free tunable-color-emitting BCNO phosphors,” J. Mater. Chem.21(14), 5183–5189 (2011).
[CrossRef]

N. Guo, H. P. You, Y. H. Song, M. Yang, K. Liu, Y. H. Zheng, Y. J. Huang, and H. J. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+, Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem.20(41), 9061–9067 (2010).
[CrossRef]

D. Geng, G. Li, M. Shang, D. Yang, Y. Zhang, Z. Cheng, and J. Lin, “Color tuning via energy transfer in Sr3In(PO4)3:Ce3+/Tb3+/Mn2+ phosphors,” J. Mater. Chem.22(28), 14262–14271 (2012).
[CrossRef]

G. G. Li, D. L. Geng, M. M. Shang, C. Peng, Z. Y. Cheng, and J. Lin, “Tunable luminescence of Ce3+/Mn2+ -coactivated Ca2Gd8(SiO4)6O2 through energy transfer and modulation of excitation: potential single-phase white/yellow-emitting phosphors,” J. Mater. Chem.21(35), 13334–13344 (2011).
[CrossRef]

G. J. Gao, S. Reibstein, M. Y. Peng, and L. Wondraczek, “Tunable dual-mode photoluminescence from nanocrystalline Eu-doped Li2ZnSiO4 glass ceramic phosphors,” J. Mater. Chem.21(9), 3156–3161 (2011).
[CrossRef]

J. Mater. Res. (1)

H. Yang, G. Lakshminarayana, Y. Teng, S. Zhou, and J. Qiu, “Tunable luminescence from Sm3+, Ce3+ codoped Al2O3-La2O3-SiO2 glasses for white light emission,” J. Mater. Res.24(05), 1730–1734 (2009).
[CrossRef]

J. Phys. Chem. (1)

J. D. Barrie, B. Dunn, G. Hollingsworth, and J. I. Zink, “Optical spectroscopy of copper(I)-doped Na+-β″-alumina,” J. Phys. Chem.93(10), 3958–3963 (1989).
[CrossRef]

J. Phys. Chem. C (2)

C. H. Huang, W. R. Liu, and T. M. Chen, “Single-phased white-light phosphors Ca9Gd(PO4)7:Eu2+, Mn2+ under near-ultraviolet excitation,” J. Phys. Chem. C114(43), 18698–18701 (2010).
[CrossRef]

C. H. Huang and T. M. Chen, “A novel single-composition trichromatic white-light Ca3Y(GaO)3(BO3)4:Ce3+, Mn2+, Tb3+ phosphor for UV-light emitting diodes,” J. Phys. Chem. C115(5), 2349–2355 (2011).
[CrossRef]

J. Solid State Chem. (1)

P. Boutinaud, E. Duloisy, C. Pedrini, B. Moine, C. Parent, and G. Le Flem, “Fluorescence properties of Cu+ ion in phosphate glasses of the BaLiPO4P2O5 system,” J. Solid State Chem.94(2), 236–243 (1991).
[CrossRef]

Nucl. Instrum. Meth. B. (1)

K. Fukumi, A. Chayahara, K. Ohora, N. Kitamura, Y. Horino, K. Fujii, M. Makihara, J. Hayakaya, and N. Ohno, “Photoluminescence of Cu+-doped silica glass prepared by MeV ion implantation,” Nucl. Instrum. Meth. B.149(1-2), 77–80 (1999).
[CrossRef]

Opt. Express (6)

Opt. Lett. (3)

Science (1)

E. F. Schubert and J. K. Kim, “Solid-state light sources getting smart,” Science308(5726), 1274–1278 (2005).
[CrossRef] [PubMed]

Other (1)

G. Blasse and B. C. Grabmaier, Luminescent Materials (Springer, Berlin, 1994), p. 95.

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Figures (6)

Fig. 1
Fig. 1

Transmission spectra of G-host, GSm2 and GCu2Smy (y = 0, 1, 2, 4, 6) samples.

Fig. 2
Fig. 2

(a) Excitation spectra, (b) emission spectra and (c) decay curves of GCu2 sample.

Fig. 3
Fig. 3

(a) Excitation spectra and (b) emission spectra of GCuy (y = 0.5, 1, 2, 3) samples.

Fig. 4
Fig. 4

(a) The CIE chromaticity diagram corresponding to emission of GCu2 and GCu2Sm2 samples for excitation wavelengths from 280 to 330 nm with 10 nm steps, photos of (b) GCu2 and (c) GCu2Sm2 samples excited by 280, 310 and 330 nm light, respectively.

Fig. 5
Fig. 5

(a) Spectral overlap between excitation of GSm2 and emission of GCu2 samples. (b) Emission spectra (λex = 330) of G-host, GSm2, and GCu2Smy samples (y = 0, 1, 2, 4, 6). (c) Excitation spectra of GSm2, GCu2 and GCu2Sm2 samples. (d) Energy-level diagram of Cu+ and Sm3+ ions and possible ET process.

Fig. 6
Fig. 6

Emission spectra of GCu2Sm2 sample for excitation wavelengths from 280 to 330 nm with 10 nm steps.

Tables (1)

Tables Icon

Table 1 Chromaticity coordinates (x, y) of GCu2 and GCu2Sm2 samples under UV excitation (λex = 280, 290, 300, 310, 320 and 330 nm) and GCu2Smy (y = 1, 4, 6) samples under 330 excitation.

Equations (2)

Equations on this page are rendered with MathJax. Learn more.

τ ¯ = 0 tI(t)dt / 0 I(t)dt
η=1 I S / I S0

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