Abstract

In this study, the optimal condition of a silver (Ag) film deposited on a cover slip for surface plasmon-coupled emission (SPCE) induced two-photon excited fluorescence (TPEF) based on an objective-based, total internal reflection (TIR) microscope was investigated. According to the theoretical simulations of local electric field enhancement and fluorescence coupled emission efficiency, the thickness of the Ag film should be about 40 nm in order to maximize the TPEF collection efficiency by the objective. The deposited Ag film with a germanium seed layer on a cover slip exhibits additional improvement in surface smoothness by reducing variations in surface roughness to below 1.0 nm, thereby reduces local hot spots which degrade the image uniformity. Moreover, an Ag film with a 20 nm-thick SiO2 spacer not only prevents damage caused through interaction with the aqueous solution under high laser power irradiance, but also reduces the fluorescence quenching effect by the Ag film. By optimizing the Ag film thickness, surface smoothness, and a protective dielectric spacer, efficient TIR TPEF imaging can be achieved through SPCE.

© 2011 OSA

Full Article  |  PDF Article
OSA Recommended Articles
Surface plasmon-enhanced and quenched two-photon excited fluorescence

Chun-Yu Lin, Kuo-Chih Chiu, Chia-Yuan Chang, Shih-Hui Chang, Tzung-Fang Guo, and Shean-Jen Chen
Opt. Express 18(12) 12807-12817 (2010)

Fluorescence correlation spectroscopy in surface plasmon coupled emission microscope

J. Borejdo, N. Calander, Z. Gryczynski, and I. Gryczynski
Opt. Express 14(17) 7878-7888 (2006)

Surface plasmon-coupled emission from shaped PMMA films doped with fluorescence molecules

D. G . Zhang, K. J. Moh, and X.-C. Yuan
Opt. Express 18(12) 12185-12190 (2010)

More Recommended Articles

References

  • View by:
  • Article Order
  • |
  • Year
  • |
  • Author
  • |
  • Publication
  1. K. Tawa and W. Knoll, “Mismatching base-pair dependence of the kinetics of DNA-DNA hybridization studied by surface plasmon fluorescence spectroscopy,” Nucleic Acids Res. 32(8), 2372–2377 (2004).
    [Crossref] [PubMed]
  2. F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
    [Crossref] [PubMed]
  3. E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
    [Crossref] [PubMed]
  4. O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
    [Crossref]
  5. H. Raether, Surface Plasmons on Smooth and Rough Surfaces and on Gratings (Springer, 1998).
  6. B. Huang, F. Yu, and R. N. Zare, “Surface plasmon resonance imaging using a high numerical aperture microscope objective,” Anal. Chem. 79(7), 2979–2983 (2007).
    [Crossref] [PubMed]
  7. C.-Y. Lin, K.-C. Chiu, C.-Y. Chang, S.-H. Chang, T.-F. Guo, and S.-J. Chen, “Surface plasmon-enhanced and quenched two-photon excited fluorescence,” Opt. Express 18(12), 12807–12817 (2010).
    [Crossref] [PubMed]
  8. V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
    [Crossref]
  9. L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
    [Crossref] [PubMed]
  10. H.-K. Yuan, U. K. Chettiar, W. Cai, A. V. Kildishev, A. Boltasseva, V. P. Drachev, and V. M. Shalaev, “A negative permeability material at red light,” Opt. Express 15(3), 1076–1083 (2007).
    [Crossref] [PubMed]
  11. Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
    [Crossref]
  12. N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
    [Crossref]
  13. H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
    [Crossref] [PubMed]
  14. A. Kolomenski, A. Kolomenskii, J. Noel, S. Peng, and H. Schuessler, “Propagation length of surface plasmons in a metal film with roughness,” Appl. Opt. 48(30), 5683–5691 (2009).
    [Crossref] [PubMed]
  15. C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
    [Crossref] [PubMed]
  16. J. R. Lakowicz, “Radiative decay engineering: biophysical and biomedical applications,” Anal. Biochem. 298(1), 1–24 (2001).
    [Crossref] [PubMed]
  17. R.-Y. He, Y.-D. Su, K.-C. Cho, C.-Y. Lin, N.-S. Chang, C.-H. Chang, and S.-J. Chen, “Surface plasmon-enhanced two-photon fluorescence microscopy for live cell membrane imaging,” Opt. Express 17(8), 5987–5997 (2009).
    [Crossref] [PubMed]
  18. M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
    [Crossref] [PubMed]
  19. I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
    [Crossref]
  20. K. Ray, M. H. Chowdhury, and J. R. Lakowicz, “Observation of surface plasmon-coupled emission using thin platinum films,” Chem. Phys. Lett. 465(1-3), 92–95 (2008).
    [Crossref]
  21. D. G. Zhang, X.-C. Yuan, and A. Bouhelier, “Direct image of surface-plasmon-coupled emission by leakage radiation microscopy,” Appl. Opt. 49(5), 875–879 (2010).
    [Crossref] [PubMed]
  22. D. G. Zhang, X.-C. Yuan, A. Bouhelier, P. Wang, and H. Ming, “Excitation of surface plasmon polaritons guided mode by Rhodamine B molecules doped in a PMMA stripe,” Opt. Lett. 35(3), 408–410 (2010).
    [Crossref] [PubMed]
  23. W. T. Tang, E. Chung, Y.-H. Kim, P. T. C. So, and C. J. R. Sheppard, “Surface-plasmon-coupled emission microscopy with a spiral phase plate,” Opt. Lett. 35(4), 517–519 (2010).
    [Crossref] [PubMed]
  24. E. D. Palik, Handbook of Optical Constant of Solids (Academic, 1985).
  25. H. Benisty, R. Stanley, and M. Mayer, “Method of source terms for dipole emission modification in modes of arbitrary planar structures,” J. Opt. Soc. Am. A 15(5), 1192–1201 (1998).
    [Crossref]
  26. H. Benisty, H. De Neve, and C. Weisbuch, “Impact of planar microcavity effects on light extraction-Part I: Basic concepts and analytical trends,” IEEE J. Quantum Electron. 34(9), 1612–1631 (1998).
    [Crossref]
  27. E. Fontana and R. H. Pantell, “Characterization of multilayer rough surfaces by use of surface-plasmon spectroscopy,” Phys. Rev. B Condens. Matter 37(7), 3164–3182 (1988).
    [Crossref] [PubMed]
  28. Y.-D. Su, K.-C. Chiu, N.-S. Chang, H.-L. Wu, and S.-J. Chen, “Study of cell-biosubstrate contacts via surface plasmon polariton phase microscopy,” Opt. Express 18(19), 20125–20135 (2010).
    [Crossref] [PubMed]
  29. G. Valette, “Silver-water interactions: Part I. Model of the inner layer at the metal/water interface,” J. Electroanal. Chem. 230(1-2), 189–204 (1987).
    [Crossref]
  30. K. G. Sullivan and D. G. Hall, “Enhancement and inhibition of electromagnetic radiation in plane-layered media. I. Plane-wave spectrum approach to modeling classical effects,” J. Opt. Soc. Am. B 14(5), 1149–1159 (1997).
    [Crossref]
  31. K. G. Sullivan and D. G. Hall, “Enhancement and inhibition of electromagnetic radiation in plane-layered media. II. Enhanced fluorescence in optical waveguide sensors,” J. Opt. Soc. Am. B 14(5), 1160–1166 (1997).
    [Crossref]
  32. D. G. Zhang, K. J. Moh, and X.-C. Yuan, “Surface plasmon-coupled emission from shaped PMMA films doped with fluorescence molecules,” Opt. Express 18(12), 12185–12190 (2010).
    [Crossref] [PubMed]

2010 (7)

2009 (3)

2008 (2)

K. Ray, M. H. Chowdhury, and J. R. Lakowicz, “Observation of surface plasmon-coupled emission using thin platinum films,” Chem. Phys. Lett. 465(1-3), 92–95 (2008).
[Crossref]

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

2007 (2)

H.-K. Yuan, U. K. Chettiar, W. Cai, A. V. Kildishev, A. Boltasseva, V. P. Drachev, and V. M. Shalaev, “A negative permeability material at red light,” Opt. Express 15(3), 1076–1083 (2007).
[Crossref] [PubMed]

B. Huang, F. Yu, and R. N. Zare, “Surface plasmon resonance imaging using a high numerical aperture microscope objective,” Anal. Chem. 79(7), 2979–2983 (2007).
[Crossref] [PubMed]

2006 (1)

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

2005 (4)

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
[Crossref]

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

2004 (3)

K. Tawa and W. Knoll, “Mismatching base-pair dependence of the kinetics of DNA-DNA hybridization studied by surface plasmon fluorescence spectroscopy,” Nucleic Acids Res. 32(8), 2372–2377 (2004).
[Crossref] [PubMed]

F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
[Crossref] [PubMed]

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

2003 (1)

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

2001 (1)

J. R. Lakowicz, “Radiative decay engineering: biophysical and biomedical applications,” Anal. Biochem. 298(1), 1–24 (2001).
[Crossref] [PubMed]

1998 (2)

H. Benisty, R. Stanley, and M. Mayer, “Method of source terms for dipole emission modification in modes of arbitrary planar structures,” J. Opt. Soc. Am. A 15(5), 1192–1201 (1998).
[Crossref]

H. Benisty, H. De Neve, and C. Weisbuch, “Impact of planar microcavity effects on light extraction-Part I: Basic concepts and analytical trends,” IEEE J. Quantum Electron. 34(9), 1612–1631 (1998).
[Crossref]

1997 (2)

1988 (1)

E. Fontana and R. H. Pantell, “Characterization of multilayer rough surfaces by use of surface-plasmon spectroscopy,” Phys. Rev. B Condens. Matter 37(7), 3164–3182 (1988).
[Crossref] [PubMed]

1987 (1)

G. Valette, “Silver-water interactions: Part I. Model of the inner layer at the metal/water interface,” J. Electroanal. Chem. 230(1-2), 189–204 (1987).
[Crossref]

Benisty, H.

H. Benisty, H. De Neve, and C. Weisbuch, “Impact of planar microcavity effects on light extraction-Part I: Basic concepts and analytical trends,” IEEE J. Quantum Electron. 34(9), 1612–1631 (1998).
[Crossref]

H. Benisty, R. Stanley, and M. Mayer, “Method of source terms for dipole emission modification in modes of arbitrary planar structures,” J. Opt. Soc. Am. A 15(5), 1192–1201 (1998).
[Crossref]

Boltasseva, A.

Bouhelier, A.

Brown, D. E.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Cai, W.

Calander, N.

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

Carty, A. J.

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

Chang, C.-H.

Chang, C.-Y.

Chang, N.-S.

Chang, S.-H.

Chaturvedi, P.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Chen, S.-J.

Chettiar, U. K.

Chi, Y.

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

Chiu, K.-C.

Cho, K.-C.

Chou, T.-Y.

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

Chowdhury, M. H.

K. Ray, M. H. Chowdhury, and J. R. Lakowicz, “Observation of surface plasmon-coupled emission using thin platinum films,” Chem. Phys. Lett. 465(1-3), 92–95 (2008).
[Crossref]

Chung, E.

De Neve, H.

H. Benisty, H. De Neve, and C. Weisbuch, “Impact of planar microcavity effects on light extraction-Part I: Basic concepts and analytical trends,” IEEE J. Quantum Electron. 34(9), 1612–1631 (1998).
[Crossref]

Drachev, V. P.

Enderlein, J.

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

Fang, N. X.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Fontana, E.

E. Fontana and R. H. Pantell, “Characterization of multilayer rough surfaces by use of surface-plasmon spectroscopy,” Phys. Rev. B Condens. Matter 37(7), 3164–3182 (1988).
[Crossref] [PubMed]

Geddes, C. D.

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

Goldys, E. M.

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

Gryczynski, I.

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

Gryczynski, Z.

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

Guo, T.-F.

Hall, D. G.

He, R.-Y.

Hiller, J. M.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Hua, J.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Huang, B.

B. Huang, F. Yu, and R. N. Zare, “Surface plasmon resonance imaging using a high numerical aperture microscope objective,” Anal. Chem. 79(7), 2979–2983 (2007).
[Crossref] [PubMed]

Islam, M. S.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Kapaklis, V.

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

Karoutsos, V.

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

Kildishev, A. V.

Kim, Y.-H.

Kimball, C. W.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Knoll, W.

F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
[Crossref] [PubMed]

K. Tawa and W. Knoll, “Mismatching base-pair dependence of the kinetics of DNA-DNA hybridization studied by surface plasmon fluorescence spectroscopy,” Nucleic Acids Res. 32(8), 2372–2377 (2004).
[Crossref] [PubMed]

Kobayashi, N. P.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Kolomenski, A.

Kolomenskii, A.

Lakowicz, J. R.

K. Ray, M. H. Chowdhury, and J. R. Lakowicz, “Observation of surface plasmon-coupled emission using thin platinum films,” Chem. Phys. Lett. 465(1-3), 92–95 (2008).
[Crossref]

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

J. R. Lakowicz, “Radiative decay engineering: biophysical and biomedical applications,” Anal. Biochem. 298(1), 1–24 (2001).
[Crossref] [PubMed]

Lay, E.

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

Leong, E. S. P.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Lin, C.-Y.

Liu, H.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Löfås, S.

F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
[Crossref] [PubMed]

MacCraith, B. D.

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
[Crossref]

Maier, S. A.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Malicka, J.

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

Manouras, T.

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

Matveeva, E.

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

Mayer, M.

McDonagh, C.

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
[Crossref]

McEvoy, H. M.

O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
[Crossref]

Ming, H.

Moh, K. J.

Noel, J.

Pantell, R. H.

E. Fontana and R. H. Pantell, “Characterization of multilayer rough surfaces by use of surface-plasmon spectroscopy,” Phys. Rev. B Condens. Matter 37(7), 3164–3182 (1988).
[Crossref] [PubMed]

Parfenov, A.

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

Pearson, J.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Peng, S.

Persson, B.

F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
[Crossref] [PubMed]

Politis, C.

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

Poulopoulos, P.

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

Ray, K.

K. Ray, M. H. Chowdhury, and J. R. Lakowicz, “Observation of surface plasmon-coupled emission using thin platinum films,” Chem. Phys. Lett. 465(1-3), 92–95 (2008).
[Crossref]

Roll, D.

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

Ruckstuhl, T.

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

Schuessler, H.

Shalaev, V. M.

Sheppard, C. J. R.

Si, G.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

So, P. T. C.

Song, Y.-H.

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

Stanley, R.

Stranik, O.

O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
[Crossref]

Su, Y.-D.

Sullivan, K. G.

Tang, W. T.

Tawa, K.

K. Tawa and W. Knoll, “Mismatching base-pair dependence of the kinetics of DNA-DNA hybridization studied by surface plasmon fluorescence spectroscopy,” Nucleic Acids Res. 32(8), 2372–2377 (2004).
[Crossref] [PubMed]

Teng, J.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Trnavsky, M.

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

Uddin, M. J.

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

Valette, G.

G. Valette, “Silver-water interactions: Part I. Model of the inner layer at the metal/water interface,” J. Electroanal. Chem. 230(1-2), 189–204 (1987).
[Crossref]

Vlasko-Vlasov, V. K.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Wang, B.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Wang, P.

Wang, S. Y.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Weisbuch, C.

H. Benisty, H. De Neve, and C. Weisbuch, “Impact of planar microcavity effects on light extraction-Part I: Basic concepts and analytical trends,” IEEE J. Quantum Electron. 34(9), 1612–1631 (1998).
[Crossref]

Welp, U.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Williams, R. S.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Wu, H.-L.

Wu, W.

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

Yang, P.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Yin, L.

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Yu, F.

B. Huang, F. Yu, and R. N. Zare, “Surface plasmon resonance imaging using a high numerical aperture microscope objective,” Anal. Chem. 79(7), 2979–2983 (2007).
[Crossref] [PubMed]

F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
[Crossref] [PubMed]

Yuan, H.-K.

Yuan, X.-C.

Zare, R. N.

B. Huang, F. Yu, and R. N. Zare, “Surface plasmon resonance imaging using a high numerical aperture microscope objective,” Anal. Chem. 79(7), 2979–2983 (2007).
[Crossref] [PubMed]

Zhang, D. G.

Zong, Y.

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

ACS Nano (1)

H. Liu, B. Wang, E. S. P. Leong, P. Yang, Y. Zong, G. Si, J. Teng, and S. A. Maier, “Enhanced surface plasmon resonance on a smooth silver film with a seed growth layer,” ACS Nano 4(6), 3139–3146 (2010).
[Crossref] [PubMed]

Anal. Biochem. (2)

J. R. Lakowicz, “Radiative decay engineering: biophysical and biomedical applications,” Anal. Biochem. 298(1), 1–24 (2001).
[Crossref] [PubMed]

E. Matveeva, Z. Gryczynski, J. Malicka, I. Gryczynski, and J. R. Lakowicz, “Metal-enhanced fluorescence immunoassays using total internal reflection and silver island-coated surfaces,” Anal. Biochem. 334(2), 303–311 (2004).
[Crossref] [PubMed]

Anal. Chem. (2)

F. Yu, B. Persson, S. Löfås, and W. Knoll, “Surface plasmon fluorescence immunoassay of free prostate-specific antigen in human plasma at the femtomolar level,” Anal. Chem. 76(22), 6765–6770 (2004).
[Crossref] [PubMed]

B. Huang, F. Yu, and R. N. Zare, “Surface plasmon resonance imaging using a high numerical aperture microscope objective,” Anal. Chem. 79(7), 2979–2983 (2007).
[Crossref] [PubMed]

Appl. Opt. (2)

Chem. Phys. Lett. (1)

K. Ray, M. H. Chowdhury, and J. R. Lakowicz, “Observation of surface plasmon-coupled emission using thin platinum films,” Chem. Phys. Lett. 465(1-3), 92–95 (2008).
[Crossref]

Chem. Vap. Deposition (1)

Y. Chi, E. Lay, T.-Y. Chou, Y.-H. Song, and A. J. Carty, “Deposition of silver thin films using the pyrazolate complex [Ag(3,5-(CF3)2C3HN2)]3,” Chem. Vap. Deposition 11(4), 206–212 (2005).
[Crossref]

IEEE J. Quantum Electron. (1)

H. Benisty, H. De Neve, and C. Weisbuch, “Impact of planar microcavity effects on light extraction-Part I: Basic concepts and analytical trends,” IEEE J. Quantum Electron. 34(9), 1612–1631 (1998).
[Crossref]

J. Biomed. Opt. (1)

M. Trnavsky, J. Enderlein, T. Ruckstuhl, C. McDonagh, and B. D. MacCraith, “Experimental and theoretical evaluation of surface plasmon-coupled emission for sensitive fluorescence detection,” J. Biomed. Opt. 13(5), 054021 (2008).
[Crossref] [PubMed]

J. Electroanal. Chem. (1)

G. Valette, “Silver-water interactions: Part I. Model of the inner layer at the metal/water interface,” J. Electroanal. Chem. 230(1-2), 189–204 (1987).
[Crossref]

J. Fluoresc. (1)

C. D. Geddes, A. Parfenov, D. Roll, M. J. Uddin, and J. R. Lakowicz, “Fluorescence Spectral Properties of Indocyanine Green on a Roughened Platinum Electrode: Metal-Enhanced Fluorescence,” J. Fluoresc. 13(6), 453–457 (2003).
[Crossref] [PubMed]

J. Opt. Soc. Am. A (1)

J. Opt. Soc. Am. B (2)

Nano Lett. (2)

N. P. Kobayashi, M. S. Islam, W. Wu, P. Chaturvedi, N. X. Fang, S. Y. Wang, and R. S. Williams, “Ultrasmooth silver thin films deposited with a germanium nucleation layer,” Nano Lett. 9(1), 178–182 (2009).
[Crossref]

L. Yin, V. K. Vlasko-Vlasov, J. Pearson, J. M. Hiller, J. Hua, U. Welp, D. E. Brown, and C. W. Kimball, “Subwavelength focusing and guiding of surface plasmons,” Nano Lett. 5(7), 1399–1402 (2005).
[Crossref] [PubMed]

Nucleic Acids Res. (1)

K. Tawa and W. Knoll, “Mismatching base-pair dependence of the kinetics of DNA-DNA hybridization studied by surface plasmon fluorescence spectroscopy,” Nucleic Acids Res. 32(8), 2372–2377 (2004).
[Crossref] [PubMed]

Opt. Express (5)

Opt. Lett. (2)

Phys. Rev. B Condens. Matter (1)

E. Fontana and R. H. Pantell, “Characterization of multilayer rough surfaces by use of surface-plasmon spectroscopy,” Phys. Rev. B Condens. Matter 37(7), 3164–3182 (1988).
[Crossref] [PubMed]

Sens. Actuators B Chem. (1)

O. Stranik, H. M. McEvoy, C. McDonagh, and B. D. MacCraith, “Plasmonic enhancement of fluorescence for sensor applications,” Sens. Actuators B Chem. 107(1), 148–153 (2005).
[Crossref]

Thin Solid Films (2)

V. Kapaklis, P. Poulopoulos, V. Karoutsos, T. Manouras, and C. Politis, “Growth of thin Ag films produced by radio frequency magnetron sputtering,” Thin Solid Films 510(1-2), 138–142 (2006).
[Crossref]

I. Gryczynski, J. Malicka, J. R. Lakowicz, E. M. Goldys, N. Calander, and Z. Gryczynski, “Directional two-photon induced surface plasmon-coupled emission,” Thin Solid Films 491(1-2), 173–176 (2005).
[Crossref]

Other (2)

H. Raether, Surface Plasmons on Smooth and Rough Surfaces and on Gratings (Springer, 1998).

E. D. Palik, Handbook of Optical Constant of Solids (Academic, 1985).

Cited By

OSA participates in Crossref's Cited-By Linking service. Citing articles from OSA journals and other participating publishers are listed here.

Alert me when this article is cited.


Figures (7)

Fig. 1
Fig. 1

Schematic diagram of the optical setup of the TPEF evanescence wave microscopy based on the objective-coupled TIR method. Red and green lines indicate the respective optical paths of the excitation source and fluorescence collection.

Download Full Size | PPT Slide | PDF

Fig. 2
Fig. 2

(a) Electric field enhancement and (b) fluorescence coupled emission as function of Ag film thickness. (c) Electric field enhancement and (d) fluorescence coupled emission as function of the Au film thickness.

Download Full Size | PPT Slide | PDF

Fig. 3
Fig. 3

AFM topography analysis of: (a) 40 nm Ag film, (b) 40 nm Ag film with a 2 nm Ge seed layer, and (c) 2 nm Ge on cover glasses. (d)-(f) are the corresponding histograms of the 2D surface-height values of (a)-(c).

Download Full Size | PPT Slide | PDF

Fig. 4
Fig. 4

(a) White-light and (b) TPL images of the damaged Ag/Ge film in H2O after 15-second femtosecond laser irradiance (780 nm at 30 mW). (c) White-light image of Ag/Ge film in H2O after 15-second CW laser irradiance showing the damage to the film. (d) Gaussian SPCE TPEF image with 1 mM R6G solution placed on top of the Ag/Ge film.

Download Full Size | PPT Slide | PDF

Fig. 5
Fig. 5

Quantum yield of the fluorescent dyes on the Ag film as a function of the dielectric spacer thickness.

Download Full Size | PPT Slide | PDF

Fig. 6
Fig. 6

SPCE TPEF images of R6G at (a) the Ag surface and (b) the BFP of the objective.

Download Full Size | PPT Slide | PDF

Fig. 7
Fig. 7

SPCE TPEF images of a fluorescent bead pattern at (a) the Ag surface and (b) the BFP of the objective.

Download Full Size | PPT Slide | PDF

Equations (4)

Equations on this page are rendered with MathJax. Learn more.

P ( θ ) = P 2 ( θ 2 ) ⋅ T 210 ⋅ n 0 k 0 z n 2 k 2 z ⋅ e − | Im ( 2 k 2 z ⋅ h ) | ,
I V E D ( u ) = 3 2 Re ( u 3 1 − u 2 ( 1 + r 43210 p ⋅ e j 2 k 4 z ⋅ h ) ) ,
I H E D ( u ) = 3 4 Re ( u 1 − u 2 ( ( 1 − u 2 ) ⋅ ( 1 − r 43210 p ⋅ e j 2 k 4 z ⋅ h )   + ( 1 + r 43210 s ⋅ e j 2 k 4 z ⋅ h ) ) ) ,
Q = ∫ 0 1 I ( u ) ⋅ d u / ∫ 0 ∞ I ( u ) ⋅ d u .

Metrics