Optimisation of photopolymers for holographic applications using the Non-local Photo-polymerization Driven Diffusion model

Michael R. Gleeson; Jinxin Guo; John T. Sheridan

doi:10.1364/OE.19.022423

Optimisation of photopolymers for holographic applications using the Non-local Photo-polymerization Driven Diffusion model

Michael R. Gleeson, Jinxin Guo, and John T. Sheridan

Optics Express
Vol. 19,
Issue 23,
pp. 22423-22436
(2011)
•https://doi.org/10.1364/OE.19.022423

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Michael R. Gleeson, Jinxin Guo, and John T. Sheridan, "Optimisation of photopolymers for holographic applications using the Non-local Photo-polymerization Driven Diffusion model," Opt. Express 19, 22423-22436 (2011)

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Related Topics
Table of Contents Category
- Holography
Optics & Photonics Topics
?

The topics in this list come from the OSA Optics and Photonics Topics applied to this article.
Previously assigned OCIS codes
- Diffraction gratings (050.1950)
- Volume gratings (050.7330)
- Holographic optical elements (090.2890)
- Optical storage materials (090.2900)
- Polymers (160.5470)
- Photosensitive materials (160.5335)

About this Article
History
- Original Manuscript: June 20, 2011
- Revised Manuscript: July 15, 2011
- Manuscript Accepted: July 17, 2011
- Published: October 24, 2011

Accessible

Open Access

Abstract

An understanding of the photochemical and photo-physical processes, which occur during photopolymerization is of extreme importance when attempting to improve a photopolymer material’s performance for a given application. Recent work carried out on the modelling of the mechanisms which occur in photopolymers during- and post-exposure, has led to the development of a tool, which can be used to predict the behaviour of these materials under a wide range of conditions. In this paper, we explore this Non-local Photo-polymerisation Driven Diffusion model, illustrating some of the useful trends, which the model predicts and we analyse their implications on the improvement of photopolymer material performance.

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References

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M. R. Gleeson and J. T. Sheridan, “Non-local photo-polymerization kinetics including multiple termination mechanisms and dark reactions: Part I. Modelling,” J. Opt. Soc. Am. B 26(9), 1736–1745 (2009).
[Crossref]
M. R. Gleeson, S. Liu, R. R. McLeod, and J. T. Sheridan, “Non-local photo-polymerization kinetics including multiple termination mechanisms and dark reactions: Part II. Experimental Validation,” J. Opt. Soc. Am. B 26(9), 1746–1754 (2009).
[Crossref]
M. R. Gleeson, S. Liu, J. Guo, and J. T. Sheridan, “Non-Local photo-polymerization kinetics including multiple termination mechanisms and dark reactions: Part III. Primary Radical Generation and Inhibition,” J. Opt. Soc. Am. B 27(9), 1804–1812 (2010).
[Crossref]
S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]
J. Lougnot, P. Jost, and L. Lavielle, “Polymers for holographic recording: VI. some basic ideas for modelling the kinetics of the recording process,” Pure Appl. Opt. 6(2), 225–245 (1997).
[Crossref]
J. T. Sheridan and J. R. Lawrence, “Nonlocal-response diffusion model of holographic recording in photopolymer,” J. Opt. Soc. Am. A 17(6), 1108–1114 (2000).
[Crossref] [PubMed]
J. R. Lawrence, F. T. O’Neill, and J. T. Sheridan, “Adjusted intensity nonlocal diffusion model of photopolymer grating formation,” J. Opt. Soc. Am. B 19(4), 621–629 (2002).
[Crossref]
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C. Ye and R. R. McLeod, “GRIN lens and lens array fabrication with diffusion-driven photopolymer,” Opt. Lett. 33(22), 2575–2577 (2008).
[Crossref] [PubMed]
A. B. Villafranca and K. Saravanamuttu, “Diffraction rings due to spatial self-phase modulation in a photopolymerizable medium,” J. Opt. A, Pure Appl. Opt. 11(12), 125202 (2009).
[Crossref]
K. Curtis, L. Dhar, L. Murphy, and A. Hill, Future Developments, in Holographic Data Storage: From Theory to Practical Systems, (Wiley 2010).
A. C. Sullivan, M. W. Grabowski, and R. R. McLeod, “Three-dimensional direct-write lithography into photopolymer,” Appl. Opt. 46(3), 295–301 (2007).
[Crossref] [PubMed]
J. V. Kelly, M. R. Gleeson, C. E. Close, F. T. O’Neill, J. T. Sheridan, S. Gallego, and C. Neipp, “Temporal analysis of grating formation in photopolymer using the nonlocal polymerization-driven diffusion model,” Opt. Express 13(18), 6990–7004 (2005).
[Crossref] [PubMed]
M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]
M. R. Gleeson and J. T. Sheridan, “A review of the modelling of free-radical photopolymerization in the formation of holographic gratings,” J. Opt. A, Pure Appl. Opt. 11(2), 024008 (2009).
[Crossref]
G. H. Zhao and P. Mouroulis, “Diffusion-model of hologram formation in dry photopolymer materials,” J. Mod. Opt. 41(10), 1929–1939 (1994).
[Crossref]
J. T. Sheridan, M. R. Gleeson, C. E. Close, and J. V. Kelly, “Optical response of photopolymer materials for holographic data storage applications,” J. Nanosci. Nanotechnol. 7(1), 232–242 (2007).
[PubMed]
T. Trentler, J. Boyd, and V. Colvin, “Epoxy resin photopolymer composites for volume holography,” Chem. Mater. 12(5), 1431–1438 (2000).
[Crossref]
S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “Modeling the Photochemical Kinetics Induced by Holographic Exposures in PQ/PMMA Photopolymer Material,” J. Opt. Soc. Am. B (to be published).
M. R. Gleeson, J. T. Sheridan, F. Bruder, T. Rölle, H. Berneth, M-S. Weiser and T. Fäcke, are preparing a manuscript to be called “Analysis of the holographic performance of a commercially available photopolymer using the NPDD model.”
J. H. Kwon, H. C. Hwang, and K. C. Woo, “Analysis of temporal behaviour of beams diffracted by volume gratings formed in photopolymers,” J. Opt. Soc. Am. B 16(10), 1651–1657 (1999).
[Crossref]
J. R. Lawrence, F. T. O'Neill, and J. T. Sheridan, “Photopolymer holographic recording material,” Optik (Stuttg.) 112(10), 449–463 (2001).
[Crossref]
S. Blaya, L. Carretero, R. F. Madrigal, M. Ulibarrena, P. Acebal, and A. Fimia, “Photopolymerization model for holographic gratings formation in photopolymers,” Appl. Phys. B: Lasers Opt. 77(6–7), 639–662 (2003).
[Crossref]
L. Carretero, S. Blaya, R. Mallavia, R. F. Madrigal, A. Beléndez, and A. Fimia, “Theoretical and experimental study of the bleaching of a dye in a film-polymerization process,” Appl. Opt. 37(20), 4496–4499 (1998).
[Crossref] [PubMed]
S. Gallego, M. Ortuño, C. Neipp, A. Márquez, A. Beléndez, I. Pascual, J. V. Kelly, and J. T. Sheridan, “Physical and effective optical thickness of holographic diffraction gratings recorded in photopolymers,” Opt. Express 13(6), 1939–1947 (2005).
[Crossref] [PubMed]
G. Odian, Principles of Polymerization 4th Edition (Wiley, New York, 1991).
S. Liu, M. R. Gleeson, and J. T. Sheridan, “Analysis of the photoabsorptive behaviour of two different photosensitizers in a photopolymer material,” J. Opt. Soc. Am. B 26(3), 528–536 (2009).
[Crossref]
M. R. Gleeson, J. V. Kelly, C. E. Close, F. T. O'Neill, and J. T. Sheridan, “Effects of absorption and inhibition during grating formation in photopolymer materials,” J. Opt. Soc. Am. B 23(10), 2079–2088 (2006).
[Crossref]
S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]
A. Fimia, N. Lopez, F. Mateos, R. Sastre, J. Pineda, and F. Amatguerri, “Elimination of oxygen inhibition in photopolymer system used as holographic recording materials,” J. Mod. Opt. 40(4), 699–706 (1993).
[Crossref]
M. R. Gleeson, D. Sabol, S. Liu, C. E. Close, J. V. Kelly, and J. T. Sheridan, “Improvement of the spatial frequency response of photopolymer materials by modifying polymer chain length,” J. Opt. Soc. Am. B 25(3), 396–406 (2008).
[Crossref]
J. Guo, M. R. Gleeson, S. Liu, and J. T. Sheridan, “Non-local spatial frequency response of photopolymer materials containing chain transfer agents: Part I. Theoretical modelling,” J. Opt. A, Pure Appl. Opt. (to be published).
J. Guo, M. R. Gleeson, S. Liu, and J. T. Sheridan, “Non-local spatial frequency response of photopolymer materials containing chain transfer agents: Part II. Experimental results,” J. Opt. A, Pure Appl. Opt. (to be published).
H. M. Karpov, V. V. Obukhovsky, and T. N. Smirnova, “Generalized model of holographic recording in photopolymer materials,” Semi Conduct. Phys. Quantum Electron. Optoelectron. 2(3), 66–70 (1999).
M. Toishi, T. Tanaka, K. Watanabe, and K. Betsuyaku, “Analysis of photopolymer media of holographic data storage using non-local polymerization driven diffusion model,” Jpn. J. Appl. Phys. 46(6A), 3438–3447 (2007).
[Crossref]
M. Toishi, T. Takeda, K. Tanaka, T. Tanaka, A. Fukumoto, and K. Watanabe, “Two-dimensional simulation of holographic data storage medium for multiplexed recording,” Opt. Express 16(4), 2829–2839 (2008).
[Crossref] [PubMed]
R. R. A. Syms, Practical Volume Holography (Clarendon Press, Oxford, 1990).
I. Aubrecht, M. Miler, and I. Koudela, “Recording of holographic diffraction gratings in photopolymers: Theoretical modelling and real-time monitoring of grating growth,” J. Mod. Opt. 45(7), 1465–1477 (1998).
[Crossref]
M. D. Goodner and C. N. Bowman, “Modeling primary radical termination and its effects on autoacceleration in photopolymerization kinetics,” Macromol. 32(20), 6552–6559 (1999).
[Crossref]
C. E. Close, M. R. Gleeson, and J. T. Sheridan, “Monomer diffusion rates in photopolymer material. Part I. Low spatial frequency holographic gratings,” J. Opt. Soc. Am. B 28(4), 658–666 (2011).
[Crossref]
C. E. Close, M. R. Gleeson, D. A. Mooney, and J. T. Sheridan, “Monomer diffusion rates in photopolymer material. Part II. High-frequency gratings and bulk diffusion,” J. Opt. Soc. Am. B 28(4), 842–850 (2011).
[Crossref]

2011 (2)

C. E. Close, M. R. Gleeson, and J. T. Sheridan, “Monomer diffusion rates in photopolymer material. Part I. Low spatial frequency holographic gratings,” J. Opt. Soc. Am. B 28(4), 658–666 (2011).
[Crossref]

C. E. Close, M. R. Gleeson, D. A. Mooney, and J. T. Sheridan, “Monomer diffusion rates in photopolymer material. Part II. High-frequency gratings and bulk diffusion,” J. Opt. Soc. Am. B 28(4), 842–850 (2011).
[Crossref]

2010 (2)

M. R. Gleeson, S. Liu, J. Guo, and J. T. Sheridan, “Non-Local photo-polymerization kinetics including multiple termination mechanisms and dark reactions: Part III. Primary Radical Generation and Inhibition,” J. Opt. Soc. Am. B 27(9), 1804–1812 (2010).
[Crossref]

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]

2009 (6)

A. B. Villafranca and K. Saravanamuttu, “Diffraction rings due to spatial self-phase modulation in a photopolymerizable medium,” J. Opt. A, Pure Appl. Opt. 11(12), 125202 (2009).
[Crossref]

M. R. Gleeson and J. T. Sheridan, “A review of the modelling of free-radical photopolymerization in the formation of holographic gratings,” J. Opt. A, Pure Appl. Opt. 11(2), 024008 (2009).
[Crossref]

S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]

S. Liu, M. R. Gleeson, and J. T. Sheridan, “Analysis of the photoabsorptive behaviour of two different photosensitizers in a photopolymer material,” J. Opt. Soc. Am. B 26(3), 528–536 (2009).
[Crossref]

M. R. Gleeson and J. T. Sheridan, “Non-local photo-polymerization kinetics including multiple termination mechanisms and dark reactions: Part I. Modelling,” J. Opt. Soc. Am. B 26(9), 1736–1745 (2009).
[Crossref]

M. R. Gleeson, S. Liu, R. R. McLeod, and J. T. Sheridan, “Non-local photo-polymerization kinetics including multiple termination mechanisms and dark reactions: Part II. Experimental Validation,” J. Opt. Soc. Am. B 26(9), 1746–1754 (2009).
[Crossref]

2008 (4)

M. Toishi, T. Takeda, K. Tanaka, T. Tanaka, A. Fukumoto, and K. Watanabe, “Two-dimensional simulation of holographic data storage medium for multiplexed recording,” Opt. Express 16(4), 2829–2839 (2008).
[Crossref] [PubMed]

M. R. Gleeson, D. Sabol, S. Liu, C. E. Close, J. V. Kelly, and J. T. Sheridan, “Improvement of the spatial frequency response of photopolymer materials by modifying polymer chain length,” J. Opt. Soc. Am. B 25(3), 396–406 (2008).
[Crossref]

C. Ye and R. R. McLeod, “GRIN lens and lens array fabrication with diffusion-driven photopolymer,” Opt. Lett. 33(22), 2575–2577 (2008).
[Crossref] [PubMed]

M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]

2007 (3)

J. T. Sheridan, M. R. Gleeson, C. E. Close, and J. V. Kelly, “Optical response of photopolymer materials for holographic data storage applications,” J. Nanosci. Nanotechnol. 7(1), 232–242 (2007).
[PubMed]

M. Toishi, T. Tanaka, K. Watanabe, and K. Betsuyaku, “Analysis of photopolymer media of holographic data storage using non-local polymerization driven diffusion model,” Jpn. J. Appl. Phys. 46(6A), 3438–3447 (2007).
[Crossref]

A. C. Sullivan, M. W. Grabowski, and R. R. McLeod, “Three-dimensional direct-write lithography into photopolymer,” Appl. Opt. 46(3), 295–301 (2007).
[Crossref] [PubMed]

2006 (1)

M. R. Gleeson, J. V. Kelly, C. E. Close, F. T. O'Neill, and J. T. Sheridan, “Effects of absorption and inhibition during grating formation in photopolymer materials,” J. Opt. Soc. Am. B 23(10), 2079–2088 (2006).
[Crossref]

2005 (2)

S. Gallego, M. Ortuño, C. Neipp, A. Márquez, A. Beléndez, I. Pascual, J. V. Kelly, and J. T. Sheridan, “Physical and effective optical thickness of holographic diffraction gratings recorded in photopolymers,” Opt. Express 13(6), 1939–1947 (2005).
[Crossref] [PubMed]

J. V. Kelly, M. R. Gleeson, C. E. Close, F. T. O’Neill, J. T. Sheridan, S. Gallego, and C. Neipp, “Temporal analysis of grating formation in photopolymer using the nonlocal polymerization-driven diffusion model,” Opt. Express 13(18), 6990–7004 (2005).
[Crossref] [PubMed]

2003 (1)

S. Blaya, L. Carretero, R. F. Madrigal, M. Ulibarrena, P. Acebal, and A. Fimia, “Photopolymerization model for holographic gratings formation in photopolymers,” Appl. Phys. B: Lasers Opt. 77(6–7), 639–662 (2003).
[Crossref]

2002 (1)

J. R. Lawrence, F. T. O’Neill, and J. T. Sheridan, “Adjusted intensity nonlocal diffusion model of photopolymer grating formation,” J. Opt. Soc. Am. B 19(4), 621–629 (2002).
[Crossref]

2001 (1)

J. R. Lawrence, F. T. O'Neill, and J. T. Sheridan, “Photopolymer holographic recording material,” Optik (Stuttg.) 112(10), 449–463 (2001).
[Crossref]

2000 (2)

J. T. Sheridan and J. R. Lawrence, “Nonlocal-response diffusion model of holographic recording in photopolymer,” J. Opt. Soc. Am. A 17(6), 1108–1114 (2000).
[Crossref] [PubMed]

T. Trentler, J. Boyd, and V. Colvin, “Epoxy resin photopolymer composites for volume holography,” Chem. Mater. 12(5), 1431–1438 (2000).
[Crossref]

1999 (3)

J. H. Kwon, H. C. Hwang, and K. C. Woo, “Analysis of temporal behaviour of beams diffracted by volume gratings formed in photopolymers,” J. Opt. Soc. Am. B 16(10), 1651–1657 (1999).
[Crossref]

M. D. Goodner and C. N. Bowman, “Modeling primary radical termination and its effects on autoacceleration in photopolymerization kinetics,” Macromol. 32(20), 6552–6559 (1999).
[Crossref]

H. M. Karpov, V. V. Obukhovsky, and T. N. Smirnova, “Generalized model of holographic recording in photopolymer materials,” Semi Conduct. Phys. Quantum Electron. Optoelectron. 2(3), 66–70 (1999).

1998 (2)

I. Aubrecht, M. Miler, and I. Koudela, “Recording of holographic diffraction gratings in photopolymers: Theoretical modelling and real-time monitoring of grating growth,” J. Mod. Opt. 45(7), 1465–1477 (1998).
[Crossref]

L. Carretero, S. Blaya, R. Mallavia, R. F. Madrigal, A. Beléndez, and A. Fimia, “Theoretical and experimental study of the bleaching of a dye in a film-polymerization process,” Appl. Opt. 37(20), 4496–4499 (1998).
[Crossref] [PubMed]

1997 (1)

J. Lougnot, P. Jost, and L. Lavielle, “Polymers for holographic recording: VI. some basic ideas for modelling the kinetics of the recording process,” Pure Appl. Opt. 6(2), 225–245 (1997).
[Crossref]

1994 (1)

G. H. Zhao and P. Mouroulis, “Diffusion-model of hologram formation in dry photopolymer materials,” J. Mod. Opt. 41(10), 1929–1939 (1994).
[Crossref]

1993 (1)

A. Fimia, N. Lopez, F. Mateos, R. Sastre, J. Pineda, and F. Amatguerri, “Elimination of oxygen inhibition in photopolymer system used as holographic recording materials,” J. Mod. Opt. 40(4), 699–706 (1993).
[Crossref]

Acebal, P.

Amatguerri, F.

Aubrecht, I.

Beléndez, A.

Betsuyaku, K.

Blaya, S.

Bowman, C. N.

M. D. Goodner and C. N. Bowman, “Modeling primary radical termination and its effects on autoacceleration in photopolymerization kinetics,” Macromol. 32(20), 6552–6559 (1999).
[Crossref]

Boyd, J.

T. Trentler, J. Boyd, and V. Colvin, “Epoxy resin photopolymer composites for volume holography,” Chem. Mater. 12(5), 1431–1438 (2000).
[Crossref]

Carretero, L.

Close, C. E.

Colvin, V.

T. Trentler, J. Boyd, and V. Colvin, “Epoxy resin photopolymer composites for volume holography,” Chem. Mater. 12(5), 1431–1438 (2000).
[Crossref]

Fimia, A.

Fukumoto, A.

Gallego, S.

Gleeson, M. R.

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]

S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]

M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]

J. Guo, M. R. Gleeson, S. Liu, and J. T. Sheridan, “Non-local spatial frequency response of photopolymer materials containing chain transfer agents: Part I. Theoretical modelling,” J. Opt. A, Pure Appl. Opt. (to be published).

J. Guo, M. R. Gleeson, S. Liu, and J. T. Sheridan, “Non-local spatial frequency response of photopolymer materials containing chain transfer agents: Part II. Experimental results,” J. Opt. A, Pure Appl. Opt. (to be published).

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “Modeling the Photochemical Kinetics Induced by Holographic Exposures in PQ/PMMA Photopolymer Material,” J. Opt. Soc. Am. B (to be published).

Goodner, M. D.

M. D. Goodner and C. N. Bowman, “Modeling primary radical termination and its effects on autoacceleration in photopolymerization kinetics,” Macromol. 32(20), 6552–6559 (1999).
[Crossref]

Grabowski, M. W.

A. C. Sullivan, M. W. Grabowski, and R. R. McLeod, “Three-dimensional direct-write lithography into photopolymer,” Appl. Opt. 46(3), 295–301 (2007).
[Crossref] [PubMed]

Guo, J.

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “Modeling the Photochemical Kinetics Induced by Holographic Exposures in PQ/PMMA Photopolymer Material,” J. Opt. Soc. Am. B (to be published).

Hwang, H. C.

J. H. Kwon, H. C. Hwang, and K. C. Woo, “Analysis of temporal behaviour of beams diffracted by volume gratings formed in photopolymers,” J. Opt. Soc. Am. B 16(10), 1651–1657 (1999).
[Crossref]

Jost, P.

Karpov, H. M.

Kelly, J. V.

Koudela, I.

Kwon, J. H.

J. H. Kwon, H. C. Hwang, and K. C. Woo, “Analysis of temporal behaviour of beams diffracted by volume gratings formed in photopolymers,” J. Opt. Soc. Am. B 16(10), 1651–1657 (1999).
[Crossref]

Lavielle, L.

Lawrence, J. R.

J. R. Lawrence, F. T. O’Neill, and J. T. Sheridan, “Adjusted intensity nonlocal diffusion model of photopolymer grating formation,” J. Opt. Soc. Am. B 19(4), 621–629 (2002).
[Crossref]

J. R. Lawrence, F. T. O'Neill, and J. T. Sheridan, “Photopolymer holographic recording material,” Optik (Stuttg.) 112(10), 449–463 (2001).
[Crossref]

J. T. Sheridan and J. R. Lawrence, “Nonlocal-response diffusion model of holographic recording in photopolymer,” J. Opt. Soc. Am. A 17(6), 1108–1114 (2000).
[Crossref] [PubMed]

Liu, S.

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]

S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]

M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “Modeling the Photochemical Kinetics Induced by Holographic Exposures in PQ/PMMA Photopolymer Material,” J. Opt. Soc. Am. B (to be published).

Lopez, N.

Lougnot, J.

Madrigal, R. F.

Mallavia, R.

Márquez, A.

Mateos, F.

McLeod, R. R.

C. Ye and R. R. McLeod, “GRIN lens and lens array fabrication with diffusion-driven photopolymer,” Opt. Lett. 33(22), 2575–2577 (2008).
[Crossref] [PubMed]

A. C. Sullivan, M. W. Grabowski, and R. R. McLeod, “Three-dimensional direct-write lithography into photopolymer,” Appl. Opt. 46(3), 295–301 (2007).
[Crossref] [PubMed]

Miler, M.

Mooney, D. A.

Mouroulis, P.

G. H. Zhao and P. Mouroulis, “Diffusion-model of hologram formation in dry photopolymer materials,” J. Mod. Opt. 41(10), 1929–1939 (1994).
[Crossref]

Neipp, C.

O’Duill, S.

M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]

O’Neill, F. T.

J. R. Lawrence, F. T. O’Neill, and J. T. Sheridan, “Adjusted intensity nonlocal diffusion model of photopolymer grating formation,” J. Opt. Soc. Am. B 19(4), 621–629 (2002).
[Crossref]

Obukhovsky, V. V.

O'Neill, F. T.

J. R. Lawrence, F. T. O'Neill, and J. T. Sheridan, “Photopolymer holographic recording material,” Optik (Stuttg.) 112(10), 449–463 (2001).
[Crossref]

Ortuño, M.

Pascual, I.

Pineda, J.

Sabol, D.

S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]

Saravanamuttu, K.

A. B. Villafranca and K. Saravanamuttu, “Diffraction rings due to spatial self-phase modulation in a photopolymerizable medium,” J. Opt. A, Pure Appl. Opt. 11(12), 125202 (2009).
[Crossref]

Sastre, R.

Sheridan, J. T.

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]

S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]

M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]

J. R. Lawrence, F. T. O’Neill, and J. T. Sheridan, “Adjusted intensity nonlocal diffusion model of photopolymer grating formation,” J. Opt. Soc. Am. B 19(4), 621–629 (2002).
[Crossref]

J. R. Lawrence, F. T. O'Neill, and J. T. Sheridan, “Photopolymer holographic recording material,” Optik (Stuttg.) 112(10), 449–463 (2001).
[Crossref]

J. T. Sheridan and J. R. Lawrence, “Nonlocal-response diffusion model of holographic recording in photopolymer,” J. Opt. Soc. Am. A 17(6), 1108–1114 (2000).
[Crossref] [PubMed]

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “Modeling the Photochemical Kinetics Induced by Holographic Exposures in PQ/PMMA Photopolymer Material,” J. Opt. Soc. Am. B (to be published).

Smirnova, T. N.

Sullivan, A. C.

A. C. Sullivan, M. W. Grabowski, and R. R. McLeod, “Three-dimensional direct-write lithography into photopolymer,” Appl. Opt. 46(3), 295–301 (2007).
[Crossref] [PubMed]

Takeda, T.

Tanaka, K.

Tanaka, T.

Toishi, M.

Trentler, T.

T. Trentler, J. Boyd, and V. Colvin, “Epoxy resin photopolymer composites for volume holography,” Chem. Mater. 12(5), 1431–1438 (2000).
[Crossref]

Ulibarrena, M.

Villafranca, A. B.

A. B. Villafranca and K. Saravanamuttu, “Diffraction rings due to spatial self-phase modulation in a photopolymerizable medium,” J. Opt. A, Pure Appl. Opt. 11(12), 125202 (2009).
[Crossref]

Watanabe, K.

Woo, K. C.

J. H. Kwon, H. C. Hwang, and K. C. Woo, “Analysis of temporal behaviour of beams diffracted by volume gratings formed in photopolymers,” J. Opt. Soc. Am. B 16(10), 1651–1657 (1999).
[Crossref]

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C. Ye and R. R. McLeod, “GRIN lens and lens array fabrication with diffusion-driven photopolymer,” Opt. Lett. 33(22), 2575–2577 (2008).
[Crossref] [PubMed]

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G. H. Zhao and P. Mouroulis, “Diffusion-model of hologram formation in dry photopolymer materials,” J. Mod. Opt. 41(10), 1929–1939 (1994).
[Crossref]

Appl. Opt. (2)

A. C. Sullivan, M. W. Grabowski, and R. R. McLeod, “Three-dimensional direct-write lithography into photopolymer,” Appl. Opt. 46(3), 295–301 (2007).
[Crossref] [PubMed]

Appl. Phys. B: Lasers Opt. (1)

Chem. Mater. (1)

T. Trentler, J. Boyd, and V. Colvin, “Epoxy resin photopolymer composites for volume holography,” Chem. Mater. 12(5), 1431–1438 (2000).
[Crossref]

J. Appl. Phys. (2)

M. R. Gleeson, S. Liu, S. O’Duill, and J. T. Sheridan, “Examination of the photoinitiation processes in photopolymer materials,” J. Appl. Phys. 104(6), 064917 (2008).
[Crossref]

S. Liu, M. R. Gleeson, D. Sabol, and J. T. Sheridan, “Extended model of the photoinitiation mechanisms in photopolymer materials,” J. Appl. Phys. 106(10), 104911 (2009).
[Crossref]

J. Mod. Opt. (3)

G. H. Zhao and P. Mouroulis, “Diffusion-model of hologram formation in dry photopolymer materials,” J. Mod. Opt. 41(10), 1929–1939 (1994).
[Crossref]

J. Nanosci. Nanotechnol. (1)

J. Opt. A, Pure Appl. Opt. (4)

A. B. Villafranca and K. Saravanamuttu, “Diffraction rings due to spatial self-phase modulation in a photopolymerizable medium,” J. Opt. A, Pure Appl. Opt. 11(12), 125202 (2009).
[Crossref]

J. Opt. Soc. Am. A (1)

J. T. Sheridan and J. R. Lawrence, “Nonlocal-response diffusion model of holographic recording in photopolymer,” J. Opt. Soc. Am. A 17(6), 1108–1114 (2000).
[Crossref] [PubMed]

J. Opt. Soc. Am. B (11)

J. R. Lawrence, F. T. O’Neill, and J. T. Sheridan, “Adjusted intensity nonlocal diffusion model of photopolymer grating formation,” J. Opt. Soc. Am. B 19(4), 621–629 (2002).
[Crossref]

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “Modeling the Photochemical Kinetics Induced by Holographic Exposures in PQ/PMMA Photopolymer Material,” J. Opt. Soc. Am. B (to be published).

J. H. Kwon, H. C. Hwang, and K. C. Woo, “Analysis of temporal behaviour of beams diffracted by volume gratings formed in photopolymers,” J. Opt. Soc. Am. B 16(10), 1651–1657 (1999).
[Crossref]

Jpn. J. Appl. Phys. (1)

Macromol. (2)

M. D. Goodner and C. N. Bowman, “Modeling primary radical termination and its effects on autoacceleration in photopolymerization kinetics,” Macromol. 32(20), 6552–6559 (1999).
[Crossref]

S. Liu, M. R. Gleeson, J. Guo, and J. T. Sheridan, “High intensity response of photopolymer materials for holographic grating formation,” Macromol. 43(22), 9462–9472 (2010).
[Crossref]

Opt. Express (3)

Opt. Lett. (1)

C. Ye and R. R. McLeod, “GRIN lens and lens array fabrication with diffusion-driven photopolymer,” Opt. Lett. 33(22), 2575–2577 (2008).
[Crossref] [PubMed]

Optik (Stuttg.) (1)

J. R. Lawrence, F. T. O'Neill, and J. T. Sheridan, “Photopolymer holographic recording material,” Optik (Stuttg.) 112(10), 449–463 (2001).
[Crossref]

Pure Appl. Opt. (1)

Semi Conduct. Phys. Quantum Electron. Optoelectron. (1)

Other (5)

R. R. A. Syms, Practical Volume Holography (Clarendon Press, Oxford, 1990).

G. Odian, Principles of Polymerization 4th Edition (Wiley, New York, 1991).

T. Fäcke, F. Bruder, M. Weiser, T. Rölle, and D. Hönel, U.S. Patent No, US 2011/0065827 A1, (2011).

K. Curtis, L. Dhar, L. Murphy, and A. Hill, Future Developments, in Holographic Data Storage: From Theory to Practical Systems, (Wiley 2010).

M. R. Gleeson, J. T. Sheridan, F. Bruder, T. Rölle, H. Berneth, M-S. Weiser and T. Fäcke, are preparing a manuscript to be called “Analysis of the holographic performance of a commercially available photopolymer using the NPDD model.”

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Fig. 1

Flowchart of the photochemical mechanisms, which take place during photopolymerisation.

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Fig. 3

(a) Spatial frequency response for varying exposure intensities, I₀ = 0.5 mW/cm² (long dashed line), I₀ = 1.0 mW/cm² (dashed line), I₀ = 2.0 mW/cm² (short dashed line), and I₀ = 3.0 mW/cm² (shortest dashed line); (b) Spatial frequency response for varying monomer diffusion coefficients, D_m0 = 1×10⁻¹⁰ cm²/s (small dashed line), D_m0 = 1×10⁻¹¹ cm²/s (dashed line), D_m0 = 5×10⁻¹² cm²/s (long dashed line), D_m0 = 1×10⁻¹² cm²/s (longest dashed line).

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Fig. 2

Simulation of the saturated refractive index modulation, n₁^sat, for varying values of the propagation rate constant, k_p for a range of monomer diffusion coefficients, D_m0 = 1 × 10⁻¹⁰ cm²/s (small dashed line), D_m0 = 1 × 10⁻¹¹ cm²/s (dashed line), D_m0 = 5 × 10⁻¹² cm²/s (long dashed line), and D_m0 = 1 × 10⁻¹² cm²/s (longest dashed line).

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Fig. 4

Simulation of the saturated refractive index modulation for varying values of the bimolecular termination rate constant, k_t, for various values of the monomer diffusion coefficient, D_m0 = 1 × 10⁻¹⁰ cm²/s (small dashed line), D_m0 = 1 × 10⁻¹¹ cm²/s (dashed line), D_m0 = 5 × 10⁻¹² cm²/s (long dashed line), and D_m0 = 1 × 10⁻¹² cm²/s (longest dashed line).

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Fig. 5

(a) Simulation of the polymerisation rate, R_p, against monomer conversion and (b) simulation of growth curves of refractive index modulation, for varying propagation rates, k_p = 1.5×10⁷ cm³/mols (purple triangle), k_p = 2.6×10⁷ cm³/mols (red asterisk), k_p = 1.0×10⁸ cm³/mols (green filled circle), k_p = 2.6×10⁸ cm³/mols (blue empty circle).

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Fig. 6

(a) Simulation of polymerisation rate, R_p, against monomer conversion and (b) simulation of growth curves of refractive index modulation, for varying termination rates, k_t = 1.8×10¹⁰ cm³/mols (purple triangle), k_t = 6.0×10⁹ cm³/mols (red asterisk), k_t = 1.5×10⁸ cm³/mols (green filled circle), k_t = 1.5×10⁷ cm³/mols (blue empty circle).

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Equations (12)

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\frac{d D y e (x, t)}{d t} = - k_{a} D y e (x, t) + k_{r} {}^{3}D y e^{*} (x, t),

\begin{array}{l} \frac{d^{3} D y e^{*} (x, t)}{d t} = k_{a} D y e (x, t) - k_{r}^{3} D y e^{*} (x, t) \\ - k_{d}^{3} D y e^{*} (x, t) C I (x, t) - k_{z 1}^{3} D y e^{*} (x, t) Z (x, t), \end{array}

\frac{d C I (x, t)}{d t} = - k_{d}^{3} D y e^{*} (x, t) C I (x, t) - k_{b} H D y e^{•} (x, t) C I (x, t),

\frac{d H D y e^{•} (x, t)}{d t} = k_{d}^{3} D y e^{*} (x, t) C I (x, t) - k_{b} H D y e^{•} (x, t) C I (x, t),

\begin{array}{l} \frac{d R^{•} (x, t)}{d t} = k_{d}^{3} D y e^{*} (x, t) C I (x, t) - k_{i} R^{•} (x, t) u (x, t) \\ - k_{t p} R^{•} (x, t) M^{•} (x, t) - k_{z 2} R^{•} (x, t) Z (x, t), \end{array}

\begin{array}{l} \frac{d M^{•} (x, t)}{d t} = k_{i} R^{•} (x, t) u (x, t) - k_{t} {[M^{•} (x, t)]}^{}^{2} \\ - k_{t p} R^{•} (x, t) M^{•} (x, t) - k_{z 3} Z (x, t) M^{•} (x, t), \end{array}

\begin{array}{l} \frac{d u (x, t)}{d t} = \frac{d}{d x} [D_{m} (x, t) \frac{d u (x, t)}{d x}] - k_{i} R^{•} (x, t) u (x, t) \\ - \int_{- \infty}^{\infty} k_{p} M^{•} (x', t) u (x', t) G (x, x') d x', \end{array}

\frac{d N (x, t)}{d t} = \int_{- \infty}^{\infty} k_{p} M^{•} (x', t) u (x', t) G (x, x') d x' - \frac{d}{d x} [D_{N} (x, t) \frac{d N (x, t)}{d x}],

\begin{array}{l} \frac{d Z (x, t)}{d t} = \frac{d}{d x} [D_{z} (x, t) \frac{d Z (x, t)}{d x}] - k_{z 1}^{3} D y e^{*} (x, t) Z (x, t) - k_{z 2} Z (x, t) R^{•} (x, t) \\ - k_{z 3} Z (x, t) M^{•} (x, t) + τ_{z} {[Z_{0} - Z (x, t)]}^{} . \end{array}

G (x, x') = \frac{1}{\sqrt{2 π σ}} \exp [\frac{- {(x - x')}^{2}}{2 σ}],

\begin{array}{l} Z_{0} (t = 0) = Z_{0}, D y e_{0} (t = 0) = D y e_{0}, C I_{0} (t = 0) = C I_{0}, u_{0} (t = 0) = U_{0}, \\ D y e_{n > 0} (t = 0) = {}^{3}D y e_{n \geq 0}^{*} (t = 0) = H D y e_{n \geq 0}^{•} (t = 0) = C I_{n > 0}^{} (t = 0) = 0, and \\ Z_{n > 0} (t = 0) = R_{n \geq 0}^{•} (t = 0) = M_{n \geq 0}^{•} (t = 0) = N_{n \geq 0} (t = 0) = 0. \end{array}

n_{1} (t) = \frac{{(n_{d a r k}^{2} + 2)}^{2}}{6 n_{d a r k}} [φ_{1}^{(m)} (t) (\frac{n_{m}^{2} - 1}{n_{m}^{2} + 2} - \frac{n_{b}^{2} - 1}{n_{b}^{2} + 2}) + φ_{1}^{(p)} (t) (\frac{n_{p}^{2} - 1}{n_{p}^{2} + 2} - \frac{n_{b}^{2} - 1}{n_{b}^{2} + 2})] .