Abstract

Organic-inorganic nanohybrid materials were successfully fabricated from organically modified colloidal-silica nanoparticles synthesized through the sol-gel process and using the modified acryl resin. The materials exhibited the simple solution-processible film formation and high transmittance of above 90% in the visible wavelength regions. The materials were used for the fabrication of various patterns using the photolithography. We could simply fabricate the photopatterns and easily control the surface structures by changing the content of organically modified colloidal-silica nanoparticles. Also, the thermal and mechanical properties of the formed nanohybrid films could be efficiently enhanced through the synergistic combination of organically modified colloidal-silica nanoparticles with the modified acryl resin.

© 2008 Optical Society of America

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  1. B. M. Novak, "Hybrid nanocomposite materials between inorganic glasses and organic polymers," Adv. Mater. 5, 422-433 (1993).
    [CrossRef]
  2. X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).
  3. D. J. Kang, J. U. Park, and B. S. Bae, J. Nishii and K. Kintaka, "Single-step photo patterning of diffraction gratings in highly photosensitive hybrid gel films," Opt. Express 11, 1144-1148 (2003).
  4. D. J. Kang, J. K. Kim, and B. S. Bae, "Simple fabrication of diffraction gratings by two-beam interference method in highly photosensitive hybrid sol-gel films," Opt. Express 12, 3947-3953 (2004).
    [CrossRef]
  5. D. J. Kang, J. P. Jeong, and B. S. Bae, "Direct photofabrication of focal-length controlled microlens array using photoinduced migration mechanisms of photosensitive sol-gel hybrid materials," Opt. Express 14, 8347-8353 (2006).
    [CrossRef]
  6. A. Ulman, "Self-assembled monolayers of alkyltrichiorosilanes: Building blocks for future organic materials,"Adv. Mater. 2, 573-582 (1990).
    [CrossRef]
  7. P. Judeinstein and C. Sanchez, "Hybrid organic-inorganic materials: a land of multidisciplinarity," J. Mater. Chem. 6, 511-525 (1996).
    [CrossRef]
  8. B. Darracq, F. Chaput, K. Lahill, Y. Lẻvy, J. P. Boilot, "Photoinscription of surface relief gratings on azo-hybrid gels,"Adv. Mater. 10, 1133-1138 (1998).
    [CrossRef]
  9. A. H. O. Kärkkäinen, J. M. Tamkin, J. D. Rogers, D. R. Neal, O. E. Hormi, G. E. Jabbour, J. T. Rantala, and M. R. Descour, "Direct photolithographic deforming of organomodified siloxane films for micro-optics fabrication," Appl. Opt. 41, 3988 (2002).
    [CrossRef]
  10. D. Blanc and S. Pelissier, "Fabrication of sub-micron period diffraction gratings in self-processing sol-gel glasses," Thin Solid Films 384, 251-253 (2001).
    [CrossRef]
  11. W. Yu and X. -C. Yuan, "Variable surface profile gratings in sol-gel glass fabricated by holographic interference," Opt. Express 11,1925-1930 (2003).
  12. D. J. Kang and B. S. Bae, Photo-imageable sol-gel hybrid materials for simple fabrication of micro-optical elements," Acc. Chem. Res. 40, 903-912 (2007).
    [CrossRef]

2007 (1)

D. J. Kang and B. S. Bae, Photo-imageable sol-gel hybrid materials for simple fabrication of micro-optical elements," Acc. Chem. Res. 40, 903-912 (2007).
[CrossRef]

2006 (1)

2004 (1)

2003 (2)

2002 (2)

A. H. O. Kärkkäinen, J. M. Tamkin, J. D. Rogers, D. R. Neal, O. E. Hormi, G. E. Jabbour, J. T. Rantala, and M. R. Descour, "Direct photolithographic deforming of organomodified siloxane films for micro-optics fabrication," Appl. Opt. 41, 3988 (2002).
[CrossRef]

X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).

2001 (1)

D. Blanc and S. Pelissier, "Fabrication of sub-micron period diffraction gratings in self-processing sol-gel glasses," Thin Solid Films 384, 251-253 (2001).
[CrossRef]

1998 (1)

B. Darracq, F. Chaput, K. Lahill, Y. Lẻvy, J. P. Boilot, "Photoinscription of surface relief gratings on azo-hybrid gels,"Adv. Mater. 10, 1133-1138 (1998).
[CrossRef]

1996 (1)

P. Judeinstein and C. Sanchez, "Hybrid organic-inorganic materials: a land of multidisciplinarity," J. Mater. Chem. 6, 511-525 (1996).
[CrossRef]

1993 (1)

B. M. Novak, "Hybrid nanocomposite materials between inorganic glasses and organic polymers," Adv. Mater. 5, 422-433 (1993).
[CrossRef]

1990 (1)

A. Ulman, "Self-assembled monolayers of alkyltrichiorosilanes: Building blocks for future organic materials,"Adv. Mater. 2, 573-582 (1990).
[CrossRef]

Bae, B. S.

Blanc, D.

D. Blanc and S. Pelissier, "Fabrication of sub-micron period diffraction gratings in self-processing sol-gel glasses," Thin Solid Films 384, 251-253 (2001).
[CrossRef]

Chaput, F.

B. Darracq, F. Chaput, K. Lahill, Y. Lẻvy, J. P. Boilot, "Photoinscription of surface relief gratings on azo-hybrid gels,"Adv. Mater. 10, 1133-1138 (1998).
[CrossRef]

Cheong, W. C.

X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).

Darracq, B.

B. Darracq, F. Chaput, K. Lahill, Y. Lẻvy, J. P. Boilot, "Photoinscription of surface relief gratings on azo-hybrid gels,"Adv. Mater. 10, 1133-1138 (1998).
[CrossRef]

Descour, M. R.

Hormi, O. E.

Jabbour, G. E.

Jeong, J. P.

Judeinstein, P.

P. Judeinstein and C. Sanchez, "Hybrid organic-inorganic materials: a land of multidisciplinarity," J. Mater. Chem. 6, 511-525 (1996).
[CrossRef]

Kang, D. J.

Kärkkäinen, A. H. O.

Kim, J. K.

Kintaka, K.

Lahill, K.

B. Darracq, F. Chaput, K. Lahill, Y. Lẻvy, J. P. Boilot, "Photoinscription of surface relief gratings on azo-hybrid gels,"Adv. Mater. 10, 1133-1138 (1998).
[CrossRef]

Neal, D. R.

Ngo, N. Q.

X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).

Nishii, J.

Novak, B. M.

B. M. Novak, "Hybrid nanocomposite materials between inorganic glasses and organic polymers," Adv. Mater. 5, 422-433 (1993).
[CrossRef]

Park, J. U.

Pelissier, S.

D. Blanc and S. Pelissier, "Fabrication of sub-micron period diffraction gratings in self-processing sol-gel glasses," Thin Solid Films 384, 251-253 (2001).
[CrossRef]

Rantala, J. T.

Rogers, J. D.

Sanchez, C.

P. Judeinstein and C. Sanchez, "Hybrid organic-inorganic materials: a land of multidisciplinarity," J. Mater. Chem. 6, 511-525 (1996).
[CrossRef]

Tamkin, J. M.

Ulman, A.

A. Ulman, "Self-assembled monolayers of alkyltrichiorosilanes: Building blocks for future organic materials,"Adv. Mater. 2, 573-582 (1990).
[CrossRef]

Yu, W.

Yu, W. X.

X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).

Yuan, X. -C.

Yuan, X.-C.

X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).

Acc. Chem. Res. (1)

D. J. Kang and B. S. Bae, Photo-imageable sol-gel hybrid materials for simple fabrication of micro-optical elements," Acc. Chem. Res. 40, 903-912 (2007).
[CrossRef]

Adv. Mater. (3)

B. M. Novak, "Hybrid nanocomposite materials between inorganic glasses and organic polymers," Adv. Mater. 5, 422-433 (1993).
[CrossRef]

A. Ulman, "Self-assembled monolayers of alkyltrichiorosilanes: Building blocks for future organic materials,"Adv. Mater. 2, 573-582 (1990).
[CrossRef]

B. Darracq, F. Chaput, K. Lahill, Y. Lẻvy, J. P. Boilot, "Photoinscription of surface relief gratings on azo-hybrid gels,"Adv. Mater. 10, 1133-1138 (1998).
[CrossRef]

Appl. Opt. (1)

J. Mater. Chem. (1)

P. Judeinstein and C. Sanchez, "Hybrid organic-inorganic materials: a land of multidisciplinarity," J. Mater. Chem. 6, 511-525 (1996).
[CrossRef]

Opt. Express (4)

Opt. Express. (1)

X.-C. Yuan, W. X. Yu, N. Q. Ngo, and W. C. Cheong, "Cost-effective fabrication of microlenses on hybrid sol-gel glass with a high-energy beam sensitive gray-scale mask," Opt. Express. 10, 303-308 (2002).

Thin Solid Films (1)

D. Blanc and S. Pelissier, "Fabrication of sub-micron period diffraction gratings in self-processing sol-gel glasses," Thin Solid Films 384, 251-253 (2001).
[CrossRef]

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