Abstract

The single-phased K2Y1-xEuxZr(PO4)3 (x = 0~1) phosphors were prepared by solid-state reaction. The greenish-blue Zr4+-emission due to the Zr4+-O2- charge transfer transition is observed in the K2YZr(PO4)3 (x = 0) phosphor under UV excitation. Together with the Zr4+-emission, the red emission of Eu3+ is progressively developed by replacement of Y3+ to Eu3+ over the full Eu-content (x = 0~1) in K2Y1-xEuxZr(PO4)3. The emission color varies from greenish-blue to whitish with increasing Eu3+-content and the white-light emission is realized in single-phased phosphor of K2EuZr(PO4)3 (x = 1) by combining the Zr4+-emission and the Eu3+-emission.

© 2011 OSA

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  1. H. Guo, X. F. Wang, J. D. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express 18(18), 18900–18905 (2010).
    [CrossRef] [PubMed]
  2. P. Babu, K. H. Jang, Ch. S. Rao, L. Shi, C. K. Jayasankar, V. Lavín, and H. J. Seo, “White light generation in Dy3+-doped oxyfluoride glass and transparent glass-ceramics containing CaF2 nanocrystals,” Opt. Express 19(3), 1836–1841 (2011).
    [CrossRef] [PubMed]
  3. W.-J. Yang and T.-M. Chen, “White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes,” Appl. Phys. Lett. 88, 1019031 (2006).
  4. X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Appl. Phys. Lett. 90(8), 081904 (2007).
    [CrossRef]
  5. N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
    [CrossRef]
  6. E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
    [CrossRef] [PubMed]
  7. G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
    [CrossRef]
  8. Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
    [CrossRef]
  9. M. Kaneyoshi, “Luminescence of some zirconium-containing compounds under vacuum ultraviolet excitation,” J. Lumin. 121(1), 102–108 (2006).
    [CrossRef]
  10. L. Zhang, G. Y. Hong, and X. L. Sun, “The luminescence of the phosphor Sr2ZrO4 with one-dimensional chains structure,” Chin. Chem. Lett. 10, 799–802 (1999).
  11. G. Blasse, J. de Blank, and D. J. W. IJdo, “The luminescence of the garnet Ca4ZrGe3O12,” Mater. Res. Bull. 30(7), 845–850 (1995).
    [CrossRef]
  12. L. Li, S. Zhou, and S. Zhang, “Investigation on charge transfer bands of Ce4+ in Sr2CeO4 blue phosphor,” Chem. Phys. Lett. 453(4-6), 283–289 (2008).
    [CrossRef]
  13. S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
    [CrossRef] [PubMed]
  14. W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
    [CrossRef]
  15. I. V. Ogorodnyk, I. V. Zatovsky, and N. S. Slobodyanik, “Rietveld refinement of langbeinite-type K2YHf(PO4)3,” Acta Crystallogr. Sect. E Struct. Rep. Online 65(8), i63–i64 (2009).
    [CrossRef] [PubMed]
  16. I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
    [CrossRef]
  17. Q. Sun and J. Shi, “Calculation and prediction the charge transfer energy of O2- - Zr4+ in inorganic crystals,” J. Phys. Chem. C 114(7), 3230–3234 (2010).
    [CrossRef]
  18. D. L. Dexter, “A theory of sensitized luminescence in solids,” J. Chem. Phys. 21(5), 836–851 (1953).
    [CrossRef]
  19. S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
    [CrossRef]

2011 (1)

2010 (3)

H. Guo, X. F. Wang, J. D. Chen, and F. Li, “Ultraviolet light induced white light emission in Ag and Eu3+ co-doped oxyfluoride glasses,” Opt. Express 18(18), 18900–18905 (2010).
[CrossRef] [PubMed]

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Q. Sun and J. Shi, “Calculation and prediction the charge transfer energy of O2- - Zr4+ in inorganic crystals,” J. Phys. Chem. C 114(7), 3230–3234 (2010).
[CrossRef]

2009 (1)

I. V. Ogorodnyk, I. V. Zatovsky, and N. S. Slobodyanik, “Rietveld refinement of langbeinite-type K2YHf(PO4)3,” Acta Crystallogr. Sect. E Struct. Rep. Online 65(8), i63–i64 (2009).
[CrossRef] [PubMed]

2008 (1)

L. Li, S. Zhou, and S. Zhang, “Investigation on charge transfer bands of Ce4+ in Sr2CeO4 blue phosphor,” Chem. Phys. Lett. 453(4-6), 283–289 (2008).
[CrossRef]

2007 (1)

X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Appl. Phys. Lett. 90(8), 081904 (2007).
[CrossRef]

2006 (4)

W.-J. Yang and T.-M. Chen, “White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes,” Appl. Phys. Lett. 88, 1019031 (2006).

Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
[CrossRef]

M. Kaneyoshi, “Luminescence of some zirconium-containing compounds under vacuum ultraviolet excitation,” J. Lumin. 121(1), 102–108 (2006).
[CrossRef]

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

2004 (1)

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

1999 (1)

L. Zhang, G. Y. Hong, and X. L. Sun, “The luminescence of the phosphor Sr2ZrO4 with one-dimensional chains structure,” Chin. Chem. Lett. 10, 799–802 (1999).

1998 (1)

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

1997 (1)

W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
[CrossRef]

1996 (1)

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

1995 (2)

G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
[CrossRef]

G. Blasse, J. de Blank, and D. J. W. IJdo, “The luminescence of the garnet Ca4ZrGe3O12,” Mater. Res. Bull. 30(7), 845–850 (1995).
[CrossRef]

1953 (1)

D. L. Dexter, “A theory of sensitized luminescence in solids,” J. Chem. Phys. 21(5), 836–851 (1953).
[CrossRef]

Babu, P.

Basun, S. A.

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

Bernardi, G.

G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
[CrossRef]

Beskrovnyi, A. I.

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

Blasse, G.

G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
[CrossRef]

G. Blasse, J. de Blank, and D. J. W. IJdo, “The luminescence of the garnet Ca4ZrGe3O12,” Mater. Res. Bull. 30(7), 845–850 (1995).
[CrossRef]

Chen, J. D.

Chen, T.-M.

W.-J. Yang and T.-M. Chen, “White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes,” Appl. Phys. Lett. 88, 1019031 (2006).

Danger, T.

W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
[CrossRef]

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

Danielson, E.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

de Blank, J.

G. Blasse, J. de Blank, and D. J. W. IJdo, “The luminescence of the garnet Ca4ZrGe3O12,” Mater. Res. Bull. 30(7), 845–850 (1995).
[CrossRef]

Devenney, M.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Dexter, D. L.

D. L. Dexter, “A theory of sensitized luminescence in solids,” J. Chem. Phys. 21(5), 836–851 (1953).
[CrossRef]

Feofilov, S. P.

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Giaquinta, D. M.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Golden, J. H.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Guo, H.

Guo, N.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Haushalter, R. C.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Hong, G. Y.

L. Zhang, G. Y. Hong, and X. L. Sun, “The luminescence of the phosphor Sr2ZrO4 with one-dimensional chains structure,” Chin. Chem. Lett. 10, 799–802 (1999).

Huang, Y.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Huber, G.

W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
[CrossRef]

IJdo, D. J. W.

G. Blasse, J. de Blank, and D. J. W. IJdo, “The luminescence of the garnet Ca4ZrGe3O12,” Mater. Res. Bull. 30(7), 845–850 (1995).
[CrossRef]

G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
[CrossRef]

Inoue, S.

Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
[CrossRef]

Iyi, N.

Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
[CrossRef]

Jang, K. H.

Jayasankar, C. K.

Jeong, J. Y.

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Kaneyoshi, M.

M. Kaneyoshi, “Luminescence of some zirconium-containing compounds under vacuum ultraviolet excitation,” J. Lumin. 121(1), 102–108 (2006).
[CrossRef]

Kaplyanskii, A. A.

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

Keszler, D. A.

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Kitamura, K.

Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
[CrossRef]

Kurazhkovskaya, V. S.

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

Lavín, V.

Li, F.

Li, L.

L. Li, S. Zhou, and S. Zhang, “Investigation on charge transfer bands of Ce4+ in Sr2CeO4 blue phosphor,” Chem. Phys. Lett. 453(4-6), 283–289 (2008).
[CrossRef]

Lin, C.

X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Appl. Phys. Lett. 90(8), 081904 (2007).
[CrossRef]

Lin, J.

X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Appl. Phys. Lett. 90(8), 081904 (2007).
[CrossRef]

Liu, K.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Liu, X.

X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Appl. Phys. Lett. 90(8), 081904 (2007).
[CrossRef]

McClure, D. S.

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

McFarland, E. W.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Meltzer, R. S.

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Ogorodnyk, I. V.

I. V. Ogorodnyk, I. V. Zatovsky, and N. S. Slobodyanik, “Rietveld refinement of langbeinite-type K2YHf(PO4)3,” Acta Crystallogr. Sect. E Struct. Rep. Online 65(8), i63–i64 (2009).
[CrossRef] [PubMed]

Orlova, A. I.

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

Orlova, V. A.

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

Petermann, K.

W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
[CrossRef]

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

Plaisier, J. R.

G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
[CrossRef]

Poojary, D. M.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Rao, Ch. S.

Reaves, C. M.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Seo, H. J.

P. Babu, K. H. Jang, Ch. S. Rao, L. Shi, C. K. Jayasankar, V. Lavín, and H. J. Seo, “White light generation in Dy3+-doped oxyfluoride glass and transparent glass-ceramics containing CaF2 nanocrystals,” Opt. Express 19(3), 1836–1841 (2011).
[CrossRef] [PubMed]

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Shi, J.

Q. Sun and J. Shi, “Calculation and prediction the charge transfer energy of O2- - Zr4+ in inorganic crystals,” J. Phys. Chem. C 114(7), 3230–3234 (2010).
[CrossRef]

Shi, L.

Slobodyanik, N. S.

I. V. Ogorodnyk, I. V. Zatovsky, and N. S. Slobodyanik, “Rietveld refinement of langbeinite-type K2YHf(PO4)3,” Acta Crystallogr. Sect. E Struct. Rep. Online 65(8), i63–i64 (2009).
[CrossRef] [PubMed]

Song, Y.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Sun, Q.

Q. Sun and J. Shi, “Calculation and prediction the charge transfer energy of O2- - Zr4+ in inorganic crystals,” J. Phys. Chem. C 114(7), 3230–3234 (2010).
[CrossRef]

Sun, X. L.

L. Zhang, G. Y. Hong, and X. L. Sun, “The luminescence of the phosphor Sr2ZrO4 with one-dimensional chains structure,” Chin. Chem. Lett. 10, 799–802 (1999).

Takahashi, Y.

Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
[CrossRef]

Trubach, I. G.

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

Wang, X. F.

Weinberg, W. H.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Wong, W. C.

W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
[CrossRef]

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

Wu, X. D.

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

Yang, M.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Yang, W.-J.

W.-J. Yang and T.-M. Chen, “White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes,” Appl. Phys. Lett. 88, 1019031 (2006).

You, H.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Zatovsky, I. V.

I. V. Ogorodnyk, I. V. Zatovsky, and N. S. Slobodyanik, “Rietveld refinement of langbeinite-type K2YHf(PO4)3,” Acta Crystallogr. Sect. E Struct. Rep. Online 65(8), i63–i64 (2009).
[CrossRef] [PubMed]

Zhang, H.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Zhang, L.

L. Zhang, G. Y. Hong, and X. L. Sun, “The luminescence of the phosphor Sr2ZrO4 with one-dimensional chains structure,” Chin. Chem. Lett. 10, 799–802 (1999).

Zhang, S.

L. Li, S. Zhou, and S. Zhang, “Investigation on charge transfer bands of Ce4+ in Sr2CeO4 blue phosphor,” Chem. Phys. Lett. 453(4-6), 283–289 (2008).
[CrossRef]

Zheng, Y.

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

Zhou, S.

L. Li, S. Zhou, and S. Zhang, “Investigation on charge transfer bands of Ce4+ in Sr2CeO4 blue phosphor,” Chem. Phys. Lett. 453(4-6), 283–289 (2008).
[CrossRef]

Zhou, Y.

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Acta Crystallogr. Sect. E Struct. Rep. Online (1)

I. V. Ogorodnyk, I. V. Zatovsky, and N. S. Slobodyanik, “Rietveld refinement of langbeinite-type K2YHf(PO4)3,” Acta Crystallogr. Sect. E Struct. Rep. Online 65(8), i63–i64 (2009).
[CrossRef] [PubMed]

Appl. Phys. Lett. (3)

W.-J. Yang and T.-M. Chen, “White-light generation and energy transfer in SrZn2(PO4)2:Eu,Mn phosphor for ultraviolet light-emitting diodes,” Appl. Phys. Lett. 88, 1019031 (2006).

X. Liu, C. Lin, and J. Lin, “White light emission from Eu3+ in CaIn2O4 host lattices,” Appl. Phys. Lett. 90(8), 081904 (2007).
[CrossRef]

Y. Takahashi, K. Kitamura, N. Iyi, and S. Inoue, “Visible orange photoluminescence in a barium titanosilicate BaTiSi2O7,” Appl. Phys. Lett. 88(15), 151903 (2006).
[CrossRef]

Chem. Phys. Lett. (1)

L. Li, S. Zhou, and S. Zhang, “Investigation on charge transfer bands of Ce4+ in Sr2CeO4 blue phosphor,” Chem. Phys. Lett. 453(4-6), 283–289 (2008).
[CrossRef]

Chin. Chem. Lett. (1)

L. Zhang, G. Y. Hong, and X. L. Sun, “The luminescence of the phosphor Sr2ZrO4 with one-dimensional chains structure,” Chin. Chem. Lett. 10, 799–802 (1999).

Crystallogr. Rep. (1)

I. G. Trubach, A. I. Beskrovnyi, A. I. Orlova, V. A. Orlova, and V. S. Kurazhkovskaya, “Synthesis and investigation of the new phosphates K2LnZr(PO4)3 (Ln=Ce–Yb, Y) with langbeinite structure,” Crystallogr. Rep. 49(4), 614–618 (2004).
[CrossRef]

J. Alloy. Comp. (1)

G. Blasse, G. Bernardi, D. J. W. IJdo, and J. R. Plaisier, “Yellow zirconate luminescence in Ca3ZrSi2O9,” J. Alloy. Comp. 217(1), 29–30 (1995).
[CrossRef]

J. Chem. Phys. (1)

D. L. Dexter, “A theory of sensitized luminescence in solids,” J. Chem. Phys. 21(5), 836–851 (1953).
[CrossRef]

J. Lumin. (2)

W. C. Wong, T. Danger, G. Huber, and K. Petermann, “Spectroscopy and excited-state absorption of Ti4+:Li4Ge5O12 and Ti4+:Y2SiO5,” J. Lumin. 72–74, 208–210 (1997).
[CrossRef]

M. Kaneyoshi, “Luminescence of some zirconium-containing compounds under vacuum ultraviolet excitation,” J. Lumin. 121(1), 102–108 (2006).
[CrossRef]

J. Mater. Chem. (1)

N. Guo, H. You, Y. Song, M. Yang, K. Liu, Y. Zheng, Y. Huang, and H. Zhang, “White-light emission from a single-emitting-component Ca9Gd(PO4)7:Eu2+,Mn2+ phosphor with tunable luminescent properties for near-UV light-emitting diodes,” J. Mater. Chem. 20(41), 9061–9067 (2010).
[CrossRef]

J. Phys. Chem. C (1)

Q. Sun and J. Shi, “Calculation and prediction the charge transfer energy of O2- - Zr4+ in inorganic crystals,” J. Phys. Chem. C 114(7), 3230–3234 (2010).
[CrossRef]

Mater. Res. Bull. (1)

G. Blasse, J. de Blank, and D. J. W. IJdo, “The luminescence of the garnet Ca4ZrGe3O12,” Mater. Res. Bull. 30(7), 845–850 (1995).
[CrossRef]

Opt. Express (2)

Phys. Rev. B (1)

S. P. Feofilov, Y. Zhou, H. J. Seo, J. Y. Jeong, D. A. Keszler, and R. S. Meltzer, “Host sensitization of Gd3+ ions in yttrium and scandium borates and phosphates: application to quantum cutting,” Phys. Rev. B 74(8), 085101 (2006).
[CrossRef]

Phys. Rev. B Condens. Matter (1)

S. A. Basun, T. Danger, A. A. Kaplyanskii, D. S. McClure, K. Petermann, and W. C. Wong, “Optical and photoelectrical studies of charge-transfer processes in YAlO3:Ti crystals,” Phys. Rev. B Condens. Matter 54(9), 6141–6149 (1996).
[CrossRef] [PubMed]

Science (1)

E. Danielson, M. Devenney, D. M. Giaquinta, J. H. Golden, R. C. Haushalter, E. W. McFarland, D. M. Poojary, C. M. Reaves, W. H. Weinberg, and X. D. Wu, “A rare-earth phosphor containing one-dimensional chains identified through combinatorial methods,” Science 279(5352), 837–839 (1998).
[CrossRef] [PubMed]

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Figures (4)

Fig. 1
Fig. 1

XRD patterns of the K2Y1-xEuxZr(PO4)3 (x = 0 and 1) phosphors and the structural fragment {M2(PO4)3} of K2YZr(PO4)3.

Fig. 2
Fig. 2

Excitation and emission spectra of the K2YZr(PO4)3 (a) and K2EuZr(PO4)3 (b) phosphors at room temperature. The excitation and monitoring wavelengths are indicated.

Fig. 3
Fig. 3

(a) Emission spectra of the K2Y1-xEuxZr(PO4)3 (x = 0 ~1) phosphors for various amounts of Eu3+ under 320 nm excitation at room temperature. (b) The integrated intensity of the Zr4+-emisison (square) and Eu3+-emission (circle).

Fig. 4
Fig. 4

The CIE chromaticity diagram for K2Y1-xEuxZr(PO4)3 (x = 0-1) phosphors excited at 320 nm. The upper inset is the luminescent photography of K2YZr(PO4)3 (point 1) and K2EuZr(PO4)3 (point 6) phosphors. The photographs of the K2YZr(PO4)3 (point 1) and K2EuZr(PO4)3 (point 6) phosphors under 320 nm excitation are shown at the top right.

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