Abstract

We demonstrate filtering characteristics of a polymer band-rejection filter (PBRF) with highly-ordered microphase-separated structure of block copolymers (BCPs). This PBRF is characterized by an Optical Density > 5 blocking at the center wavelength and narrow blocking full bandwidth of 8 nm. Moreover, the wavelength is easily tuned by blending two BCPs with different molecular-weight. A low frequency Raman shift of 200 cm−1 are, in fact, detected with a sufficient resolution by using this filter in Raman spectroscopy.

© 2011 OSA

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  1. P. A. Urbas, Y. Fink, and E. L. Thomas, “One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer-Homopolymer Blends,” Macromolecules 32(14), 4748–4750 (1999).
    [CrossRef]
  2. T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
    [CrossRef]
  3. A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
    [CrossRef]
  4. K. Tsuchiya, S. Nagayasu, S. Okamoto, T. Hayakawa, T. Hihara, K. Yamamoto, I. Takumi, S. Hara, H. Hasegawa, S. Akasaka, and N. Kosikawa, “Nonlinear optical properties of gold nanoparticles selectively introduced into the periodic microdomains of block copolymers,” Opt. Express 16(8), 5362–5371 (2008).
    [CrossRef] [PubMed]
  5. J. Yoon, W. Lee, and E. L. Thomas, “Optically pumped surface-emitting lasing using self-assembled block-copolymer-distributed Bragg reflectors,” Nano Lett. 6(10), 2211–2214 (2006).
    [CrossRef] [PubMed]
  6. Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
    [CrossRef] [PubMed]
  7. E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
    [CrossRef]
  8. A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
    [CrossRef] [PubMed]
  9. A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
    [CrossRef]
  10. J. Yoon, W. Lee, and E. L. Thomas, “Thermochromic Block Copolymer Photonic Gel,” Macromolecules 41(13), 4582–4584 (2008).
    [CrossRef]
  11. I. W. Hamley, “Structure and flow behaviour of block copolymers,” J. Phys. Condens. Matter 13(33), R643–R671 (2001).
    [CrossRef]
  12. I. Rychkov and K. Yoshikawa, “Structural Changes in Block Copolymer Solutions under Shear Flow as Determined by Non-Equilibrium Molecular Dynamics,” Macromol. Theory and Simul. 13(3), 257–264 (2004).
    [CrossRef]
  13. Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
    [CrossRef]
  14. T. Hashimoto, K. Yamasaki, S. Koizumi, and H. Hasegawa, “Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers,” Macromolecules 26(11), 2895–2904 (1993).
    [CrossRef]
  15. H. V. Baghdasaryan and T. M. Knyazyan, “Modelling of strongly nonlinear sinusoidal Bragg gratings by the Method of Single Expression,” Opt. Quantum Electron. 32(6/8), 869–883 (2000).
    [CrossRef]

2011 (2)

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

2010 (1)

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

2008 (2)

2007 (1)

Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
[CrossRef] [PubMed]

2006 (1)

J. Yoon, W. Lee, and E. L. Thomas, “Optically pumped surface-emitting lasing using self-assembled block-copolymer-distributed Bragg reflectors,” Nano Lett. 6(10), 2211–2214 (2006).
[CrossRef] [PubMed]

2005 (1)

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

2004 (1)

I. Rychkov and K. Yoshikawa, “Structural Changes in Block Copolymer Solutions under Shear Flow as Determined by Non-Equilibrium Molecular Dynamics,” Macromol. Theory and Simul. 13(3), 257–264 (2004).
[CrossRef]

2003 (1)

T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
[CrossRef]

2002 (1)

A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
[CrossRef]

2001 (1)

I. W. Hamley, “Structure and flow behaviour of block copolymers,” J. Phys. Condens. Matter 13(33), R643–R671 (2001).
[CrossRef]

2000 (1)

H. V. Baghdasaryan and T. M. Knyazyan, “Modelling of strongly nonlinear sinusoidal Bragg gratings by the Method of Single Expression,” Opt. Quantum Electron. 32(6/8), 869–883 (2000).
[CrossRef]

1999 (1)

P. A. Urbas, Y. Fink, and E. L. Thomas, “One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer-Homopolymer Blends,” Macromolecules 32(14), 4748–4750 (1999).
[CrossRef]

1993 (1)

T. Hashimoto, K. Yamasaki, S. Koizumi, and H. Hasegawa, “Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers,” Macromolecules 26(11), 2895–2904 (1993).
[CrossRef]

Adawi, A. M.

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

Akasaka, S.

Akazawa, Y.

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

Baek, H.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Baghdasaryan, H. V.

H. V. Baghdasaryan and T. M. Knyazyan, “Modelling of strongly nonlinear sinusoidal Bragg gratings by the Method of Single Expression,” Opt. Quantum Electron. 32(6/8), 869–883 (2000).
[CrossRef]

Chen, C.

T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
[CrossRef]

Deng, T.

T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
[CrossRef]

DeRege, P.

A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
[CrossRef]

Fairclough, J. P. A.

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Fink, Y.

P. A. Urbas, Y. Fink, and E. L. Thomas, “One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer-Homopolymer Blends,” Macromolecules 32(14), 4748–4750 (1999).
[CrossRef]

Gorishnyy, T.

Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
[CrossRef] [PubMed]

Hamley, I. W.

I. W. Hamley, “Structure and flow behaviour of block copolymers,” J. Phys. Condens. Matter 13(33), R643–R671 (2001).
[CrossRef]

Hara, S.

Hasegawa, H.

Hashimoto, T.

T. Hashimoto, K. Yamasaki, S. Koizumi, and H. Hasegawa, “Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers,” Macromolecules 26(11), 2895–2904 (1993).
[CrossRef]

Hayakawa, T.

Hihara, T.

Honeker, C.

T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
[CrossRef]

Howse, J. R.

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Hwang, K.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Kang, C.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Kang, Y.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
[CrossRef] [PubMed]

Kim, E.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Knyazyan, T. M.

H. V. Baghdasaryan and T. M. Knyazyan, “Modelling of strongly nonlinear sinusoidal Bragg gratings by the Method of Single Expression,” Opt. Quantum Electron. 32(6/8), 869–883 (2000).
[CrossRef]

Koizumi, S.

T. Hashimoto, K. Yamasaki, S. Koizumi, and H. Hasegawa, “Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers,” Macromolecules 26(11), 2895–2904 (1993).
[CrossRef]

Kosikawa, N.

Kwak, D.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Lee, E.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Lee, W.

J. Yoon, W. Lee, and E. L. Thomas, “Thermochromic Block Copolymer Photonic Gel,” Macromolecules 41(13), 4582–4584 (2008).
[CrossRef]

J. Yoon, W. Lee, and E. L. Thomas, “Optically pumped surface-emitting lasing using self-assembled block-copolymer-distributed Bragg reflectors,” Nano Lett. 6(10), 2211–2214 (2006).
[CrossRef] [PubMed]

Maldovan, M.

A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
[CrossRef]

Matsushita, Y.

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

Mykhaylyk, O. O.

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

Nagayasu, S.

Naruse, M.

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

Okamoto, S.

Panine, P.

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Parnell, A. J.

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Pryke, A.

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Ryan, A. J.

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Rychkov, I.

I. Rychkov and K. Yoshikawa, “Structural Changes in Block Copolymer Solutions under Shear Flow as Determined by Non-Equilibrium Molecular Dynamics,” Macromol. Theory and Simul. 13(3), 257–264 (2004).
[CrossRef]

Takahashi, Y.

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

Takano, A.

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

Takumi, I.

Terrill, N. J.

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

Thomas, E. L.

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

J. Yoon, W. Lee, and E. L. Thomas, “Thermochromic Block Copolymer Photonic Gel,” Macromolecules 41(13), 4582–4584 (2008).
[CrossRef]

Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
[CrossRef] [PubMed]

J. Yoon, W. Lee, and E. L. Thomas, “Optically pumped surface-emitting lasing using self-assembled block-copolymer-distributed Bragg reflectors,” Nano Lett. 6(10), 2211–2214 (2006).
[CrossRef] [PubMed]

T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
[CrossRef]

A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
[CrossRef]

P. A. Urbas, Y. Fink, and E. L. Thomas, “One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer-Homopolymer Blends,” Macromolecules 32(14), 4748–4750 (1999).
[CrossRef]

Tsuchiya, K.

Tzokova, N.

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Urbas, A. M.

A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
[CrossRef]

Urbas, P. A.

P. A. Urbas, Y. Fink, and E. L. Thomas, “One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer-Homopolymer Blends,” Macromolecules 32(14), 4748–4750 (1999).
[CrossRef]

Walish, J. J.

Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
[CrossRef] [PubMed]

Yamamoto, K.

Yamasaki, K.

T. Hashimoto, K. Yamasaki, S. Koizumi, and H. Hasegawa, “Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers,” Macromolecules 26(11), 2895–2904 (1993).
[CrossRef]

Yoon, J.

J. Yoon, W. Lee, and E. L. Thomas, “Thermochromic Block Copolymer Photonic Gel,” Macromolecules 41(13), 4582–4584 (2008).
[CrossRef]

J. Yoon, W. Lee, and E. L. Thomas, “Optically pumped surface-emitting lasing using self-assembled block-copolymer-distributed Bragg reflectors,” Nano Lett. 6(10), 2211–2214 (2006).
[CrossRef] [PubMed]

Yoshikawa, K.

I. Rychkov and K. Yoshikawa, “Structural Changes in Block Copolymer Solutions under Shear Flow as Determined by Non-Equilibrium Molecular Dynamics,” Macromol. Theory and Simul. 13(3), 257–264 (2004).
[CrossRef]

Adv. Funct. Mater. (1)

E. Kim, C. Kang, H. Baek, K. Hwang, D. Kwak, E. Lee, Y. Kang, and E. L. Thomas, “Control of Optical Hysteresis in Block Copolymer Photonic Gels: A Step Towards Wet Photonic Memory Films,” Adv. Funct. Mater. 20(11), 1728–1732 (2010).
[CrossRef]

Adv. Mater. (Deerfield Beach Fla.) (1)

A. M. Urbas, M. Maldovan, P. DeRege, and E. L. Thomas, “Bicontinuous Cubic Block Copolymer Photonic Crystals,” Adv. Mater. (Deerfield Beach Fla.) 14(24), 1850–1853 (2002).
[CrossRef]

J. Phys. Condens. Matter (1)

I. W. Hamley, “Structure and flow behaviour of block copolymers,” J. Phys. Condens. Matter 13(33), R643–R671 (2001).
[CrossRef]

Macromol. Theory and Simul. (1)

I. Rychkov and K. Yoshikawa, “Structural Changes in Block Copolymer Solutions under Shear Flow as Determined by Non-Equilibrium Molecular Dynamics,” Macromol. Theory and Simul. 13(3), 257–264 (2004).
[CrossRef]

Macromolecules (3)

T. Hashimoto, K. Yamasaki, S. Koizumi, and H. Hasegawa, “Ordered structure in blends of block copolymers. 1. Miscibility criterion for lamellar block copolymers,” Macromolecules 26(11), 2895–2904 (1993).
[CrossRef]

J. Yoon, W. Lee, and E. L. Thomas, “Thermochromic Block Copolymer Photonic Gel,” Macromolecules 41(13), 4582–4584 (2008).
[CrossRef]

P. A. Urbas, Y. Fink, and E. L. Thomas, “One-Dimensionally Periodic Dielectric Reflectors from Self-Assembled Block Copolymer-Homopolymer Blends,” Macromolecules 32(14), 4748–4750 (1999).
[CrossRef]

Nano Lett. (1)

J. Yoon, W. Lee, and E. L. Thomas, “Optically pumped surface-emitting lasing using self-assembled block-copolymer-distributed Bragg reflectors,” Nano Lett. 6(10), 2211–2214 (2006).
[CrossRef] [PubMed]

Nat. Mater. (1)

Y. Kang, J. J. Walish, T. Gorishnyy, and E. L. Thomas, “Broad-wavelength-range chemically tunable block-copolymer photonic gels,” Nat. Mater. 6(12), 957–960 (2007).
[CrossRef] [PubMed]

Opt. Express (1)

Opt. Quantum Electron. (1)

H. V. Baghdasaryan and T. M. Knyazyan, “Modelling of strongly nonlinear sinusoidal Bragg gratings by the Method of Single Expression,” Opt. Quantum Electron. 32(6/8), 869–883 (2000).
[CrossRef]

Phys. Chem. Chem. Phys. (1)

A. J. Parnell, N. Tzokova, A. Pryke, J. R. Howse, O. O. Mykhaylyk, A. J. Ryan, P. Panine, and J. P. A. Fairclough, “Shear ordered diblock copolymers with tuneable optical properties,” Phys. Chem. Chem. Phys. 13(8), 3179–3186 (2011).
[CrossRef] [PubMed]

Polym. J. (1)

Y. Takahashi, M. Naruse, Y. Akazawa, A. Takano, and Y. Matsushita, “Comparison between Flow-Induced Alignment Behaviors of Poly(styrene-block-2-vinylpyridine)s and Poly(styrene-block-isoprene)s Solutions near ODT,” Polym. J. 37(12), 900–905 (2005).
[CrossRef]

Polymer (Guildf.) (1)

T. Deng, C. Chen, C. Honeker, and E. L. Thomas, “Two-dimensional block copolymer photonic crystals,” Polymer (Guildf.) 44(21), 6549–6553 (2003).
[CrossRef]

Soft Matter (1)

A. J. Parnell, A. Pryke, O. O. Mykhaylyk, J. R. Howse, A. M. Adawi, N. J. Terrill, and J. P. A. Fairclough, “Continuously tuneable optical filters from self-assembled block copolymer blends,” Soft Matter 7(8), 3721–3725 (2011).
[CrossRef]

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Figures (6)

Fig. 1
Fig. 1

Photograph of our PBRF prepared by UV cure. The diameter and thickness of this flexible film are 100 mm and 230 μm, respectively. The observed color is due to periodic structure of BCPs.

Fig. 2
Fig. 2

TEM image of highly-ordered lamellar structure in the PBRF, in which the dark and bright regions correspond to PS domains stained with RuO4 and to PtBuMA domains, respectively. The domain spacing is approximately 180 nm.

Fig. 3
Fig. 3

2D SAXS image of the PBRF. The incident direction of X-ray was normal to the cross section of the film. The parasitic scattering at the center is due to thin film. The domain spacing is estimated at 180 nm.

Fig. 4
Fig. 4

Spectral transmission characteristics of the PBRFs. The OD values were corrected by monochromatic laser light transmission. The inset shows a transmission spectrum measured just after applying shear flow field.

Fig. 5
Fig. 5

Comparing measured transmission spectrum with the spectra estimated by transfer matrix method for a finite 1D periodic structure.

Fig. 6
Fig. 6

Raman spectra of chlorobenzene pumped at 532 nm by using conventional dielectric multilayered filter and our PBRF.

Equations (3)

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q=(4π/ λ x-ray )sin(θ/2),
d=2π/q.
OD= log 10 (1/T),

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