Abstract

We report on the conception, design, fabrication, experimental characterization, and theoretical analysis of nanocrystal scintillators hybridized on Si detectors and CCDs for enhanced detection and imaging in UV. Integrating luminescent CdSe/ZnS core-shell nanocrystals (NCs of 3.2 and 5.2 nm in diameter with 5% size distribution) to efficiently convert incident UV radiation to visible emission, we demonstrate hybrid NC-Si photodetectors that exhibit significantly improved responsivity between 200-240nm, experimentally with a two orders of magnitude peak enhancement and theoretically with a three orders of magnitude peak enhancement. Such nanocrystal based scintillators hold great promise in UV detection and imaging on Si platforms.

© 2007 Optical Society of America

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  1. L. Pavesi and D. J. Lockwood, Silicon Photonics (Springer, 2004).
  2. G. T. Reed and A. P. Knights, Silicon Photonics: An Introduction (John Wiley and Sons, 2004).
    [CrossRef]
  3. R. Soref, "Silicon photonics technology: past, present, and future," Proc. SPIE 5730,19-28 (2005).
    [CrossRef]
  4. C. Gunn, "CMOS photonics for high-speed interconnects," IEEE Micro 26, 58-66 (2006).
    [CrossRef]
  5. C. Gunn, "Photonics integration for optical interconnects," in Proceedings of IEEE LEOS 2005 Annual Meeting (IEEE, 2005) pp. 732.
  6. T. T. Saito, "Technological opportunities in homeland security," http://www.coloradophotonics.org
  7. T. Price, "Homeland security forces seek help from optical science," Opt. Photonics News 16-17 (2006).
  8. S. Gaponenko, Optical properties of semiconductor nanocrystals (Cambridge University Press, 1998).
    [CrossRef]
  9. M. A Hines and P. Guyot-Sionnest, "Synthesis and characterization of strongly luminescent ZnS-capped CdSe nanocrystals," J. Phys. Chem. 100, 468-471 (1996).
    [CrossRef]
  10. B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
    [CrossRef]
  11. S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
    [CrossRef] [PubMed]
  12. S. Chaudhary, M. Ozkan, and W. C. W. Chan, "Trilayer hybrid polymer-quantum dot light-emitting diodes," Appl. Phys. Lett. 84, 2925-2927 (2004).
    [CrossRef]
  13. S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
    [CrossRef]
  14. J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
    [CrossRef] [PubMed]
  15. D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
    [CrossRef]
  16. M. B. Fischbein and M. Drndic, "CdSe nanocrystal quantum-dot memory," Appl. Phys. Lett. 86, 193106 (2005).
    [CrossRef]
  17. H. V. Demir, I. M. Soganci, and E. Mutlugun, "CdSe/ZnS core-shell nanocrystal based scintillators for enhanced detection in UV," in Proceedings of IEEE LEOS 2006 Annual Meeting (IEEE 2006), pp. WN3.

2007 (1)

S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
[CrossRef]

2006 (1)

C. Gunn, "CMOS photonics for high-speed interconnects," IEEE Micro 26, 58-66 (2006).
[CrossRef]

2005 (3)

R. Soref, "Silicon photonics technology: past, present, and future," Proc. SPIE 5730,19-28 (2005).
[CrossRef]

D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
[CrossRef]

M. B. Fischbein and M. Drndic, "CdSe nanocrystal quantum-dot memory," Appl. Phys. Lett. 86, 193106 (2005).
[CrossRef]

2004 (2)

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

S. Chaudhary, M. Ozkan, and W. C. W. Chan, "Trilayer hybrid polymer-quantum dot light-emitting diodes," Appl. Phys. Lett. 84, 2925-2927 (2004).
[CrossRef]

2002 (1)

S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
[CrossRef] [PubMed]

1997 (1)

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

1996 (1)

M. A Hines and P. Guyot-Sionnest, "Synthesis and characterization of strongly luminescent ZnS-capped CdSe nanocrystals," J. Phys. Chem. 100, 468-471 (1996).
[CrossRef]

Alivisatos, A. P.

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

Bawendi, M.

S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
[CrossRef] [PubMed]

Bawendi, M. G.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Bulovic, V.

S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
[CrossRef] [PubMed]

Chan, W. C. W.

S. Chaudhary, M. Ozkan, and W. C. W. Chan, "Trilayer hybrid polymer-quantum dot light-emitting diodes," Appl. Phys. Lett. 84, 2925-2927 (2004).
[CrossRef]

Chaudhary, S.

S. Chaudhary, M. Ozkan, and W. C. W. Chan, "Trilayer hybrid polymer-quantum dot light-emitting diodes," Appl. Phys. Lett. 84, 2925-2927 (2004).
[CrossRef]

Coe, S.

S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
[CrossRef] [PubMed]

Dabbousi, B. O.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Demir, H. V.

S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
[CrossRef]

Drndic, M.

D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
[CrossRef]

M. B. Fischbein and M. Drndic, "CdSe nanocrystal quantum-dot memory," Appl. Phys. Lett. 86, 193106 (2005).
[CrossRef]

Fischbein, M. B.

M. B. Fischbein and M. Drndic, "CdSe nanocrystal quantum-dot memory," Appl. Phys. Lett. 86, 193106 (2005).
[CrossRef]

D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
[CrossRef]

Fréchet, J. M. J.

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

Gunn, C.

C. Gunn, "CMOS photonics for high-speed interconnects," IEEE Micro 26, 58-66 (2006).
[CrossRef]

Guyot-Sionnest, P.

M. A Hines and P. Guyot-Sionnest, "Synthesis and characterization of strongly luminescent ZnS-capped CdSe nanocrystals," J. Phys. Chem. 100, 468-471 (1996).
[CrossRef]

Heine, J. R.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Hines, M. A

M. A Hines and P. Guyot-Sionnest, "Synthesis and characterization of strongly luminescent ZnS-capped CdSe nanocrystals," J. Phys. Chem. 100, 468-471 (1996).
[CrossRef]

Jensen, K. F.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Liu, J.

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

Mattoussi, H.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Mikulec, F. V.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Nizamoglu, S.

S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
[CrossRef]

Ober, R.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Ozel, T.

S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
[CrossRef]

Ozkan, M.

S. Chaudhary, M. Ozkan, and W. C. W. Chan, "Trilayer hybrid polymer-quantum dot light-emitting diodes," Appl. Phys. Lett. 84, 2925-2927 (2004).
[CrossRef]

Qi, D.

D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
[CrossRef]

Rodriguez-Viejo, J.

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Sari, E.

S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
[CrossRef]

Selmic, S.

D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
[CrossRef]

Sivula, K.

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

Soref, R.

R. Soref, "Silicon photonics technology: past, present, and future," Proc. SPIE 5730,19-28 (2005).
[CrossRef]

Tanaka, T.

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

Woo, W.-K.

S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
[CrossRef] [PubMed]

Appl. Phys. Lett. (3)

S. Chaudhary, M. Ozkan, and W. C. W. Chan, "Trilayer hybrid polymer-quantum dot light-emitting diodes," Appl. Phys. Lett. 84, 2925-2927 (2004).
[CrossRef]

D. Qi, M. B. Fischbein, M. Drndic, and S. Selmic, "Efficient polymer-nanocrystal quantum-dot photodetectors," Appl. Phys. Lett. 86, 093103 (2005).
[CrossRef]

M. B. Fischbein and M. Drndic, "CdSe nanocrystal quantum-dot memory," Appl. Phys. Lett. 86, 193106 (2005).
[CrossRef]

IEEE Micro (1)

C. Gunn, "CMOS photonics for high-speed interconnects," IEEE Micro 26, 58-66 (2006).
[CrossRef]

J. Am. Chem. Soc. (1)

J. Liu, T. Tanaka, K. Sivula, A. P. Alivisatos, and J. M. J. Fréchet, "Employing end-functional polythiophene to control the morphology of nanocrystal-polymer composites in hybrid solar cells," J. Am. Chem. Soc. 126, 6550-6551 (2004).
[CrossRef] [PubMed]

J. Phys. Chem. (1)

M. A Hines and P. Guyot-Sionnest, "Synthesis and characterization of strongly luminescent ZnS-capped CdSe nanocrystals," J. Phys. Chem. 100, 468-471 (1996).
[CrossRef]

J. Phys. Chem. B (1)

B. O. Dabbousi, J. Rodriguez-Viejo, F. V. Mikulec, J. R. Heine, H. Mattoussi, R. Ober, K. F. Jensen and M. G. Bawendi, "(CdSe)ZnS core-shell quantum dots: synthesis and characterization of a size series of highly luminescent nanocrystallites," J. Phys. Chem. B 101, 9463-9475 (1997).
[CrossRef]

Nanotechnology (1)

S. Nizamoglu, T. Ozel, E. Sari, and H. V. Demir, "White light generation using CdSe/ZnS core-shell nanocrystals hybridized with InGaN/GaN light emitting diodes," Nanotechnology 18, 065709 (2007).
[CrossRef]

Nature (1)

S. Coe, W.-K. Woo, M. Bawendi, and V. Bulovic, "Electroluminescence from single monolayers of nanocrystals in molecular organic devices," Nature 420, 800-803 (2002).
[CrossRef] [PubMed]

Proc. SPIE (1)

R. Soref, "Silicon photonics technology: past, present, and future," Proc. SPIE 5730,19-28 (2005).
[CrossRef]

Other (7)

H. V. Demir, I. M. Soganci, and E. Mutlugun, "CdSe/ZnS core-shell nanocrystal based scintillators for enhanced detection in UV," in Proceedings of IEEE LEOS 2006 Annual Meeting (IEEE 2006), pp. WN3.

L. Pavesi and D. J. Lockwood, Silicon Photonics (Springer, 2004).

G. T. Reed and A. P. Knights, Silicon Photonics: An Introduction (John Wiley and Sons, 2004).
[CrossRef]

C. Gunn, "Photonics integration for optical interconnects," in Proceedings of IEEE LEOS 2005 Annual Meeting (IEEE, 2005) pp. 732.

T. T. Saito, "Technological opportunities in homeland security," http://www.coloradophotonics.org

T. Price, "Homeland security forces seek help from optical science," Opt. Photonics News 16-17 (2006).

S. Gaponenko, Optical properties of semiconductor nanocrystals (Cambridge University Press, 1998).
[CrossRef]

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Figures (8)

Fig. 1.
Fig. 1.

Experimental demonstration of improvement in the spectral response of a Si detector when hybridized with a nanocrystal scintillator (using red CdSe/ZnS nanocrystals).

Fig. 2.
Fig. 2.

Photoluminescence spectra of our red and yellow nanocrystals (NC). Insets show the absorption spectrum along with the photoluminescence spectrum of the respective nanocrystal.

Fig. 3.
Fig. 3.

The spectral ratio of the emitted optical power to the incident power measured on red type nanocrystals at room temperature.

Fig. 4.
Fig. 4.

The spectral responsivity of a Si photodetector with and without hybridizing red nanocrystal scintillator measured at room temperature. (The responsivity of bare Si detector is shown in navy curve and that of the same Si detector integrated with red nanocrystal scintillator is shown in red curve; the inset shows improvement of the spectral responsivity.)

Fig. 5.
Fig. 5.

Transmission spectra of red nanocrystals and host polymer measured at room temperature.

Fig. 6.
Fig. 6.

Semi-empirical simulation results for the improvement in the spectral responsivity of the Si photodetector integrating with red nanocrystal scintillators.

Fig. 7.
Fig. 7.

The spectral responsivity of a Si photodetector with and without hybridizing yellow nanocrystal scintillator measured at room temperature. (The responsivity of bare Si detector is shown in navy curve and that of the same Si detector integrated with yellow nanocrystal scintillator is shown in yellow curve; the inset shows improvement of the spectral responsivity).

Fig. 8.
Fig. 8.

Snapshots taken from CCD cameras under UV illumination at room temperature: the response of a CCD (a) without and (b) with hybridizing nanocrystal scintillator under broad UV illumination; and the response of another CCD (c) without and (d) with the scintillator when a UV optical beam is incident.

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