Abstract

This paper discusses homogeneous nanocomposite media that contain up to 12 wt% of SiO<sub>2</sub> nanoparticles. The method of producing nanocomposites is based on the processes of self-organization accompanying the formation of thin polymer shells around each nanoparticle, which is the main way of obtaining an optical quasi-homogeneous material. When the initial monomeric compound is polymerized with UV irradiation, a solid transparent nanocomposite is obtained. Infrared spectroscopy and the determination of the sorption and hardness of the composites are used to confirm the presence of self-organization processes accompanying the formation of the material. The types of nanoparticle–polymer chemical bonds are investigated and determined.

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  1. A. S. Rozenberg, G. I. Dzhardimalieva, and A. D. Pomogailo, “Polymer composites of nano-sized particles isolated in matrix,” Polym. Adv. Technol. 9, 527 (1998).
    [CrossRef]
  2. A. D. Pomogailo and V. S. Savost’yanov, Synthesis and Polymerization of Metal-Containing Monomers (CRC Press, Boca Raton, 1994).
  3. A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).
  4. Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].
  5. I. Yu. Denisyuk, T. R. Williams, and J. E. Burunkova, “Hybrid optical material based on high nanoparticles concentration in UV-curable polymers–technology and proprieties,” Mol. Cryst. Liq. Cryst. 497, 142 (2008).
  6. A. P. Vinogradov, Electrodynamics of Composite Materials (URSS, Moscow, 2001).
  7. S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
    [CrossRef]
  8. A. Kh. Kuptsov and G. N. Zhizhin, Fourier–Raman and Fourier-IR Spectra of Polymers. A Handbook (Fizmatlit, 2001).

2008 (2)

Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].

I. Yu. Denisyuk, T. R. Williams, and J. E. Burunkova, “Hybrid optical material based on high nanoparticles concentration in UV-curable polymers–technology and proprieties,” Mol. Cryst. Liq. Cryst. 497, 142 (2008).

2006 (1)

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

2001 (1)

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).

1998 (1)

A. S. Rozenberg, G. I. Dzhardimalieva, and A. D. Pomogailo, “Polymer composites of nano-sized particles isolated in matrix,” Polym. Adv. Technol. 9, 527 (1998).
[CrossRef]

Bertsch, A.

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

Burunkova, J. E.

I. Yu. Denisyuk, T. R. Williams, and J. E. Burunkova, “Hybrid optical material based on high nanoparticles concentration in UV-curable polymers–technology and proprieties,” Mol. Cryst. Liq. Cryst. 497, 142 (2008).

Burunkova, Yu. É.

Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].

Denisyuk, I. Yu.

I. Yu. Denisyuk, T. R. Williams, and J. E. Burunkova, “Hybrid optical material based on high nanoparticles concentration in UV-curable polymers–technology and proprieties,” Mol. Cryst. Liq. Cryst. 497, 142 (2008).

Dzhardimalieva, G. I.

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).

A. S. Rozenberg, G. I. Dzhardimalieva, and A. D. Pomogailo, “Polymer composites of nano-sized particles isolated in matrix,” Polym. Adv. Technol. 9, 527 (1998).
[CrossRef]

Hofmann, H.

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

Jiguet, S.

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

Judelewicz, M.

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

Kaporskii, L. N.

Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].

Kuptsov, A. Kh.

A. Kh. Kuptsov and G. N. Zhizhin, Fourier–Raman and Fourier-IR Spectra of Polymers. A Handbook (Fizmatlit, 2001).

Leonowicz, M.

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).

Levichev, V. V.

Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].

Pomogailo, A. D.

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).

A. S. Rozenberg, G. I. Dzhardimalieva, and A. D. Pomogailo, “Polymer composites of nano-sized particles isolated in matrix,” Polym. Adv. Technol. 9, 527 (1998).
[CrossRef]

A. D. Pomogailo and V. S. Savost’yanov, Synthesis and Polymerization of Metal-Containing Monomers (CRC Press, Boca Raton, 1994).

Renaud, P.

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

Rozenberg, A. S.

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).

A. S. Rozenberg, G. I. Dzhardimalieva, and A. D. Pomogailo, “Polymer composites of nano-sized particles isolated in matrix,” Polym. Adv. Technol. 9, 527 (1998).
[CrossRef]

Savost’yanov, V. S.

A. D. Pomogailo and V. S. Savost’yanov, Synthesis and Polymerization of Metal-Containing Monomers (CRC Press, Boca Raton, 1994).

Sem’ina, S. A.

Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].

Vinogradov, A. P.

A. P. Vinogradov, Electrodynamics of Composite Materials (URSS, Moscow, 2001).

Williams, T. R.

I. Yu. Denisyuk, T. R. Williams, and J. E. Burunkova, “Hybrid optical material based on high nanoparticles concentration in UV-curable polymers–technology and proprieties,” Mol. Cryst. Liq. Cryst. 497, 142 (2008).

Zhizhin, G. N.

A. Kh. Kuptsov and G. N. Zhizhin, Fourier–Raman and Fourier-IR Spectra of Polymers. A Handbook (Fizmatlit, 2001).

Adv. Mater. Sci. (1)

A. D. Pomogailo, A. S. Rozenberg, G. I. Dzhardimalieva, and M. Leonowicz, “Polymer nanocomposites on the base of metal carboxylates,” Adv. Mater. Sci. 1, 19 (2001).

Microelectron. Eng. (1)

S. Jiguet, A. Bertsch, M. Judelewicz, H. Hofmann, and P. Renaud, “SU-8 nanocomposite photoresist with low stress properties for microfabrication applications,” Microelectron. Eng. No. 83, 1966 (2006).
[CrossRef]

Mol. Cryst. Liq. Cryst. (1)

I. Yu. Denisyuk, T. R. Williams, and J. E. Burunkova, “Hybrid optical material based on high nanoparticles concentration in UV-curable polymers–technology and proprieties,” Mol. Cryst. Liq. Cryst. 497, 142 (2008).

Opt. Zh. (1)

Yu. É. Burunkova, S. A. Sem’ina, L. N. Kaporskiĭ, and V. V. Levichev, “Nanomodified optical acrylate composites,” Opt. Zh. 75, No. 10, 54 (2008). [J. Opt. Technol. 75, 653 (2008)].

Polym. Adv. Technol. (1)

A. S. Rozenberg, G. I. Dzhardimalieva, and A. D. Pomogailo, “Polymer composites of nano-sized particles isolated in matrix,” Polym. Adv. Technol. 9, 527 (1998).
[CrossRef]

Other (3)

A. D. Pomogailo and V. S. Savost’yanov, Synthesis and Polymerization of Metal-Containing Monomers (CRC Press, Boca Raton, 1994).

A. P. Vinogradov, Electrodynamics of Composite Materials (URSS, Moscow, 2001).

A. Kh. Kuptsov and G. N. Zhizhin, Fourier–Raman and Fourier-IR Spectra of Polymers. A Handbook (Fizmatlit, 2001).

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