Abstract

This paper discusses how acidic solutions affect the variation of the refractive index and thickness of a nanosize film of oxide composition (20 mol% Bi<sub>2</sub>O<sub>3</sub>, 25 mol% Fe<sub>2</sub>O<sub>3</sub>, 55 mol% TiO<sub>2</sub>), deposited on a glass substrate by the sol–gel method. When the film is allowed to stand in the solutions, it simultaneously swells, with an increase of its thickness, and dissolves. The swelling initiates an increase of the refractive index, and the dissolution reduces it.

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  1. N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].
  2. K. V. Dukel’skiĭ and S. K. Evstrop’ev, “Forming nanosize MgO coatings on a glass surface,” Opt. Zh. 77, No. 1, 58 (2010). [J. Opt. Technol. 77, 45 (2010)].
  3. N. V. Suĭkovskaya, Chemical Methods of Obtaining Thin Transparent Films (Khimiya, Leningrad, 1971).
  4. P. Legrand, R. Temey, K. Vandiest, and M. Hannotiau, “Vitrage portant un revetement pyrolytique,” Swiss Patent No. 690 302 (2000).
  5. H. Tomonaga, T. Morimoto, and K. Sunahara, “Glass for screening IR radiation,” Application 1541536 EPV, MKI7 S03S17/25, Asachi Glass Co., No. 03771402.9, applied for 7/29/2003, published 6/15/2005.
  6. V. Srikanth, D. A. Strickler, and K. Sanderson, “Method of forming niobium-doped tin oxide coatings on glass and coated glass formed thereby,” U.S. Patent No. 6 827 970 (2004).
  7. L. P. Borilo, A. M. Shul’pekov, and O. V. Turetskova, “Multifunctional thin-film materials based on oxides,” Steklo i Keramika No. 2, 20 (2003).
  8. A. B. Atkarskaya, P. V. Chartiĭ, and V. G. Shemanin, “The effect of the technological coating conditions on the properties of nanofilms of the Bi2O3–TiO2–Fe2O3 system,” Opt. Zh. 78, No. 2, 82 (2011). [J. Opt. Technol. 78, 145 (2011)].
  9. A. B. Atkarskaya, “Sol–gel coating on float glass,” Steklo i Keramika No. 4, 5 (2006).
  10. A. B. Atkarskaya, V. I. Borul’ko, and V. Yu. Goĭkhman, “Heat-reflecting coating for glass,” Inventor’s Certificate 1 799 856, Byull. Izobr. No. 9, 157 (1993).
  11. A. A. Barybin and V. I. Shapovalov, “Differential equation for the melting temperature of small-size particles,” Pis’ma Zh. Tekh. Fiz. 36, No. 22, 69 (2010). [Tech. Phys. Lett. 36, 1058 (2010)].
  12. V. A. Rabinovich and Z. Ya. Khavin, Brief Chemical Handbook (Khimiya, Leningrad, 1978).
  13. D. A. Fanderlik, Course of Colloidal Chemistry (Khimiya, Leningrad, 1974).
  14. A. B. Atkarskaya and V. I. Kiyan, “Microhardness of sol–gel films of various textures,” Steklo i Keramika No. 7, 5 (2000).
  15. P. G. Cheremskoĭ, V. V. Slezov, and V. P. Betekhshin, Pores in Solids (Énergoatomizdat, Moscow, 1990).

2011 (1)

A. B. Atkarskaya, P. V. Chartiĭ, and V. G. Shemanin, “The effect of the technological coating conditions on the properties of nanofilms of the Bi2O3–TiO2–Fe2O3 system,” Opt. Zh. 78, No. 2, 82 (2011). [J. Opt. Technol. 78, 145 (2011)].

2010 (2)

K. V. Dukel’skiĭ and S. K. Evstrop’ev, “Forming nanosize MgO coatings on a glass surface,” Opt. Zh. 77, No. 1, 58 (2010). [J. Opt. Technol. 77, 45 (2010)].

A. A. Barybin and V. I. Shapovalov, “Differential equation for the melting temperature of small-size particles,” Pis’ma Zh. Tekh. Fiz. 36, No. 22, 69 (2010). [Tech. Phys. Lett. 36, 1058 (2010)].

2008 (1)

N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].

2006 (1)

A. B. Atkarskaya, “Sol–gel coating on float glass,” Steklo i Keramika No. 4, 5 (2006).

2003 (1)

L. P. Borilo, A. M. Shul’pekov, and O. V. Turetskova, “Multifunctional thin-film materials based on oxides,” Steklo i Keramika No. 2, 20 (2003).

2000 (1)

A. B. Atkarskaya and V. I. Kiyan, “Microhardness of sol–gel films of various textures,” Steklo i Keramika No. 7, 5 (2000).

1993 (1)

A. B. Atkarskaya, V. I. Borul’ko, and V. Yu. Goĭkhman, “Heat-reflecting coating for glass,” Inventor’s Certificate 1 799 856, Byull. Izobr. No. 9, 157 (1993).

Atkarskaya, A. B.

A. B. Atkarskaya, P. V. Chartiĭ, and V. G. Shemanin, “The effect of the technological coating conditions on the properties of nanofilms of the Bi2O3–TiO2–Fe2O3 system,” Opt. Zh. 78, No. 2, 82 (2011). [J. Opt. Technol. 78, 145 (2011)].

A. B. Atkarskaya, “Sol–gel coating on float glass,” Steklo i Keramika No. 4, 5 (2006).

A. B. Atkarskaya and V. I. Kiyan, “Microhardness of sol–gel films of various textures,” Steklo i Keramika No. 7, 5 (2000).

A. B. Atkarskaya, V. I. Borul’ko, and V. Yu. Goĭkhman, “Heat-reflecting coating for glass,” Inventor’s Certificate 1 799 856, Byull. Izobr. No. 9, 157 (1993).

Barybin, A. A.

A. A. Barybin and V. I. Shapovalov, “Differential equation for the melting temperature of small-size particles,” Pis’ma Zh. Tekh. Fiz. 36, No. 22, 69 (2010). [Tech. Phys. Lett. 36, 1058 (2010)].

Betekhshin, V. P.

P. G. Cheremskoĭ, V. V. Slezov, and V. P. Betekhshin, Pores in Solids (Énergoatomizdat, Moscow, 1990).

Borilo, L. P.

L. P. Borilo, A. M. Shul’pekov, and O. V. Turetskova, “Multifunctional thin-film materials based on oxides,” Steklo i Keramika No. 2, 20 (2003).

Borul’ko, V. I.

A. B. Atkarskaya, V. I. Borul’ko, and V. Yu. Goĭkhman, “Heat-reflecting coating for glass,” Inventor’s Certificate 1 799 856, Byull. Izobr. No. 9, 157 (1993).

Chartii, P. V.

A. B. Atkarskaya, P. V. Chartiĭ, and V. G. Shemanin, “The effect of the technological coating conditions on the properties of nanofilms of the Bi2O3–TiO2–Fe2O3 system,” Opt. Zh. 78, No. 2, 82 (2011). [J. Opt. Technol. 78, 145 (2011)].

Cheremskoi, P. G.

P. G. Cheremskoĭ, V. V. Slezov, and V. P. Betekhshin, Pores in Solids (Énergoatomizdat, Moscow, 1990).

Dukel’skii, K. V.

K. V. Dukel’skiĭ and S. K. Evstrop’ev, “Forming nanosize MgO coatings on a glass surface,” Opt. Zh. 77, No. 1, 58 (2010). [J. Opt. Technol. 77, 45 (2010)].

Evstrop’ev, S. K.

K. V. Dukel’skiĭ and S. K. Evstrop’ev, “Forming nanosize MgO coatings on a glass surface,” Opt. Zh. 77, No. 1, 58 (2010). [J. Opt. Technol. 77, 45 (2010)].

Fanderlik, D. A.

D. A. Fanderlik, Course of Colloidal Chemistry (Khimiya, Leningrad, 1974).

Goikhman, V. Yu.

A. B. Atkarskaya, V. I. Borul’ko, and V. Yu. Goĭkhman, “Heat-reflecting coating for glass,” Inventor’s Certificate 1 799 856, Byull. Izobr. No. 9, 157 (1993).

Kamanina, N. V.

N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].

Khavin, Z. Ya.

V. A. Rabinovich and Z. Ya. Khavin, Brief Chemical Handbook (Khimiya, Leningrad, 1978).

Kiyan, V. I.

A. B. Atkarskaya and V. I. Kiyan, “Microhardness of sol–gel films of various textures,” Steklo i Keramika No. 7, 5 (2000).

Rabinovich, V. A.

V. A. Rabinovich and Z. Ya. Khavin, Brief Chemical Handbook (Khimiya, Leningrad, 1978).

Shapovalov, V. I.

A. A. Barybin and V. I. Shapovalov, “Differential equation for the melting temperature of small-size particles,” Pis’ma Zh. Tekh. Fiz. 36, No. 22, 69 (2010). [Tech. Phys. Lett. 36, 1058 (2010)].

Shemanin, V. G.

A. B. Atkarskaya, P. V. Chartiĭ, and V. G. Shemanin, “The effect of the technological coating conditions on the properties of nanofilms of the Bi2O3–TiO2–Fe2O3 system,” Opt. Zh. 78, No. 2, 82 (2011). [J. Opt. Technol. 78, 145 (2011)].

Shul’pekov, A. M.

L. P. Borilo, A. M. Shul’pekov, and O. V. Turetskova, “Multifunctional thin-film materials based on oxides,” Steklo i Keramika No. 2, 20 (2003).

Slezov, V. V.

P. G. Cheremskoĭ, V. V. Slezov, and V. P. Betekhshin, Pores in Solids (Énergoatomizdat, Moscow, 1990).

Studenov, V. I.

N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].

Suikovskaya, N. V.

N. V. Suĭkovskaya, Chemical Methods of Obtaining Thin Transparent Films (Khimiya, Leningrad, 1971).

Turetskova, O. V.

L. P. Borilo, A. M. Shul’pekov, and O. V. Turetskova, “Multifunctional thin-film materials based on oxides,” Steklo i Keramika No. 2, 20 (2003).

Usanov, Yu. E.

N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].

Vasil’ev, P. Ya.

N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].

Byull. Izobr. (1)

A. B. Atkarskaya, V. I. Borul’ko, and V. Yu. Goĭkhman, “Heat-reflecting coating for glass,” Inventor’s Certificate 1 799 856, Byull. Izobr. No. 9, 157 (1993).

Opt. Zh. (3)

N. V. Kamanina, P. Ya. Vasil’ev, V. I. Studenov, and Yu. E. Usanov, “Strengthening transparent conductive coatings and ‘soft’ materials of the IR range when nanotechnology is used,” Opt. Zh. 75, No. 1, 83 (2008). [J. Opt. Technol. 75, 67 (2008)].

K. V. Dukel’skiĭ and S. K. Evstrop’ev, “Forming nanosize MgO coatings on a glass surface,” Opt. Zh. 77, No. 1, 58 (2010). [J. Opt. Technol. 77, 45 (2010)].

A. B. Atkarskaya, P. V. Chartiĭ, and V. G. Shemanin, “The effect of the technological coating conditions on the properties of nanofilms of the Bi2O3–TiO2–Fe2O3 system,” Opt. Zh. 78, No. 2, 82 (2011). [J. Opt. Technol. 78, 145 (2011)].

Pis’ma Zh. Tekh. Fiz. (1)

A. A. Barybin and V. I. Shapovalov, “Differential equation for the melting temperature of small-size particles,” Pis’ma Zh. Tekh. Fiz. 36, No. 22, 69 (2010). [Tech. Phys. Lett. 36, 1058 (2010)].

Steklo i Keramika (3)

A. B. Atkarskaya, “Sol–gel coating on float glass,” Steklo i Keramika No. 4, 5 (2006).

A. B. Atkarskaya and V. I. Kiyan, “Microhardness of sol–gel films of various textures,” Steklo i Keramika No. 7, 5 (2000).

L. P. Borilo, A. M. Shul’pekov, and O. V. Turetskova, “Multifunctional thin-film materials based on oxides,” Steklo i Keramika No. 2, 20 (2003).

Other (7)

P. G. Cheremskoĭ, V. V. Slezov, and V. P. Betekhshin, Pores in Solids (Énergoatomizdat, Moscow, 1990).

V. A. Rabinovich and Z. Ya. Khavin, Brief Chemical Handbook (Khimiya, Leningrad, 1978).

D. A. Fanderlik, Course of Colloidal Chemistry (Khimiya, Leningrad, 1974).

N. V. Suĭkovskaya, Chemical Methods of Obtaining Thin Transparent Films (Khimiya, Leningrad, 1971).

P. Legrand, R. Temey, K. Vandiest, and M. Hannotiau, “Vitrage portant un revetement pyrolytique,” Swiss Patent No. 690 302 (2000).

H. Tomonaga, T. Morimoto, and K. Sunahara, “Glass for screening IR radiation,” Application 1541536 EPV, MKI7 S03S17/25, Asachi Glass Co., No. 03771402.9, applied for 7/29/2003, published 6/15/2005.

V. Srikanth, D. A. Strickler, and K. Sanderson, “Method of forming niobium-doped tin oxide coatings on glass and coated glass formed thereby,” U.S. Patent No. 6 827 970 (2004).

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