Abstract

Nine Stark-tuned infrared–infrared double-resonance (IIDR) signals were obtained when CHD₂F was investigated, using isotopically labeled CO₂ lasers. An interesting range of IIDR patterns was observed and analyzed, using a spectrum simulation program. From the analysis of these data, the following values of the a component of the dipole moment were derived: μ_a⁰ = 1.85, D, μ_a⁵ = 1.85 D, and μ_a⁶ = 1.87 D. We have also been able to assign a number of strong optically pumped far-infrared laser lines in CHD₂F and to predict some new lines.

© 1987 Optical Society of America

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