Abstract

After a brief introduction to the field of light-responsive materials, this paper provides a general theory for modeling the photomechanical response of a material, applies it to the two best-known mechanisms of photothermal heating and photoisomerization, and then describes an experimental procedure for quantitative measurements of the stress response. Several different materials are characterized to illustrate how the experiments and theory can be used to isolate the contributing mechanisms through both photomechanical measurements and auxiliary measurements of laser heating and thermal expansion. The efficiency and figure of merit of the photomechanical response are defined on several scales from the molecule to the bulk, and the photomorphon—the basic material element that determines the bulk response—is introduced. The photomorphon provides a conceptual model that can be expressed in terms of viscoelastic elements, such as springs in series and parallel with the photoactive molecule. The photomechanical response, figure of merit, and the deduced microscopic photomechanical properties are tabulated and proposals for new materials classes are made.

© 2019 Optical Society of America

Full Article  |  PDF Article
OSA Recommended Articles
Optically activated cantilever using photomechanical effects in dye-doped polymer fibers

Shaoping Bian, Dirk Robinson, and Mark G. Kuzyk
J. Opt. Soc. Am. B 23(4) 697-708 (2006)

The Einthoven String Galvanometer, A Theoretical and Experimental Study

Horatio B. Williams
J. Opt. Soc. Am. 13(3) 313-382 (1926)

References

You do not have subscription access to this journal. Citation lists with outbound citation links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription

Cited By

You do not have subscription access to this journal. Cited by links are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription

Figures (29)

You do not have subscription access to this journal. Figure files are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription

Tables (3)

You do not have subscription access to this journal. Article tables are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription

Equations (132)

You do not have subscription access to this journal. Equations are available to subscribers only. You may subscribe either as an OSA member, or as an authorized user of your institution.

Contact your librarian or system administrator
or
Login to access OSA Member Subscription