W. E. Behring, J. F. Seely, Samuel Goldsmith, Leonard Cohen, M. Richardson, and U. Feldman, "Transitions of the type 2s–2p in highly ionized Cu, Zn, Ga, and Ge," J. Opt. Soc. Am. B 2, 886-890 (1985)
Transitions of the type 2s–2p in the F i, O i, N i, and C i isoelectronic sequences of copper, zinc, gallium, and germanium have been identified in the spectra from plasmas produced by the omega laser system at the University of Rochester. The wavelengths are in the range 50 to 112 Å and are measured using silicon and oxygen lines as wavelength standards for gallium and using several lines from the F i, O i, and Na i isoelectronic sequences as wavelength standards for copper, zinc, and germanium. The energy levels that are determined from the measured wavelengths are also presented. Based on these measurements, the wavelengths for a number of magnetic-dipole transitions within the ground configurations of the F i, O i, and N i isoelectronic sequences are predicted.
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Classifications of Lines Isoelectronic with F i (in angstroms)a
Transition
Cu xxi
Zn xxii
Int.
Ga xxiii
Int.
Ge xxiv
Int.
2s2p5–2s2p6
2P3/2–2S1/2
78.390 B
73.941 A,B
20
69.782 B
40
65.893 A,B
10
2P1l2–2S1/2
90.354 B
86.538 A,B
13
83.013 B
25
79.736 A,B
7
A indicates transitions previously identified by Behring et al.3; B indicates transitions previously identified by Kononov et al.9
Table 2
Classifications of Lines Isoelectronic with O i (in angstroms)a
Transition
Cu xxii
Zn xxiii
Int.
Ga xxiv
Int.
Ge xxv
Int.
2s2p4–2s2p5
3P2–1P1
[65.43]
61.491 B
6
57.779
6
[54.27]
1D2–1P1
77.521 B
73.583 A,B
17
69.862
30
66.364 A
9
3P2–3P1
83.170 B
77.948 A,B
9
73.107
15
68.616 A
5
3P1–3P0
[88.38]
83.228 A,B
7
78.385
12
[73.88]
3P2–3P2
90.257 B
85.022 A,B
15
80.110 b1
30
75.514 A
4
3P0–3P1
[90.85]
85.283 A,B
7
80.110 b1
30
75.177 A
2
1S0–1P1
[93.30]
89.754 A,B
5
86.552
4
83.590
2
3P1–3P1
[95.22]
90.582 b1,A,B
4
86.316
4
82.385
2
3P1–3P2
[104.61]
100.303 B
6
96.255
4
[92.53]
2s2p5–2p6
1P1–1S0
[98.18]
93.347
6
88.900
2
84.826
3
A indicates transitions previously identified by Behring et al.3; B indicates transitions previously identified by Kononov et al.9; b1, blend; data in brackets, interpolated.
Table 3
Classification of Lines Isoelectronic with N i (in angstroms)a
Transition
Cu xxiii
Zn xxiv
Int.
Ga xxv
Int.
Ge xxvi
Int.
2s2p3–2s2p4
4S3/2–2P3/2
[67.31]
63.346
4
[59.56]
[55.95]
2D3/2–2P3/2
[76.06]
71.917
0
68.009
1
[64.36]
2D3/2–2S1/2
79.636 bl
75.290
8
71.232 bl
2
67.433
1
2D5/2–2P3/2
79.636 b1,B
75.499 A
13
71.561
6
67.836
3
2P3/2–2P1/2
83.335 B
78.957 A
9
74.866
8
70.990
2
2P1/2–2P3/2
[86.38]
81.866
3
77.54
5
[73.48]
2P1/2–2S1/2
91.028
86.266
7
81.776
4
77.512 bl
2
2D3/2–2D3/2
92.695 B
87.686 B
9
[83.05]
78.698
2
2D5/2–2D5/2
94.847 B
89.474 A,B
8
84.401
11
79.637
2
4S3/2–4P1/2
96.457
90.046
4
84.110
5
[74.49]
4S3/2–4P3/2
98.892
92.182 bl
6
85.910
2
80.079
2
4S3/2–4P5/2
[111.05]
104.537
3
98.333 b1
6
92.624 b1
3
2s2p4–2p5
2D3/2–2P3/2
[93.63]
89.013
4
84.713 b1
4
[80.74]
2D5/2–2P3/2
96.762 b1
92.617
5
88.749
6
85.181
1
2P1/2–2P1/2
[118.11]
112.37 b1
4
A indicates transitions previously identified by Behring et al.3; B indicates transitions previously identified by Kononov et al.9; b1, blend; data in brackets, interpolated.
Table 4
Classification of Lines Isoelectronic with C i (in angstroms)a
Transition
Cu xxiv
Zn xxv
Int.
Ga xxvi
Int.
Ge xxvii
Int.
2s2p2–2s2p3
3P2–1D2
77.111
2
3P1–3S1
83.052
78.714
2
74.60
6
[70.73]
3P2–3S1
87.107
82.640
7
78.385
12
74.301
1
3P2–3P2
99.206
92.85
5
86.946
2
81.370
0
3P0–3D1
[104.41]
97.449
3
91.063
6
[85.25]
b1, blend; data in brackets, interpolated.
Table 5
Energy Levels Isoelectronic with F i (in inverse centimeters)
Level
Cu xxi
Zn xxii
Ga xxiii
Ge xxiv
2s2p5 2P3/2
0
0
0
0
2Pl/2
168 920
196 870
228 400
263 470
2s 2p6 2S1/2
1 275 670
1 352 430
1 433 030
1 517 610
Table 6
Energy Levels Isoelectronic with O i (in inverse centimeters)
Level
Cu xxii
Zn xxiii
Ga xxiv
Ge xxv
2s2p4 3P2
0
0
0
0
3P0
110 340
119 58
127 190
3P1
179 060
209 330
243 570
1D2
238 280 + z
267 120
299 410
335 890 + z
1S0
512 070
575 490
646 420 + z
2s2p53P2
1 107 950
1 176 110
1 248 280
1 324 260
3P1
1 202 360
1 282 970
1 367 860
1 457 390
3P0
1 380 580
1 485 080
1P1
1 528 250 + z
1 626 230
1 730 860
1 842 730 + z
2p61S0
2 697 570
2 855 840
3 021 620 + z
Table 7
Energy Levels Isoelectronic with N i (in inverse centimeters)
Level
Cu xxiii
Zn xxiv
Ga xxv
Ge xxvi
2s2p3 4S3/2
0
0
0
0
2D3/2
170 940 + x
188 130
208 480 + x
233 620 + x
2D5/2
230 020 + y
254 110
281 460 + x
313 240 + y
2Pl/2
328 090 + x
357 130
389 300 + x
426 450 + x
2P3/2
446 810 + z
500 140 + z
560 690 + z
629 140 + z
2s2p4 4P5/2
956 600
1 016 950
1 079 630
4P3/2
1 011 200
1 084 810
1 164 010
1 248 770
4Pl/2
1 036 730
1 110 540
1 188 920
2D3/2
1 249 750 + x
1 328 550
1 412 600 + x
1 504 300 + x
2D5/2
1 284 350 + y
1 371 750
1 466 280 + x
1 568 940 + y
2Sl/2
1 426 650 + x
1 516 340
1 612 340 + x
1 716 570 + x
2P3/2
1 485 730 + y
1 578 630
1 678 870 + x
1 787 390 + y
2Pl/2
1 646 790 + z
1 766 650 + z
1 896 410 + z
2 037 790 + z
2p5 2P3/2
2 317 810 + y
2 451 700 + z
2 593 060 + x
2 742 910 + y
2Pl/2
2 656 040 + z
Table 8
Energy Levels Isoelectronic with C i (in inverse centimeters)
Level
Cu xxiv
Zn xxv
Ga xxvi
Ge xxvii
2s2p2 3P0
0
0
0
0
3P1
132 110 + x
157 710 + x
186 880 + x
3P2
188 160 + x
218 070 + x
251 610 + x
287 920 + x
2s2p33D1
1 026 180
1 098 140
3P2
1 196 160 + x
1 295 060 + x
1 401 740 + x
1 516 880 + x
3S1
1 336 170 + x
1 428 130 + x
1 527 360 + x
1 633 800 + x
1D2
1 514 880 + x
Table 9
Predicted Wavelengths of Magnetic-Dipole Transitions (in angstroms)a
Cu
Zn
Ga
Ge
2s2p5
2P3/2–2Pl/2
592.00 H
507.95
437.83
379.55 H
2s2p4
3P2–3P1
558.47
477.71
410.56 H
3P0–3P1
1455.18
1114. 21
859.25
3P2–1D2
374.36
333.99
3P1–1D2
1135.59
1110.12
1083.19
3P1–1S0
300.29
273.10
248.23
2s2p3
4S3/2–2D3/2
531.55
4S3/2–2D5/2
393.53
2D3/2–2D5/2
1515.61
H indicates wavelengths identified in PLT tokamak spectra by Hinnov et al.13
Tables (9)
Table 1
Classifications of Lines Isoelectronic with F i (in angstroms)a
Transition
Cu xxi
Zn xxii
Int.
Ga xxiii
Int.
Ge xxiv
Int.
2s2p5–2s2p6
2P3/2–2S1/2
78.390 B
73.941 A,B
20
69.782 B
40
65.893 A,B
10
2P1l2–2S1/2
90.354 B
86.538 A,B
13
83.013 B
25
79.736 A,B
7
A indicates transitions previously identified by Behring et al.3; B indicates transitions previously identified by Kononov et al.9
Table 2
Classifications of Lines Isoelectronic with O i (in angstroms)a
Transition
Cu xxii
Zn xxiii
Int.
Ga xxiv
Int.
Ge xxv
Int.
2s2p4–2s2p5
3P2–1P1
[65.43]
61.491 B
6
57.779
6
[54.27]
1D2–1P1
77.521 B
73.583 A,B
17
69.862
30
66.364 A
9
3P2–3P1
83.170 B
77.948 A,B
9
73.107
15
68.616 A
5
3P1–3P0
[88.38]
83.228 A,B
7
78.385
12
[73.88]
3P2–3P2
90.257 B
85.022 A,B
15
80.110 b1
30
75.514 A
4
3P0–3P1
[90.85]
85.283 A,B
7
80.110 b1
30
75.177 A
2
1S0–1P1
[93.30]
89.754 A,B
5
86.552
4
83.590
2
3P1–3P1
[95.22]
90.582 b1,A,B
4
86.316
4
82.385
2
3P1–3P2
[104.61]
100.303 B
6
96.255
4
[92.53]
2s2p5–2p6
1P1–1S0
[98.18]
93.347
6
88.900
2
84.826
3
A indicates transitions previously identified by Behring et al.3; B indicates transitions previously identified by Kononov et al.9; b1, blend; data in brackets, interpolated.
Table 3
Classification of Lines Isoelectronic with N i (in angstroms)a
Transition
Cu xxiii
Zn xxiv
Int.
Ga xxv
Int.
Ge xxvi
Int.
2s2p3–2s2p4
4S3/2–2P3/2
[67.31]
63.346
4
[59.56]
[55.95]
2D3/2–2P3/2
[76.06]
71.917
0
68.009
1
[64.36]
2D3/2–2S1/2
79.636 bl
75.290
8
71.232 bl
2
67.433
1
2D5/2–2P3/2
79.636 b1,B
75.499 A
13
71.561
6
67.836
3
2P3/2–2P1/2
83.335 B
78.957 A
9
74.866
8
70.990
2
2P1/2–2P3/2
[86.38]
81.866
3
77.54
5
[73.48]
2P1/2–2S1/2
91.028
86.266
7
81.776
4
77.512 bl
2
2D3/2–2D3/2
92.695 B
87.686 B
9
[83.05]
78.698
2
2D5/2–2D5/2
94.847 B
89.474 A,B
8
84.401
11
79.637
2
4S3/2–4P1/2
96.457
90.046
4
84.110
5
[74.49]
4S3/2–4P3/2
98.892
92.182 bl
6
85.910
2
80.079
2
4S3/2–4P5/2
[111.05]
104.537
3
98.333 b1
6
92.624 b1
3
2s2p4–2p5
2D3/2–2P3/2
[93.63]
89.013
4
84.713 b1
4
[80.74]
2D5/2–2P3/2
96.762 b1
92.617
5
88.749
6
85.181
1
2P1/2–2P1/2
[118.11]
112.37 b1
4
A indicates transitions previously identified by Behring et al.3; B indicates transitions previously identified by Kononov et al.9; b1, blend; data in brackets, interpolated.
Table 4
Classification of Lines Isoelectronic with C i (in angstroms)a
Transition
Cu xxiv
Zn xxv
Int.
Ga xxvi
Int.
Ge xxvii
Int.
2s2p2–2s2p3
3P2–1D2
77.111
2
3P1–3S1
83.052
78.714
2
74.60
6
[70.73]
3P2–3S1
87.107
82.640
7
78.385
12
74.301
1
3P2–3P2
99.206
92.85
5
86.946
2
81.370
0
3P0–3D1
[104.41]
97.449
3
91.063
6
[85.25]
b1, blend; data in brackets, interpolated.
Table 5
Energy Levels Isoelectronic with F i (in inverse centimeters)
Level
Cu xxi
Zn xxii
Ga xxiii
Ge xxiv
2s2p5 2P3/2
0
0
0
0
2Pl/2
168 920
196 870
228 400
263 470
2s 2p6 2S1/2
1 275 670
1 352 430
1 433 030
1 517 610
Table 6
Energy Levels Isoelectronic with O i (in inverse centimeters)
Level
Cu xxii
Zn xxiii
Ga xxiv
Ge xxv
2s2p4 3P2
0
0
0
0
3P0
110 340
119 58
127 190
3P1
179 060
209 330
243 570
1D2
238 280 + z
267 120
299 410
335 890 + z
1S0
512 070
575 490
646 420 + z
2s2p53P2
1 107 950
1 176 110
1 248 280
1 324 260
3P1
1 202 360
1 282 970
1 367 860
1 457 390
3P0
1 380 580
1 485 080
1P1
1 528 250 + z
1 626 230
1 730 860
1 842 730 + z
2p61S0
2 697 570
2 855 840
3 021 620 + z
Table 7
Energy Levels Isoelectronic with N i (in inverse centimeters)
Level
Cu xxiii
Zn xxiv
Ga xxv
Ge xxvi
2s2p3 4S3/2
0
0
0
0
2D3/2
170 940 + x
188 130
208 480 + x
233 620 + x
2D5/2
230 020 + y
254 110
281 460 + x
313 240 + y
2Pl/2
328 090 + x
357 130
389 300 + x
426 450 + x
2P3/2
446 810 + z
500 140 + z
560 690 + z
629 140 + z
2s2p4 4P5/2
956 600
1 016 950
1 079 630
4P3/2
1 011 200
1 084 810
1 164 010
1 248 770
4Pl/2
1 036 730
1 110 540
1 188 920
2D3/2
1 249 750 + x
1 328 550
1 412 600 + x
1 504 300 + x
2D5/2
1 284 350 + y
1 371 750
1 466 280 + x
1 568 940 + y
2Sl/2
1 426 650 + x
1 516 340
1 612 340 + x
1 716 570 + x
2P3/2
1 485 730 + y
1 578 630
1 678 870 + x
1 787 390 + y
2Pl/2
1 646 790 + z
1 766 650 + z
1 896 410 + z
2 037 790 + z
2p5 2P3/2
2 317 810 + y
2 451 700 + z
2 593 060 + x
2 742 910 + y
2Pl/2
2 656 040 + z
Table 8
Energy Levels Isoelectronic with C i (in inverse centimeters)
Level
Cu xxiv
Zn xxv
Ga xxvi
Ge xxvii
2s2p2 3P0
0
0
0
0
3P1
132 110 + x
157 710 + x
186 880 + x
3P2
188 160 + x
218 070 + x
251 610 + x
287 920 + x
2s2p33D1
1 026 180
1 098 140
3P2
1 196 160 + x
1 295 060 + x
1 401 740 + x
1 516 880 + x
3S1
1 336 170 + x
1 428 130 + x
1 527 360 + x
1 633 800 + x
1D2
1 514 880 + x
Table 9
Predicted Wavelengths of Magnetic-Dipole Transitions (in angstroms)a
Cu
Zn
Ga
Ge
2s2p5
2P3/2–2Pl/2
592.00 H
507.95
437.83
379.55 H
2s2p4
3P2–3P1
558.47
477.71
410.56 H
3P0–3P1
1455.18
1114. 21
859.25
3P2–1D2
374.36
333.99
3P1–1D2
1135.59
1110.12
1083.19
3P1–1S0
300.29
273.10
248.23
2s2p3
4S3/2–2D3/2
531.55
4S3/2–2D5/2
393.53
2D3/2–2D5/2
1515.61
H indicates wavelengths identified in PLT tokamak spectra by Hinnov et al.13