Abstract

The structure of the line λ=613.4nm(6p32P3/2°7s2P3/2) in Bi i has been completely analyzed by means of a Fourier-transform spectrometer. From the intensity calculations it is seen that only 9 components of the possible 10 can be observed. The A and B constants are also calculated and compared with earlier results. The values of the levels 7s 2P3/2 and 6p32P3/2° have been recalculated to be 49 460.91 ±0.01 and 33 164.82 ±0.01 cm−1, respectively.

© 1985 Optical Society of America

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References

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  1. S. Goudsmit and E. Back, “Feinstructuren und Termordnung des Wismutspektrums,” Z. Phys. 43, 321–334 (1927).
    [CrossRef]
  2. E. U. Mintz, “A test of the interval rule in the 2D3/2state of bismuth I,” J. Franklin Inst. 222, 613–623 (1936).
    [CrossRef]
  3. H. Schüler and T. Schmidt, “Das elektrische Quadrupolmoment des 20983Bi-Kerns,” Z. Phys. 99, 717–728 (1936).
    [CrossRef]
  4. S. Mrozowski, “Arc spectrum of bismuth Bi i,” Phys. Rev. 62, 526–533 (1942).
    [CrossRef]
  5. R. Chuckrow, P. C. Magnante, and H. H. Stroke, “Hyperfine structure of 209bismuth in the 6p2(3P0)7s4 P1/2state,” J. Opt. Soc. Am. 58, 922–923 (1968).
    [CrossRef]
  6. L. O. Dicke and F. M. Kelly, “Hyperfine structure in the ground configuration of bismuth,” Can. J. Phys. 45, 2249–2251 (1967).
    [CrossRef]
  7. S. George and R. A. Klingberg, “Interferometric measurements of the hyperfine structure in bismuth,” J. Opt. Soc. Am. 60, 869–870 (1970).
    [CrossRef]
  8. J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
    [CrossRef]
  9. J. Dembczynski and J. Frakowiak, “Hyperfine structure in immediate coupling of the first excited electron configuration 6p2 7s of 20989Bi (I= 9/2),” Acta Phys. Pol. A48, 139–155 (1975).
  10. R. J. Hull and G. O. Brink, “Hyperfine structure of Bi209,” Phys. Rev. A 1, 685–693 (1970).
    [CrossRef]
  11. J. Heldt, “Hyperfine structure of the multipole lines of bismuth (Bi i),” J. Opt. Soc. Am. 58, 1516–1519 (1968).
    [CrossRef]
  12. A. Lurio and D. Landman, La Structure Hyperfine Magnétique des Atomes et des Molecules (Editions du Centre National de la Recherche Scientifique, Paris, 1967), p. 211.
  13. D. A. Landman and A. Lurio, “Hyperfine structure of the 6p3configuration of Bi209,” Phys. Rev. A 1, 1330–1338 (1970).
    [CrossRef]

1975 (1)

J. Dembczynski and J. Frakowiak, “Hyperfine structure in immediate coupling of the first excited electron configuration 6p2 7s of 20989Bi (I= 9/2),” Acta Phys. Pol. A48, 139–155 (1975).

1970 (4)

R. J. Hull and G. O. Brink, “Hyperfine structure of Bi209,” Phys. Rev. A 1, 685–693 (1970).
[CrossRef]

D. A. Landman and A. Lurio, “Hyperfine structure of the 6p3configuration of Bi209,” Phys. Rev. A 1, 1330–1338 (1970).
[CrossRef]

S. George and R. A. Klingberg, “Interferometric measurements of the hyperfine structure in bismuth,” J. Opt. Soc. Am. 60, 869–870 (1970).
[CrossRef]

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

1968 (2)

1967 (1)

L. O. Dicke and F. M. Kelly, “Hyperfine structure in the ground configuration of bismuth,” Can. J. Phys. 45, 2249–2251 (1967).
[CrossRef]

1942 (1)

S. Mrozowski, “Arc spectrum of bismuth Bi i,” Phys. Rev. 62, 526–533 (1942).
[CrossRef]

1936 (2)

E. U. Mintz, “A test of the interval rule in the 2D3/2state of bismuth I,” J. Franklin Inst. 222, 613–623 (1936).
[CrossRef]

H. Schüler and T. Schmidt, “Das elektrische Quadrupolmoment des 20983Bi-Kerns,” Z. Phys. 99, 717–728 (1936).
[CrossRef]

1927 (1)

S. Goudsmit and E. Back, “Feinstructuren und Termordnung des Wismutspektrums,” Z. Phys. 43, 321–334 (1927).
[CrossRef]

Back, E.

S. Goudsmit and E. Back, “Feinstructuren und Termordnung des Wismutspektrums,” Z. Phys. 43, 321–334 (1927).
[CrossRef]

Brink, G. O.

R. J. Hull and G. O. Brink, “Hyperfine structure of Bi209,” Phys. Rev. A 1, 685–693 (1970).
[CrossRef]

Chuckrow, R.

Connes, J.

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Connes, P.

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Delouis, H.

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Dembczynski, J.

J. Dembczynski and J. Frakowiak, “Hyperfine structure in immediate coupling of the first excited electron configuration 6p2 7s of 20989Bi (I= 9/2),” Acta Phys. Pol. A48, 139–155 (1975).

Dicke, L. O.

L. O. Dicke and F. M. Kelly, “Hyperfine structure in the ground configuration of bismuth,” Can. J. Phys. 45, 2249–2251 (1967).
[CrossRef]

Frakowiak, J.

J. Dembczynski and J. Frakowiak, “Hyperfine structure in immediate coupling of the first excited electron configuration 6p2 7s of 20989Bi (I= 9/2),” Acta Phys. Pol. A48, 139–155 (1975).

George, S.

Goudsmit, S.

S. Goudsmit and E. Back, “Feinstructuren und Termordnung des Wismutspektrums,” Z. Phys. 43, 321–334 (1927).
[CrossRef]

Guelachvili, G.

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Heldt, J.

Hull, R. J.

R. J. Hull and G. O. Brink, “Hyperfine structure of Bi209,” Phys. Rev. A 1, 685–693 (1970).
[CrossRef]

Kelly, F. M.

L. O. Dicke and F. M. Kelly, “Hyperfine structure in the ground configuration of bismuth,” Can. J. Phys. 45, 2249–2251 (1967).
[CrossRef]

Klingberg, R. A.

Landman, D.

A. Lurio and D. Landman, La Structure Hyperfine Magnétique des Atomes et des Molecules (Editions du Centre National de la Recherche Scientifique, Paris, 1967), p. 211.

Landman, D. A.

D. A. Landman and A. Lurio, “Hyperfine structure of the 6p3configuration of Bi209,” Phys. Rev. A 1, 1330–1338 (1970).
[CrossRef]

Lurio, A.

D. A. Landman and A. Lurio, “Hyperfine structure of the 6p3configuration of Bi209,” Phys. Rev. A 1, 1330–1338 (1970).
[CrossRef]

A. Lurio and D. Landman, La Structure Hyperfine Magnétique des Atomes et des Molecules (Editions du Centre National de la Recherche Scientifique, Paris, 1967), p. 211.

Magnante, P. C.

Maillard, J. P.

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Michel, G.

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Mintz, E. U.

E. U. Mintz, “A test of the interval rule in the 2D3/2state of bismuth I,” J. Franklin Inst. 222, 613–623 (1936).
[CrossRef]

Mrozowski, S.

S. Mrozowski, “Arc spectrum of bismuth Bi i,” Phys. Rev. 62, 526–533 (1942).
[CrossRef]

Schmidt, T.

H. Schüler and T. Schmidt, “Das elektrische Quadrupolmoment des 20983Bi-Kerns,” Z. Phys. 99, 717–728 (1936).
[CrossRef]

Schüler, H.

H. Schüler and T. Schmidt, “Das elektrische Quadrupolmoment des 20983Bi-Kerns,” Z. Phys. 99, 717–728 (1936).
[CrossRef]

Stroke, H. H.

Acta Phys. Pol. (1)

J. Dembczynski and J. Frakowiak, “Hyperfine structure in immediate coupling of the first excited electron configuration 6p2 7s of 20989Bi (I= 9/2),” Acta Phys. Pol. A48, 139–155 (1975).

Can. J. Phys. (1)

L. O. Dicke and F. M. Kelly, “Hyperfine structure in the ground configuration of bismuth,” Can. J. Phys. 45, 2249–2251 (1967).
[CrossRef]

J. Franklin Inst. (1)

E. U. Mintz, “A test of the interval rule in the 2D3/2state of bismuth I,” J. Franklin Inst. 222, 613–623 (1936).
[CrossRef]

J. Opt. Soc. Am. (3)

Nouv. Rev. Opt. Appl. (1)

J. Connes, H. Delouis, P. Connes, G. Guelachvili, J. P. Maillard, and G. Michel, “Spectroscopie de Fourier avec transformation d’un million de points,” Nouv. Rev. Opt. Appl. 1, 3–22 (1970).
[CrossRef]

Phys. Rev. (1)

S. Mrozowski, “Arc spectrum of bismuth Bi i,” Phys. Rev. 62, 526–533 (1942).
[CrossRef]

Phys. Rev. A (2)

R. J. Hull and G. O. Brink, “Hyperfine structure of Bi209,” Phys. Rev. A 1, 685–693 (1970).
[CrossRef]

D. A. Landman and A. Lurio, “Hyperfine structure of the 6p3configuration of Bi209,” Phys. Rev. A 1, 1330–1338 (1970).
[CrossRef]

Z. Phys. (2)

S. Goudsmit and E. Back, “Feinstructuren und Termordnung des Wismutspektrums,” Z. Phys. 43, 321–334 (1927).
[CrossRef]

H. Schüler and T. Schmidt, “Das elektrische Quadrupolmoment des 20983Bi-Kerns,” Z. Phys. 99, 717–728 (1936).
[CrossRef]

Other (1)

A. Lurio and D. Landman, La Structure Hyperfine Magnétique des Atomes et des Molecules (Editions du Centre National de la Recherche Scientifique, Paris, 1967), p. 211.

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Figures (2)

Fig. 1
Fig. 1

Observed hyperfine-structure transitions in the 613.4-nm line. The dashed line indicates the component F′ = 4 to F = 4 that is too weak to be seen (see Table 1).

Fig. 2
Fig. 2

Actual plot of the line λ = 613.4 nm. The number 2 indicates the second component, which lies very close to the first one.

Tables (3)

Tables Icon

Table 1 Measured Hyperfine-Structure Components of the Line λ = 613.4 nm (16296.09 cm−1)

Tables Icon

Table 2 Hyperfine Structures (in millikaysers)a

Tables Icon

Table 3 Hyperfine Interaction Constants A and B (in millikaysers)a

Equations (2)

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6 p 3 2 P 3 / 2 °
6 p 3 2 P 3 / 2 °

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