Table 1
Measured Lines of Pt i
Wave Numbera Assignmentb I c Coded 13 851.295e 526672 –388152 0 B 14 053.465e 185661 –326202 1 NP 14 610.306e 523793 –377693 1 N 14 788.81P 523793 –375904 9 N 14 898.127e 526672 –377693 3 N 15 037.275e 523793 –373422 0 N 15 325.119 526672 –373422 4 N 15 801.953 219674 –377693 1 N 15 822.513 526672 –368441 1 N 15 910.341 606402 –447303 1 N 16 590.106 567844 –401944 3 N 16 595.031 597821 –431871 1 WP 17 057.700 523793 –353213 1 W 17 104.463 556405 –385365 3 N 17 118.198 155012 –326202 4 N 17 345.564 526672 –353213 1 N 18 130.341 607903 –426603 1 B 18 248.167 567844 –385365 13 N 18 257.216 523793 –341223 11 N 18 545.043 526672 –341223 8 N 18 555.064 603571 –418021 2 N 18 620.324 155012 –341223 4 NP 18 859.072 556405 –367816 31 N 18 912.287 598824 –409703 2 NB* 19 003.063 219674 –409703 1 N 19 123.745 134962 –326202 14 N 19 248.024 597643 –405162 0 N 19 355.899 598723 –405162 0 NP 19 670.502 606402 –409703 0 N 19 688.203 598824 –401944 0 NP 19 696.089 641284 –444324 0 N* 19 759.366 523793 –326202 25 N 19 775.521 645054 –447303 0 WP 19 819.798 155012 –353213 2 NPB 19 820.222 607903 –409703 2 NPB 19 841.558 603571 –405162 0 WP 19 983.894 266382 –466223 1 NP 20 002.531 607903 –407872 2 NP 20 047.200 526672 –326202 1 N 20 073.177 645054 –444324 2 NP 20 124.422 606402 –405162 0 N 20 488.000 567844 –362964 8 WPB 20 560.282 645054 –439453 1 NP 20 596.159 607903 –401944 4 WP 20 689.765 608834 –401944 1 NP 20 692.941 219674 –426603 1 NP 20 948.360 597643 –388152 1 WP 20 966.938 597821 –388152 1 NP 21 056.230 598723 –388152 2 WP 21 092.260 599082 –388152 1 WP 21 101.958 266382 –477401 0 NP 21 342.875 155012 –368441 0 WP 21 541.902 603571 –388152 2 N 21 824.766 606402 –388152 1 N 21 825.384 134962 –353213 5 NB 21 840.278 155012 –373422 0 WP 21 845.780 645054 –426603 0 WP 21 949.688 185661 –405162 2 WP 21 960.221 556405 –336805 23 NP 21 962.494 597313 –377693 1 W 21 982.099 597513 –377693 4 w 22 103.059 598723 –377693 9 w 22 113.339 598824 –377693 18 w 22 139.099 599082 –377693 0 w 22 160.610 597513 –375904 3 N 22 173.696 597643 –375904 0 N 22 221.307 185661 –407872 0 W 22 222.587 523793 –301564 0 NB* 22 281.571 598723 –375904 1 N 22 291.847 598824 –375904 9 N 22 347.841 608834 –385365 4 WP 22 389.456 597313 –373422 0 NP 22 422.167 597643 –373422 2 W 22 440.746 597821 –373422 0 W 22 488.127 101311 –326202 3 WP 22 503.288 101163 –326202 33 WP 22 530.038 598723 –373422 8 w 22 566.070 599082 –373422 100 NB 22 647.540 266382 –492863 0 N 22 662.164 567844 –341223 4 WP 22 763.198 219674 –447303 6 NP 22 871.596 606402 –377693 0 N 22 905.974 266382 –495441 0 NP 22 938.134 597821 –368441 5 NP 23 015.710 603571 –373422 0 N 23 021.336 607903 –377693 0 N 23 063.455 599082 –368441 3 NP 23 103.919 567844 –336805 14 N 23 199.768 607903 –375904 1 WB* 23 236.193 185661 –418021 1 NP 23 298.584 606402 –373422 1 NP 23 314.060 155012 –388152 2 WP 23 348.425 134962 –368441 0 N 23 416.733 266382 –500551 0 NP 23 448.296 607903 –373422 1 WP 23 467.953 597643 –362964 1 NP 23 535.673 645054 –409703 1 WP 23 795.961 606402 –368441 2 N 23 845.835 134962 –373422 11 WP 24 005.436 101163 –341223 27 WP 24 272.808 134962 –377693 31 NP 24 409.933 597313 –353213 0 NP 24 429.526 597513 –353213 6 NP 24 442.603 597643 –353213 1 NP 24 458.937 266382 –510973 0 WP 24 494.080 607903 –362964 6 WP 24 560.769 598824 –353213 0 NP 24 587.691 608834 –362964 7 NP 24 655.373 219674 –466223 0 NP 24 997.610 219674 –469644 1 NP 25 014.399 155012 –405162 5 WP 25 114.731 266382 –517532 0 W 25 204.921 101163 –353213 56 WP 25 286.008 155012 –407872 0 NP 25 319.637 134962 –388152 12 WP 25 468.315 155012 –409703 7 WP 25 468.731 607903 –353213 1 WP 25 483.766 556405 –301564 48 NP 25 562.351 608834 –353213 9 N 25 592.562 641284 –385365 11 N 25 604.993 641416 –385365 10 NP 25 609.412 597313 –341223 3 WP 25 629.014 597513 –341223 26 WP 25 642.103 597643 –341223 12 NP 25 749.982 598723 –341223 0 NP 25 760.258 598824 –341223 0 NP 25 785.997 599082 –341223 0 W 25 877.790 185661 –444442 1 NP 26 179.579 101163 –362964 121 NP 26 300.899 155012 –418021 8 WP 26 380.723 266382 –530191 0 N 26 518.505 606402 –341223 0 N 26 627.473 567844 –301564 1 N 26 668.223 607903 –341223 1 WP 26 712.862 101311 –368441 0 N* 26 736.776 645054 –377693 1 WP 26 761.830 608834 –341223 3 WP 27 019.976 134962 –405162 13 w 27 111.550 597313 –326202 19 N 27 144.252 597643 –326202 9 N 27 158.210 155012 –426603 3 N 27 162.842 597821 –326202 1 N 27 203.607 608834 –336805 2 WP 27 210.210 101311 –373422 12 WP 27 225.370 101163 –373422 17 WP 27 288.162 599082 –326202 0 N 27 252.125 598723 –326202 2 N 27 291.587 134962 –407872 6 WP 27 319.004 219674 –492863 1 w 27 359.603 641416 –367816 2 N 27 372.544 266382 –540113 1 WP 27 473.848 134962 –409703 14 WPB* 27 473.848 101163 –375904 14 WPB 27 554.699 65672 –341223 60 NP 27 603.818 185661 –461702 1 N 27 685.982 155012 –431871 1 WP 27 737.772 603571 –326202 0 N 27 832.417 641284 –362964 0 N 27 867.353 185661 –464330 3 NP 28 170.377 607903 –326202 0 N 28 200.612 266382 –548393 0 W 28 209.541 645054 –362964 0 N 28 306.471 134962 –418021 0 WP 28 443.688 155012 –439453 10 WP 28 578.243 266382 –552161 0 N 28 684.020 101311 –388152 115 N 28 699.179 101163 –388152 18 WP 28 754.285 65672 –353213 81 WB* 28 897.679 266382 –555363 0 N 29 130.408 219674 –510973 1 NP 29 163.790 134962 –426603 41 NP 29 174.006 185661 –477401 0 WP 29 184.195 645054 –353213 1 WP 29 333.181 8234 –301564 1000 WP 29 691.563 134962 –431871 4 W 29 896.640 155012 –453981 7 NP 29 969.051 185661 –485352 0 W 30 077.500 101163 –401944 19 W 30 156.852 03 –301564 124 N 30 277.246 65672 –368441 234 WP 30 383.662 645054 –341223 0 N 30 384.356 101311 –405162 33 WP 30 448.310 641284 –336805 7 N 30 449.274 134962 –439453 3 N 30 460.756 641416 –336805 18 N 30 655.958 101311 –407872 0 N 30 668.536 155012 –461702 4 NP 30 704.536 61400 –368441 42 NP 30 741.642 101311 –408730 31 NP 30 774.649 65672 –373422 0 N 30 853.430 101163 –409703 4 NP 30 918.113 155012 –464192 5 NP 30 948.099 134962 –444442 10 WP 30 978.011 185661 –495441 0 WP 31 120.602 155012 –466223 2 WP* 31 201.615 65672 –377693 86 NP 31 234.044 134962 –447303 49 NP 31 314.331 185661 –498802 0 NP 31 488.707 185661 –500551 1 N* 31 670.862 101311 –418021 33 N 31 844.126 7752 –326202 100 NP 31 902.206 134962 –45398x 0 N 32 044.044 219674 –540113 1 WP 32 238.725 155012 –477401 1 NP 32 248.444 65672 –388152 42 NP 32 543.331f 101163 –426603 29 N 32 620.023f 03 –326202 603 WP 32 674.121f 134962 –461702 2 WP 32 720.372 185661 –512862 0 NP 32 856.724f 8234 –336805 788 WP 32 872.100 219674 –548393 0 N 32 923.694f 134962 –464192 17 NP 33 033.742 155012 –485352 0 N 33 055.954 101311 –431871 0 N 33 126.289f 134962 –466223 8 WP* 33 298.489f 8234 –341223 40 WP 33 346.268f 7752 –341223 426 WP 33 505.136 185661 –520711 0 NP 33 784.263 155012 –492863 2 NP 33 948.786 65672 –405162 3 W 33 971.871 641284 –301564 19 N 34 122.163f 03 –341223 261 WP 34 141.798 185661 –527082 1 W 34 220.391 65672 –407872 6 N 34 244.291f 134962 –477401 4 W 34 312.477 101311 –444442 13 NP 34 315.940 101163 –444324 1 WP 34 327.641f 101163 –444442 12 NP 34 348.985 645054 –301564 1 N 34 379.055 155012 –498802 0 N 34 402.699f 65672 –409703 6 W 34 497.976f 8234 –353213 46 NP 34 545.759f 7752 –353213 99 NP 34 553.466 155012 –500551 3 NP 34 613.582 101163 –447303 2 NP 35 039.335 134962 –485352 2 WP 35 266.596 101311 –453981 13 NP 35 321.653f 03 –353213 205 WP 35 472.632f 8234 –362964 19 W 35 539.076 219674 –575063 0 N 35 595.677 155012 –510973 1 W 35 662.553 61400 –418021 15 W 35 785.109 155012 –512862 0 N 35 789.849 134962 –492863 4 NP 36 038.494f 101311 –461702 3 NP 36 043.710 155012 –515452 0 W 36 048.299 134962 –495441 3 N 36 053.654 101163 –461702 1 W 36 068.819f 7752 –368441 64 N 36 092.599 65672 –426603 7 N 36 288.071f 101311 –464192 23 NP 36 302.027 101311 –464330 7 NP 36 303.237 101163 –464192 0 W 36 384.609 134962 –498802 4 WP 36 505.764 101163 –466223 6 N 36 559.030 134962 –500551 3 WP 36 566.201f 7752 –373422 182 NP 36 569.829 155012 –520711 1 W 36 620.372f 65672 –431871 15 N 36 766.883f 8234 –375904 122 NP 36 847.953 101163 –469644 7 N 36 945.391f 8234 –377693 101 N 36 993.178f 7752 –377693 133 NP 37 047.665f 61400 –431871 23 N 37 342.092f 03 –373422 51 WP 37 378.079f 65672 –439453 12 N 37 517.439 155012 –530191 0 N 37 590.571f 03 –375904 216 WP 37 601.260 134962 –510973 1 N 37 608.684 101311 –477401 1 N 37 712.487f 8234 –385365 317 NP 37 769.077f 03 –377693 66 WP 37 790.666 134962 –512862 1 NP 37 876.908f 65672 –444442 13 N 38 040.016f 7752 –388152 120 N 38 049.262 134962 –515452 0 N 38 162.854f 65672 –447303 3 N 38 403.708f 101311 –485352 12 N 38 509.308f 155012 –540113 4 NP 38 831.008f 65672 –453981 0 N 39 169.380 101163 –492863 1 N 39 212.103 134962 –527082 2 N 39 370.552f 8234 –401944 22 N 39 412.668f 101311 –495441 2 NP 39 420.834 185661 –579872 0 W 39 523.029 134962 –530191 0 N 39 602.929f 65672 –461702 6 N 39 740.349f 7752 –405162 25 WP 39 748.984f 101311 –498802 2 N 39 764.160 101163 –498802 2 W 39 852.500f 65672 –464192 4 N 39 923.427 101311 –500551 0 N 40 011.958 7752 –407872 30 N 40 055.032 65672 –466223 12 N 40 146.489 8234 –409703 13 N 40 194.232 03 –401944 34 WPB 40 194.232 7752 –409703 34 WPB* 40 457.098 134962 –539532 1 WP 40 514.888 134962 –540113 5 WP 40 516.236 03 –405162 22 NP 40 787.870 03 –407872 3 WP 40 970.165f 03 –409703 26 WP 41 026.858 7752 –418021 6 N 41 155.073 101311 –512862 0 N 41 170.220 101163 –512862 2 N 41 173.099 65672 –477401 1 N 41 342.934 134962 –548393 3 NP 41 600.398 61400 –477401 2 NP 41 621.432 101311 –517532 1 NP 41 636.581 101163 –517532 0 NP 41 720.552 134962 –552161 0 N 41 836.382 8234 –426603 7 N 41 884.176 7752 –426603 2 NP 41 939.797 101311 –520711 1 NP 41 968.121 65672 –485352 0 N 42 040.012 134962 –555363 0 N 42 211.876 65672 –487793 2 W 42 411.956 7752 –431871 6 WP 42 660.057 03 –426603 1 WP 42 718.654f 65672 –492863 1 N 42 887.428 101311 –530191 0 N 42 977.122 6567M95441 0 N 43 121.864f 8234 –439453 4 NP 43 313.411 65672 –498802 1 N 43 404.369 61400 –495441 0 N 43 608.986f 8234 –444324 5 NP 43 668.457 7752 –444442 1 N 43 836.661 101163 –539532 0 N 43 906.665 8234 –447303 0 N* 43 915.004 61400 –500551 2 N* 43 945.541 03 –439453 0 N 43 954.415 7752 –447303 2 N 44 432.659 03 –444324 0 N 44 444.377 03 –444442 0 N 44 530.086 65672 –510973 0 N 44 730.299 03 –447303 0 N 44 978.049 65672 –515452 0 N* 45 394.510 7752 –461702 0 N 45 419.547 101163 –555363 0 N
a Measured centroid of transition.
b Assignments given as integer wave number parts of even and odd levels with
J values as superscripts.
c Intensity as area of centroid scaled to maximum of 1000. Zero intensity denotes a value less than 0.5 on this scale.
d Code is as follows: N, narrow line; W, wide line; P, resolved pattern; B, blended; *, line not used in least-squares-level analysis.
e Line also given in Ref.
13 .
f Line also given in Ref.
2 .
Table 2
Even Levels of Pt i a
Level Config. Term J Linesb 0.000 d 9 s 3 D 3 16 775.892 d 9 s 3 D 2 15 823.678 d 8 s 2 3 F 4 13 6140.180 d 10 1 S 0 5 6567.461 d 8 s 2 3 P2 24 10 116.729 d 8 s 2 3 F 3 23 10 131.887 d 9 s 3 D 1 22 13 496.271 d 9 s 1 D 2 33 15 501.845 d 8 s 2 3 F 2 27 18 566.558 d 8 s 2 3 P1 15 21 967.111 d 8 s 2 1 G 4 10 26 638.591 d 8 s 2 1 D 2 12 52 379.375 d 9 7s 3 D 3 6 52 667.213 d 9 7s 3 D 2 7 55 640.623 d 8 s 7s 5 F 5 4 56 784.325 – 4 6 59 731.571 – 3 5 59 751.177 – 3 4 59 764.266 – 3 8 59 782.853 – 1 5 59 872.140 – 3 7 59 882.421 – 4 5 59 908.170 – 2 6 60 357.804 d 97 S 3 D 1 5 60 640.669 d 9 7s 1 D 2 8 60 790.393 – 3 10 60 884.000 – 4 6 64 128.722 – 4 4 64 141.155 – 6 3 64 505.839 – 4 10
a Configuration assignments from Ref.
1 .
b The number of transitions connected to this level in the least-squares energy-level fit.
Table 3
Odd Levels of Pt i a
Level Config. Term J Linesb 30 156.854 d 8 sp 5 D 4 6 32 620.018 d 9 p 2 16 33 680.402 d 8 sp 5 6 34 122.165 d 9 p 3 19 35 321.653 d 8 sp 3 15 36 296.310 d 8 sp 4 8 36 781.551 d 8 sp 6 2 36 844.710 d 8 sp 1 9 37 342.101 2 17 37 590.569 d 9 p 4 8 37 769.073 d 9 p 3 16 38 536.160 d 8 sp 5 6 38 815.908 2 13 40 194.228 d 8 sp 4 7 40516.243 2 11 40 787.857 2 8 40 873.529 d 9 p 0 1 40 970.165 d 8 sp 3 9 41 802.744 1 7 42 660.058 d 8 sp 3 10 43 187.836 1 7 43 945.543 3 6 44 432.663 d 8 sp 4 4 44 444.364 2 7 44 730.312 d 8 sp 3 8 45 398.478 1 4 46 170.386 2 7 46 419.962 2 5 46 433.912 d 8 sp 0 2 46 622.489 d 9 p 3 4 46 964.701 d 8 sp 4 2 47 740.564 d 9 p 1 7 48 351.9c d 8 sp 4 48 535.596 2 5 48 779.336 d 8 sp 3 1 49 286.116 d 8 sp 3 6 49 544.565 1 6 49 880.883 2 6 50 055.313 1 4 51 097.529 d 8 sp 3 5 51 286.946 2 5 51 545.544 2 2 51 753.317 2 3 52 071.684 1 3 52 708.365 2 2 53 019.303 1 4 53 953.379 2 2 54 011.150 d 8 sp 3 4 54 839.206 d 8 sp 3 3 55 216.828 1 2 55 536.276 d 8 sp 3 3 57 506.187 3 1 57 987.392 2 1
a Configuration assignments from Ref.
1 .
b The number of transitions connected to this level in the least-squares energy-level fit.
c This level is given in Ref.
1 but was not determined in the present study.
Table 4
Predicted VUV Transitions of Pt i a
Wave Number Assignmentb 44 444.364 03 –444442 44 491.121 134962 –579872 44 530.068 65672 –510973 44 622.586c 7752 –453981 44 719.485c 65672 –512862 44 722.477 101163 –548393 44 730.313c 03 –447303 44 978.083c 65672 –515452 45 084.941c 101311 –552161 45 185.856 65672 –517532 45 394.494c 7752 –461702 45 419.547 101163 –555363 45 504.223c 65672 –520711 45 644.069c 7752 –464192 45 798.811c 8234 –466223 45 846.596c 7752 –466223 45 931.504c 61400 –520711 46 140.904c 65672 –527082 46 141.024c 8234 –469644 46 170.386 03 –461702 46 419.962c 03 –464192 46 451.842c 65672 –530191 46 622.489c 03 –466223 46 879.123c 61400 –530191 46 964.672c 7752 –477401 46 964.701c 03 –469644 47 385.919c 65672 –539532 47 389.458c 101163 –575063 47 443.689 65672 –540113 47 528.222c d 8234 –483514 47 759.703 7752 –485352 47 855.505c 101311 –579872 47 870.663c 101163 –579872 47 955.659c 8234 –487793 48 003.444c 7752 –487793 48 271.745c 65672 –548393 48 351.900c d 03 –483514 48 462.439c 8234 –492863 48 510.224c 7752 –492863 48 535.596c 03 –485352 48 649.367 65672 –552161 48 768.673c 7752 –495441 48 779.336c 03 –487793 48 968.815c 65672 –555363 49 076.649 61400 –552161 49 104.991c 7752 –498802 49 279.420c 7752 –500551 49 286.116c 03 –492863 49 880.883c 03 –498802 50 273.852c 8234 –510973 50 321.637 7752 –510973 50 511.054c 7752 –512862 50 769.651c 7752 –515452 50 938.726c 65672 –575063 50 977.424 7752 –517532 51 097.529 03 –510973 51 286.946c 03 –512862 51 295.792 7752 –520711 51 419.931 65672 –579872 51 545.544 03 –515452 51 753.317 03 –517532 51 932.473 7752 –527082 52 243.411 7752 –530191 52 708.365 03 –527082 53 177.487 7752 –539532 53 187.472 8234 –540113 53 235.258 7752 –540113 53 953.379 03 –539532 54 011.150 03 –540113 54 015.528 8234 –548393 54 063.314 7752 –548393 54 440.936 7752 –552161 54 712.599 8234 –555363 54 760.384 7752 –555363 54 839.206 03 –548393 55 536.276 03 –555363 56 682.509 8234 –575063 56 730.295 7752 –575063 57 211.500 7752 –579872 57 506.187 03 –575063 57 987.392 03 –579872
a Calculated using levels from
Tables 2 and
3 and the
J selection rules: Δ
J = 0, ±1, but Δ
J = 0 is not allowed if
J = 0.
b Assignments given as integer wave-number parts of even and odd levels with
J values as superscripts.
c These calculated lines were matched with platinum lines measured in Ref.
9 .
d These transitions involve the odd 48 351
4 level, for which an accurate value was not obtained in this study.