Transitions of the type 2s–2p in fluorinelike and oxygenlike As, Se, Br, and Rb

U. Feldman; J. F. Seely; W. E. Behring; M. C. Richardson; Samuel Goldsmith

doi:10.1364/JOSAB.2.001658

Journal of the Optical Society of America B
Vol. 2,
Issue 10,
pp. 1658-1660
(1985)
•https://doi.org/10.1364/JOSAB.2.001658

Transitions of the type 2s–2p in fluorinelike and oxygenlike As, Se, Br, and Rb

U. Feldman, J. F. Seely, W. E. Behring, M. C. Richardson, and Samuel Goldsmith

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U. Feldman, J. F. Seely, W. E. Behring, M. C. Richardson, and Samuel Goldsmith, "Transitions of the type 2s–2p in fluorinelike and oxygenlike As, Se, Br, and Rb," J. Opt. Soc. Am. B 2, 1658-1660 (1985)

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Abstract

Transitions of the type 2s–2p in the F and O i isoelectronic sequences of arsenic, selenium, bromine, and rubidium have been identified in spectra from laser-produced plasmas. Wavelengths in the range 50 to 90 Å were measured to an accuracy of 0.01 Å or better. The wavelengths of the magnetic-dipole transitions within the ground configurations are predicted.

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Corrections

U. Feldman, J. F. Seely, W. E. Behring, Leonard Cohen, M. C. Richardson, and Samuel Goldsmith, "Transitions of the type 2s–2p in fluorinelike and oxygenlike As, Se, Br, and Rb: erratum," J. Opt. Soc. Am. B 3, 239-239 (1986)
https://opg.optica.org/josab/abstract.cfm?uri=josab-3-2-239

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Transition		Int	λ_meas	λ_pred	Int	λ_meas	λ_pred	Int	λ_meas	λ_pred	Int	λ_meas	λ_pred
F i			As xxv			Se xxvi			Br xxvii			Rb xxix
2s²2p^{5 2}P_3/2–2s2p⁶	²S_1/2	40	62.250	62.258	20	58.828	58.837	100	55.613	55.619	60	49.728	49.732
²P_1/2	²S_1/2	25	76.699	76.704	10	73.866	73.867	80	71.200	71.215	35	66.376	66.392
O i			As xxvi			Se xxvii			Br xxviii			Rb xxx
2s²2p^{4 3}P₂–2s2p⁵	¹P₁	2	50.949	50.952				2	44.84	44.856
¹D₂	¹P₁	20	63.027	63.051	9	59.869	59.883	40	56.840	56.862	12	51.20
³P₂	³P₁	9	64.442	64.447	7	60.571	60.577	30	56.970	56.979	13	50.52
³P₁	³P₀	14	69.659	69.650	4	65.69	65.674	11	61.931	61.934	35	55.143
³P₂	³P₂	16	71.196	71.188	8	67.141	67.123	40	63.301	63.295	13	56.31
³P₀	³P₁	6	70.606	70.657	2	66.36	66.408	2	62.354	62.440
¹S₀	¹P₁	3	80.844	80.887	3	78.29	78.333
³P₁	³P₁	8	78.757	78.749	3	75.40	75.392	20	72.27	72.288
³P₁	³P₂	2	89.055	89.053	5	85.83	85.806	11	82.79	82.765
2s2p^{5 1}P₁–2p⁶	¹S₀	0	81.048	81.083	5	77.55^b	77.610	12	74.350	74.402

Level	As xxv	Se xxvi	Br xxvii	Rb xxix
2s²2p^{5 2}P_3/2	0	0	0	0
²P_1/2	302630	346070	393650	504370
2s2p^{6 2}S_1/2	1606430	1699870	1798140	2010940

Level	As xxvi	Se xxvii	Br xxviii	Rb xxx
2s²2p^{4 3}P₂	0	0	0	0
³P₀	135470	144020	151560
³P₁	281860	324500	371740	481500 + y
¹D₂	376130	420920 + x	470830	584100 + x
¹S₀	725800	813930 + x
2s2p^{5 3}P₂	1404670	1489500	1579620	1775900
³P₁	1551780	1650960	1755310	1979400
³P₀	1717430	1846870	1986440	2295000 + y
¹P₁	1962750	2091230 + x	2230150	2537200 + x
2p^{6 1}S₀	3196580	3380720 + x	3575140

Transition	As	Se	Br	Rb
2s²2p⁵
2P_3/2–²P_1/2	330.44	288.96	254.03	198.27
2s²2p⁴
³P₁–¹S₀	225.26	204.32
³P₂–¹D₂	265.87	237.57	212.39	171.2
³P₂–³P₁	354.79	308.17	269.01	207.7
³P₀–³P₁	683.11	554.08	454.17
³P₁–¹D₂	1060.78	1037.13	1009.18	974.7

Transition		Int	λ_meas	λ_pred	Int	λ_meas	λ_pred	Int	λ_meas	λ_pred	Int	λ_meas	λ_pred
F i			As xxv			Se xxvi			Br xxvii			Rb xxix
2s²2p^{5 2}P_3/2–2s2p⁶	²S_1/2	40	62.250	62.258	20	58.828	58.837	100	55.613	55.619	60	49.728	49.732
²P_1/2	²S_1/2	25	76.699	76.704	10	73.866	73.867	80	71.200	71.215	35	66.376	66.392
O i			As xxvi			Se xxvii			Br xxviii			Rb xxx
2s²2p^{4 3}P₂–2s2p⁵	¹P₁	2	50.949	50.952				2	44.84	44.856
¹D₂	¹P₁	20	63.027	63.051	9	59.869	59.883	40	56.840	56.862	12	51.20
³P₂	³P₁	9	64.442	64.447	7	60.571	60.577	30	56.970	56.979	13	50.52
³P₁	³P₀	14	69.659	69.650	4	65.69	65.674	11	61.931	61.934	35	55.143
³P₂	³P₂	16	71.196	71.188	8	67.141	67.123	40	63.301	63.295	13	56.31
³P₀	³P₁	6	70.606	70.657	2	66.36	66.408	2	62.354	62.440
¹S₀	¹P₁	3	80.844	80.887	3	78.29	78.333
³P₁	³P₁	8	78.757	78.749	3	75.40	75.392	20	72.27	72.288
³P₁	³P₂	2	89.055	89.053	5	85.83	85.806	11	82.79	82.765
2s2p^{5 1}P₁–2p⁶	¹S₀	0	81.048	81.083	5	77.55^b	77.610	12	74.350	74.402

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