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Constant-electric-field ionization mass spectroscopy in laser-excited Yb+ Rydberg states

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Abstract

Using a new method of constant-electric-field ionization of Rydberg states of ions, we have eliminated the influence of the direct multiphoton ionization background in multistep excitation of Yb+ Rydberg states and obtained the pure spectrum of np(n = 17−86) Rydberg levels of Yb+.The precision of the value of the Yb ii ionization potential has been greatly improved to 98 231.75(20) cm−1.

© 1995 Optical Society of America

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