High-resolution spectra of H216O, H217O, and H218O were recorded with a Fourier-transform spectrometer, covering transitions in the (020)–(010) and (020)–(000) bands. The measured line frequencies were used to determine high-accuracy values of rotational energy levels in the (020) vibrational states for the three isotopic species. Measurements of the line strengths were fitted to a model in which 19 transition moment parameters were determined for each band and molecule. The fitting technique did not consider interactions between the (020), (100), and (001) vibrational states. The experimental results provide a more accurate representation of the line positions and strengths than those currently available for these bands.
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J′(J′ + 1) if m = 0 and J = Kc or J′ = Kc′, otherwise 0
18
1
J′(J′ + 1) if m = 0 and J = Kc or J′ = Kc′ − 1, otherwise 0
19
1
J′(J′ + 1) if m ≠ 0 and J = Kc and J′ = Kc′, otherwise 0
From Ref. 14; J′ − J = 0, ±1; m = [J′(J′ + 1) − J(J + 1)]/2; K′ − K = nΔK.
Table 4
Effective Dipole Moment Expansion Coefficients (in debyes) Derived from Least-Squares Fits of H216O, H217O, and H218O Measured Line Strengths in the (020)–(010) and (020)–(000) Bandsa
Values given within parentheses are uncertainties in the last digit(s).
From Ref. 17; effective constants were computed from the constants given in that study. N represent the number of line strengths used in the least-squares fit. σ% is the standard deviation resulting from the least-squares fit in percent; σ% = {Σ[(Sobs − Scal)/Sobs]2/N}1/2 × 100.
From Ref. 14. Effective constants were computed from the constants given in that study.
From Ref. 15. Effective constants were computed from the constants given in that study.
From Ref. 16. Effective constants were computed from the constants given in that study.
Table 5
Line Positions (cm−1) and Strengths (cm−2/atma at 296 K) Observed in the (020)–(010) Bands of H216O, H217O and H218Ob
Observed Position
o − c
Upper
Lower
Observed Strength
%s
(o − c)%
R
Mol
J
Ka
Kc
J
Ka
Kc
1304.2856
−12
6
3
3
7
4
4
6.48E-05
6
−7.7
1.05
6
1315.9257
−58
5
2
4
6
3
3
1.61E-04
5
10.2
1.35
6
1316.12975
13
5
4
1
6
5
2
3.27E-04
2
3.9
1.11
6
1316.5410
12
5
5
1
6
6
0
6.23E-05
4
2.6
1.11
6
1320.32726
−8
5
3
3
6
4
2
1.64E-04
3
0.7
1.17
6
1324.4947
−2
5
3
2
6
4
3
5.02E-04
2
1.3
1.18
6
1327.73560
8
4
1
4
5
2
3
4.00E-04
3
4.9
1.37
6
1337.29574
−5
7
2
5
8
3
6
1.15E-04
2
−1.4
1.10
6
1340.61955
0
4
4
1
5
5
0
6.63E-04
3
−2.4
1.10
6
1340.63498
0
4
4
0
5
5
1
2.21E-04
2
−2.4
1.10
6
1344.59250
5
10
1
10
11
0
11
5.87E-05
2
−0.6
1.03
6
1346.00352
−1
4
3
2
5
4
1
1.03E-03
3
0.1
1.18
6
1347.03157
−4
4
3
1
5
4
2
3.48E-04
3
1.1
1.20
6
1348.5919
−28
5
0
5
5
3
2
2.95E-05
5
−1.2
1.52
6
1351.57014
−2
4
2
3
5
3
2
1.06E-03
5
−1.1
1.22
6
1355.20988
3
5
2
3
6
3
4
5.85E-04
2
−3.7
1.14
6
1356.03840
−16
10
1
10
10
2
9
4.78E-05
15
12.4
1.94
6
1357.2062
49
10
0
10
10
1
9
1.34E-05
10
−5.7
1.62
6
1358.7220
−13
9
1
8
10
2
9
4.40E-05
3
−7.7
0.96
6
1363.56407
−12
9
0
9
10
1
10
1.45E-04
5
−5.1
1.00
6
1363.83430
24
9
1
9
10
0
10
5.44E-05
3
6.8
1.13
6
1369.53155
12
4
2
2
5
3
3
4.20E-04
3
2.8
1.25
6
1370.89231
−9
3
3
1
4
4
0
6.33E-04
2
−0.5
1.20
6
1371.03946
−2
3
3
0
4
4
1
1.92E-03
4
0.5
1.22
6
1377.09005
10
3
1
3
4
2
2
3.40E-04
4
2.2
1.32
6
1378.3371
−29
9
1
9
9
2
8
3.86E-05
5
6.6
1.76
6
1380.6236
−22
9
0
9
9
1
8
1.10E-04
3
−0.2
1.63
6
1381.628
127
3
0
3
3
3
0
1.63E-05
10
2.2
1.52
6
1381.76344
−11
3
2
2
4
3
1
7.39E-04
3
3.0
1.29
6
1382.42319
−2
8
0
8
9
1
9
1.15E-04
4
−3.3
1.04
6
1382.97003
−6
8
1
8
9
0
9
3.59E-04
2
0.8
1.08
6
1383.65332
−2
8
2
7
9
1
8
1.10E-04
3
−4.2
1.00
6
1384.17029
−2
7
1
6
8
2
7
2.68E-04
3
0.6
1.10
6
1387.93363
1
3
2
1
4
3
2
2.15E-03
4
−4.0
1.19
6
1400.08708
1
8
1
8
8
2
7
2.47E-04
3
−2.7
1.54
6
1400.94226
1
7
0
7
8
1
8
7.51E-04
3
0.0
1.09
6
1402.05544
−1
7
1
7
8
0
8
2.46E-04
2
−1.4
1,07
6
1404.16854
2
5
1
4
6
2
5
9.54E-04
2
−1.6
1.14
6
1404.4444
−48
8
0
8
8
1
7
9.50E-05
5
8.4
1.71
6
1406.1886
15
8
3
6
9
2
7
2.80E-05
4
−7.2
0.90
6
1408.52956
0
2
2
1
3
3
0
3.56E-03
3
−2.4
1.24
6
1409.75911
−7
2
2
0
3
3
1
1.23E-03
2
0.5
1.27
6
1410.5015
8
10
2
9
10
3
8
3.03E-05
4
2.1
1.52
6
1414.42225
−2
4
1
3
5
2
4
5.32E-04
2
−0.7
1.18
6
1418.58218
0
2
1
2
3
2
1
2.17E-03
3
−1.5
1.26
6
1420.97888
4
7
1
7
7
2
6
1.70E-04
2
−5.4
1.44
6
1421.21595
3
6
1
6
7
0
7
1.45E-03
2
3.0
1.14
6
1426.44056
4
6
2
5
7
1
6
4.53E-04
3
−0.2
1.07
6
1426.61023
5
3
1
2
4
2
3
2.50E-03
3
2.1
1.24
6
1426.81052
46
9
2
8
9
3
7
3.16E-05
15
13.8
1.65
6
1428.87888
3
7
0
7
7
1
6
5.40E-04
2
−6.1
1.41
6
1436.23315
4
5
0
5
6
1
6
2.42E-03
3
1.8
1.15
6
1437.80136
−19
7
3
5
8
2
6
2.10E-05
6
8.6
1.07
6
1440.57280
0
6
1
6
6
2
5
9.88E-04
2
−3.9
1.41
6
1440.69965
0
5
1
5
6
0
6
7.87E-04
2
0.9
1.13
6
1441.54075
7
8
2
7
8
3
6
1.98E-04
2
−3.8
1.36
6
1441.55834
1
2
1
1
3
2
2
1.12E-03
3
−2.1
1.22
6
1444.75223
−4
9
1
8
9
2
7
9.89E-05
2
1.1
1.43
6
1445.1889
−44
10
3
8
10
4
7
1.59E-05
3
−4.4
1.29
6
1452.25217
−5
5
2
4
6
1
5
2.27E-04
2
−0.8
1.08
6
1452.46881
4
4
0
4
5
1
5
1.20E-03
2
2.5
1.19
6
1452.60703
3
1
1
1
2
2
0
1.27E-03
4
−1.9
1.26
6
1453.61730
−3
9
3
7
9
4
6
1.53E-05
3
−2.2
1.30
6
1453.78864
1
6
0
6
6
1
5
3.81E-04
2
−1.9
1.41
6
1454.21313
−17
7
2
6
7
3
5
1.50E-04
3
−0.6
1.38
6
1458.8659
2
10
4
7
10
5
6
7.50E-06
3
−3.3
1.27
6
1459.60773
2
1
1
0
2
2
1
4.39E-03
3
−1.6
1.25
6
1459.88895
−12
8
3
6
8
4
5
1.18E-04
2
2.2
1.34
6
1460.93765
−6
4
1
4
5
0
5
3.65E-03
7
7.9
1.24
6
1462.10226
−10
8
4
5
8
5
4
4.83E-05
2
−1.8
1.26
6
1462.5273
−77
7
4
4
7
5
3
3.85E-05
5
17.7
1.51
6
1462.65777
−1
6
4
3
6
5
2
1.43E-04
3
−6.3
1.18
6
1462.73198
1
5
4
2
5
5
1
5.44E-05
4
0.1
1.26
6
1462.84380
−2
5
4
1
5
5
0
1.61E-04
2
−1.3
1.25
6
1462.9107
−21
8
5
4
8
6
3
1.69E-05
2
−1.3
1.27
6
1463.1153
1
7
5
3
7
6
2
1.05E-05
4
4.5
1.33
6
1463.17298
−5
6
4
2
6
5
1
5.02E-05
3
−1.2
1.25
6
1463.20339
−7
7
5
2
7
6
1
2.78E-05
3
−8.0
1.17
6
1463.2238
−52
8
5
3
8
6
2
5.00E-06
10
−13.2
1.13
6
1463.37604
−1
6
5
2
6
6
1
3.71E-05
3
2.9
1.30
6
1463.39803
0
6
5
1
6
6
0
1.18E-05
3
−1.8
1.25
6
1463.6486
−10
9
5
4
9
6
3
7.70E-06
3
−1.5
1.28
6
1464.10649
1
7
3
5
7
4
4
8.20E-05
2
1.0
1.31
6
1464.22716
0
7
4
3
7
5
2
9.75E-05
2
0.5
1.27
6
1464.45849
0
6
2
5
6
3
4
8.45E-04
2
−1.9
1.33
6
1464.6143
36
11
2
9
11
3
8
6.86E-06
10
−5.0
1.25
6
P1466.18106
−4
8
4
4
8
5
3
1.10E-05
3
−50.7
1.33
6
1466.58454
−6
6
3
4
6
4
3
4.32E-04
2
0.3
1.30
6
1467.0251
2
8
1
7
8
2
6
8.75E-05
3
−3.9
1.32
6
1467.64570
1
3
0
3
4
1
4
4.55E-03
2
0.5
1.18
6
1467.79752
2
5
3
3
5
4
2
2.00E-04
2
−1.3
1.28
6
1468.26682
−3
4
3
2
4
4
1
5.80E-04
2
−0.7
1.29
6
P1468.970
−85
7
6
2
7
7
1
1.76E-06
10
−31.8
1.09
6
P1469.066
−35
7
6
1
7
7
0
5.20E-06
10
−34.0
1.09
6
1470.74848
−22
9
4
5
9
5
4
2.30E-05
4
7.6
1.38
6
1470.86848
−3
5
3
2
5
4
1
6.10E-04
2
−0.4
1.29
6
1472.37346
−6
6
3
4
7
2
5
9.82E-05
2
5.5
1.05
6
1474.62823
2
6
3
3
6
4
2
1.46E-04
2
−0.4
1.28
6
1477.24875
−2
4
2
3
4
3
2
1.73E-03
2
−2.1
1.30
6
1478.12349
4
5
0
5
5
1
4
2.20E-03
4
−0.5
1.38
6
1480.22927
5
3
2
2
3
3
1
4.97E-04
3
−3.6
1.28
6
1480.69765
−8
7
3
4
7
4
3
2.62E-04
2
2.7
1.31
6
1482.47745
2
2
0
2
3
1
3
1.70E-03
3
−0.2
1.20
6
1482.53983
−4
3
1
3
4
0
4
1.35E-03
2
0.2
1.15
6
1485.13356
0
3
2
1
3
3
0
1.57E-03
3
−0.6
1.30
6
1486.74365
5
7
1
6
7
2
5
6.90E-04
2
−1.3
1.32
6
1490.0218
−29
4
2
2
4
3
1
5.25E-04
15
−18.3
1.08
6
1494.8717
11
9
2
7
9
3
6
8.71E-05
7
−0.2
1.27
6
1495.03784
−9
9
3
6
9
4
5
5.00E-05
4
−4.0
1.21
6
1495.61167
0
2
1
2
2
2
1
2.57E-03
3
−0.9
1.31
6
1498.37984
−5
1
0
1
2
1
2
5.05E-03
2
−0.2
1.22
6
1498.5172
32
11
3
8
11
4
7
5.26E-06
6
−0.9
1.24
6
1499.82819
6
4
0
4
4
1
3
1.27E-03
2
−1.8
1.31
6
1502.08947
−1
6
2
4
6
3
3
3.50E-04
4
−1.0
1.26
6
1502.43622
10
8
2
6
8
3
5
9.10E-05
15
10.8
1.41
6
1502.6598
−56
8
1
8
7
2
5
6.00E-06
10
−1.2
2.43
6
1504.61315
2
7
2
5
7
3
4
5.74E-04
2
1.1
1.27
6
1506.0207
9
2
1
2
3
0
3
4.00E-03
8
6.9
1.25
6
1508.3019
−33
5
3
3
6
2
4
4.00E-05
4
−3.4
0.97
6
1511.48584
−2
5
1
4
5
2
3
3.16E-03
2
6.1
1.37
6
1511.85960
4
2
1
1
2
2
0
1.18E-03
2
1.9
1.31
6
1515.29144
3
3
1
2
3
2
1
4.80E-03
2
−1.2
1.27
6
1515.67386
3
4
1
3
4
2
2
1.50E-03
3
1.8
1.30
6
1528.31120
0
2
0
2
2
1
1
2.44E-03
3
0.0
1.27
6
1531.12875
−3
1
1
1
2
0
2
7.44E-04
2
0.5
1.18
6
1534.93548
4
1
0
1
1
1
0
6.33E-03
3
0.3
1.26
6
1543.7319
8
2
2
1
3
1
2
3.88E-04
10
−11.8
0.98
6
1543.8972
−13
4
3
2
5
2
3
1.28E-04
5
−2.7
0.99
6
1547.8894
−74
6
1
6
5
2
3
6.11E-05
5
0.9
1.76
6
1583.3559
−29
1
1
0
1
0
1
5.53E-03
5
−0.8
1.16
6
1586.9943
23
2
0
2
1
1
1
9.42E-04
5
−2.5
1.22
6
1590.3812
−14
2
1
1
2
0
2
2.02E-03
3
−0.7
1.15
6
1592.3218
90
3
1
2
2
2
1
7.32E-04
3
1.3
1.32
6
1601.3467
−33
1
1
1
0
0
0
1.49E-03
4
5.0
1.23
6
1602.72990
6
3
1
2
3
0
3
4.75E-03
3
4.8
1.21
6
1619.36015
0
2
1
2
1
0
1
5.69E-03
5
−1.9
1.16
6
1620.33590
8
3
2
1
3
1
2
3.54E-03
3
3.8
1.16
6
1620.4691
−38
4
2
2
4
1
3
9.92E-04
5
−2.1
1.10
6
1621.1241
35
4
1
3
4
0
4
8.64E-04
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1
6
3.20E-03
10
−8.1
1.19
8
1690.97723
2
7
1
7
6
0
6
1.16E-03
5
−0.0
1.29
8
1691.4169
−8
7
2
5
6
3
4
2.48E-04
10
3.3
1.39
8
1701.8743
8
4
2
3
3
1
2
2.85E-03
10
−3.5
1.06
8
1707.0111
1
8
0
8
7
1
7
7.15E-04
5
0.3
1.38
8
1707.8239
2
8
1
8
7
0
7
2.14E-03
5
−0.0
1.32
8
1712.1433
23
7
1
6
6
2
5
1.05E-03
4
6.5
1.31
8
1724.25837
−43
9
0
9
8
1
8
1.17E-03
5
−1.2
1.34
8
1724.6424
−12
9
1
9
8
0
8
3.98E-04
10
0.8
1.36
8
1727.43150
0
6
2
5
5
1
4
1.55E-03
5
−4.4
1.06
8
1728.8245
−46
5
4
1
5
3
2
3.54E-04
10
10.9
1.32
8
1738.0231
−24
8
1
7
7
2
6
2.06E-04
10
2.4
1.23
8
1741.1290
−8
10
0
10
9
1
9
1.85E-04
10
−6.9
1.30
8
1741.31288
14
10
1
10
9
0
9
5.94E-04
6
1.4
1.40
8
1748.40805
12
3
3
1
2
2
0
9.60E-04
4
−9.9
0.99
8
1749.7621
2
3
3
0
2
2
1
3.06E-03
6
−3.3
1.06
8
1754.3625
−1
8
2
7
7
1
6
6.12E-04
3
−1.0
1.13
8
1757.6911
4
11
0
11
10
1
10
2.88E-04
10
5.7
1.54
8
1761.3855
76
9
1
8
8
2
7
3.07E-04
10
−4.5
1.16
8
1769.78478
−3
4
3
2
3
2
1
2.18E-03
3
3.6
1.07
8
1776.4078
10
4
3
1
3
2
2
6.42E-04
10
−4.9
0.98
8
1787.6560
3
5
3
3
4
2
2
4.38E-04
10
3.5
1.03
8
1788.2920
−14
5
5
0
5
4
1
7.96E-05
10
−2.6
1.43
8
1798.3760
−53
5
2
3
4
1
4
4.20E-04
10
−2.7
0.88
8
1801.8622
38
6
3
4
5
2
3
7.27E-04
4
1.7
0.98
8
1806.3396
−5
5
3
2
4
2
3
1.18E-03
5
7.4
1.03
8
1829.5689
−11
4
4
1
3
3
0
1.55E-03
4
−0.2
1.05
8
1829.7576
−20
4
4
0
3
3
1
4.88E-04
5
−5.9
0.99
8
1853.2859
−15
5
4
2
4
3
1
3.06E-04
10
4.9
1.00
8
1854.57636
6
5
4
1
4
3
2
8.88E-04
4
1.8
0.97
8
1875.1726
−19
6
4
3
5
3
2
4.50E-04
5
2.1
0.88
8
1884.0157
15
7
3
4
6
2
5
1.76E-04
10
4.6
0.78
8
1910.4178
−10
5
5
1
4
4
0
1.60E-04
10
−2.7
0.98
8
1910.4407
0
5
5
0
4
4
1
5.10E-04
8
3.3
1.05
8
1934.9394
−11
6
5
2
5
4
1
2.39E-04
10
1.4
0.87
8
1 atm = 760 Torr.
o − c, Observed minus computed line positions (cm−1 × 105). Computed values are derived from the energy levels given in Table 2 and the lower state, (010), levels given in Ref. 1 for H216O and Ref. 2 for H217O and H218O. %s, Estimated uncertainties in the measured line strengths given in percent. (o − c)%, Percent difference between the observed and computed line strengths. R, Ratio of the observed line strength derived in this study to the computed value given in Refs. 17–19. Mol, Isotopic species in which 6 represents H216O, 7 represents H217O, and 8 represents H218O. An asterisk denotes a doubled absorption with the quantum assignment given for the stronger transition. The strength given represents the sum of the strengths of the two comparable transitions. P denotes that the transition is strongly perturbed.
Table 6
Line Positions (cm−1) and Strengths (cm−2/atma at 296 K) Observed in the (020)–(000) Band of H216Ob
Observed Position
o − c
Upper
Lower
Observed Strength
%s
(o − c)%
R
J
Ka
Kc
J
Ka
Kc
2622.5753
−15
9
0
9
10
3
8
3.10E-06
10
1.3
1.06
2670.0044
−3
10
2
9
11
3
8
1.88E-06
5
−12.7
0.90
2681.8148
58
9
1
8
10
4
7
3.54E-06
7
1.5
1.03
2693.3318
41
8
1
8
9
2
7
1.35E-05
4
−0.4
1.05
2730.089
−228
9
2
8
10
3
7
3.60E-06
10
5.3
1.09
2732.49271
−41
7
0
7
8
3
6
2.68E-05
4
−7.0
0.99
2788.8142
3
8
2
7
9
3
6
5.04E-05
8
6.1
1.12
2819.44924
25
6
1
6
7
2
5
1.66E-04
3
−3.7
1.05
2820.48697
−39
9
3
7
10
4
6
1.00E-05
10
0.5
1.04
2830.00743
−34
5
0
5
6
3
4
1.36E-04
3
2.5
1.11
2844.0105
45
7
2
6
8
3
5
7.10E-05
4
3.1
1.10
2864.35029
−84
8
3
6
9
4
5
1.31E-04
3
−4.6
1.00
2871.3305
84
4
0
4
5
3
3
6.00E-05
10
1.2
1.11
2879.70636
−36
5
1
5
6
2
4
1.98E-04
5
0.8
1.11
2883.027
−66
10
5
6
11
6
5
1.31E-05
10
9.0
1.21
2890.1627
14
12
0
12
13
1
13
3.43E-05
7
0.3
1.09
2890.19489
−28
12
1
12
13
0
13
1.10E-04
6
7.0
1.16
2893.07588
6
9
4
5
10
5
6
5.55E-05
2
−3.8
0.99
2893.81418
4
6
2
5
7
3
4
8.11E-04
2
0.2
1.09
2904.43818
19
8
4
5
9
5
4
1.74E-04
2
0.6
1.04
2906.72554
−9
3
0
3
4
3
2
1.45E-04
2
2.6
1.14
2909.4350
−90
11
3
8
12
4
9
9.70E-06
10
10.6
1.13
2909.68935
46
9
5
4
10
6
5
4.10E-05
4
5.1
1.05
2911.33232
8
8
4
4
9
5
5
4.75E-05
3
4.02E-05
1.13
2911.88958
2
11
0
11
12
1
12
2.95E-04
3
−5.7
1.06
2911.95194
1
11
1
11
12
0
12
9.90E-05
5
−4.7
1.07
2912.46818
2
9
3
6
10
4
7
8.70E-05
2
−1.6
1.03
2918.99160
10
8
3
5
9
4
6
8.57E-05
2
−0.8
1.05
2922.1143
22
12
1
12
12
2
11
1.54E-05
10
7.6
1.08
2924.2591
16
12
1
11
13
2
12
1.00E-05
6
7.0
1.10
2930.12835
−1
7
3
4
8
4
5
7.16E-04
2
0.7
1.08
2930.65783
−10
7
4
4
8
5
3
1.76E-04
2
1.1
1.05
2932.65156
−6
8
5
4
9
6
3
1.27E-04
3
2.0
1.02
2933.1213
26
8
5
3
9
6
4
4.10E-05
4
−1.6
0.99
2933.35685
9
10
1
10
11
0
11
8.28E-04
3
2.6
1.13
2933.72895
1
6
3
4
7
4
3
1.53E-03
3
−2.4
1.05
2934.028
−222
12
2
10
13
3
11
4.10E-06
10
2.86E-06
1.10
2935.19362
2
4
1
4
5
2
3
1.92E-03
2
0.7
1.13
2936.7416
−19
2
0
2
3
3
1
1.72E-05
4
2.6
1.15
2936.96703
4
5
2
4
6
3
3
8.90E-04
2
−0.4
1.10
2940.06758
−1
11
1
10
12
2
11
8.87E-05
2
0.7
1.05
2941.76294
−2
11
2
10
12
1
11
3.02E-05
5
2.0
1.06
2941.9863
28
9
6
3
10
7
4
1.10E-05
4
1.41E-05
1.03
2943.1464
−16
11
2
9
12
3
10
2.77E-05
5
0.8
1.01
2944.6606
24
11
1
11
11
2
10
1.74E-05
3
1.1
1.12
2946.0497
−8
6
3
3
7
4
4
5.95E-04
4
−0.3
1.08
2949.1483
8
10
2
8
11
3
9
2.66E-05
5
0.0
1.04
2951.536
−156
10
7
4
11
8
3
5.18E-06
4
3.73E-06
1.27
2951.553
190
10
7
3
11
8
4
1.73E-06
4
1.24E-06
1.27
2953.41383
11
9
2
7
10
3
8
2.07E-04
4
−1.2
1.05
2954.15386
−1
9
0
9
10
1
10
1.93E-03
2
−1.2
1.09
2954.39855
−14
9
1
9
10
0
10
6.81E-04
3
5.8
1.15
2955.1132
−13
5
1
4
5
4
1
9.55E-06
5
24.5
1.23
2955.25618
−1
10
1
9
11
2
10
8.40E-05
3
0.6
1.06
2955.67958
1
6
4
3
7
5
2
1.36E-03
2
0.0
1.05
2956.40613
4
6
4
2
7
5
3
4.62E-04
3
1.2
1.06
2956.90400
−2
7
5
3
8
6
2
1.22E-04
3
4.4
1.03
2956.99441
1
8
2
6
9
3
7
1.65E-04
2
−2.1
1.05
2957.02575
28
7
5
2
8
6
3
3.85E-04
4
7.7
1.09
2958.37995
0
10
2
9
11
1
10
2.51E-04
2
−1.3
1.04
2961.37252
3
7
2
5
8
3
6
1.13E-03
2
−0.9
1.08
2961.71263
0
5
3
3
6
4
2
1.29E-03
2
−0.5
1.08
2961.88288
17
11
3
9
12
2
10
9.91E-06
10
7.6
0.99
2964.21697
10
8
6
3
9
7
2
7.22E-05
2
−3.5
0.97
2964.50474
−12
8
6
2
9
7
3
2.66E-05
2
6.5
1.17
2966.0063
12
5
3
2
6
4
3
4.14E-03
2
1.8
1.11
2966.83284
12
10
1
10
10
2
9
1.53E-04
4
−2.3
1.09
2967.33362
4
10
0
10
10
1
9
5.25E-05
3
−0.2
1.11
2967.98477
−1
6
2
4
7
3
5
8.15E-04
2
0.7
1.11
2969.51627
−2
9
1
8
10
2
9
6.50E-04
2
1.5
1.08
2970.1744
0
5
0
5
5
3
2
6.75E-05
5
8.5
1.17
2973.25241
3
4
2
3
5
3
2
7.00E-03
4
−1.4
1.10
2974.58888
4
8
0
8
9
1
9
1.43E-03
2
0.3
1.12
2974.8280
−45
12
4
9
13
3
10
6.50E-06
8
3.01E-06
1.27
2975.08458
5
8
1
8
9
0
9
4.29E-03
5
0.3
1.11
2975.22271
6
9
2
8
10
1
9
2.16E-04
2
−1.3
1.05
*2975.2944
−68
9
7
2
10
8
3
1.76E-05
2
1.5
0.93
2977.94343
−1
5
2
3
6
3
4
4.95E-03
2
1.3
1.12
2979.07153
5
10
3
8
11
2
9
9.09E-05
2
2.6
1.06
2980.24024
1
5
4
2
6
5
1
1.03E-03
2
−0.5
1.05
2980.38811
−4
5
4
1
6
5
2
3.08E-03
2
−1.0
1.04
2981.14415
−5
6
5
2
7
6
1
9.13E-04
2
1.0
1.03
2981.17111
−4
6
5
1
7
6
2
3.08E-04
3
2.1
1.04
2982.45252
−5
8
1
7
9
2
8
4.85E-04
2
−0.3
1.07
2984.21159
5
3
1
3
4
2
2
1.88E-03
2
1.6
1.15
2987.52481
1
4
3
2
5
4
1
8.06E-03
3
−1.0
1.08
2988.19165
3
7
6
2
8
7
1
7.13E-05
2
0.8
1.01
2988.28775
−1
7
6
1
8
7
2
2.08E-04
2
−2.0
1.00
2988.54570
10
9
1
9
9
2
8
1.39E-04
2
−3.7
1.09
2988.61258
6
4
3
1
5
4
2
2.74E-03
2
−0.2
1.10
2989.62427
4
9
0
9
9
1
8
4.27E-04
2
−3.2
1.09
2991.45528
−4
4
0
4
4
3
1
3.17E-05
3
4.5
1.15
2991.9710
−1
4
2
2
5
3
3
3.08E-03
2
0.3
1.12
2992.65373
−2
8
2
7
9
1
8
1.53E-03
3
0.8
1.09
2993.73595
0
7
1
6
8
2
7
2.95E-03
2
−0.1
1.09
2994.44644
2
7
0
7
8
1
8
8.70E-03
4
3.1
1.15
2995.45513
1
7
1
7
8
0
8
2.85E-03
2
1.0
1.13
2998.97188
0
9
3
7
10
2
8
7.83E-05
2
1.0
1.06
*2999.15758
−18
8
7
2
9
8
1
5.45E-05
4
−2.9
0.92
2999.8623
54
11
4
8
12
3
9
3.22E-06
4
−4.1
0.88
3003.47424
−2
6
1
5
7
2
6
1.83E-03
2
2.9
1.14
3004.6868
46
4
4
1
5
5
0
6.30E-03
4
0.3
1.07
3004.7025
−38
4
4
0
5
5
1
2.10E-03
4
0.2
1.07
3004.98381
−2
12
2
11
12
3
10
1.15E-05
3
−9.2
0.95
3005.4456
17
5
5
1
6
6
0
7.25E-04
5
6.1
1.09
3005.4544
−40
5
5
0
6
6
1
2.18E-03
5
6.4
1.10
3006.42575
0
12
1
11
12
2
10
4.52E-06
3
7.8
1.08
3009.65271
0
8
1
8
8
2
7
1.10E-03
3
1.0
1.14
3010.2322
−26
3
2
1
4
3
2
1.58E-02
3
−1.6
1.11
301}.27736
1
7
2
6
8
1
7
1.05E-03
3
1.3
1.10
3011.90863
9
8
0
8
8
1
7
3.73E-04
2
−1.2
1.12
*3012.0683
16
9
8
1
10
9
2
1.07E-05
7
8.9
0.93
3012.23200
−1
6
6
1
7
7
0
4.55E-04
4
4.84E-04
0.95
3012.34352
−3
6
6
0
7
7
1
1.78E-04
3
−0.8
0.99
3012.37684
1
3
3
1
4
4
0
4.90E-03
2
−0.9
1.09
3013.57316
0
6
0
6
7
1
7
4.98E-03
5
0.5
1.13
3015.61527
−1
6
1
6
7
0
7
1.56E-02
3
4.0
1.17
3021.31066
7
11
2
10
11
3
9
1.47E-05
3
2.2
1.03
*3021.5496
0
10
9
2
11
10
1
6.85E-06
10
1.54E-06
3.08
3022.3662
−3
4
1
3
5
2
4
4.38E-03
3
−0.2
1.13
3022.66503
1
8
3
6
9
2
7
5.33E-04
2
1.2
1.08
*3023.14995
17
7
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1.9
0.59
3791.1037
7
11
2
9
10
1
10
3.80E-06
7
5.47E-06
0.32
3799.83402
−2
8
4
4
7
1
7
1.45E-03
2
3.72E-06
1.11
3812.767
−45
12
5
8
12
2
11
7.00E-06
10
2.27E-07
0.93
3817.9348
0
9
7
3
8
6
2
1.30E-05
4
5.4
0.47
3817.96755
2
9
7
2
8
6
3
4.05E-05
2
9.2
0.49
3825.1526
3
10
5
6
9
2
7
7.50E-06
10
6.51E-06
0.49
3842.565
−190
10
7
3
9
6
4
2.90E-06
10
−9.3
0.33
*3866.6566
0
8
8
1
7
7
0
7.20E-05
10
5.59E-05
0.54
3871.9912
27
6
5
2
5
0
5
4.14E-05
2
9.46E-07
0.05
3874.7641
13
7
6
1
7
1
6
1.25E-04
3
3.63E-07
0.79
3892.1983
36
8
6
2
8
1
7
4.50E-05
4
1.41E-07
1.05
*3892.6331
−1
9
8
1
8
7
2
3.46E-05
6
1.44E-05
0.76
3898.2343
5
6
6
1
5
3
2
7.40E-02
3
1.40E-06
0.84
3903.18980
12
6
6
0
5
3
3
3.50E-04
2
4.60E-07
0.75
3915.27836
−3
10
5
5
10
0
10
1.90E-05
4
6.82E-08
0.43
3929.99945
12
7
6
1
6
3
4
1.37E-03
3
1.54E-06
0.76
3932.4485
23
8
6
3
7
3
4
3.20E-04
6
1.19E-06
0.74
3944.1634
13
10
4
6
9
1
9
2.34E-05
3
1.36E-07
0.45
3949.42522
−8
10
5
5
9
2
8
4.95E-04
3
1.89E-07
0.36
3955.4666
−46
10
6
5
9
3
6
1.30E-05
10
2.54E-07
0.80
3958.39407
4
8
6
2
7
3
5
5.12E-04
2
2.83E-07
0.83
3959.7943
30
6
6
1
6
1
6
1.19E-04
3
1.42E-08
0.81
3960.1815
0
14
2
12
13
1
13
1.55E-05
4
4.12E-09
1.55
3983.76244
0
14
3
12
13
0
13
1.06E-04
2
1.11E-08
1.29
4006.544
5
11
5
6
10
2
9
2.65E-06
6
3.04E-08
0.21
4007.5890
15
6
6
1
5
1
4
6.35E-03
2
1.78E-08
0.75
4018.00805
0
15
3
12
14
2
13
1.14E-04
2
9.02E-11
0.97
4021.1890
16
10
6
4
9
3
7
4.46E-05
3
4.28E-09
1.68
4035.97683
15
7
6
2
6
1
5
8.73E-05
3
7.50E-09
0.71
4070.5912
35
8
6
3
7
1
6
6.83E-05
2
1.04E-09
0.63
4077.72
575
8
7
2
7
4
3
2.90E-07
UL
3.10E-09
0.07
4106.87
−49
9
7
2
8
4
5
3.20E-07
UL
5.98E-08
0.08
4131.7260
29
7
6
1
6
1
6
1.32E-05
4
8.96E-10
0.80
4159.3060
−64
10
6
5
9
1
8
9.30E-06
10
8.31E-08
0.52
4188.6099
70
8
6
2
7
1
7
2.20E-06
5
4.20E-09
0.67
4252.1690
26
9
6
3
8
1
8
4.80E-06
10
3.84E-08
0.58
4260.40872
9
12
5
8
11
0
11
3.95E-05
3
5.43E-08
1.11
1 atm = 760 Torr.
o − c, Observed minus computed line positions (cm−1 × 105). Computed values are derived from the energy levels given in Table 2 and the ground-state levels given in Ref. 1. %s, Estimated uncertainties in the measured line strengths given in percent. (o − c)%, Percent difference between the observed and the computed line strengths or the value of the computed strength if the difference between the observed and the computed values is ≈±14% or larger in magnitude. R Ratio of the observed line strength derived in this study to the computed value given in Refs. 18 and 19. UL, upper limit; there were no apparent absorption features in any of the spectra within ±0.015 cm−1 of the listed frequency. The observed strength given represents the maximum strength that the transition can have, with nearby absorption features of other transitions and also the signal-to-noise ratio of the spectra taken into consideration. An asterisk denotes a doubled absorption with the quantum assignment given for the stronger transition. The strength given represents the sum of the strengths of the two comparable transitions.
Table 7
Line Positions (cm−1) and Strengths (cm−2/atma at 296 K) Observed in the (020)–(000) Band of H217Ob
Observed Position
o − c
Upper
Lower
Observed Strength
%s
(o − c)%
R
J
Ka
Kc
J
Ka
Kc
2927.3410
32
7
4
3
8
5
4
5.60E-04
10
3.8
2927.5810
36
6
3
4
7
4
3
1.50E-03
10
−4.1
1.12
2930.5584
56
5
2
4
6
3
3
7.99E-04
10
−8.7
1.08
2948.0040
−17
9
0
9
10
1
10
1.92E-03
2
−3.0
1.12
2948.2350
19
9
1
9
10
0
10
6.87E-04
5
4.0
2949.7345
20
6
4
3
7
5
2
1.40E-03
10
0.2
1.17
2955.7105
−5
5
3
3
6
4
2
1.27E-03
3
−2.9
1.15
2955.8535
−2
7
2
5
8
3
6
1.16E-03
3
1.9
1.17
2960.1463
3
5
3
2
6
4
3
4.15E-03
3
1.0
1.20
2962.3611
−35
6
2
4
7
3
5
8.34E-04
10
3.5
1.21
2963.428
105
9
1
8
10
2
9
6.77E-04
10
3.5
2967.0677
9
4
2
3
5
3
2
6.90E-03
3
−1.2
1.18
2968.3892
39
8
0
8
9
1
9
1.44E-03
4
0.2
1.16
2968.8573
−1
8
1
8
9
0
9
4.60E-03
10
6.3
1.24
2972.2035
23
5
2
3
6
3
4
4.86E-03
4
0.2
1.18
2974.3245
−49
5
4
2
6
5
1
1.10E-03
3
1.4
1.23
2974.4798
23
5
4
1
6
5
2
3.25E-03
3
−0.3
1.20
2977.8327
10
3
1
3
4
2
2
1.83E-03
6
1.4
1.24
2981.5858
7
4
3
2
5
4
1
8.10E-03
5
−2.5
1.18
2982.7100
0
4
3
1
5
4
2
2.85E-03
4
1.8
1.23
2986.1218
23
4
2
2
5
3
3
3.05E-03
3
0.1
1.20
2986.1579
6
8
2
7
9
1
8
1.60E-03
10
4.4
1.19
2987.7522
−24
7
1
6
8
2
7
3.15E-03
4
5.8
1.22
2988.2029
−11
7
0
7
8
1
8
8.70E-03
5
2.5
1.20
2989.1625
−17
7
1
7
8
0
8
2.80E-03
4
−1.3
1.16
2997.52760
11
6
1
5
7
2
6
1.90E-03
4
6.3
1.24
2997.7850
−17
3
2
2
4
3
1
5.00E-03
3
2.5
1.24
2998.7838
10
4
4
1
5
5
0
6.13E-03
5
−8.2
1.14
2998.802
84
4
4
0
5
5
1
2.00E-03
5
−10.9
1.11
2999.5344
18
5
5
0
6
6
1
2.68E-03
4
−0.2
1.11
3004.2996
1
3
2
1
4
3
2
1.62E-02
2
1.6
1.23
3004.6257
−22
7
2
6
8
1
7
1.00E-03
10
−4.0
1.11
3006.4576
31
3
3
1
4
4
0
4.75E-03
6
−6.9
1.16
3006.5880
−7
5
1
4
6
2
5
8.77E-03
3
0.4
1.19
3006.61685
−15
3
3
0
4
4
1
1.50E-02
2
−1.9
1.21
3007.2977
21
6
0
6
7
1
7
5.02E-03
3
0.7
1.20
3009.2520
15
6
1
6
7
0
7
1.50E-02
2
−0.4
1.18
3016.3655
−33
4
1
3
5
2
4
4.36E-03
4
−0.5
1.20
3019.50149
−10
2
1
2
3
2
1
1.33E-02
2
0.7
1.24
3024.72450
−8
2
2
1
3
3
0
2.56E-02
5
2.4
1.26
3025.1088
22
6
2
5
7
1
6
5.52E-03
4
0.1
1.16
3025.4393
15
5
0
5
6
1
6
2.36E-02
4
0.9
1.21
3026.01336
9
2
2
0
3
3
1
8.40E-03
3
−0.8
1.22
3027.8084
51
7
0
7
7
1
6
2.68E-03
3
1.2
1.25
3028.20585
13
3
1
2
4
2
3
1.83E-02
3
−0.8
1.20
3029.3396
0
5
1
5
6
0
6
7.65E-03
5
−3.0
1.16
3042.3669
−13
4
0
4
5
1
5
1.05E-02
3
−2.0
1.20
3042.5832
−16
6
1
6
6
2
5
5.05E-03
3
1.5
1.24
3042.9350
−23
2
1
1
3
2
2
8.10E-03
2
0.5
1.24
3048.5478
0
5
2
4
6
1
5
2.68E-03
2
−1.5
1.16
3049.8176
34
4
1
4
5
0
5
3.29E-02
2
1.4
1.23
3050.463
40
6
0
6
6
1
5
2.02E-03
5
3.3
1.29
3053.74258
0
1
1
1
2
2
0
8.47E-03
4
2.7
1.28
3058.08305
−13
3
0
3
4
1
4
3.87E-02
2
0.6
1.24
3059.1772
−30
8
2
7
8
3
6
1.10E-03
5
−4.1
1.15
3060.8654
17
1
1
0
2
2
1
3.08E-02
3
3.0
1.28
3071.2902
−8
3
1
3
4
0
4
1.23E-02
3
−1.4
1.21
3072.8047
−1
5
0
5
5
1
4
1.19E-02
3
−1.4
1.24
3073.32730
0
2
0
2
3
1
3
1.37E-02
3
1.8
1.27
3074.4990
−24
6
3
4
7
2
5
1.53E-03
3
−4.9
1.09
3075.03925
−8
4
1
4
4
2
3
1.43E-02
2
2.1
1.27
3075.36258
−2
4
2
3
5
1
4
9.70E-03
3
0.5
1.20
3080.92261
26
6
2
5
6
3
4
5.17E-03
2
−0.2
1.21
3087.4293
3
3
1
.3
3
2
2
6.00E-03
2
1.6
1.27
3089.54250
−3
1
0
1
2
1
2
3.78E-02
2
0.9
1.26
3090.0273
22
7
1
6
7
2
5
4.40E-03
7
2.7
1.28
3093.11650
−21
4
0
4
4
1
3
7.35E-03
3
−3.2
1.23
3093.4361
3
4
2
3
4
3
2
1.15E-02
2
3.0
1.27
3094.3997
−5
2
1
2
3
0
3
3.44E-02
2
2.4
1.26
3095.6222
19
8
3
6
8
4
5
8.00E-04
10
−1.0
1.18
3096.4000
50
3
2
2
3
3
1
3.27E-03
3
−0.6
1.23
3096.79208
−2
2
1
2
2
2
1
1.57E-02
2
0.4
1.26
3099.719
136
7
3
5
7
4
4
5.81E-04
10
1.0
3101.3375
−26
3
2
1
3
3
0
1.01E-02
3
−3.3
1.20
3102.1712
−21
6
3
4
6
4
3
3.10E-03
5
0.8
1.23
3103.3627
−37
5
3
3
5
4
2
1.40E-03
5
−3.6
1.19
3103.5828
−25
6
1
5
6
2
4
3.30E-03
5
−2.1
1.22
3103.77398
−12
4
3
2
4
4
1
4.27E-03
4
1.9
1.27
3104.6324
−5
4
3
1
4
4
0
1.42E-03
3
0.9
1.26
3104.8306
−1
3
2
2
4
1
3
2.82E-03
3
−1.7
1.18
3106.1251
−16
4
2
2
4
3
1
4.54E-03
4
4.8
1.28
3106.45393
−4
5
3
2
5
4
1
4.47E-03
2
−0.2
1.22
3108.0493
−10
0
0
0
1
1
1
1.00E-02
5
0.8
1.28
3108.5615
−6
5
3
3
6
2
4
7.00E-04
10
−1.1
3109.27735
3
3
0
3
3
1
2
3.68E-02
3
−1.0
1.26
3109.735
−85
9
2
7
9
3
6
5.50E-04
6
−10.0
3110.1230
51
6
3
3
6
4
2
1.06E-03
6
−3.7
1.16
3112.4039
−11
5
1
4
5
2
3
1.95E-02
3
−1.1
1.23
3112.9860
13
2
1
1
2
2
0
7.75E-03
3
0.1
1.25
3115.7351
12
7
3
4
7
4
3
2.04E-03
4
2.6
1.23
3116.20892
6
3
1
2
3
2
1
3.35E-02
3
1.1
1.26
3116.4150
−36
4
1
3
4
2
2
9.75E-03
2
−2.5
1.21
3116.9851
−31
6
2
4
6
3
3
2.55E-03
4
−1.0
1.19
3118.7700
2
7
2
5
7
3
4
3.87E-03
4
−6.4
1.13
3119.1696
51
1
1
1
2
0
2
7.10E-03
6
9.6
1.37
3120.25917
0
2
0
2
2
1
1
1.59E-02
3
0.0
1.26
3120.475
−89
8
4
5
8
5
4
4.20E-04
10
−1.3
3120.9115
−31
6
4
3
6
5
2
1.47E-03
10
12.2
1.41
3120.932
−121
5
4
1
5
5
0
1.30E-03
8
−5.4
1.18
3126.5830
7
1
0
1
1
1
0
4.22E-02
2
−0.1
1.26
3135.3826
35
2
2
1
3
1
2
4.95E-03
3
2.1
1.24
3143.1903
61
4
3
2
5
2
3
2.22E-03
5
0.5
1.19
3156.919
106
6
3
3
7
2
6
2.74E-04
10
−0.0
3157.484 <
;09
3
1
3
2
2
0
4.83E-04
10
−4.5
3160.8014
11
3
2
1
4
1
4
2.57E-03
3
−1.1
1.19
3162.2421
11
5
3
2
6
2
5
1.56E-03
7
3.9
1.20
3162.418
−302
4
2
2
5
1
5
4.96E-04
10
−5.4
3167.6720
−52
2
2
0
3
1
3
8.59E-04
5
5.0
1.28
3171.2372
21
1
1
0
1
0
1
4.36E-02
4
−1.4
1.24
3173.030
−51
5
2
3
6
1
6
7.26E-04
10
1.0
3174.742
73
4
3
1
5
2
4
6.65E-04
5
3.2
3176.620
436
3
3
1
4
2
2
4.65E-04
10
−5.8
3178.29860
0
2
0
2
1
1
1
6.22E-03
2
−0.5
1.26
3178.41238
0
2
1
1
2
0
2
1.57E-02
2
−2.5
1.23
3189.1738
4
1
1
1
0
0
0
1.06E-02
3
−1.0
1.26
3190.474
−24
4
2
3
3
3
0
9.00E-04
10
−5.3
1.18
3191.10688
−14
3
1
2
3
0
3
3.50E-02
3
−2.8
1.22
3193.49930
−7
3
1
2
2
2
1
4.50E-03
3
1.5
1.27
3203.1602
13
3
0
3
2
1
2
3.43E-02
3
1.2
1.28
3207.16385
−1
2
1
2
1
0
1
4.25E-02
3
1.9
1.29
3209.87327
23
4
1
3
4
0
4
7.18E-03
5
0.6
1.26
3211.99541
−2
3
2
1
3
1
2
3.10E-02
3
−0.2
1.23
3213.1707
0
4
2
2
4
1
3
8.85E-03
2
−1.3
1.21
3214.6042
−19
2
2
0
2
1
1
8.10E-03
4
4.1
1.29
3220.8196
−56
6
2
5
5
3
2
6.47E-04
6
1.8
3222.90650
8
3
1
3
2
0
2
1.55E-02
3
−0.4
1.26
3226.0120
−3
4
1
3
3
2
2
2.50E-03
7
−6.5
1.16
3226.34500
15
4
0
4
3
1
3
1.35E-02
3
0.9
1.27
3229.2651
10
2
2
1
2
1
2
1.78E-02
2
0.0
1.24
3233.53650
4
5
1
4
5
0
5
1.13E-02
4
−1.5
1.21
3234.9759
53
6
2
4
6
1
5
2.72E-03
3
−1.0
1.21
3237.94060
−3
4
1
4
3
0
3
4.57E-02
3
−0.4
1.25
3238.0587
−5
3
2
2
3
1
3
6.65E-03
3
−0.2
1.22
3238.4700
46
5
2
3
4
3
2
1.70E-03
4
−5.6
1.15
3247.37984
−4
5
0
5
4
1
4
3.58E-02
3
−3.0
1.21
3256.7495
62
7
2
5
7
1
6
3.28E-03
3
−2.6
1.18
3258.75817
−36
5
1
4
4
2
3
9.58E-03
4
3.3
1.25
3259.8246
−3
6
1
5
6
0
6
2.15E-03
10
10.3
1.34
3262.65353
−5
7
3
4
7
2
5
3.07E-03
3
3.3
1.19
3262.9735
0
6
3
3
6
2
4
1.90E-03
6
−3.4
1.12
3264.6639
−50
5
2
4
5
1
5
3.38E-03
4
0.4
1.19
3266.30544
4
2
2
1
1
1
0
3.55E-02
3
−1.1
1.22
3266.5792
0
6
0
6
5
1
5
9.38E-03
3
−0.5
1.23
3268.05806
13
5
3
2
5
2
3
9.42E-03
3
−0.2
1.17
3269.53175
0
6
1
6
5
0
5
2.90E-02
3
−0.1
1.24
3272.64375
−7
2
2
0
1
1
1
1.07E-02
2
1.1
1.25
3274.79105
25
4
3
1
4
2
2
4.60E-03
10
12.4
1.34
3280.39036
11
3
3
0
3
2
1
1.12E-02
4
1.4
1.21
3281.7498
21
6
2
5
6
1
6
5.80E-03
5
3.2
1.21
3284.44890
0
7
0
7
6
1
6
1.85E-02
3
−1.6
1.21
3284.9907
8
3
2
2
2
1
1
1.02E-02
2
2.7
1.26
3285.8422
18
7
1
7
6
0
6
6.30E-03
4
−0.5
1.22
3286.2120
−31
3
3
1
3
2
2
3.50E-03
4
−6.0
1.13
3286.4631
−36
7
1
6
7
0
7
2.73E-03
3
−2.3
1.14
3289.5439
−31
4
3
2
4
2
3
1.19E-02
4
−1.6
1.17
3295.3940
−34
5
3
3
5
2
4
2.80E-03
4
−5.7
1.10
3300.5637
69
7
2
6
7
1
7
9.51E-04
2
2.4
1.17
3301.1320
9
4
2
3
3
1
2
2.39E-02
2
2.2
1.24
3301.3670
−37
8
0
8
7
1
7
3.50E-03
4
−5.1
1.15
3302.01842
0
8
1
8
7
0
7
1.12E-02
3
0.8
1.22
3304.2670
−13
6
3
4
6
2
5
5.28E-03
3
1.3
1.16
3305.8784
22
3
2
1
2
1
2
2.00E-02
3
−0.3
1.21
3312.034
0
8
1
7
8
0
8
4.00E-04
10
−3.8
3312.5625
−15
7
2
5
6
3
4
1.30E-03
10
−6.4
1.08
3313.2791
−16
7
6
1
8
5
4
1.70E-03
10
1.52E-05
1.15
3314.203
−31
9
2
7
9
1
8
4.69E-04
10
7.0
3315.4143
22
5
2
4
4
1
3
5.87E-03
4
2.3
1.23
3316.342
−81
7
3
5
7
2
6
9.32E-04
4
8.4
1.22
3317.5542
−28
9
0
9
8
1
8
5.97E-03
3
2.3
1.23
3317.8611
−13
9
1
9
8
0
8
2.11E-03
3
7.9
1.30
3319.7950
3
7
1
6
6
2
5
6.40E-03
10
5.8
1.24
3329.11495
−20
6
2
5
5
1
4
1.15E-02
3
−2.1
1.15
3331.4580
−13
8
3
6
8
2
7
1.10E-03
2
−0.3
1.11
3333.127
0
10
0
10
9
1
9
9.00E-04
10
−3.3
1.16
3333.2743
9
10
1
10
9
0
9
2.70E-03
5
−3.4
1.15
3336.122
−148
9
1
8
9
0
9
5.21E-04
10
1.7
3336.9745
0
7
4
3
7
3
4
1.47E-03
5
2.6
1.11
3343.7275
−62
7
2
6
6
1
5
2.41E-03
3
−1.0
1.15
3345.5637
−13
6
4
2
6
3
3
9.10E-04
3
−1.7
1.07
3348.1525
0
11
0
11
10
1
10
1.15E-03
6
−5.6
1.13
3351.3826
−37
5
4
1
5
3
2
4.40E-03
4
1.5
1.11
3354.2460
22
4
4
0
4
3
1
1.52E-03
5
0.3
1.12
3355.6020
8
4
4
1
4
3
2
4.50E-03
3
−1.8
1.10
3357.6808
4
3
3
0
2
2
1
3.27E-02
2
−0.2
1.18
3357.9177
30
6
4
3
6
3
4
2.92E-03
2
0.1
1.07
3360.0730
14
8
2
7
7
1
6
4.07E-03
3
0.1
1.14
3361.3285
0
7
4
4
7
3
5
5.54E-04
10
8.5
3362.700
0
12
1
12
11
0
11
4.97E-04
10
2.1
3367.195
175
8
4
5
8
3
6
7.66E-04
10
13.3
3370.574
43
9
1
8
8
2
7
1.90E-03
10
−1.4
1.12
3377.54735
0
4
3
2
3
2
1
2.08E-02
4
−0.4
1.16
3377.9722
0
9
2
8
8
1
7
7.00E-04
10
3.4
3389.192
162
5
3
2
5
0
5
7.14E-04
10
7.1
3394.97120
−4
5
2
3
4
1
4
4.52E-03
3
1.8
1.16
3395.44395
8
5
3
3
4
2
2
3.95E-03
4
−2.4
1.11
3410.0833
23
6
3
4
5
2
3
6.56E-03
2
−0.2
1.11
3414.41235
−10
5
3
2
4
2
3
1.14E-02
2
−0.2
1.12
3422.399
63
7
3
5
6
2
4
1.14E-03
10
1.5
1.11
3430.9022
−1
5
5
0
5
4
1
1.50E-03
10
1.25E-03
1.10
3431.139
−15
5
5
1
5
4
2
5.00E-04
10
4.16E-04
3431.3297
−52
6
5
2
6
4
3
1.23E-03
10
1.08E-03
1.01
3433.732
−77
8
3
6
7
2
5
1.53E-03
3
−7.0
1.01
3449.8060
−28
6
3
3
5
2
4
1.66E-03
6
−5.6
1.01
3451.092
3
6
2
4
5
1
5
5.68E-04
7
−0.9
3452.4452
−31
4
3
2
3
0
3
7.60E−04
10
−5.2
0.98
3452.64003
−6
4
4
1
3
3
0
1.92E-02
4
0.8
1.08
3452.8599
−21
4
4
0
3
3
1
6.50E-03
3
2.3
1.10
3476.2629
0
5
4
2
4
3
1
3.59E-03
2
1.5
1.05
3476.9284
0
6
5
1
7
2
6
3.60E-03
10
1.06E-06
1.19
3477.75143
0
5
4
1
4
3
2
1.10E-02
3
3.0
1.06
3492.4212
−27
7
3
4
6
2
5
1.96E-03
10
−2.8
0.98
3497.8150
−21
6
4
3
5
3
2
5.22E-03
3
−0.6
0.98
3503.3710
6
6
4
2
5
3
3
1.90E-03
10
6.3
1.05
3508.7420
−69
6
6
1
6
5
2
6.30E-04
2
1.37E-04
3513.3892
−69
7
2
5
6
1
6
7.50E-04
6
6.27E-04
3515.952
−46
7
4
4
6
3
3
7.46E-04
10
−3.2
0.93
3531.218
248
6
3
4
5
0
5
7.34E-04
10
8.5
0.99
3545.8357
−34
8
6
2
9
3
7
7.29E-04
10
7.68E-10
1.05
3551.954
−161
6
6
1
7
3
4
2.40E-03
10
3.90E-09
0.94
3553.0616
0
5
5
1
4
4
0
2.57E-03
4
2.04E-03
0.98
3553.0904
−18
5
5
0
4
4
1
7.60E-03
5
6.12E-03
0.96
3577.6376
−32
6
5
2
5
4
1
4.00E-03
2
2.92E-03
0.99
3577.782
−347
6
5
1
5
4
2
1.15E-03
6
9.75E-04
0.97
3578.0600
−14
6
6
0
7
3
5
3.09E-03
3
1.86E-13
1.11
3602.5300
0
7
5
2
6
4
3
1.70E-03
5
1.26E-03
0.91
3623.2740
0
8
5
4
7
4
3
6.51E-04
10
4.82E-04
0.84
3655.1960
−33
6
6
1
5
5
0
2.03E-03
3
3.77E-04
0.86
3679.706
584
7
6
1
6
5
2
6.20E-04
2
1.29E-04
0.90
3710.7410
−21
8
6
2
8
3
5
8.10E-04
4
2.31E-08
1.05
3732.6840
−10
6
6
0
6
3
3
3.00E-02
3
6.85E-08
1.03
3860.89204
6
7
6
1
7
1
6
2.70E-03
4
6.87E-07
1.21
3890.4918
59
6
6
0
5
3
3
4.68E-03
5
1.82E-06
1.13
3916.7057
−5
7
6
1
6
3
4
2.71E-01
3
1.17E-05
1.16
3938.91423
0
10
5
5
9
2
8
1.62E-02
3
6.88E-09
1.25
3944.7885
90
8
6
2
7
3
5
2.08E-03
5
4.72E-06
1.39
1 atm = 760 Torr.
o − c, Observed minus computed line positions (cm−1 × 105). Computed values are derived from the energy levels given in Table 2 and the ground-state levels given in Ref. 2. %s, Estimated uncertainties in the measured line strengths given in percent. (o − c)%, Percent difference between the observed and the computed line strengths or the value of the computed strength if the difference between the observed and the computed values is ≈±14% or larger in magnitude. R, Ratio of the observed line strength derived in this study to the computed value given in Refs. 15, 18, and 19. An asterisk denotes a doubled absorption with the quantum assignment given for the stronger transition. The strength given represents the sum of the strengths of the two comparable transitions.
Table 8
Line Positions (cm−1) and Strengths (cm−2/atma at 296 K) Observed in the (020)–(000) Band of H218Ob
Observed Position
o − c
Upper
Lower
Observed Strength
%s
(o − c)%
R
J
Ka
Kc
J
Ka
Kc
2892.7945
−62
8
4
5
9
5
4
1.65E-04
10
−9.4
1.09
2900.47948
0
11
0
11
12
1
12
2.76E-04
2
−5.2
0.99
2900.5349
124
11
1
11
12
0
12
9.26E-05
4
−4.6
2908.8325
64
8
3
5
9
4
6
7.91E-05
10
−9.0
2919.5619
46
7
3
4
8
4
5
7.20E-04
3
3.1
1.19
2921.7095
11
10
0
10
11
1
11
2.60E-04
4
1.2
1.07
2921.8179
14
10
1
10
11
0
11
7.73E-04
2
0.2
1.06
2922.87729
25
4
1
4
5
2
3
1.67E-03
4
−6.3
1.14
2924.8314
28
5
2
4
6
3
3
8.00E-04
3
−5.3
1.14
2935.1557
−3
6
3
3
7
4
4
5.55E-04
3
−4.3
1.11
2942.52322
51
9
0
9
10
1
10
1.85E-03
2
−0.7
1.06
2942.7410
48
9
1
9
10
0
10
6.30E-04
3
1.3
1.09
2944.42395
−23
6
4
3
7
5
2
1.31E-03
2
−3.5
1.11
2945.2189
−35
6
4
2
7
5
3
4.40E-04
4
−3.5
1.11
2945.7920
3
7
5
2
8
6
3
3.85E-04
5
2.4
1.20
2946.48584
−8
10
2
9
11
1
10
2.70E-04
3
5.5
1.13
2946.6749
14
8
2
6
9
3
7
1.70E-04
7
2.9
1.13
2950.3492
−16
5
3
3
6
4
2
1.30E-03
5
3.8
1.22
2950.92868
3
7
2
5
8
3
6
1.14E-03
3
3.3
1.16
2954.91560
2
5
3
2
6
4
3
3.90E-03
3
−0.8
1.15
2955.0047
−5
10
1
10
10
2
9
1.50E-04
10
7.3
1.21
2957.3428
−32
6
2
4
7
3
5
7.50E-04
3
−3.8
1.10
2957.99467
0
9
1
8
10
2
9
5.95E-04
3
−4.9
1.02
2961.5434
1
4
2
3
5
3
2
6.80E-03
3
0.4
1.21
2962.8610
27
8
0
8
9
1
9
1.40E-03
2
2.7
1.13
2963.30698
15
8
1
8
9
0
9
4.18E-03
2
2.0
1.12
2967.08095
−11
5
2
3
6
3
4
4.70E-03
2
0.0
1.17
2969.0414
−15
5
4
2
6
5
1
1.03E-03
2
0.6
1.16
2969.20320
−5
5
4
1
6
5
2
3.10E-03
2
0.7
1.16
2969.9217
10
6
5
2
7
6
1
9.00E-04
5
−3.1
1.11
2969.935
−74
6
5
1
7
6
2
3.00E-04
5
−3.1
1.11
2971.01988
0
8
1
7
9
2
8
4.76E-04
10
1.5
1.10
2972.1395
26
3
1
3
4
2
2
1.76E-03
3
−0.2
1.25
2976.2824
−9
4
3
2
5
4
1
7.85E-03
2
−0.3
1.17
2976.6182
12
9
1
9
9
2
8
1.41E-04
3
6.9
2976.78392
0
7
6
1
8
7
2
2.54E-04
10
8.0
1.24
2977.4403
11
4
3
1
5
4
2
2.62E-03
2
−1.4
1.16
2977.5618
6
9
0
9
9
1
8
4.12E-04
3
2.3
1.19
2980.3742
50
8
2
7
9
1
8
1.55E-03
7
5.8
1.14
2980.9013
−4
4
2
2
5
3
3
2.95E-03
4
−0.3
1.19
2982.4110
−4
7
1
6
8
2
7
2.87E-03
3
1.2
1.11
2982.63603
0
7
0
7
8
1
8
8.10E-03
2
−0.0
1.13
2983.55350
−6
7
1
7
8
0
8
2.74E-03
4
1.0
1.14
2992.21910
1
6
1
5
7
2
6
1.70E-03
5
−0.7
1.12
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2997.65047
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1.20
2998.7045
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1.07
2999.00447
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7
2.75E-03
4
1.8
1.20
3282.45531
6
4
3
2
4
2
3
1.19E-02
3
1.1
1.19
3284.6486
−13
6
1
5
5
2
4
2.65E-03
4
−0.3
1.17
3285.16477
11
7
3
4
6
4
3
3.40E-04
3
−2.8
1.09
3288.3688
11
5
3
3
5
2
4
3.00E-03
5
4.1
1.21
3294.38920
−12
4
2
3
3
1
2
2.31E-02
3
0.1
1.25
3295.16780
0
8
0
8
7
1
7
3.60E-03
2
2.1
1.21
3295.78664
−18
8
1
8
7
0
7
1.08E-02
2
1.6
1.21
3297.33351
−13
6
3
4
6
2
5
5.10E-03
2
1.1
1.15
3299.30740
−2
3
2
1
2
1
2
1.96E-02
3
−1.9
1.25
3304.98927
−17
7
6
2
8
5
3
6.90E-04
3
1.55E-05
1.10
3305.0930
−53
7
6
1
8
5
4
1.90E-04
4
4.69E-05
0.94
3306.0166
−45
8
1
7
8
0
8
3.90E-04
3
−2.0
1.11
3307.2522
32
7
2
5
6
3
4
1.30E-03
4
−2.8
1.08
3308.6380
−1
5
2
4
4
1
3
5.77E-03
3
3.0
1.25
3309.5240
−15
7
3
5
7
2
6
8.44E-04
10
2.3
1.14
3311.32580
−28
9
0
9
8
1
8
5.59E-03
3
1.2
1.17
3311.61515
−10
9
1
9
8
0
8
1.88E-03
5
1.9
1.18
3312.1610
0
9
4
5
9
3
6
2.55E-04
10
3.7
1.16
3313.87437
3
7
1
6
6
2
5
6.00E-03
2
4.2
1.18
3314.13780
−24
8
2
7
8
1
8
1.27E-03
3
5.0
1.18
3319.3890
20
8
4
4
8
3
5
1.91E-04
10
−11.0
1.02
3322.34785
−2
6
2
5
5
1
4
1.16E-02
3
2.4
1.20
3324.7576
−39
8
3
6
8
2
7
1.10E-03
4
4.0
1.14
3326.8762
−11
10
0
10
9
1
9
9.33E-04
4
6.9
1.21
3327.01431
0
10
1
10
9
0
9
2.66E-03
4
1.7
1.15
3328.6649
35
6
6
1
7
5
2
4.20E-03
4
4.02E-05
1.11
3328.9045
−11
7
4
3
7
3
4
1.42E-03
4
−1.3
1.09
3330.0037
−53
9
1
8
9
0
9
5.10E-04
10
4.8
1.15
3334.6027
−80
9
2
8
9
1
9
1.80E-04
10
9.4
1.19
3337.01940
0
7
2
6
6
1
5
2.32E-03
4
−0.0
1.14
3337.59936
−9
6
4
2
6
3
3
9.20E-04
3
−0.4
1.09
3339.92960
5
4
2
2
3
1
3
3.30E-03
4
−2.8
1.20
3340.33205
48
8
1
7
7
2
6
1.19E-03
3
2.6
1.13
3341.8821
−23
11
0 1
11
10
1 1
10
1.11E-03
3
−1.6
1.10
3341.94870
0
11
1 1
11
10
0
10
3.59E-04
2
−4.6
1.06
3342.5628
27
9
3
7
9
2
8
1.33E-04
10
−1.0
1.08
3343.55076
−1
5
4
1
5
3
2
4.40E-03
3
2.4
1.12
3345.0989
14
8
2
6
7
3
5
2.86E-04
4
−3.5
1.06
3346.5080
−10
4
4
0
4
3
1
1.47E-03
3
−1.6
1.09
3347.6440
7
3
3
0
3
0
3
3.70E-04
3
3.5
1.08
3347.90460
−3
4
4
1
4
3
2
4.50E-03
3
−0.4
1.10
3349.06255
0
3
3
1
2
2
0
1.07E-02
2
0.2
1.20
3350.2449
9
6
4
3
6
3
4
2.95E-03
3
0.9
1.09
3350.50475
−5
3
3
0
2
2
1
3.24E-02
2
0.9
1.20
3353.44260
15
8
2
7
7
1
6
3.85E-03
3
0.1
1.11
3355.2262
−19
10
2
9
10
1
10
2.03E-04
10
9.4
1.17
3356.377
0
12
0
12
11
1
11
1.50E-04
10
0.6
1.11
3356.4110
0
12
1
12
11
0
11
4.40E-04
3
−1.6
1.09
3359.7014
−7
8
4
5
8
3
6
6.70E-04
3
−3.8
1.05
3360.7510
60
4
3
1
4
0
4
2.34E-04
2
−1.7
1.00
3362.300
0
10
3
8
10
2
9
1.44E-04
10
2.5
1.15
3370.2761
−5
4
3
2
3
2
1
2.05E-02
2
0.6
1.18
*3370.3922
6
13
0
13
12
1
12
2.03E-04
10
−7.4
1.03
3371.4027
47
9
2
8
8
1
7
6.36E-04
3
−0.3
1.08
3374.8920
0
12
3
10
13
0
13
3.50E-04
10
2.56E-06
1.30
3377.22850
0
4
3
1
3
2
2
6.71E-03
2
−0.7
1.16
3381.6706
−10
9
2
7
8
3
6
4.90E:04
3
−4.9
1.04
3381.90185
1
5
3
2
5
0
5
7.00E-04
10
8.8
1.07
3386.56784
0
10
1
9
9
2
8
3.20E-04
3
12.4
1.23
3388.0775
8
5
3
3
4
2
2
3.99E-03
2
1.7
1.17
3388.63520
7
5
2
3
4
1
4
4.25E-03
3
−2.5
1.15
3390.26550
8
10
2
9
9
1
8
8.55E-04
2
−1.8
1.06
3402.6260
9
6
3
4
5
2
3
6.40E-03
3
1.0
1.13
3407.3284
−1
5
3
2
4
2
3
1.11E-02
3
0.2
1.14
3407.5685
0
11
1
10
10
2
9
3.50E-04
10
−3.3
1.07
3414.88455
43
7
3
5
6
2
4
1.02E-03
5
−5.8
1.03
3419.522
180
7
5
2
7
4
3
8.00E-04
4
2.2
1.02
3421.9175
−23
6
5
1
6
4
2
3.95E-04
2
−11.2
1.01
3422.6564
15
5
5
0
5
4
1
1.45E-03
3
−4.6
1.03
3422.9039
51
5
5
1
5
4
2
5.05E-04
3
−0.4
1.07
3423.06355
0
6
5
2
6
4
3
1.25E-03
3
−6.7
1.01
3423.7344
0
8
5
4
8
4
5
3.65E-04
10
−7.0
1.10
3426.21928
0
8
3
6
7
2
5
1.55E-03
2
−2.5
1.05
3442.88345
1
6
3
3
5
2
4
1.66E-03
2
−2.1
1.06
3444.7383
−46
4
3
2
3
0
3
8.00E-04
3
4.2
1.05
3444.8893
14
4
4
1
3
3
0
1.92E-02
6
2.1
1.11
3445.11605
1
4
4
0
3
3
1
6.30E-03
3
0.4
1.10
3450.918
−109
5
4
1
5
1
4
1.78E-04
10
−3.2
0.83
3466.760
18
7
4
3
7
1
6
2.05E-04
4
3.1
0.95
3468.45360
−6
5
4
2
4
3
1
3.50E-03
2
−0.1
1.06
3469.98793
−6
5
4
1
4
3
2
1.08E-02
2
2.1
1.08
3481.3026
−27
5
3
3
4
0
4
3.51E-04
10
17.1
1.15
3489.89860
0
6
4
3
5
3
2
5.20E-03
2
−0.9
1.02
3495.6129
−38
6
4
2
5
3
3
1.83E-03
3
2.6
1.05
3499.7910
−45
6
6
1
6
5
2
3.85E-04
3
4.63E-04
1.34
3501.2051
−20
7
6
2
7
5
3
1.20E-03
7
1.25E-04
0.96
3501.3183
10
8
6
3
8
5
4
6.88E-04
3
2.10E-04
0.94
3504.8670
5
7
6
2
8
3
5
1.21E-03
3
6.04E-07
0.99
3507.2885
22
7
2
5
6
1
6
5.80E-04
3
−5.3
0.95
3507.8740
−40
7
4
4
6
3
3
7.70E-04
5
−1.9
1.00
3521.85784
5
8
4
5
7
3
4
8.88E-04
3
−9.4
0.94
3523.0712
−32
7
4
3
6
3
4
2.36E-03
5
−2.5
0.98
3536.7125
−88
8
3
5
7
2
6
2.10E-04
4
−3.9
0.98
3544.7746
−39
5
5
1
4
4
0
2.46E-03
8
−7.7
0.95
3549.7570
68
7
6
1
8
3
6
1.00E-03
6
1.82E-06
1.16
3569.3035
−12
6
5
2
5
4
1
4.10E-03
10
3.5
1.04
3618.8435
0
8
5
3
7
4
4
2.10E-04
10
2.61E-04
0.84
3622.894
−34
8
3
6
7
0
7
1.68E-04
10
0.7
0.83
3644.2276
0
9
5
4
8
4
5
2.03E-04
10
3.20E-04
0.74
3646.1839
−81
6
6
1
5
5
0
2.20E-03
5
2.88E-02
0.89
3672.0810
3
7
6
2
6
5
1
1.56E-04
4
4.40E-04
0.91
3696.4840
15
8
6
3
7
5
2
3.85E-04
10
5.76E-04
1.12
3874.13905
8
6
6
1
5
3
2
6.88E-02
2
4.23E-06
1.25
3879.4573
42
6
6
0
5
3
3
4.65E-04
7
1.43E-06
1.28
1 atm = 760 Torr.
o − c, Observed minus computed line positions (cm−1 × 105). Computed values are derived from the energy levels given in Table 2 and the ground-state levels given in Ref. 2. %s, Estimated uncertainties in the measured line strengths given in percent. (o − c)%, Percent difference between the observed and the computed line strengths or the value of the computed strength if the difference between the observed and the computed values is ≈±14% or larger in magnitude. R, Ratio of the observed line strength derived in this study to the computed value given in Refs. 16, 18, and 19. An asterisk denotes a doubled absorption with the quantum assignment given for the stronger transition. The strength given represents the sum of the strengths of the two comparable transitions.
Table 9
Observeda and Computed Frequencies (cm−1) of Transitions in the (000)–(000), (010)–(010) and (020)–(020) Bands of H216Ob
From Ref. 20.
The computed values for the (000)–(000) and (010)–(010) bands were derived from rotational energy levels given in Ref. 1, and those for the (020)–(020) band were calculated from levels given in Table 2 of the present study.
un, Uncertainty of computed frequencies derived from estimated uncertainties given in Ref. 1 and this study; values × 105.
Δ, Observed minus computed frequencies × 105.
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