Abstract

We analyze the effects of the coordinate dependence of the transition dipole (non-Condon dipole moment) on impulsive pump–probe spectroscopy at finite temperatures, using expressions for the response functions derived by the path-integral approach. We calculate the difference probe absorption spectrum and show that the non-Condon dipole shifts the absorption to the blue and that the shift increases with temperature.

© 1993 Optical Society of America

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