Abstract

High-resolution spectra of H216O were recorded with a Fourier-transform spectrometer covering transitions in the (100)–(010), (001)–(010), (100)–(000), and (001)–(000) bands. The measured line frequencies were used to determine high-accuracy values of rotational energy levels in the (100) and (001) vibrational states. Measurements of the line strengths were fitted to a model in which 19 transition moment parameters were determined for the B-type bands and 8 parameters for the A-type bands. The fitting technique did not consider interactions between the (020), (100), and (001) vibrational states. The experimental results provide a more accurate representation of the line positions and strengths than those available at present for these bands.

© 1993 Optical Society of America

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  1. R. A. Toth, “2ν2−ν2and 2ν2bands of H216O, H217O, and H218O: line positions and strengths,” J. Opt. Soc. Am. B 10, 1526–1544 (1993).
    [CrossRef]
  2. D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).
  3. L. A. Pugh, K. Narahari Rao, “Spectrum of water vapor in the 1.9 and 2.7 μ regions,” J. Mol. Spectrosc. 47, 403–408 (1973).
    [CrossRef]
  4. L. A. Pugh, “A detailed study of the near infrared spectrum of water vapor,” Ph.D. dissertation (Ohio State University, Columbus, Ohio, 1972), microfilm 72-21,005, University Microfilms, Ann Arbor, Mich.
  5. C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
    [CrossRef]
  6. J.-M. Flaud, C. Camy-Peyret, “The 2ν2, ν1, and ν3bands of H216O rotational study of the (000) and (020) states,” Mol. Phys. 4, 811–823 (1973).
    [CrossRef]
  7. J.-M. Flaud, C. Camy-Peyret, “The interacting states (020), (100), and (001) of H216O,” J. Mol. Spectrosc. 51, 142–150 (1974).
    [CrossRef]
  8. R. A. Toth, “Strengths and air-broadened widths of H2O lines in the 2950–3400 cm−1region,” J. Quantum. Spectrosc. Radiat. Transfer 13, 1127–1142 (1973).
    [CrossRef]
  9. J.-M. Flaud, C. Camy-Peyret, “Vibration–rotation intensities in H2O-type molecules application to the 2ν2, ν1and ν3bands of H216O,” J. Mol. Spectrosc. 55, 278–310 (1975).
    [CrossRef]
  10. J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
    [CrossRef]
  11. P. E. Fraley, K. Narahari Rao, “High resolution spectra of water vapor ν1and ν3bands of H216O,” J. Mol. Spectrosc. 29, 348–364 (1969).
    [CrossRef]
  12. J.-M. Flaud, C. Camy-Peyret, J. P. Maillard, “Higher rovibrational levels of H2O deduced from high resolution oxygen-hydrogen flame spectra between 2800–6200 cm−1,” Mol. Phys. 32, 499–521 (1976).
    [CrossRef]
  13. J.-M. Flaud, C. Camy-Peyret, R. A. Toth, Water Vapour Line Parameters from Microwave to Medium Infrared (Pergamon, London, 1981).
  14. L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
    [CrossRef]
  15. J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
    [CrossRef]
  16. R. A. Toth, “ν2 band of H216O: line strengths and transition frequencies,” J. Opt. Soc. Am. B 8, 2236–2255 (1991).
    [CrossRef]
  17. R. A. Toth, “Line-frequency measurements and analysis of N2O between 900 and 4700 cm−1,” Appl. Opt. 30, 5289–5315 (1991).
    [CrossRef] [PubMed]
  18. R. A. Toth, “Line strengths (900–3600 cm−1), self-broadened linewidths and frequency shifts (1800–2630 cm−1) of N2O,” Appl. Opt. (to be published).
  19. R. A. Toth, “Transition frequencies and absolute strengths of H217O and H218O in the 6.2-μ m region,” J. Opt. Soc. Am. B 9, 462–482 (1992).
    [CrossRef]
  20. R. A. Toth, “HD 16O, HD 18O, and HD 17O transition frequencies and strengths in the ν2bands,” J. Mol. Spectrosc. (to be published).
  21. R. A. Toth, “D216O and D218O transition frequencies and strengths in the ν2bands,” J. Mol. Spectrosc. (to be published).

1993 (2)

R. A. Toth, “2ν2−ν2and 2ν2bands of H216O, H217O, and H218O: line positions and strengths,” J. Opt. Soc. Am. B 10, 1526–1544 (1993).
[CrossRef]

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

1992 (1)

1991 (3)

1977 (1)

J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
[CrossRef]

1976 (1)

J.-M. Flaud, C. Camy-Peyret, J. P. Maillard, “Higher rovibrational levels of H2O deduced from high resolution oxygen-hydrogen flame spectra between 2800–6200 cm−1,” Mol. Phys. 32, 499–521 (1976).
[CrossRef]

1975 (1)

J.-M. Flaud, C. Camy-Peyret, “Vibration–rotation intensities in H2O-type molecules application to the 2ν2, ν1and ν3bands of H216O,” J. Mol. Spectrosc. 55, 278–310 (1975).
[CrossRef]

1974 (1)

J.-M. Flaud, C. Camy-Peyret, “The interacting states (020), (100), and (001) of H216O,” J. Mol. Spectrosc. 51, 142–150 (1974).
[CrossRef]

1973 (4)

R. A. Toth, “Strengths and air-broadened widths of H2O lines in the 2950–3400 cm−1region,” J. Quantum. Spectrosc. Radiat. Transfer 13, 1127–1142 (1973).
[CrossRef]

L. A. Pugh, K. Narahari Rao, “Spectrum of water vapor in the 1.9 and 2.7 μ regions,” J. Mol. Spectrosc. 47, 403–408 (1973).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The 2ν2, ν1, and ν3bands of H216O rotational study of the (000) and (020) states,” Mol. Phys. 4, 811–823 (1973).
[CrossRef]

1969 (1)

P. E. Fraley, K. Narahari Rao, “High resolution spectra of water vapor ν1and ν3bands of H216O,” J. Mol. Spectrosc. 29, 348–364 (1969).
[CrossRef]

1964 (1)

D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).

Amiot, C.

C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
[CrossRef]

Anderson, T.

J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
[CrossRef]

Benedict, W. S.

D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).

Benner, D. C.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Brown, L. R.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Calfee, R. F.

D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).

Camy-Peyret, C.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, J. P. Maillard, “Higher rovibrational levels of H2O deduced from high resolution oxygen-hydrogen flame spectra between 2800–6200 cm−1,” Mol. Phys. 32, 499–521 (1976).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “Vibration–rotation intensities in H2O-type molecules application to the 2ν2, ν1and ν3bands of H216O,” J. Mol. Spectrosc. 55, 278–310 (1975).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The interacting states (020), (100), and (001) of H216O,” J. Mol. Spectrosc. 51, 142–150 (1974).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The 2ν2, ν1, and ν3bands of H216O rotational study of the (000) and (020) states,” Mol. Phys. 4, 811–823 (1973).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, R. A. Toth, Water Vapour Line Parameters from Microwave to Medium Infrared (Pergamon, London, 1981).

De Lucia, F. C.

J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
[CrossRef]

Devi, V. M.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Flaud, J.-M.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, J. P. Maillard, “Higher rovibrational levels of H2O deduced from high resolution oxygen-hydrogen flame spectra between 2800–6200 cm−1,” Mol. Phys. 32, 499–521 (1976).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “Vibration–rotation intensities in H2O-type molecules application to the 2ν2, ν1and ν3bands of H216O,” J. Mol. Spectrosc. 55, 278–310 (1975).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The interacting states (020), (100), and (001) of H216O,” J. Mol. Spectrosc. 51, 142–150 (1974).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The 2ν2, ν1, and ν3bands of H216O rotational study of the (000) and (020) states,” Mol. Phys. 4, 811–823 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, R. A. Toth, Water Vapour Line Parameters from Microwave to Medium Infrared (Pergamon, London, 1981).

Fraley, P. E.

P. E. Fraley, K. Narahari Rao, “High resolution spectra of water vapor ν1and ν3bands of H216O,” J. Mol. Spectrosc. 29, 348–364 (1969).
[CrossRef]

Gamache, R. R.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Gates, D. M.

D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).

Goldman, A.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Guelachvili, G.

J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
[CrossRef]

C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
[CrossRef]

Hansen, D. W.

D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).

Helminger, P.

J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
[CrossRef]

Herbst, E.

J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
[CrossRef]

Maillard, J. P.

J.-M. Flaud, C. Camy-Peyret, J. P. Maillard, “Higher rovibrational levels of H2O deduced from high resolution oxygen-hydrogen flame spectra between 2800–6200 cm−1,” Mol. Phys. 32, 499–521 (1976).
[CrossRef]

Mandin, J.-Y.

J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
[CrossRef]

Massie, S. T.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Narahari Rao, K.

L. A. Pugh, K. Narahari Rao, “Spectrum of water vapor in the 1.9 and 2.7 μ regions,” J. Mol. Spectrosc. 47, 403–408 (1973).
[CrossRef]

P. E. Fraley, K. Narahari Rao, “High resolution spectra of water vapor ν1and ν3bands of H216O,” J. Mol. Spectrosc. 29, 348–364 (1969).
[CrossRef]

Pearson, J. C.

J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
[CrossRef]

Perrin, A.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Pugh, L. A.

L. A. Pugh, K. Narahari Rao, “Spectrum of water vapor in the 1.9 and 2.7 μ regions,” J. Mol. Spectrosc. 47, 403–408 (1973).
[CrossRef]

L. A. Pugh, “A detailed study of the near infrared spectrum of water vapor,” Ph.D. dissertation (Ohio State University, Columbus, Ohio, 1972), microfilm 72-21,005, University Microfilms, Ann Arbor, Mich.

Rinsland, C. P.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Rothman, L. S.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Smith, M. A. H.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Tipping, R. H.

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

Toth, R. A.

R. A. Toth, “2ν2−ν2and 2ν2bands of H216O, H217O, and H218O: line positions and strengths,” J. Opt. Soc. Am. B 10, 1526–1544 (1993).
[CrossRef]

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

R. A. Toth, “Transition frequencies and absolute strengths of H217O and H218O in the 6.2-μ m region,” J. Opt. Soc. Am. B 9, 462–482 (1992).
[CrossRef]

R. A. Toth, “ν2 band of H216O: line strengths and transition frequencies,” J. Opt. Soc. Am. B 8, 2236–2255 (1991).
[CrossRef]

R. A. Toth, “Line-frequency measurements and analysis of N2O between 900 and 4700 cm−1,” Appl. Opt. 30, 5289–5315 (1991).
[CrossRef] [PubMed]

R. A. Toth, “Strengths and air-broadened widths of H2O lines in the 2950–3400 cm−1region,” J. Quantum. Spectrosc. Radiat. Transfer 13, 1127–1142 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, R. A. Toth, Water Vapour Line Parameters from Microwave to Medium Infrared (Pergamon, London, 1981).

R. A. Toth, “Line strengths (900–3600 cm−1), self-broadened linewidths and frequency shifts (1800–2630 cm−1) of N2O,” Appl. Opt. (to be published).

R. A. Toth, “HD 16O, HD 18O, and HD 17O transition frequencies and strengths in the ν2bands,” J. Mol. Spectrosc. (to be published).

R. A. Toth, “D216O and D218O transition frequencies and strengths in the ν2bands,” J. Mol. Spectrosc. (to be published).

Appl. Opt. (1)

Astrophys. J. (1)

J. C. Pearson, T. Anderson, E. Herbst, F. C. De Lucia, P. Helminger, “Millimeter- and submillimeter-wave spectrum of highly excited states of water,” Astrophys. J. 379, L41–L43 (1991).
[CrossRef]

J. Mol. Spectrosc. (4)

J.-M. Flaud, C. Camy-Peyret, “Vibration–rotation intensities in H2O-type molecules application to the 2ν2, ν1and ν3bands of H216O,” J. Mol. Spectrosc. 55, 278–310 (1975).
[CrossRef]

P. E. Fraley, K. Narahari Rao, “High resolution spectra of water vapor ν1and ν3bands of H216O,” J. Mol. Spectrosc. 29, 348–364 (1969).
[CrossRef]

L. A. Pugh, K. Narahari Rao, “Spectrum of water vapor in the 1.9 and 2.7 μ regions,” J. Mol. Spectrosc. 47, 403–408 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The interacting states (020), (100), and (001) of H216O,” J. Mol. Spectrosc. 51, 142–150 (1974).
[CrossRef]

J. Opt. Soc. Am. B (3)

J. Quantum Spectrosc. Rad. Transfer (1)

L. S. Rothman, R. R. Gamache, R. H. Tipping, C. P. Rinsland, M. A. H. Smith, D. C. Benner, V. M. Devi, J.-M. Flaud, C. Camy-Peyret, A. Perrin, A. Goldman, S. T. Massie, L. R. Brown, R. A. Toth, “The HITRAN molecular database: editions of 1991 and 1992,” J. Quantum Spectrosc. Rad. Transfer 48, 469–507 (1993).
[CrossRef]

J. Quantum. Spectrosc. Radiat. Transfer (1)

R. A. Toth, “Strengths and air-broadened widths of H2O lines in the 2950–3400 cm−1region,” J. Quantum. Spectrosc. Radiat. Transfer 13, 1127–1142 (1973).
[CrossRef]

Mol. Phys. (4)

C. Camy-Peyret, J.-M. Flaud, G. Guelachvili, C. Amiot, “High resolution Fourier transform spectrum of water between 2930 and 4255 cm−1,” Mol. Phys. 26, 825–855 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, “The 2ν2, ν1, and ν3bands of H216O rotational study of the (000) and (020) states,” Mol. Phys. 4, 811–823 (1973).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, J. P. Maillard, “Higher rovibrational levels of H2O deduced from high resolution oxygen-hydrogen flame spectra between 2800–6200 cm−1,” Mol. Phys. 32, 499–521 (1976).
[CrossRef]

J.-M. Flaud, C. Camy-Peyret, J.-Y. Mandin, G. Guelachvili, “H216O hot bands in the 6.3 μ m region,” Mol. Phys. 2, 413–426 (1977).
[CrossRef]

Natl. Bur. Stand. Monogr. (1)

D. M. Gates, R. F. Calfee, D. W. Hansen, W. S. Benedict, “Line parameters and computed spectra for water vapor bands at 2.7 μ,” Natl. Bur. Stand. Monogr. 71 (August3, 1964).

Other (5)

L. A. Pugh, “A detailed study of the near infrared spectrum of water vapor,” Ph.D. dissertation (Ohio State University, Columbus, Ohio, 1972), microfilm 72-21,005, University Microfilms, Ann Arbor, Mich.

J.-M. Flaud, C. Camy-Peyret, R. A. Toth, Water Vapour Line Parameters from Microwave to Medium Infrared (Pergamon, London, 1981).

R. A. Toth, “Line strengths (900–3600 cm−1), self-broadened linewidths and frequency shifts (1800–2630 cm−1) of N2O,” Appl. Opt. (to be published).

R. A. Toth, “HD 16O, HD 18O, and HD 17O transition frequencies and strengths in the ν2bands,” J. Mol. Spectrosc. (to be published).

R. A. Toth, “D216O and D218O transition frequencies and strengths in the ν2bands,” J. Mol. Spectrosc. (to be published).

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Tables (9)

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Table 1 Experimental Conditions and Extent of Measurements

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Table 2 Rotation Energy Levels (cm−1) of the (001) and (100) Vibrational States of H216O a

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Table 3 Matrix Elements Used in the Expansion of the Dipole Moment for B-Type Transitions of Water Vapora

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Table 4 Matrix Elements Used in the Expansion of the Dipole Moment for A-Type Transitions of Water Vapora

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Table 5 Dipole Moment Expansion Coefficients Derived from Least-Squares Fits of H216O Measured Line Strengths in the (100)–(010), (100)–(000), (001)–(010), and (001)–(000) Bandsa

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Table 6 Line Positions (cm−1) and Strengths (cm−2/atm at 296 K) Observed in the (100)–(010) and (001)–(010) Bands of H216Oa

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Table 7 Line Positions (cm−1) and Strengths (cm−2/atm at 296 K) Observed in the (100)–(000) Band of H216Oa

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Table 8 Line Positions (cm−1) and Strengths (cm−2/atm at 296 K) Observed in the (001)–(000) Band of H216Oa

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Table 9 Observed and Computed Frequencies of Transitions in the (100)–(000), and (001)–(001) Bands of H216Oa

Equations (6)

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S = C ( ν / Q ) ( g / T ) [ 1 exp ( ν / k T ) ] × exp [ E ( L ) / k T ] | R ( L , U ) | 2 ,
C = 8 π 3 / 3 h c , Q = Q V Q R , E ( L ) = E V ( L ) + E R ( L ) ,
R ( L , U ) = j u ( j ) x ( j ) , x ( j ) = V , J , K s , K c | A ( j ) | V , J , K a , K c ,
AS ( V , J , K a , K c ) = Ψ υ C ( J , K a , K c | J , K , γ ) s ( J , K , γ ) ,
C 32 = h 32 / ( E 3 E 2 ) , C 23 = h 32 / ( E 2 E 3 ) , C 22 = C 33 = ( 1 C 23 2 ) 1 / 2 , μ 2 0 ( j ) = C 22 μ 2 ( j ) + C 23 μ 3 ( j ) , μ 3 0 ( j ) = C 33 μ 3 ( j ) + C 32 μ 2 ( j ) ,
un = ( un 1 2 + un 2 2 ) 1 / 2 ,

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