Abstract

Multi-configuration Hartree-Fock wave functions have been obtained for many atoms of the Mg sequence for 3p 2 1D, 3s 3d 1,3D, 3p 3d 1,3F, and 3s 4f 1,3F states. Theoretical ionization energies are reported. Oscillator strengths for allowed D -F transitions are presented and compared with experiment, when available. Agreement is better for the 3s 3d 3D -3p 3d 3F sequence than for 3s 3d 3D -3s 4f 3F. Smoother trends are observed when f values for the 1D lowest-1F lowest transition, for example, are plotted than for the 3s 3d 1D -3s 4f 1F transition.

© 1979 Optical Society of America

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