Ground-state term intervals in multiply ionized zinc (Zn v, Zn vi) and gallium (Ga v, Ga vi, Ga vii)

K. A. Dick

doi:10.1364/JOSA.64.000702

Journal of the Optical Society of America
Vol. 64,
Issue 5,
pp. 702-705
(1974)
•https://doi.org/10.1364/JOSA.64.000702

Ground-state term intervals in multiply ionized zinc (Zn v, Zn vi) and gallium (Ga v, Ga vi, Ga vii)

K. A. Dick

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K. A. Dick, "Ground-state term intervals in multiply ionized zinc (Zn v, Zn vi) and gallium (Ga v, Ga vi, Ga vii)," J. Opt. Soc. Am. 64, 702-705 (1974)

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Abstract

Preliminary analyses of zinc and gallium spectra have yielded ground-state term intervals for Zn v, Zn vi, Ga v, Ga vi, and Ga vii. These values are presented, together with a discussion of a discrepancy between previously published analyses of Ga v.

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	Ni ii (Ref. 7)	Cu iii (Ref. 7)	Zn iv (Ref. 8)	Extrapolations		Observations
	Ni ii (Ref. 7)	Cu iii (Ref. 7)	Zn iv (Ref. 8)	Linear	Quadratic	Present work	Joshi et al.
Γ (cm⁻¹)	349.1	503.1	692.5	881.9	917.3	910.5	627.6
${{}^{4}D}_{3 \frac{1}{2}} °$	3.38	3.41	3.41	3.41	3.38	3.37	4.02
${{}^{4}D}_{2 \frac{1}{2}} °$	2.57	2.56	2.55	2.54	2.54	2.58	2.83
${{}^{4}D}_{1 \frac{1}{2}} °$	1.55	1.54	1.53	1.52	1.52	1.55	0.65
⁴D_1/2°

Configuration	Designation	Level (cm⁻¹)
3d⁹	$a {{}^{2}D}_{2 \frac{1}{2}}$	0
	${{}^{2}D}_{1 \frac{1}{2}}$	3582
3d⁸(³F)4p	$z {{}^{4}D}_{3 \frac{1}{2}} °$	297 078
	${{}^{4}D}_{2 \frac{1}{2}} °$	300 143
	${{}^{4}D}_{1 \frac{1}{2}} °$	302 496
3d⁸(³F)4p	$z {{}^{4}G}_{3 \frac{1}{2}} °$	(302 897)
	$z {{}^{4}D}_{\frac{1}{2}} °$	303 908
	$z {{}^{4}G}_{2 \frac{1}{2}} °$	304 454
3d⁸(³F)4p	$z {{}^{4}F}_{3 \frac{1}{2}} °$	306 619
	${{}^{4}F}_{2 \frac{1}{2}} °$	307 737
	${{}^{4}F}_{1 \frac{1}{2}} °$	307 855
3d⁸(³F)4p	$z {{}^{2}D}_{2 \frac{1}{2}} °$	309 610
3d⁸(³F)4p	$z {{}^{2}G}_{3 \frac{1}{2}} °$	309 672
3d⁸(³F)4p	$z {{}^{2}F}_{3 \frac{1}{2}} °$	310 259
	$z {{}^{2}D}_{1 \frac{1}{2}} °$	311 983
	$z {{}^{2}F}_{2 \frac{1}{2}} °$	313 079
3d⁸(³P)4p	$z {{}^{4}P}_{1 \frac{1}{2}} °$	319 564
	${{}^{4}P}_{2 \frac{1}{2}} °$	320 090
	${{}^{4}P}_{\frac{1}{2}} °$	320 424
3d⁸(¹D)4p	$y {{}^{2}F}_{2 \frac{1}{2}} °$	322 381
3d⁸(¹D)4p	$y {{}^{2}D}_{1 \frac{1}{2}} °$	324 308
	$y {{}^{2}F}_{3 \frac{1}{2}} °$	324 398
3d⁸(¹D)4p	z ²P_1/2°	324 868
	$y {{}^{2}D}_{2 \frac{1}{2}} °$	325 707
	$z {{}^{2}P}_{1 \frac{1}{2}} °$	326 542
3d⁸(³P)4p	$y {{}^{4}D}_{2 \frac{1}{2}} °$	329 095
	${{}^{4}D}_{1 \frac{1}{2}} °$	(329 119)
	${{}^{4}D}_{3 \frac{1}{2}} °$	330 185
3d⁸(³P)4p	$x {{}^{2}D}_{2 \frac{1}{2}} °$	332 473
	${{}^{2}D}_{1 \frac{1}{2}} °$	332 701
3d⁸(³P)4p	$y {{}^{2}P}_{1 \frac{1}{2}} °$	333 924
3d⁸(¹D)4p	$x {{}^{2}F}_{3 \frac{1}{2}} °$	335 080
	y ²P_1/2°	335 596
	$x {{}^{2}F}_{2 \frac{1}{2}} °$	336 901
3d⁸(³P)4p	z ²S_1/2°	337 488
3d⁸(³P)4p	$z {{}^{4}S}_{1 \frac{1}{2}} °$	337 691
3d⁸(¹P)4p	$y {{}^{2}G}_{3 \frac{1}{2}} °$	344 197

Intensity	λ (Å)	σ(cm⁻¹)	Classification
5	290.531	344 197	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{2}G}_{3 \frac{1}{2}} °$
1	296.129	337 691	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}S}_{1 \frac{1}{2}} °$
5	296.822	336 903	$a {{}^{2}D}_{2 \frac{1}{2}} - x {{}^{2}F}_{2 \frac{1}{2}} °$
30	298.436	335 080	$a {{}^{2}D}_{2 \frac{1}{2}} - x {{}^{2}F}_{3 \frac{1}{2}} °$
20	299.470	333 924	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{2}P}_{1 \frac{1}{2}} °$
10	299.486	333 906	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}S}_{1 / 2} °$
30	300.014	333 318	$a {{}^{2}D}_{1 \frac{1}{2}} - x {{}^{2}F}_{2 \frac{1}{2}} °$
25	300.570	332 701	$a {{}^{2}D}_{2 \frac{1}{2}} - x {{}^{2}D}_{1 \frac{1}{2}} °$
10	300.777	332 472	$a {{}^{2}D}_{2 \frac{1}{2}} - x {{}^{2}D}_{2 \frac{1}{2}} °$
20	301.192	332 014	$a {{}^{2}D}_{1 \frac{1}{2}} - y {{}^{2}P}_{1 / 2} °$
30	302.861	330 185	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{4}D}_{3 \frac{1}{2}} °$
20	303.842	329 119	$a {{}^{2}D}_{1 \frac{1}{2}} - x {{}^{2}D}_{1 \frac{1}{2}} °$
			$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{4}D}_{1 \frac{1}{2}} °$
1	(303.856)	329 104	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{4}D}_{2 \frac{1}{2}} °$
10	304.052	328 891	$a {{}^{2}D}_{1 \frac{1}{2}} - x {{}^{2}D}_{2 \frac{1}{2}} °$
10	306.240	326 541	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{2}P}_{1 \frac{1}{2}} °$
30	307.026	325 705	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{2}D}_{2 \frac{1}{2}} °$
15	307.208	325 513	$a {{}^{2}D}_{1 \frac{1}{2}} - y {{}^{4}D}_{2 \frac{1}{2}} °$
30	308.264	324 398	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{2}F}_{3 \frac{1}{2}} °$
10	308.350	324 307	$a {{}^{2}D}_{2 \frac{1}{2}} - y {{}^{2}D}_{1 \frac{1}{2}} °$
15	309.636	322 960	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}P}_{1 \frac{1}{2}} °$
5	310.438	322 126	$a {{}^{2}D}_{1 \frac{1}{2}} - y {{}^{2}D}_{2 \frac{1}{2}} °$
1	311.249	321 286	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}P}_{1 / 2} °$
30	311.791	320 727	$a {{}^{2}D}_{1 \frac{1}{2}} - y {{}^{2}D}_{1 \frac{1}{2}} °$
25	312.410	320 092	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}P}_{2 \frac{1}{2}} °$
5	312.924	319 566	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}P}_{1 \frac{1}{2}} °$
30	313.677	318 799	$a {{}^{2}D}_{1 \frac{1}{2}} - y {{}^{2}F}_{2 \frac{1}{2}} °$
2	315.615	316 842	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}P}_{1 / 2} °$
15	315.949	316 506	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{4}P}_{2 \frac{1}{2}} °$
20	316.475	315 980	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{4}P}_{1 \frac{1}{2}} °$
40	319.410	313 078	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{2}F}_{2 \frac{1}{2}} °$
12	320.531	311 983	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{2}D}_{1 \frac{1}{2}} °$
40	322.311	310 259	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{2}F}_{3 \frac{1}{2}} °$
40	322.922	309 672	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{2}G}_{3 \frac{1}{2}} °$
50	322.987	309 610	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{2}D}_{2 \frac{1}{2}} °$
30	323.104	309 498	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}F}_{2 \frac{1}{2}} °$
40	324.253	308 401	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}D}_{1 \frac{1}{2}} °$
4	324.828	307 855	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}F}_{1 \frac{1}{2}} °$
40	324.953	307 737	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}F}_{2 \frac{1}{2}} °$
40	326.138	306 619	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}F}_{3 \frac{1}{2}} °$
30	326.769	306 027	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{2}D}_{2 \frac{1}{2}} °$
2	328.457	304 454	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}G}_{2 \frac{1}{2}} °$
30	328.653	304 272	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{4}F}_{1 \frac{1}{2}} °$
0	(330.15)	302 897	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}G}_{3 \frac{1}{2}} °$
0	330.583	302 496	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}D}_{1 \frac{1}{2}} °$
0	332.972	300 326	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{4}D}_{1 / 2} °$
0	333.178	300 140	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}D}_{2 \frac{1}{2}} °$
0	(334.54)	298 918	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{4}D}_{1 \frac{1}{2}} °$
5	336.612	297 078	$a {{}^{2}D}_{2 \frac{1}{2}} - z {{}^{4}D}_{3 \frac{1}{2}} °$
0	337.197	296 563	$a {{}^{2}D}_{1 \frac{1}{2}} - z {{}^{4}D}_{2 \frac{1}{2}} °$

	Co ii (Ref. 7)	Ni iii (Ref. 9)	Cu iv (Ref. 10)	Zn v	Ga vi
Γ (cm⁻¹)	228.2	324.2	439.8	577	737
³F₄
	4.16	4.20	4.24	4.28	4.33
³F₃
	2.84	2.80	2.76	2.72	2.67
³F₂

	Zn v	Ga vi
³F₄	0	0
³F₃	2466	3192
³F₂	4036	5162

	Fe ii (Ref. 7)	Co iii (Ref. 7)	Na iv (Ref. 11)	Zn vi	Ga vii
Γ (cm⁻¹)	118.6	177.8	249.4	439	564
${{}^{4}F}_{4 \frac{1}{2}}$
	4.70	4.73	4.76	4.86	4.94
${{}^{4}F}_{3 \frac{1}{2}}$
	3.44	3.43	3.42	3.38	3.40
${{}^{4}F}_{2 \frac{1}{2}}$
	2.36	2.34	2.32	2.26	2.15
${{}^{4}F}_{1 \frac{1}{2}}$

	Zn vi	Ga vii
${{}^{4}F}_{4 \frac{1}{2}}$	0	0
${{}^{4}F}_{3 \frac{1}{2}}$	2133	2790
${{}^{4}F}_{2 \frac{1}{2}}$	3618	4710
${{}^{4}F}_{1 \frac{1}{2}}$	4613	5925

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Journal of the Optical Society of America